Physics Commons^™

Laser-Induced Breakdown Spectroscopy And Plasmas Containing Cyanide, Christopher Matthew Helstern

Doctoral Dissertations

This dissertation focuses on laser-induced plasma of diatomic molecular cyanide. Optical breakdown plasma generation is produced by high-peak-power 1064 nm Q-switched nanosecond pulsed radiation. Laser-induced breakdown is performed on a 1:1 molar gas mixture of carbon dioxide and nitrogen held at a fixed pressure of 760 Torr, a 1:1 molar gas mixture of carbon dioxide and nitrogen held at a fixed pressure of 2069 Torr, and a flowing 1:1 molar gas mixture of carbon dioxide and nitrogen flowing at a rate of 100 mL per minute. Plasma shockwave measurements in laboratory air are shown to determine the shock front geometry …

Effects Of The Radiation Belt On The Plasmasphere Distribution, Stefan Thonnard

All Graduate Theses and Dissertations, Spring 1920 to Summer 2023

This study examines the interaction of plasma, ions and electrons created by Solar illumination in the Earth’s upper atmosphere, that travels along magnetic field lines filling the Plasmasphere, and the naturally occurring trapped particles known as the outer radiation belt. Although these two science disciplines have been largely worked independent of each other due the vast differences in the energy of the particles, recent satellite observations indicate a large population of particles with lower energy and greater mass also exist in the outer radiation belt. This study shows that during conditions of low solar output in an 11-year cycle, these …

Characterization Of A Digital Holography Diagnostic For In Situ Erosion Measurement Of Plasma-Facing Components In Fusion Devices, Cary Dean Smith

Doctoral Dissertations

Fusion energy devices, particularly tokamaks, face the challenge of interior surface damage occurring over time from the heat flux of the high-energy plasma they generate. The ability to monitor the rate of surface modification is therefore imperative, but to date no proven technique exists for real-time erosion measurement of planar regions of interest on plasma-facing components in fusion devices. In order to fill this diagnostic gap, a digital holography system has been established at ORNL [Oak Ridge National Laboratory] for the purpose of measuring the erosion effects of plasma-material interaction in situ.

The diagnostic has been designed with the …

Applications Of Cathodoluminescence In Plasmonic Nanostructures And Ultrathin Inas Quantum Layers, Qigeng Yan

Graduate Theses and Dissertations

Due to the advanced focusing ability, characterization methods based on the electron-beam excitation have been broadly applied to investigate nanomaterials. Structural or compositional information is commonly acquired using electron microscopes. Moreover, taking advantage of the super spatial resolution of the focused electron beam, optical properties of nanomaterials can be also obtained. Herein, general concepts and processes of the interaction between electrons and materials are studied. Two specific optical nanomaterials, including plasmonic nanostructures and semiconductor quantum layers, are investigated by the cathodoluminescence (CL) measurement.

Surface plasmonic resonance can be generated when high-energy electrons strike the interface between the dielectric medium and …

Setting Constraints On The Lunar Exosphere: A Comprehensive Analysis Of Velocity Resolved Sodium And Potassium Line Profile Measurements, Dona Chathuni P. Kuruppuaratchi

Doctoral Dissertations and Master's Theses

This dissertation outlines and presents the most comprehensive set of velocity-resolved measurements of sodium D2 (5889.9509 Å) lines taken over multiple lunations spanning seven years (2011 – 2017). These data are used to study the morphology and dynamics of the lunar exosphere. Additionally, potassium D1 (7698.9646 Å) is used as a complement to sodium. The two species approach, with sodium being the main attraction, provides constraints on the critical drivers of the lunar exosphere. Observations were made at the National Solar Observatory McMath – Pierce Telescope, Kitt Peak, Arizona where I personally collected both sodium and potassium data over about …

Numerical Model Of A Radio Frequency Ion Source For Fusion Plasma Using Particle-In-Cell And Finite Difference Time Domain, Augustin L. Griswold

University Honors Theses

Radio frequency (RF) plasma sources are common tool for application and study, and of particular interest for inertial electrostatic (IEC) fusion. Computational analysis is often carried out using particle in cell (PIC) methods or finite difference time domain (FDTD). However, a more holistic analysis is necessary as the particle distribution is highly dependant on the fields created by the plasma source. Herein, an analysis of a particular planar RF electrode with deuterium gas is provided which covers the fields and the particle behaviour using first FDTD then PIC. Further applications are discussed as well as further directions for this study.

