Open Access. Powered by Scholars. Published by Universities.®
Articles 1 - 4 of 4
Full-Text Articles in Physics
Steady-State Aerosol Distributions In The Extra-Tropical, Lower Stratosphere And The Processes That Maintain Them, J. Wilson, Shan-Hu Lee, J. Reeves, C. Brock, H. Jonsson, B. Lafleur, M. Loewenstein, J. Podolske, E. Atlas, K. Boering, G. Toon, D. Fahey, T. Bui, G. Diskin, F. Moore
Steady-State Aerosol Distributions In The Extra-Tropical, Lower Stratosphere And The Processes That Maintain Them, J. Wilson, Shan-Hu Lee, J. Reeves, C. Brock, H. Jonsson, B. Lafleur, M. Loewenstein, J. Podolske, E. Atlas, K. Boering, G. Toon, D. Fahey, T. Bui, G. Diskin, F. Moore
Shan-Hu Lee
Measurements of aerosol, N2O and OCS made in the Northern Hemisphere below 21 km altitude following the eruption of Pinatubo are presented and analyzed. After September 1999, the oxidation of OCS and sedimentation of particles in the extra-tropical overworld north of 45 N are found to maintain the aerosol in a steady state. This analysis empirically links precursor gas to aerosol abundance throughout this region. These processes are tracked with age-of-air which offers advantages over tracking as a function of latitude and altitude. In the extra-tropical, lowermost stratosphere, normalized volume distributions appear constant in time after the fall of 1999. …
Laboratory Studies Of H2so4/H2o Binary Homogeneous Nucleation From The So2+Oh Reaction: Evaluation Of The Experimental Setup And Preliminary Results, L. Young, D. Benson, F. Kameel, J. Pierce, H. Junninen, M. Kulmala, Shan-Hu Lee
Laboratory Studies Of H2so4/H2o Binary Homogeneous Nucleation From The So2+Oh Reaction: Evaluation Of The Experimental Setup And Preliminary Results, L. Young, D. Benson, F. Kameel, J. Pierce, H. Junninen, M. Kulmala, Shan-Hu Lee
Shan-Hu Lee
Binary homogeneous nucleation (BHN) of sulphuric acid and water (H2SO4/H2O) is one of the most important atmospheric nucleation processes, but laboratory observations of this nucleation process are very limited and there are also large discrepancies between different laboratory studies. The difficulties associated with these experiments include wall loss of H2SO4 and uncertainties in estimation of H2SO4 concentration ([H2SO4]) involved in nucleation. We have developed a new laboratory nucleation setup to study H2SO4/H2O BHN kinetics and provide relatively constrained [H2SO4] needed for nucleation. H2SO4 is produced from the SO2+OH→HSO3 reaction and OH radicals are produced from water vapor UV absorption. The …
Ternary Homogeneous Nucleation Of H2so4, Nh3, And H2o Under Conditions Relevant To The Lower Troposphere, D. Benson, J. Yu, A. Markovich, Shan-Hu Lee
Ternary Homogeneous Nucleation Of H2so4, Nh3, And H2o Under Conditions Relevant To The Lower Troposphere, D. Benson, J. Yu, A. Markovich, Shan-Hu Lee
Shan-Hu Lee
Ternary homogeneous nucleation (THN) of H2SO4, NH3 and H2O has been used to explain new particle formation in various atmospheric regions, yet laboratory measurements of THN have failed to reproduce atmospheric observations. Here, we report first laboratory observations of THN made under conditions relevant to the lower troposphere ([H2SO4] of 106–107 cm−3, [NH3] of 0.08–20 ppbv, and a temperature of 288 K). Our observations show that NH3 can enhance atmospheric H2SO4aerosol nucleation and the enhancement factor (EF) in nucleation rate (J) due to NH3 (the ratio of Jmeasured with vs. without NH3) increases linearly with increasing [NH3] and increases with …
The Effects Of Airmass History On New Particle Formation In The Free Troposphere: Case Studies, D. Benson, Li-Hao Young, Shan-Hu Lee, T. Campos, D. Rogers, J. Jensen
The Effects Of Airmass History On New Particle Formation In The Free Troposphere: Case Studies, D. Benson, Li-Hao Young, Shan-Hu Lee, T. Campos, D. Rogers, J. Jensen
Shan-Hu Lee
Recent aircraft studies showed that new particle formation (NPF) is very active in the free troposphere. And, these observations lead to a new question: when does NPF not occur? Here, we provide case studies to show how different meteorological parameters affect NPF in the upper troposphere, using the aerosol size distributions measured at latitudes from 18° N–52° N and altitudes up to 14 km during the NSF/NCAR GV Progressive Science Missions. About 95% of the total samples showed the NPF feature with median number concentrations of particles with diameters from 4 to 9 nm (N4–9), 288±199 cm−3, and the total …