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Full-Text Articles in Physics

Characterization Of The Anomalous Ph Of Aqueous Nanoemulsions, Kieran P. Ramos Oct 2019

Characterization Of The Anomalous Ph Of Aqueous Nanoemulsions, Kieran P. Ramos

Doctoral Dissertations

Aqueous water-in-oil nanoemulsions have emerged as a versatile tool for use in microfluidics, drug delivery, single-molecule measurements, and other research. Nanoemulsions are often prepared with perfluorocarbons which are remarkably biocompatbile due to their stability, low surface tension, lipophobicity, and hydrophobicity. Therefore it is often assumed that droplet contents are unperturbed by the perfluorinated surface. However, in microemulsions, which are similar to nanoemulsions, it is known that either the pH of the aqueous phase or the ionization constants of encapsulated molecules are different from bulk solution. There is also recent evidence of low pH in perfluorinated aqueous nanoemulsions. The current underlying …


Probing Quantized Excitations And Many-Body Correlations In Transition Metal Dichalcogenides With Optical Spectroscopy, Shao-Yu Chen Mar 2019

Probing Quantized Excitations And Many-Body Correlations In Transition Metal Dichalcogenides With Optical Spectroscopy, Shao-Yu Chen

Doctoral Dissertations

Layered transition metal dichalcogenides (TMDCs) have attracted great interests in recent years due to their physical properties manifested in different polytypes: Hexagonal(H)-TMDC,which is semiconducting, exhibits strong Coulomb interaction and intriguing valleytronic properties; distorted octahedral(T’)-TMDC,which is semi-metallic, is predicted to exhibit rich nontrivial topological physics. In this dissertation,we employ the polarization-resolved micron-Raman/PL spectroscopy to investigate the optical properties of the atomic layer of several polytypes of TMDC. In the first part for polarization-resolved Raman spectroscopy, we study the lattice vibration of both H and T’-TMDC, providing a thorough understanding of the polymorphism of TMDCs. We demonstrate that Raman spectroscopy is a …


Wavelength-Selective Metamaterial Absorber And Emitter, Zhigang Li Jan 2019

Wavelength-Selective Metamaterial Absorber And Emitter, Zhigang Li

Doctoral Dissertations

"Electromagnetic absorbers and emitters have been attracting interest in lots of fields, which are significantly revitalized because of the novel properties brought by the development of the metamaterials, the artificially designed materials. Metamaterials broadens the approaches to design the electromagnetic absorbers and emitters, making it possible to obtain the perfect absorption or emission at the wavelengths covering a wide range. Metamaterial absorbers and emitters are promising for various applications, including solar thermal-photovoltaics and thermal-photovoltaics for energy harvesting, chemical and biomedical sensors, nanoscale imaging and color printing. This work focuses on three aspects (materials, structures and design methods) to improve the …