Open Access. Powered by Scholars. Published by Universities.®
- Discipline
-
- Engineering (3)
- Nanoscience and Nanotechnology (2)
- Applied Mechanics (1)
- Astrophysics and Astronomy (1)
- Condensed Matter Physics (1)
-
- Defense and Security Studies (1)
- Engineering Physics (1)
- Materials Science and Engineering (1)
- Mechanical Engineering (1)
- Other Materials Science and Engineering (1)
- Other Mechanical Engineering (1)
- Public Affairs, Public Policy and Public Administration (1)
- Quantum Physics (1)
- Social and Behavioral Sciences (1)
- Institution
Articles 1 - 14 of 14
Full-Text Articles in Physics
Investigation Of Carbon Nanomaterials Embedded In A Cementitious Matrix, Clarissa A. Roe
Investigation Of Carbon Nanomaterials Embedded In A Cementitious Matrix, Clarissa A. Roe
Masters Theses & Specialist Projects
The objective of this thesis was to investigate whether the addition of carbon nanofibers had an effect on the splitting tensile strength of Hydro-Stone gypsum concrete. The carbon nanofibers used were single-walled carbon nanotubes (SWNT), buckminsterfullerene (C60), and graphene oxide (GO). Evidence of the nanofibers interacting with gypsum crystals in a connective manner was identified in both 1 mm thick concrete discs and concrete columns possessing a height of 2 in and a diameter of 1 in. Before imaging, the columns were subjected to a splitting tensile strength test. The results illustrate that while there is a general decrease in …
Synthesis And Electron Emission Properties Of Aligned Carbon Nanotube Arrays, Suman Neupane
Synthesis And Electron Emission Properties Of Aligned Carbon Nanotube Arrays, Suman Neupane
FIU Electronic Theses and Dissertations
Carbon nanotubes (CNTs) have become one of the most interesting allotropes of carbon due to their intriguing mechanical, electrical, thermal and optical properties. The synthesis and electron emission properties of CNT arrays have been investigated in this work. Vertically aligned CNTs of different densities were synthesized on copper substrate with catalyst dots patterned by nanosphere lithography. The CNTs synthesized with catalyst dots patterned by spheres of 500 nm diameter exhibited the best electron emission properties with the lowest turn-on/threshold electric fields and the highest field enhancement factor. Furthermore, CNTs were treated with NH3 plasma for various durations and the …
Hetero-Junctions Of Boron Nitride And Carbon Nanotubes: Synthesis And Characterization, Yoke Khin Yap
Hetero-Junctions Of Boron Nitride And Carbon Nanotubes: Synthesis And Characterization, Yoke Khin Yap
Department of Physics Publications
Hetero-junctions of boron nitride nanotubes (BNNTs) and carbon nanotubes (CNTs) are expected to have appealing new properties that are not available from pure BNNTs and CNTs. Theoretical studies indicate that BNNT/CNT junctions could be multifunctional and applicable as memory, spintronic, electronic, and photonics devices with tunable band structures. This will lead to energy and material efficient multifunctional devices that will be beneficial to the society. However, experimental realization of BNNT/CNT junctions was hindered by the absent of a common growth technique for BNNTs and CNTs. In fact, the synthesis of BNNTs was very challenging and may involve high temperatures (up …
Impaired Cleanance And Enhanced Pulmonary Inflammatory/Fibrotic Response To Carbon Nanotubes In Myeloperoxidase-Deficient Mice, Anna A. Shvedova, Alexandr A. Kapralov, Wei Hong Feng, Elena R. Kisin, Ashley R. Murray, Robert R. Mercer, Claudette M. St. Croix, Megan A. Lang, Simon C. Watkins, Nagarjun V. Konduru, Brett L. Allen, Jennifer Conroy, Gregg P. Kotchey, Bashir M. Mohamed, Aidan Meade, Yuri Volkov, Alexander Star, Bengt Fadeel, Valerian E. Kagan
Impaired Cleanance And Enhanced Pulmonary Inflammatory/Fibrotic Response To Carbon Nanotubes In Myeloperoxidase-Deficient Mice, Anna A. Shvedova, Alexandr A. Kapralov, Wei Hong Feng, Elena R. Kisin, Ashley R. Murray, Robert R. Mercer, Claudette M. St. Croix, Megan A. Lang, Simon C. Watkins, Nagarjun V. Konduru, Brett L. Allen, Jennifer Conroy, Gregg P. Kotchey, Bashir M. Mohamed, Aidan Meade, Yuri Volkov, Alexander Star, Bengt Fadeel, Valerian E. Kagan
Articles
Advancement of biomedical applications of carbonaceous nanomaterials is hampered by their biopersistence and pro-inflammatory action in vivo. Here, we used myeloperoxidase knockout B6.129X1-MPO (MPO k/o) mice and showed that oxidation and clearance of single walled carbon nanotubes (SWCNT) from the lungs of these animals after pharyngeal aspiration was markedly less effective whereas the inflammatory response was more robust than in wild-type C57Bl/6 mice. Our results provide direct evidence for the participation of MPO – one of the key-orchestrators of inflammatory response – in the in vivo pulmonary oxidative biodegradation of SWCNT and suggest new ways to control the biopersistence …
