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Technological University Dublin

2008

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Articles 1 - 19 of 19

Full-Text Articles in Physics

Structure Property Relationships In Organic Conjugated Systems, Luke O'Neill Nov 2008

Structure Property Relationships In Organic Conjugated Systems, Luke O'Neill

Doctoral

A series of pi(п) conjugated oligomers containing 1 to 6 monomer units were studied by absorption and photoluminescence spectroscopies. The results are discussed and examined with regard to the variation of the optical properties with the increase of effective conjugation length. It was found that there was a linear relationship between the positioning of the absorption and photoluminescence maxima plotted against inverse conjugation length. The relationships are in good agreement with the simple particle in a box method, one of the earliest descriptions of the properties of one-dimensional organic molecules. Variations in the infinite chain limit band gap for a …


Hand-Held Flyback Driven Coaxial Dielectric Barrier Discharge: Development And Characterization, Victor J. Law, Vladimir Milosavljevic, Neil O’Connor, James F. Lalor, Steven Daniels Sep 2008

Hand-Held Flyback Driven Coaxial Dielectric Barrier Discharge: Development And Characterization, Victor J. Law, Vladimir Milosavljevic, Neil O’Connor, James F. Lalor, Steven Daniels

Articles

The development of a handheld single and triple chamber atmospheric pressure coaxial dielectric barrier discharge driven by Flyback circuitry for helium and argon discharges is described. The Flyback uses external metal-oxide-semiconductor field-effect transistor power switching technology and the transformer operates in the continuous current mode to convert a continuous dc power of 10–33 W to generate a 1.2–1.6 kV 3.5 μs pulse. An argon discharge breakdown voltage of ∼768 V is measured. With a 50 kHz, pulse repetition rate and an argon flow rate of 0.5–10 argon slm (slm denotes standard liters per minute), the electrical power density deposited in …


Some Rather Mechanical Reflections On Symmetry: In Art, Science, Engineering, Mathematics, Etc., Jim Mcgovern Sep 2008

Some Rather Mechanical Reflections On Symmetry: In Art, Science, Engineering, Mathematics, Etc., Jim Mcgovern

Articles

This Inaugural Lecture consists of some of my rather mechanical, being an engineer, reflections on symmetry in diverse areas such as art, science, engineering, mathematics, etc. I explain what symmetry is to me, giving examples with lots of images and mentioning or at least barely referencing art, science, architecture, engineering, heritage, cosmology, bicycles, flight, invention, ingenuity, history, wallpaper, mathematics, typography, structures, regular shapes, coordinate systems, spacetime, thermodynamics and suchlike.


An Exploration Of A Discrete Rhombohedral Lattice Of Possible Engineering Or Physical Relevance (Revised Version) 2008, Jim Mcgovern Jun 2008

An Exploration Of A Discrete Rhombohedral Lattice Of Possible Engineering Or Physical Relevance (Revised Version) 2008, Jim Mcgovern

Conference Papers

A particular discrete rhombohedral lattice consisting of four symmetrically interlaced cuboctahedral point lattices is described that is interesting because of the high degree of symmetry it exhibits. The four constituent cuboctahedral lattices are denoted by four colours and the composite lattice is referred to as a 4-colour rhombohedral lattice. Each point of the 4-colour lattice can be referenced by an integer 4-tuple containing only the positive non-zero integers (the counting numbers). The relationship between the discrete rhombohedral lattice and a discrete Cartesian lattice is explained. Some interesting aspects of the lattice and of the counting-number 4-tuple coordinate system are pointed …


An Exploration Of A Discrete Rhombohedral Lattice Of Possible Engineering Or Physical Relevance, Jim Mcgovern Jun 2008

An Exploration Of A Discrete Rhombohedral Lattice Of Possible Engineering Or Physical Relevance, Jim Mcgovern

Conference Papers

A particular discrete rhombohedral lattice consisting of four symmetrically interlaced cuboctahedral or cubic point lattices is described that is interesting because of the high degree of symmetry it exhibits. The four constituent lattices are denoted by four colours and the composite lattice is referred to as a 4-colour rhombohedral lattice. Each point of the 4-colour lattice can be referenced by an integer 4-tuple containing only the positive non-zero integers (the counting numbers). The relationship between the discrete rhombohedral lattice and a discrete Cartesian lattice is explained. Some interesting aspects of the lattice and of the counting-number 4-tuple coordinate system are …


