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2014

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Full-Text Articles in Physics

Sulfur Vacancies In Photorefractive Sn2P2S6 Crystals, Eric M. Golden, Sergey A. Basun, A. A. Grabar, I. M. Stoika, Nancy C. Giles, D. R. Evans, Larry E. Halliburton Dec 2014

Sulfur Vacancies In Photorefractive Sn2P2S6 Crystals, Eric M. Golden, Sergey A. Basun, A. A. Grabar, I. M. Stoika, Nancy C. Giles, D. R. Evans, Larry E. Halliburton

Faculty Publications

A photoinduced electron paramagnetic resonance (EPR) spectrum in single crystals of Sn2P2S6 (SPS) is assigned to an electron trapped at a sulfur vacancy. These vacancies are unintentionally present in undoped SPS crystals and are expected to play an important role in the photorefractive behavior of the material. Nonparamagnetic sulfur vacancies are formed during the initial growth of the crystal. Subsequent illumination below 100 K with 442 nm laser light easily converts these vacancies to EPR-active defects. The resulting S = 1/2 spectrum shows well-resolved and nearly isotropic hyperfine interactions with two P ions and two Sn ions. Partially resolved interactions …


Ogden College Of Science & Engineering Newsletter (Winter 2014), Cheryl Stevens, Dean Dec 2014

Ogden College Of Science & Engineering Newsletter (Winter 2014), Cheryl Stevens, Dean

Ogden College of Science & Engineering Publications

No abstract provided.


Split-Step Approach To Electromagnetic Propagation Through Atmospheric Turbulence Using The Modified Von Karman Spectrum And Planar Apertures, Monish Ranjan Chatterjee, Fathi H.A. Mohamed Dec 2014

Split-Step Approach To Electromagnetic Propagation Through Atmospheric Turbulence Using The Modified Von Karman Spectrum And Planar Apertures, Monish Ranjan Chatterjee, Fathi H.A. Mohamed

Electrical and Computer Engineering Faculty Publications

The impact of atmospheric phase turbulence on Gaussian beam propagation along propagation paths of varying lengths is examined using multiple random phase screens. The work is motivated by research involving generation and encryption of acousto-optic chaos, and the interest in examining propagation of such chaotic waves through atmospheric turbulence. A phase screen technique is used to simulate perturbations to the refractive index of the medium through the propagation path. A power spectral density based on the modified von Karman spectrum model for turbulence is used to describe the random phase behavior of the medium.

In recent work, results for the …


Performance Analysis Of A Hybrid Raman Optical Parametric Amplifier In The O- And E-Bands For Cwdm Pons, Sasanthi Peiris, Nicolas Madamopoulos, Neophytos A. Antoniades, Dwight Richards, Roger Dorsinville Dec 2014

Performance Analysis Of A Hybrid Raman Optical Parametric Amplifier In The O- And E-Bands For Cwdm Pons, Sasanthi Peiris, Nicolas Madamopoulos, Neophytos A. Antoniades, Dwight Richards, Roger Dorsinville

Publications and Research

We describe a hybrid Raman-optical parametric amplifier (HROPA) operating at the O- and E-bands and designed for coarse wavelength division multiplexed (CWDM) passive optical networks (PONs). We present the mathematical model and simulation results for the optimization of this HROPA design. Our analysis shows that separating the two amplification processes allows for optimization of each one separately, e.g., proper selection of pump optical powers and wavelengths to achieve maximum gain bandwidth and low gain ripple. Furthermore, we show that the proper design of optical filters incorporated in the HROPA architecture can suppress idlers generated during the OPA process, as well …


Improved Performance Of Analog And Digital Acousto-Optic Modulation With Feedback Under Profiled Beam Propagation For Secure Communication Using Chaos, Fares S. Almehmadi, Monish Ranjan Chatterjee Dec 2014

Improved Performance Of Analog And Digital Acousto-Optic Modulation With Feedback Under Profiled Beam Propagation For Secure Communication Using Chaos, Fares S. Almehmadi, Monish Ranjan Chatterjee

Electrical and Computer Engineering Faculty Publications

Using intensity feedback, the closed-loop behavior of an acousto-optic hybrid device under profiled beam propagation has been recently shown to exhibit wider chaotic bands potentially leading to an increase in both the dynamic range and sensitivity to key parameters that characterize the encryption. In this work, a detailed examination is carried out vis-à-vis the robustness of the encryption/decryption process relative to parameter mismatch for both analog and pulse code modulation signals, and bit error rate (BER) curves are used to examine the impact of additive white noise.

