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Ftir Studies Of Pema/Pvdf-Hfp Blend Polymer Electrolyte System Incorporated With Licf3so3 Salt, Siti Rohana Majid, Sim L. N., Arof A. K. Dec 2011

Ftir Studies Of Pema/Pvdf-Hfp Blend Polymer Electrolyte System Incorporated With Licf3so3 Salt, Siti Rohana Majid, Sim L. N., Arof A. K.

Siti Rohana Majid

Poly(ethyl methacrylate), PEMA and poly(vinylidenefluoride-co-hexafluoropropylene). PVdF-HFP have been chosen as hosts for the development of a polymer blend electrolyte system. Lithium trifluoromethanesulfonate (triflate), LiCF3SO3 is the lithium ion, Li+ provider. The ratio of PEMA:PVdF-HFP in the blend is fixed at 70:30 in order to obtain transparent films with good mechanical stability. The polymers and LiCF3SO3 salt have been refluxed for 2 h at temperatures between 55 and 65 degrees C. The concentration of LiCF3SO3 salt has been varied from 0 to 40 wt.%. Fourier transform infrared (FTIR) spectroscopy has shown that blending between PEMA and PVdF-HFP has occurred from the …