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Full-Text Articles in Physics
Hopping Versus Bulk Conductivity In Transparent Oxides: 12cao - 7al₂O₃, Julia E. Medvedeva, Arthur J. Freeman
Hopping Versus Bulk Conductivity In Transparent Oxides: 12cao - 7al₂O₃, Julia E. Medvedeva, Arthur J. Freeman
Physics Faculty Research & Creative Works
First-principles calculations of the mayenite-based oxide, [Ca12Al14O32]2+(2e-), reveal the mechanism responsible for its high conductivity. A detailed comparison of the electronic and optical properties of this material with those of the recently discovered transparent conducting oxide, H-doped UV-activated Ca12Al14O33, allowed us to conclude that the enhanced conductivity in [Ca12Al14O32]2+(2e-) is achieved by elimination of the Coulomb blockade of the charge carriers. This results in a transition from variable range-hopping behavior with a Coulomb gap in H-doped UV-irradiated Ca …
Electronic Structure And Light-Induced Conductivity Of A Transparent Refractory Oxide, Julia E. Medvedeva, Arthur J. Freeman, Mariana I. Bertoni, Thomas O. Mason
Electronic Structure And Light-Induced Conductivity Of A Transparent Refractory Oxide, Julia E. Medvedeva, Arthur J. Freeman, Mariana I. Bertoni, Thomas O. Mason
Physics Faculty Research & Creative Works
Combined first-principles and experimental investigations reveal the underlying mechanism responsible for a drastic change of the conductivity (by 10 orders of magnitude) following hydrogen annealing and UV irradiation in a transparent oxide, 12CaO · 7Al2O3, found by Hayashi et al. [Nature (London) 419, 462 (2002).] The charge transport associated with photoexcitation of an electron from H- occurs by electron hopping.We identify the atoms participating in the hops, determine the exact paths for the carrier migration, estimate the temperature behavior of the hopping transport, and predict a way to enhance the conductivity by specific doping.
Statistics Of Transmission In One-Dimensional Disordered Systems: Universal Characteristics Of States In The Fluctuation Tails, Lev I. Deych, Mikhail V. Erementchouk, Alexander A. Lisyansky, Alexey Yamilov, Hui Cao
Statistics Of Transmission In One-Dimensional Disordered Systems: Universal Characteristics Of States In The Fluctuation Tails, Lev I. Deych, Mikhail V. Erementchouk, Alexander A. Lisyansky, Alexey Yamilov, Hui Cao
Physics Faculty Research & Creative Works
We numerically study the distribution function of the conductance (transmission) in the one-dimensional tight-binding Anderson and periodic-on-average superlattice models in the region of fluctuation states where single parameter scaling is not valid. We show that the scaling properties of the distribution function depend upon the relation between the system's length L and the length ls determined by the integral density of states. For long enough systems, L ≫ ls, the distribution can still be described within a new scaling approach based upon the ratio of the localization length lloc and ls. In an intermediate …
Density Of Resonant States And A Manifestation Of Photonic Band Structure In Small Clusters Of Spherical Particles, Alexey Yamilov, Hui Cao
Density Of Resonant States And A Manifestation Of Photonic Band Structure In Small Clusters Of Spherical Particles, Alexey Yamilov, Hui Cao
Physics Faculty Research & Creative Works
We introduce a numerical recipe for calculating the density of the resonant states of the clusters of dielectric spheres. Using truncated multipole expansions (generalized multisphere Mie solution) we obtain the scattering matrix of the problem. By introducing an infinitesimal absorption in the spheres we express the dwell time of the electromagnetic wave in terms of the elements of the scattering matrix. Using the parameters in recent light localization experiments [Phys. Rev. Lett. 87, 153901 (2001)], we demonstrate that the density of the resonant states, related to the dwell time, shows the formation of the photonic band structure in small clusters …
Electric Field Gradients In S-, P-, And D-Metal Diborides And The Effect Of Pressure On The Band Structure And TC In Mgb₂, Nadezhda I. Medvedeva, Alexander L. Ivanovskii, Julia E. Medvedeva, Arthur J. Freeman, Dmitrii L. Novikov
Electric Field Gradients In S-, P-, And D-Metal Diborides And The Effect Of Pressure On The Band Structure And TC In Mgb₂, Nadezhda I. Medvedeva, Alexander L. Ivanovskii, Julia E. Medvedeva, Arthur J. Freeman, Dmitrii L. Novikov
Physics Faculty Research & Creative Works
Results of full-potential linear muffin-tin orbital generalized gradient approximation calculations of the band structure and boron electric field gradients (EFG's) for the new medium-Tc superconductor MgB2 and related diborides MB2, M = Be, Al, Sc, Ti, V, Cr, Mo, and Ta are reported. The boron EFG variations are found to be related to specific features of their band structure and particularly to the M-B hybridization. The strong charge anisotropy at the B site in MgB2 is completely defined by the valence electrons - a property which sets MgB2 apart from other diborides. The boron …