The Density Factor In The Synthesis Of Carbon Nanotube Forest By Injection Chemical Vapor Deposition, Robert W. Call, C. Read, C Mart, T. C. Shen
The Density Factor In The Synthesis Of Carbon Nanotube Forest By Injection Chemical Vapor Deposition, Robert W. Call, C. Read, C Mart, T. C. Shen
Graduate Student Publications
Beneath the seeming straight-forwardness of growing carbon nanotube(CNT) forests by the injection chemical vapor deposition(CVD) method, control of the forest morphology on various substrates is yet to be achieved. Using ferrocene dissolved in xylene as the precursor, we demonstrate that the concentration of ferrocene and the injection rate of the precursor dictate the CNT density of these forests. However, CNT density will also be affected by the substrates and the growth temperature which determine the diffusion of the catalyst adatoms. The CNT growth rate is controlled by the temperature and chemical composition of the gases in the CVD reactor. We …
Interactions Of Carbon Nanotubes With Human Lung Epithelial Cells In Vitro, Assessed By Raman Spectroscopy, Peter Knief
Interactions Of Carbon Nanotubes With Human Lung Epithelial Cells In Vitro, Assessed By Raman Spectroscopy, Peter Knief
Doctoral
Current methods for the evaluation of cellular interactions with nanoparticles are non-specific, relatively slow and invasive to the cell. Raman spectroscopy is a non invasive technique whose potential in the biosciences has already been demonstrated and has been used in the investigation of cell interactions with various external agents. The main focus of this study is to employ Raman spectroscopy to investigate the interaction of A549 human lung cells with single walled carbon nanotubes. · Carbon nanotubes have attracted considerable interest not only for their outstanding physical and electronic properties, promising a potentially vast number of applications, but also for …
Diode Properties Of Nanotube Networks, David D. Allred, Bryan Hicks, Stephanie Getty
Diode Properties Of Nanotube Networks, David D. Allred, Bryan Hicks, Stephanie Getty
Faculty Publications
Single-walled carbon nanotubes (SWCNT) were prepared using iron catalysts deposited by indirect evaporation on silicon substrate covered with 500 nm-thick thermal oxide. Diode SWCNT devices have been fabricated using Au and Al, as the asymmetric metal contacts, and a random network of metallic and semiconducting nanotubes as the device channel. No effort was made to align the SWCNTs or to eliminate metallic nanotubes in our devices. Asymmetric voltage-current behavior was seen. Current rectification was observed in the source-drain bias range of -3 V to +3 V. Rectification was somewhat surprising since, although metallic tubes are in the minority (~ 1/3), …
Van Der Waals-London Dispersion Interaction Framework For Experimentally Realistic Carbon Nanotube Systems, Roger H. French
Van Der Waals-London Dispersion Interaction Framework For Experimentally Realistic Carbon Nanotube Systems, Roger H. French
Faculty Scholarship
A system's van der Waals–London dispersion interactions are often ignored, poorly understood, or crudely approximated, despite their importance in determining the intrinsic properties and intermolecular forces present in a given system. There are several key barriers that contribute to this issue: 1) lack of the required full spectral optical properties, 2) lack of the proper geometrical formulation to give meaningful results, and 3) a perception that a full van der Waals–London dispersion calculation is somehow unwieldy or difficult to understand conceptually. However, the physical origin of the fundamental interactions for carbon nanotube systems can now be readily understood due to …
Strain Energy And Lateral Friction Force Distributions Of Carbon Nanotubes Manipulated Into Shapes By Atomic Force Microscopy, Mark C. Strus, Roya R. Lahiji, Pablo Ares, Vincente Lopez, Arvind Raman, Ron R. Reifenberger
Strain Energy And Lateral Friction Force Distributions Of Carbon Nanotubes Manipulated Into Shapes By Atomic Force Microscopy, Mark C. Strus, Roya R. Lahiji, Pablo Ares, Vincente Lopez, Arvind Raman, Ron R. Reifenberger
Other Nanotechnology Publications
The interplay between local mechanical strain energy and lateral frictional forces determines the shape of carbon nanotubes on substrates. In turn, because of its nanometer-size diameter, the shape of a carbon nanotube strongly influences its local electronic, chemical, and mechanical properties. Few, if any, methods exist for resolving the strain energy and static frictional forces along the length of a deformed nanotube supported on a substrate. We present a method using nonlinear elastic rod theory in which we compute the flexural strain energy and static frictional forces along the length of single walled carbon nanotubes (SWCNTs) manipulated into various shapes …
