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Radiation-Induced Decomposition Of The Metal-Organic Molecule Bis(4-Cyano-2,2,6,6-Tetramethyl-3,5-Heptanedionato)Copper(Ii), David Wisbey, Ning Wu, Yaroslav B. Losovyj, Ihor Ketsman, A. N. Caruso, Danqin Feng, John Belot, Elio Vescovo, Peter A. Dowben
Radiation-Induced Decomposition Of The Metal-Organic Molecule Bis(4-Cyano-2,2,6,6-Tetramethyl-3,5-Heptanedionato)Copper(Ii), David Wisbey, Ning Wu, Yaroslav B. Losovyj, Ihor Ketsman, A. N. Caruso, Danqin Feng, John Belot, Elio Vescovo, Peter A. Dowben
Ning Wu
The effects of vacuum ultraviolet radiation on the adsorbed copper center molecule bis(4-cyano-2,2,6,6- tetramethyl-3,5-heptanedionato)copper(II) (or Cu(CNdpm)2), (C24H36N2O4Cu, Cu(II)) was studied by photoemission spectroscopy. Changes in the ultraviolet photoemission spectra (UPS) of Cu(CNdpm)2, adsorbed on Co(1 1 1), indicate that the ultraviolet radiation leads to decomposition of Cu(CNdpm)2 and this decomposition is initially dominated by loss of peripheral hydrogen.