Growth Of Small Particles In Nonequilibrium Plasmas, Necip Berker Üner

McKelvey School of Engineering Theses & Dissertations

Nonequilibrium plasma (NEP) is an extraordinary environment for material synthesis. NEP is comprised of hot electrons with temperatures greater than 10000 K and of cold ions and neutrals that are usually at few hundred kelvins above room temperature. Due to this large difference in species’ temperatures, the assumption of local thermal equilibrium does not hold in NEP. Therefore, NEP can act as a unique processor of mass, and it can transform materials along pathways that are not accessible by methods wherein local thermal equilibrium is valid. For decades, NEPs have been employed in the semiconductor industry to manufacture many thin …

Investigation Of The Chemical Kinetics In An Atmospheric Cold Plasma Towards Co2 Conversion, Daniel Piatek

Seton Hall University Dissertations and Theses (ETDs)

Hydrogenation of carbon dioxide (CO2) to methanol (CH3OH) is a promising route for utilization of excess and residual CO2. The conversion of CO to methanol is a well-developed process but the ability to use CO2 as a feed gas still requires high pressures (30-300 atm) to attain conversion. In this work, the hydrogenation of CO2 is explored using H2O as well as H2 in an atmospheric pressure nonthermal (cold) plasma created with a dielectric barrier discharge (DBD) reactor. Different gas mixtures such as argon (Ar) and helium (He) are used to understand their interactions in the process of CO2 hydrogenation. …

Characterization Of A Novel Double Cooled Electrode Dbd Reactor For Ozone Generation, Gustavo Duarte

Seton Hall University Dissertations and Theses (ETDs)

The Dielectric Barrier Discharge (DBD) is used to generate atmospheric or higher-pressure non-thermal plasmas and has found various commercial applications such as in industrial large-scale ozone generation. Ozone (O₃ ) is a powerful chemical reactant that is used to kill bacteria, to deodorize and to perform water purification. The effectiveness of the DBD reactors depends on the electrode arrangements, gap lengths, dielectric materials, operating gases and feed gas quality to name a few. However, the production of O₃ is heat sensitive. In order to prevent O₃ destruction thermal cooling of the DBD is needed. The industry approach …

Topics In Gravitational Wave Physics, Aaron David Johnson

Graduate Theses and Dissertations

We begin with a brief introduction to gravitational waves. Next we look into the origin of the Chandrasekhar transformations between the different equations found by perturbing a Schwarzschild black hole. Some of the relationships turn out to be Darboux transformations. Then we turn to GW150914, the first detected black hole binary system, to see if the nonlinear memory might be detectable by current and future detectors. Finally, we develop an updated code for computing equatorial extreme mass ratio inspirals which will be open sourced as soon as it has been generalized for arbitrary inclinations.

Cherenkov Gamma Ray Detectors On High-Energy-Density Systems, Kevin Daniel Meaney

Physics & Astronomy ETDs

High energy density (HED) systems are some of the most extreme environments ever created by mankind. Systems with pressures greater than 1 MBar can only be created by a handful of devices on earth, often utilizing high intensity lasers or pulsed power machines. HED systems offer a view into an extreme form of matter only seen in stellar cores, supernovas and other powerful astrophysical systems. Creating HED systems on Earth offer the possibility, if the physics and technology can be matured, to one day create a fusion power plant. If a system is hot and dense enough, the fusion reaction …

Investigation Of Mnxni1-Xo Thin Films Using Pulsed Laser Deposition, Md Ashif Anwar

