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Articles 1 - 2 of 2
Full-Text Articles in Physics
Transport Studies Of Nh4no3 Doped Methyl Cellulose Electrolyte, Siti Rohana Majid, Shuhaimi N. E. A., Teo L. P., Arof A. K.
Transport Studies Of Nh4no3 Doped Methyl Cellulose Electrolyte, Siti Rohana Majid, Shuhaimi N. E. A., Teo L. P., Arof A. K.
Siti Rohana Majid
This work reports on the transport properties of NH4NO3 doped methyl cellulose (MC) polymer electrolyte. The polymer electrolyte films were prepared by the technique of solvent casting. The highest room temperature conductivity of MC doped with 25 wt.% NH4NO3 is 2.10 +/- 0.37 x 10(-6) S cm(-1). Conductivity-temperature relationship obeys the Vogel-Tamman-Fulcher (VTF) rule from which the glass transition temperature, T-g was evaluated. The mobility, p and number density of charge carrier, n were calculated using the Rice and Roth model. (C) 2010 Elsevier B.V. All rights reserved.
Characteristics Of Methyl Cellulose-Nh4no3-Peg Electrolyte And Application In Fuel Cells, Siti Rohana Majid, Shuhaimi N. E. A., Alias N. A., Kufian M. Z., Arof A. K.
Characteristics Of Methyl Cellulose-Nh4no3-Peg Electrolyte And Application In Fuel Cells, Siti Rohana Majid, Shuhaimi N. E. A., Alias N. A., Kufian M. Z., Arof A. K.
Siti Rohana Majid
We report the viability of methyl cellulose (MC) as a membrane in a polymer electrolyte membrane fuel cell (PEMFC). Methyl cellulose serves as the polymer host, ammonium nitrate (NH4NO3) as the doping salt and poly(ethylene glycol) (PEG) as plasticizer. Conductivity measurement was carried out using electrochemical impedance spectroscopy. The room temperature conductivity of pure MC film is is (3.08 +/- 0.63) x 10(-11)S cm(-1). The conductivity increased to (2.10 +/- 0.37) x 10(-6)S cm(-1) on addition of 25 wt.% NH4NO3. By adding 15 wt.% of PEG 200 to the highest conducting sample in the MC-NH4NO3 system, the conductivity was further …