Spectroscopic Investigations On Polypropylene-Carbon Nanofiber Composites: I. Raman And Electron Spin Resonance Spectroscopy, Mircea Chipara, John R. Villarreal, Magdalena Dorina Chipara, Karen Lozano, Alin Cristian Chipara, David J. Sellmyer
Spectroscopic Investigations On Polypropylene-Carbon Nanofiber Composites: I. Raman And Electron Spin Resonance Spectroscopy, Mircea Chipara, John R. Villarreal, Magdalena Dorina Chipara, Karen Lozano, Alin Cristian Chipara, David J. Sellmyer
David Sellmyer Publications
Isotactic polypropylene-vapor grown carbon nanofiber composites containing various fractions of carbon nanofibers, ranging from 0 to 20 wt %, have been prepared. Raman spectroscopy was used to analyze the effect of the dispersion of carbon nanofibers within polypropylene and the interactions between carbon nanofibers and macromolecular chains. The as-recorded Raman spectra have been successfully fitted by a linear convolution of Lorentzian lines. Changes of the Raman lines parameters (position, intensity, width, and area) of polypropylene and carbon nanofibers were analyzed in detail. The Raman spectra of the polymeric matrix—at low concentrations of nanofibers—show important modifications that indicate strong interactions between …
Toxicity Assessment Of Single-Walled Carbon Nanotubes, Eva Herzog
Toxicity Assessment Of Single-Walled Carbon Nanotubes, Eva Herzog
Doctoral
The objective of this study was to investigate the potential adverse health effects of occupational exposure to SWCNT dust using various in vitro approaches. Lung epithelium (represented by A549 and NHBE cells) was chosen as target cell model and exposed to minimally processed particle samples under submerse conditions and effects were compared to that of carbon black and crocidolite asbestos exposure. Cytotoxicity studies indicated low acute cytotoxicity of SWCNT. Morphological changes included decreases in microvilli and increased numbers of surfactant storing lamellar bodies and changes in cytoskeleton. Due to interactions of SWCNT and toxicity indicator dyes, the clonogenic assay was …
Use Of Raman Spectroscopy In The Investigation Of Debundling Of Single Walled Carbon Nanotubes, Elizabeth Gregan, Sinead Keogh, Theresa Hedderman, Gordon Chambers, Hugh Byrne
Use Of Raman Spectroscopy In The Investigation Of Debundling Of Single Walled Carbon Nanotubes, Elizabeth Gregan, Sinead Keogh, Theresa Hedderman, Gordon Chambers, Hugh Byrne
Conference papers
Samples of raw nanotubes are compared to those deposited from solutions to examine separation of nanotube bundles. Single wall nanotubes bundles produced by the arc-discharge and HiPco methods were solubilised in toluene, DMF and 1,2 dichloroethane. Resonant Raman spectroscopy was used to determine if debundling of the tubes sample occurred. The results showed some degree of debundling, best for the 1,2 dichloroethane solvent, which also shows long term solubility.
Interaction Of Carbon Nanotubes With Saccharides: A Possible Route To Biocompatible Composites, Alan Casey, Jonathan Moghal, Gerald Farrell, Hugh Byrne, Gordon Chambers
Interaction Of Carbon Nanotubes With Saccharides: A Possible Route To Biocompatible Composites, Alan Casey, Jonathan Moghal, Gerald Farrell, Hugh Byrne, Gordon Chambers
Conference papers
Inclusion complexes of saccharides and HiPco Carbon Nanotubes (HCNT) were formed, resulting in water soluble complexes. These complexes were then characterised using a variety of spectroscopic techniques. Raman spectroscopy was used to probe changes in the vibrational character of both the host and guest species and also to assess if any selectivity of tube diameter occurred. UV-Vis-NIR and circular dichroic spectroscopies were used to assess the effect of inclusion on the electronic properties of the tubes. Spectroscopic analysis of these species showed clear evidence of an intermolecular interaction between the host material and the HCNT.
Characterization Of The Interaction Of Gamma Cyclodextrin With Single-Walled Carbon Nanotubes, Gordon Chambers, Clodagh Carroll, Garrett Farrell, Alan Dalton, Mary Mcnamara, Marc In Het Panhuis, Hugh Byrne
Characterization Of The Interaction Of Gamma Cyclodextrin With Single-Walled Carbon Nanotubes, Gordon Chambers, Clodagh Carroll, Garrett Farrell, Alan Dalton, Mary Mcnamara, Marc In Het Panhuis, Hugh Byrne
Articles
In this study a number of composite-like samples of ç-cyclodextrin and HiPco carbon nanotubes were prepared. The first sample was prepared by a simple grinding procedure, which has been reported to cut HiPco carbon nanotubes. The other samples were obtained via a refluxing procedure analogous to similar studies on other fullerenes and ç-cyclodextrin. The samples were analyzed using absorption and Raman spectroscopy, and differential scanning calorimetry. The results presented show clear evidence of an intermolecular interaction between ç-cyclodextrin and single-walled carbon nanotubes.