Open Access. Powered by Scholars. Published by Universities.®
Articles 1 - 2 of 2
Full-Text Articles in Physics
Structural Investigations And Magnetic Properties Of Sol-Gel Ni0.5zn0.5fe2o4 Thin Films For Microwave Heating, Pengzhao Z. Gao, Evgeny V. Rebrov, Tiny M. W. G. M. Verhoeven, Jaap C. Schouten, Richard Kleismit, Gregory Kozlowski, John S. Cetnar, Zafer Turgut, Guru Subramanyam
Structural Investigations And Magnetic Properties Of Sol-Gel Ni0.5zn0.5fe2o4 Thin Films For Microwave Heating, Pengzhao Z. Gao, Evgeny V. Rebrov, Tiny M. W. G. M. Verhoeven, Jaap C. Schouten, Richard Kleismit, Gregory Kozlowski, John S. Cetnar, Zafer Turgut, Guru Subramanyam
Physics Faculty Publications
Nanocrystalline Ni0.5Zn0.5Fe2O4 thin films have been synthesized with various grain sizes by a sol-gel method on polycrystalline silicon substrates. The morphology, magnetic, and microwave absorption properties of the films calcined in the 673–1073 K range were studied with x-ray diffraction, scanning electron microscopy, x-ray photoelectron spectroscopy, atomic force microscopy, vibrating sample magnetometry, and evanescent microwave microscopy. All films were uniform without microcracks. Increasing the calcination temperature from 873 to 1073 K and time from 1 to 3 h resulted in an increase of the grain size from 12 to 27 nm. The saturation …
A Proton Spin-Lattice Relaxation Rate Study Of Methyl And T-Butyl Group Reorientation In The Solid State, Laura C. Popa, Arnold L. Rheingold, Peter A. Beckmann
A Proton Spin-Lattice Relaxation Rate Study Of Methyl And T-Butyl Group Reorientation In The Solid State, Laura C. Popa, Arnold L. Rheingold, Peter A. Beckmann
Physics Faculty Research and Scholarship
We have measured the solid state nuclear magnetic resonance (NMR) 1H spin-lattice relaxation rate from 93 to 340 K at NMR frequencies of 8.5 and 53 MHz in 5-t-butyl-4-hydroxy-2-methylphenyl sulfide. We have also determined the molecular and crystal structures from X-ray diffraction experiments. The relaxation is caused by methyl and t-butyl group rotation modulating the spin–spin interactions and we relate the NMR dynamical parameters to the structure. A successful fit of the data requires that the 2-methyl groups are rotating fast (on the NMR time scale) even at the lowest temperatures employed. The rotational barrier for …