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Full-Text Articles in Physics

Polymer And Small Molecule Designs For Anion Conducting Membranes: Connected Ion-Channel Morphologies And Highly Alkaline Stable Ammonium Cations, Sedef P. Ertem Nov 2016

Polymer And Small Molecule Designs For Anion Conducting Membranes: Connected Ion-Channel Morphologies And Highly Alkaline Stable Ammonium Cations, Sedef P. Ertem

Doctoral Dissertations

Fuel cells are one of the oldest sustainable energy generation devices, converting chemical energy into electrical energy via reverse-electrolysis reactions. With the rapid development of polymer science, solid polymer electrolyte (SPE) membranes replaced the conventional liquid ion transport media, rendering low-temperature fuel cells more accessible for applications in portable electronics and transportation. However, SPE fuel cells are still far from commercialization due to high operation cost, and insufficient lifetime and performance limitations. Anion exchange membrane fuel cells (AEMFCs) are inexpensive alternatives to current proton exchange membrane fuel cell (PEMFC) technology, which relies on utilizing expensive noble-metal catalysts and perfluorinated SPE …


Robust Identification Of Dynamically Distinct Regions In Stratified Turbulence, Gavin D. Portwood, Stephen M. De Bruyn Kops, J. R. Taylor, H. Salehipour, C. P. Caulfield Jan 2016

Robust Identification Of Dynamically Distinct Regions In Stratified Turbulence, Gavin D. Portwood, Stephen M. De Bruyn Kops, J. R. Taylor, H. Salehipour, C. P. Caulfield

Mechanical and Industrial Engineering Faculty Publication Series

we present a new robust method for identifying three dynamically distinct regions in a stratified turbulent flow, which we characterise as quiescent flow, intermittent layers, and turbulent patches. The method uses the cumulative filtered distribution function of the local density gradient to identify each region. We apply it to data from direct numerical simulations of homogeneous stratified turbulence, with unity Prandtl number, resolved on up to 8192x8192x4092 grid points. In addition to classifying regions consistently with contour plots of potential enstropy, our method identifies quiescent regions as regions where ∊ ⁄ νΝ2 ~ Ο(1), layers as regions where …