Real-Time Plasma Controlled Chemistry In A Two-Frequency, Confined Plasma Etcher, Vladimir Milosavljevic, Albert R. Ellingboe, Cezar Gaman, John V. Ringwood Apr 2008

Real-Time Plasma Controlled Chemistry In A Two-Frequency, Confined Plasma Etcher, Vladimir Milosavljevic, Albert R. Ellingboe, Cezar Gaman, John V. Ringwood

Articles

The physics issues of developing model-based control of plasma etching are presented. A novel methodology for incorporating real-time model-based control of plasma processing systems is developed. The methodology is developed for control of two dependent variables (ion flux and chemical densities) by two independent controls (27 MHz power and O2flow). A phenomenological physics model of the nonlinear coupling between the independent controls and the dependent variables of the plasma is presented. By using a design of experiment, the functional dependencies of the response surface are determined. In conjunction with the physical model, the dependencies are used to deconvolve the sensor …


Quantification Of The Environmental Solar Ultraviolet Radiation Field At The Human Eye And The Investigation Of Peripherally Focused Rays., David P. Fleming Apr 2008

Quantification Of The Environmental Solar Ultraviolet Radiation Field At The Human Eye And The Investigation Of Peripherally Focused Rays., David P. Fleming

Doctoral

The increase of terrestrial solar ultraviolet radiation (UVR) due to the reduction of the ozone layer has promoted a variety of research into establishing the impact of this elevated potential dose of UVR on biological tissues. Anterior ocular tissues such as the cornea have been found to be susceptible to damage by terrestrial solar UVR and diseases such as pterygium are commonly thought to be a direct result of absorbed UVR at the nasal limbus. There is a need for more accurate quantification and localisation of incident UVR at the anterior ocular surface. A novel solar blind photodiode sensor array …


A Visual Indication Of Environmental Humidity Using A Colour Changing Hologram Recorded In A Self-Developing Photopolymer, Izabela Naydenova, Raghavendra Jallapuram, Vincent Toal, Suzanne Martin Jan 2008

A Visual Indication Of Environmental Humidity Using A Colour Changing Hologram Recorded In A Self-Developing Photopolymer, Izabela Naydenova, Raghavendra Jallapuram, Vincent Toal, Suzanne Martin

Articles

A reflection hologram for visual indication of environmental humidity has been studied. The hologram is recorded in a self-developing photopolymer and changes colour when exposed to a change in humidity and is fully reversible. The range of colour change, reversibility and the response time of the hologram have been studied in a controlled humidity environment. Fully reversible holograms with response times from few seconds to tens of minutes have been designed. Extremely sensitive bright visual humidity indicators, capable of dramatic colour change within a few seconds of breathing on them are demonstrated.


Fabrication Of Switchable Liquid Crystal Devices Using Surface Relief Gratings In Photopolymer, Pavani Kotakonda, Izabela Naydenova, Robert Howard, Suzanne Martin, Vincent Toal Jan 2008

Fabrication Of Switchable Liquid Crystal Devices Using Surface Relief Gratings In Photopolymer, Pavani Kotakonda, Izabela Naydenova, Robert Howard, Suzanne Martin, Vincent Toal

Articles

Holographically recorded surface relief gratings in dry, self-developing acrylamide based photopolymer were used to fabricate two types of switchable liquid crystal (LC) device. One is an electrically switchable LC diffraction grating and the other is an electrically switchable polarization rotator. The electrically switchable diffraction grating was characterized by measuring the dependence of the intensity in the first diffracted order on the applied electric field. The polarization rotator was characterized by studying the influence of the applied electric field on the twist angle and the variation of intensity in the zero and the first orders of diffraction.


