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Full-Text Articles in Physics
A Magnetic, Neutron Diffraction, And Mössbauer Spectral Study Of The Nd₂Fe₁₇₋ₓalₓ Solid Solutions, Gary J. Long, Gaya Kanishka Marasinghe, Sanjay R. Mishra, Oran Allan Pringle, Zhongbo Hu, William B. Yelon, D. P. Middleton, K. H. J. Buschow, Fernande Grandjean
A Magnetic, Neutron Diffraction, And Mössbauer Spectral Study Of The Nd₂Fe₁₇₋ₓalₓ Solid Solutions, Gary J. Long, Gaya Kanishka Marasinghe, Sanjay R. Mishra, Oran Allan Pringle, Zhongbo Hu, William B. Yelon, D. P. Middleton, K. H. J. Buschow, Fernande Grandjean
Chemistry Faculty Research & Creative Works
The magnetic properties of a series of Nd2Fe17-xAlx solid solutions, with x equal to 2.04, 4.01, 5.97, 7.94, and 9.06, have been studied by magnetic measurements, neutron diffraction, and Mössbauer spectroscopy. Magnetization studies indicate that the Curie temperature increases from 330 K in Nd2Fe17 to a maximum of ~470 K at an x of 3.5. The compounds crystallize in the Th2Zn17 structure with lattice parameters and unit cell volumes which increase linearly with increasing aluminum content. The neutron diffraction results indicate that aluminum atoms are excluded from the 9d …
Comparative Mössbauer Effect Study Of Several R₂Fe₁₇ And R₂Fe₁₇Nₓ Compounds, Gary J. Long, Sanjay R. Mishra, Oran Allan Pringle, Fernande Grandjean, K. H. Buschow
Comparative Mössbauer Effect Study Of Several R₂Fe₁₇ And R₂Fe₁₇Nₓ Compounds, Gary J. Long, Sanjay R. Mishra, Oran Allan Pringle, Fernande Grandjean, K. H. Buschow
Chemistry Faculty Research & Creative Works
The Mössbauer spectra of Sm2Fe17 and Ho 2Fe17 and their nitrides have been measured between 295 and 85 K and analyzed with a model which is consistent with our earlier work on R2Fe17 and R2Fe17Nx compounds, where R is Pr, Nd, and Th. This model is completely consistent throughout these rare-earth compounds and is in agreement with the crystallographic changes occurring upon nitrogenation and with the prediction of band structure calculations. The dramatic increase in Curie temperature in the nitrides results from the expansion of the crystallographic …
A Mössbauer Effect Study Of The Microscopic Magnetic Properties Of Th₂Fe₁₇ And Its Nitride, Th₂Fe₁₇N₂.₆, Gary J. Long, Oran Allan Pringle, Fernande Grandjean, T. H. Jacobs, K. H. Buschow
A Mössbauer Effect Study Of The Microscopic Magnetic Properties Of Th₂Fe₁₇ And Its Nitride, Th₂Fe₁₇N₂.₆, Gary J. Long, Oran Allan Pringle, Fernande Grandjean, T. H. Jacobs, K. H. Buschow
Chemistry Faculty Research & Creative Works
The Mössbauer spectra of Th2Fe17 and Th2Fe17N2.6 have been measured at various temperatures between 85 and 295 K and analyzed with a model that is based on the Wigner-Seitz cell environment of each iron site, the orientation of the magnetization, and the magnetic moments as determined from either neutron-diffraction measurements or band-structure calculations. Upon nitrogenation of Th2Fe17, the 85 K weighted average isomer shift increases from 0.037 to 0.156 mm/s and further the isomer shifts of the four crystallographically distinct sites increase in agreement with the increase observed …