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Direct Nmr Observation Of Rotational Freeze-Out In The Smectic C-Phase, Demetri J. Photinos, Philip J. Bos, Mary E. Neubert, J. William Doane
Direct Nmr Observation Of Rotational Freeze-Out In The Smectic C-Phase, Demetri J. Photinos, Philip J. Bos, Mary E. Neubert, J. William Doane
Philip J. Bos
We report here a simple and direct observation that the molecular long axis is not, on the average, a rotation axis for the entire molecule in the smectic C phase (rotational freeze-out). This observation is made in the compound 4-n-heptyl-d15-oxybenzoic acid-d1 where experiment clearly shows that the principal axes of the time-averaged deuterium quadrupole interactions at specific sites of the hydrocarbon chain are not all parallel, demonstrating that they do not share a common axis of rotation.