Digital Close Range Photogrammetry In Motor Vehicle Accident Reconstruction, Fiona Coyle Jan 2008

Digital Close Range Photogrammetry In Motor Vehicle Accident Reconstruction, Fiona Coyle

Doctoral

Road traffic accidents are consistently in the top ten causes of death world-wide. In order to reduce the number of fatalities caused by traffic collision, better knowledge and understanding of the sequence of events prior to and during a traffic accident, i.e. Accident Reconstruction, is required, so it is important to obtain detailed quantitative information about the damage sustained by the crashed vehicle(s). The research reported here was aimed at developing a fast and accurate method of measuring the damage. Digital Close Range Photogrammetry is the technique chosen for obtaining vehicle profiles from which accurate measurements of crust damage could …


Luminescent Solar Concentrators: A Review Of Recent Results, Wilfrid G.J.H.M. Van Sark, Keith W.J. Barnham, Lenneke H. Slooff, Amanda J. Chatten, Andreas Buchtemann, Andreas Meyer, Sarah Mccormack, Rolf Koole, Daniel J. Farrell, Rahul Bose, Evert E. Bende, Antonius R. Burgers, Tristram Budel, Jana Quilitz, Manus Kennedy, Toby Meyer, C. De Mello Donega, Andries Meijerink Jan 2008

Luminescent Solar Concentrators: A Review Of Recent Results, Wilfrid G.J.H.M. Van Sark, Keith W.J. Barnham, Lenneke H. Slooff, Amanda J. Chatten, Andreas Buchtemann, Andreas Meyer, Sarah Mccormack, Rolf Koole, Daniel J. Farrell, Rahul Bose, Evert E. Bende, Antonius R. Burgers, Tristram Budel, Jana Quilitz, Manus Kennedy, Toby Meyer, C. De Mello Donega, Andries Meijerink

Articles

Luminescent solar concentrators (LSCs) generally consist of transparent polymer sheets doped with luminescent species. Incident sunlight is absorbed by the luminescent species and emitted with high quantum efficiency, such that emitted light is trapped in the sheet and travels to the edges where it can be collected by solar cells. LSCs offer potentially lower cost per Wp. This paper reviews results mainly obtained within the framework of the Fullspectrum project. Two modeling approaches are presented, i.e., a thermodynamic and a ray-trace one, as well as experimental results, with a focus on LSC stability.


A Visual Indication Of Environmental Humidity Using A Color Changing Hologram Recorded In A Self-Developing Photopolymer, Izabela Naydenova, Raghavendra Jallapuram, Vincent Toal, Suzanne Martin Jan 2008

A Visual Indication Of Environmental Humidity Using A Color Changing Hologram Recorded In A Self-Developing Photopolymer, Izabela Naydenova, Raghavendra Jallapuram, Vincent Toal, Suzanne Martin

Articles

A reflection hologram for visual indication of environmental humidity has been studied. The hologram is recorded in a self-developing photopolymer and changes color when exposed to a change in humidity and is fully reversible. The range of color change, reversibility, and the response time of the hologram have been studied in a controlled humidity environment. Fully reversible holograms with response times from few seconds to tens of minutes have been designed. Extremely sensitive bright visual humidity indicators, capable of dramatic color change within a few seconds of breathing on them are demonstrated


Nearly-Hamiltonian Structure For Water Waves With Constant Vorticity, Adrian Constantin, Rossen Ivanov, Emil Prodanov Jan 2008

Nearly-Hamiltonian Structure For Water Waves With Constant Vorticity, Adrian Constantin, Rossen Ivanov, Emil Prodanov

Articles

We show that the governing equations for two-dimensional gravity water waves with constant non-zero vorticity have a nearly-Hamiltonian structure, which becomes Hamiltonian for steady waves.


Investigation Of The Electronic Properties Of Organic Systems Using Electroabsorption Spectroscopy, Garrett F. Farrell Jan 2008

Investigation Of The Electronic Properties Of Organic Systems Using Electroabsorption Spectroscopy, Garrett F. Farrell

Doctoral

The aim of this project is to investigate the effect of bulk structural modification on the electronic properties of fullerene systems as measured using electronic and Electroabsorption (EA) spectroscopy. The existence of a unique solid state feature in C60 is the first indication that the material’s electronic properties may be influenced by its crystalline environment and as such merits investigation. The nature and extent of these interactions in the solid state is still unclear, in particular whether the molecular electrons remain located on the individual molecules or whether they are delocalised across the solid. The extent of these interactions has …