MSU Graduate Theses

The exchange bias (EB) effect, especially in nanomaterials, is highly promising for use in antiferromagnet-based spintronics applications. NiO is a well known antiferromagnetic material with a high Néel temperature (525K) and can exhibit ferromagnetism/ ferrimagnetism by adding other magnetic transition elements. Our previous work has shown that the antiferromagnetic characteristics of conventional NiO insulating nanostructured material can be altered to have substantial ferrimagnetic characteristics by doping NiO with Mn or Co. Pulsed laser deposition (PLD) was used to grow heterostructures comprised of a nanostructured thin NiO film deposited on the surface of a MgO (100) and Al₂O_{3 …}

Optimizing Llrf Parameters In The Electron-Ion Collider, William M. Bjorndahl

Physics

To improve particle interaction in the future Electron-Ion Collider (EIC), we investigated different feedback implementations to control the accelerating voltage and examined the power and beam phase for each instance. Using MATLAB, we studied three feedback mechanisms: Direct, One Turn, and Feedforward. Enacting feedforward yielded the best performance. To minimize the klystron power consumption, we analyzed different Low-Level Radio Frequency (LLRF) parameters such as detuning. Combining theory and simulated results, we found the optimal detuning value that minimizes klystron power consumption.

Conduction Mapping For Quality Control Of Laser Powder Bed Fusion Additive Manufacturing, Chance M. Baxter

Theses and Dissertations

A process was developed to identify potential defects in previous layers of Selective Laser Melting (SLM) Powder Bed Fusion (PBF) 3D printed metal parts using a mid-IR thermal camera to track infrared 3.8-4 m band emission over time as the part cooled to ambient temperature. Efforts focused on identifying anomalies in thermal conduction. To simplify the approach and reduce the need for significant computation, no attempts were made to calibrate measured intensity, extract surface temperature, apply machine learning, or compare measured cool-down behavior to computer model predictions. Raw intensity cool-down curves were fit to a simplified functional form designed to …

Laser Induced Thermal Degradation Of Carbon Fiber-Carbon Nanotube Hybrid Laminates, Joshua A. Key

Theses and Dissertations

Recent advancements in fiber laser technology have increased interest in target material interactions and the development of thermal protection layers for tactical laser defense. A significant material of interest is carbon fiber reinforced polymers due to their increased use in aircraft construction. In this work, the thermal response of carbon fiber-carbon nanotube (CNT) hybrid composites exposed to average irradiances of 0.87-6.8 W/cm² were observed using a FLIR sc6900 thermal camera. The camera had a pixel resolution of 640x512 which resulted in a spatial resolution of 0.394x0.383 mm/pixel for the front and 0.463x0.491 mm/pixel for the back. The hybrid samples …

Laser Shock Peening Pressure Impulse Determination Via Empirical Data-Matching With Optimization Software, Colin C. Engebretsen

Theses and Dissertations

Laser shock peening (LSP) is a form of work hardening by means of laser induced pressure impulse. LSP imparts compressive residual stresses which can improve fatigue life of metallic alloys for structural use. The finite element modeling (FEM) of LSP is typically done by applying an assumed pressure impulse, as useful experimental measurement of this pressure impulse has not been adequately accomplished. This shortfall in the field is a current limitation to the accuracy of FE modeling, and was addressed in the current work. A novel method was tested to determine the pressure impulse shape in time and space by …

Determining Bulk Aerosol Absorption From Off Axis Backscattering Using Rayleigh Beacon Laser Pulses, Julie C. Grossnickle

Theses and Dissertations

Aerosol absorption and scattering can play a key role in degrading high energy laser performance in the form of thermal blooming and beam attenuation. Aerosol absorption properties are not completely understood, and thus affect how we are able to quantify expected high energy laser weapon performance. The Air Force Institute of Technology Center for Directed Energy (AFIT CDE) developed both Laser Environmental Effects Definition and Reference (LEEDR) and the High Energy Laser End-to-End Operational Simulation (HELEEOS) code to characterize atmospheric radiative transfer effects and evaluate expected directed energy weapon system performance. These packages enable modeling of total irradiance at given …

Cn And C2 Spectroscopy On The Pulsed Ablation Of Graphite In The Visible Spectrum, Brandon A. Pierce

