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Full-Text Articles in Physics
Development Of Photopolymer Material With Improved Dynamic Range And Sensitivity, Brian Rogers, Izabela Naydenova, Suzanne Martin
Development Of Photopolymer Material With Improved Dynamic Range And Sensitivity, Brian Rogers, Izabela Naydenova, Suzanne Martin
Conference Papers
In this study the effect of the concentration of acrylamide and the influence of different initiators in a photopolymer composition for holographic recording of diffraction gratings is investigated. Light manipulating Holographic Optical Elements (HOEs) have a number of characteristics which can be optimised for different roles. However, at the core of these devices is the refractive index modulation that has been created in the material during recording. Typically higher refractive index modulation will enable greater diffraction efficiency. Solar concentrating HOEs can particularly benefit from material that experiences higher refractive index modulation. For a solar concentrator to have a high acceptance …
Determination Of The Polymerisation Rate Of A Low-Toxicity Diacetone Acrylamide-Based Holographic Photopolymer Using Raman Spectroscopy, Dervil Cody, Emilia Mihaylova, Luke O'Neill, Izabela Naydenova
Determination Of The Polymerisation Rate Of A Low-Toxicity Diacetone Acrylamide-Based Holographic Photopolymer Using Raman Spectroscopy, Dervil Cody, Emilia Mihaylova, Luke O'Neill, Izabela Naydenova
Articles
The polymerisation rate of a low-toxicity Diacetone Acrylamide (DA)-based photopolymer has been measured for the first time using Raman spectroscopy. A value for the polymerisation rate of 0.020 s−1 has been obtained for the DA photopolymer by modelling the polymerisation reaction dynamics as a stretched exponential or Kohlrausch decay function. This is significantly lower than the polymerisation rate of 0.100 s−1 measured for the well known Acrylamide (AA)-based photopolymer composition. The effect of the additive glycerol on the polymerisation rate of the DA-based photopolymer has also been investigated. The inclusion of glycerol is observed to increase the rate …
Investigation Of The Sensitivity To Humidity Of An Acrylamide-Based Photopolymer Containing N-Phenylglycine As A Photoinitiator, Tatsiana Mikulchyk, Suzanne Martin, Izabela Naydenova
Investigation Of The Sensitivity To Humidity Of An Acrylamide-Based Photopolymer Containing N-Phenylglycine As A Photoinitiator, Tatsiana Mikulchyk, Suzanne Martin, Izabela Naydenova
Articles
Sensitivity of holographic recording materials to the relative humidity (RH) of the environment often restricts their use in fabrication of holographic optical elements and other applications. It is important to develop materials with little or no sensitivity to humidity. In this paper the humidity response of transmission gratings recorded in an acrylamide-based photopolymer containing N-phenylglycine (NPG) as a photoinitiator is studied at RH = 20 – 90 %. The hologram is found to be completely insensitive to humidity at RH below 70 % and its diffraction efficiency remains constant. A decrease in diffraction efficiency is observed at RH = 80 …
Holographic Recording In Corona Charged Acrylamide-Based Mfi-Zeolite Photopolymer, Temenujka Yovcheva, Izabela Naydenova, Simeon Sainov, Vincent Toal, Svetlana Mintova
Holographic Recording In Corona Charged Acrylamide-Based Mfi-Zeolite Photopolymer, Temenujka Yovcheva, Izabela Naydenova, Simeon Sainov, Vincent Toal, Svetlana Mintova
Articles
The influence of corona charging on holographic recording in acrylamide-based photopolymer nanocomposite containing MFI zeolite nanoparticles has been studied. The holographic recording was carried out in two different geometries —transmission grating recording and total internal reflection grating recording. During the recording process, the layers were charged in a corona field. It was observed that independently of the corona polarity, in the case of transmission geometry of recording, the corona charging led to a decrease in the diffraction efficiency (DE) of the grating. In the case of the total internal reflection grating, the DE increased in the corona field presence.
Investigation Of Polymerization Rate In An Acrylamide-Based Photopolymer Using Raman Spectroscopy, Raghavendra Jallapuram, Izabela Naydenova, Hugh Byrne, Suzanne Martin, Robert Howard, Vincent Toal
Investigation Of Polymerization Rate In An Acrylamide-Based Photopolymer Using Raman Spectroscopy, Raghavendra Jallapuram, Izabela Naydenova, Hugh Byrne, Suzanne Martin, Robert Howard, Vincent Toal
Conference Papers
Diffusion models predict that polymerization and diffusion rates are the key factors that control the dynamics and the final properties of a holographic grating recorded in a photopolymerizable material. Diffusion rates during the initial phase of holographic recording have already been studied and reported. We now report the investigation of the polymerization rate in an acrylamide-based photopolymer using Raman spectroscopy. The polymerization rate constant was estimated by monitoring the intensity of the characteristic Raman peaks at 1284 cm-1 corresponding to the bending mode of CH vinyl bond in acrylamide and 1609 cm-1 corresponding to the carbon-carbon double bond (C=C) in …