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Processability Of Polythiophene Thin Films By Ultraviolet Photo Bleaching, Derek D. Fletcher
Processability Of Polythiophene Thin Films By Ultraviolet Photo Bleaching, Derek D. Fletcher
Theses and Dissertations
Materials possessing strong 𝜒(3) optical properties such as Polythiophene are sought for the production of optical switches. Polythiophene thin films produced by plasma enhanced CVD show a surface rms roughness of 10-15 angstroms over single square micron areas which is acceptable for wave guiding in the near IR. This research investigates permanently changing the optical properties of such a thin film by exposure to UV radiation (254 nm, 35 mW/cm2), known as photo bleaching, in hope of creating a refractive index boundary for use in total internal reflection. After 60 minutes exposure the refractive index shows …
Cathodoluminescence Spectroscopy Of Zinc Germanium Phosphide Zngep2, Michael R. Gregg
Cathodoluminescence Spectroscopy Of Zinc Germanium Phosphide Zngep2, Michael R. Gregg
Theses and Dissertations
Zinc Germanium Phosphide (ZnGeP2) is a nonlinear semiconductor suitable for use as a laser tuning element over the two to six micron wavelength range. Although this crystal has been studied in the past, its luminescent properties are not yet well understood. In this present study, ZnGeP2 has been examined using cathodoluminescence spectroscopy (CL). Specifically, the spectral dependence of the CL was obtained as a function of electron beam energy, beam current and temperature. The resulting CL was found to be polarized with a peak structure that was dependent on the polarization. This peak structure observed by CL …