Method For Characterization Of Diffusion Properties Of Photopolymerisable Systems, Tzvetanka Babeva, Izabela Naydenova, Suzanne Martin, Vincent Toal Jan 2008

Method For Characterization Of Diffusion Properties Of Photopolymerisable Systems, Tzvetanka Babeva, Izabela Naydenova, Suzanne Martin, Vincent Toal

Articles

A novel approach for measuring the diffusion coefficients in photopolymerisable materials is proposed. The method is based on studying the evolution of the surface relief profile in a single illuminated spot using an interferometric surface profiler. It is shown that the observed post-exposure swelling in the illuminated spot is due to mass-transport of monomer from the unexposed to the exposed area driven by a monomer concentration gradient set up by the monomer polymerization in the exposed area. Appropriate choice of the thickness of the studied layers ensures both lateral movement of monomer and negligible contribution from the depth. The diffusion …


Nanocomposites For Novel Holographic Applications, Izabela Naydenova, Svetlana Mintova, Suzanne Martin, Vincent Toal Jan 2008

Nanocomposites For Novel Holographic Applications, Izabela Naydenova, Svetlana Mintova, Suzanne Martin, Vincent Toal

Articles

Nanozeolites incorporated into photopolymerizable holographic recording materials can be used for holographic sensing, data storage, and optical systems design.


Implementation Of Phase-Only Modulation Utilizing A Twisted Nematic Liquid Crystal Spatial Light Modulator, Mohammad Mahmud, Izabela Naydenova, Vincent Toal Jan 2008

Implementation Of Phase-Only Modulation Utilizing A Twisted Nematic Liquid Crystal Spatial Light Modulator, Mohammad Mahmud, Izabela Naydenova, Vincent Toal

Articles

Twisted nematic liquid crystal spatial light modulators, (SLM) are widely used for amplitude modulation of light. The technique for measuring phase and amplitude modulation introduced by a twisted nematic cell is not new but the novelty here is that after characterisation of a Holoeye LC2002 TNLC device we were able to identify specific conditions that allow for its use as a pure 180 degree or more, phase modulator with little or no amplitude modulation at 514.5 nm laser wavelength. The phase shift introduced by the SLM was measured using a Mach-Zehnder interferometer. The experimentally measured and the theoretically predicted intensity …


Hoe-Based Espi Systems, Emilia Mihaylova, Viswanath Bavigadda, Raghavendra Jallapuram, Vincent Toal Jan 2008

Hoe-Based Espi Systems, Emilia Mihaylova, Viswanath Bavigadda, Raghavendra Jallapuram, Vincent Toal

Conference Papers

Electronic speckle pattern interferometry (ESPI) is a full-field measurement technique, capable of displaying vibrational mode shapes. Two electronic speckle pattern interferometers using reflection holographic optical elements (RHOEs) are presented. In the first ESPI system the RHOE is designed to create the speckled reference beam. A partially reflective glass plate provides illumination of the object along the normal to its surface, ensuring that the system is sensitive only to out-of-plane displacement of the object. It is demonstrated that the HOE-based system can be used for vibration measurements. Phase shifting can be implemented for fringe analysis. In the second ESPI system a …


Whole Field Out-Of-Plane Vibration Analysis With A Hoe-Based Espi System, Emilia Mihaylova, Viswanath Bavigadda, Raghavendra Jallapuram, Vincent Toal Jan 2008

Whole Field Out-Of-Plane Vibration Analysis With A Hoe-Based Espi System, Emilia Mihaylova, Viswanath Bavigadda, Raghavendra Jallapuram, Vincent Toal

Conference Papers

Electronic speckle pattern interferometry (ESPI) is a full-field measurement technique, capable of displaying vibrational mode shapes. A simple optical set-up for an ESPI system using a holographic optical element (HOE) is presented. The HOE is designed to create a speckled reference beam in the interferometer. A partially reflective glass plate provides illumination of the object along the normal to its surface, ensuring that the system is sensitive only to out-of-plane displacement of the object. It is demonstrated that the HOE-based system can be used for vibration measurements. Phase shifting can be implemented for fringe analysis. A big advantage of the …