Theses and Dissertations

An experimental study was conducted on the nanosecond pulsed laser ablation of graphite using a KrF laser at a fluence of 3.8 J/cm² in Air, Ar, He, and N₂. Optical emissions spectroscopy revealed the C₂ Swan sequences and the CN Violet sequences. A spectroscopic model was developed to extract the molecular rotational and vibrational temperatures of each excited species for t=0.5-10 microseconds after laser irradiation. The rovibrational temperatures were found to vary with background gas for the CN Violet; however, only the vibrational temperature varied between He and the other background gases for C₂ Swan. …

Si Nanocrystal Synthesis Via Double Implantation And Variable Implantation, James M. Gaudet

Electronic Thesis and Dissertation Repository

Silicon (Si) nanocrystals (nc) precipitated from silicon-implanted silicon oxide (SiO₂) are of interest as a novel light source for illumination, biomedical applications, optical computing, etc. They have some advantages over conventional III-V compound semiconductor nanocrystals produced by colloidal synthesis. They are compatible with Si/SiO₂ based semiconductor processing, are stable, non-toxic at point of synthesis and consumption, and their luminescence falls with the infrared transmission window of biological materials. Unfortunately, synthesis of Si-nc embedded SiO₂ is uneconomical and is not as amenable to precise control of the size distribution of nanocrystals as is the case for III-V …

Shape Tuning Of Silicon Nano-Tip Arrays Through Reactive Ion Etching For Cold Field Emission, Giridhar Tulasi Ram Sankabathula

Graduate Research Theses & Dissertations

Large area silicon nano-tip arrays have been predominantly used as cold cathode electron sources in the wide range of field emission applications. Various fabrication methodologies have been developed over the decades to obtain sharp-pointed field emitters. In this thesis, we mainly emphasized on reproducing high aspect ratio field emitters and to study their surface topographical changes encountered through reactive ion etching. A discrete set of high-density field emitters have been fabricated over the large area surfaces through a three-step nanofabrication process. The surface curvatures of the obtained emitter tips are finely tuned with multiple oxidation cycles to achieve a tip’s …

Characterization Of A Plasma Source Simulating Solar Wind Plasma In A Vacuum Chamber, Blake Anthony Folta

Masters Theses

"The United States has set an aggressive time line to not only return to the Moon, but also to establish a sustained human presence. In the Apollo missions dust was a significant factor, but the duration of those missions was short so dust and surface charging were problems, but they did not pose an immediate threat. For a long-term mission, these problems instead become incredibly detrimental. Because of this, research needs to be conducted to investigate these phenomena so that mitigation techniques can be developed and tested. To this end, this thesis serves to demonstrate the Gas and Plasma Dynamics …

Interpretations Of Bicoherence In Space & Lab Plasma Dynamics, Gregory Allen Riggs

Graduate Theses, Dissertations, and Problem Reports

The application of bicoherence analysis to plasma research, particularly in non-linear, coupled-wave regimes, has thus far been significantly belied by poor resolution in time, and/or outright destruction of frequency information. Though the typical power spectrum cloaks the phase-coherency between frequencies, Fourier transforms of higher-order convolutions provide an n-dimensional spectrum which is adept at elucidating n-wave phase coherence. As such, this investigation focuses on the utility of the normalized bispectrum for detection of wave-wave coupling in general, with emphasis on distinct implications within the scope of non-linear plasma physics. Interpretations of bicoherent features are given for time series from …

Control Of Charged Particle Dynamics And Electron Power Absorption Dynamics Utilizing Voltage Waveform Tailoring In Capacitively Driven Radio-Frequency Plasmas, Steven W. Brandt

Graduate Theses, Dissertations, and Problem Reports

In this work, experimental measurements and analysis of numerical simulations are performed for capacitively coupled plasmas driven by tailored voltage waveforms under conditions which examine complicating factors present in industrial processes, including the influence of resonance effects, electronegative gases or gas mixtures, and plasma-surface interactions at a changing plasma-surface interface. Furthermore, the influence of different tailored voltage waveforms on the spatio-temporal electron power absorption, the generation of a DC self-bias, and on process relevant plasma parameters like ion energy distribution functions is investigated to provide a more complete understanding of the underlying fundamental plasma physics responsible for sustaining the discharge. …