The simulations with profiled input beams are shown to produce a stronger encryption …


Ogden College Of Science & Engineering Newsletter (Fall 2014), Cheryl Stevens, Dean Oct 2014

Ogden College Of Science & Engineering Newsletter (Fall 2014), Cheryl Stevens, Dean

Ogden College of Science & Engineering Publications

No abstract provided.


Mri: Acquisition Of A Squid Magnetometer For Analysis Of Advanced Materials, Robert W. Meulenberg, Robert J. Lad, David J. Frankel, Michael D. Mason, Samuel T. Hess Sep 2014

Mri: Acquisition Of A Squid Magnetometer For Analysis Of Advanced Materials, Robert W. Meulenberg, Robert J. Lad, David J. Frankel, Michael D. Mason, Samuel T. Hess

University of Maine Office of Research Administration: Grant Reports

Technical Summary: Superconducting quantum interference device (SQUID) magnetometry is a non-destructive technique that reveals detailed information about the electron spin interactions in many types of materials. This project will involve a state-of-the-art SQUID magnetometer and Magnetic Property Measurement System (MPMS), which is a critical tool for characterizing several types of materials currently being investigated by researchers within the Laboratory for Surface Science & Technology (LASST) and other University of Maine (UMaine) laboratories. Specific measurement capabilities include DC and AC magnetic susceptibility, magnetoresistivity, van der Paaw conductivity, and Hall mobility. State-of-the-art MPMS capabilities will be especially valuable to several research programs …


A Prototype Microwave Cavity Control Circuit For Use In Next Generation Free Electron Laser, Josh Thompson, Peter Neal Barrina, Jiayi Jiang, Joe Frisch, Steve Smith, Daniel Van Winkle Aug 2014

A Prototype Microwave Cavity Control Circuit For Use In Next Generation Free Electron Laser, Josh Thompson, Peter Neal Barrina, Jiayi Jiang, Joe Frisch, Steve Smith, Daniel Van Winkle

STAR Program Research Presentations

One of the current programs at SLAC National Accelerator Laboratory is the Linac Coherent Light Source, or LCLS. Using the existing hardware of the last third of their linear accelerator (or “linac”), SLAC has created one of the most energetic X-ray free electron lasers (or “FEL”). Since 2009, LCLS has used this FEL to perform a wide range of experiments across all sciences, most notably ultrafast filming at the molecular scale. As requests for beam-time with this laser increases, SLAC is purposing a linac upgrade to better match this demand. This upgrade, named LCLS-II, will replace existing copper radio frequency …


Modeling Of Power Spectral Density Of Modified Von Karman Atmospheric Phase Turbulence And Acousto-Optic Chaos Using Scattered Intensity Profiles Over Discrete Time Intervals, Monish Ranjan Chatterjee, Fathi H.A. Mohamed Aug 2014

Modeling Of Power Spectral Density Of Modified Von Karman Atmospheric Phase Turbulence And Acousto-Optic Chaos Using Scattered Intensity Profiles Over Discrete Time Intervals, Monish Ranjan Chatterjee, Fathi H.A. Mohamed

Electrical and Computer Engineering Faculty Publications

In recent research, propagation of plane electromagnetic (EM) waves through a turbulent medium with modified von Karman phase characteristics was modeled and numerically simulated using transverse planar apertures representing narrow phase turbulence along the propagation path.

The case for extended turbulence was also studied by repeating the planar phase screens multiple times over the propagation path and incorporating diffractive effects via a split-step algorithm. The goal of the research reported here is to examine two random phenomena: (a) atmospheric turbulence due to von Karman-type phase fluctuations, and (b) chaos generated in an acousto-optic (A-O) Bragg cell under hybrid feedback. The …


Realization Of Negative Index In Second-Order Dispersive Metamaterials Using Standard Dispersion Models For Electromagnetic Parameters, Tarig A. Algadey, Monish Ranjan Chatterjee Aug 2014

Realization Of Negative Index In Second-Order Dispersive Metamaterials Using Standard Dispersion Models For Electromagnetic Parameters, Tarig A. Algadey, Monish Ranjan Chatterjee

Electrical and Computer Engineering Faculty Publications

In recent work, electromagnetic propagation velocities for plane waves in dispersive metamaterials were calculated assuming frequency dispersion up to the second order. The three velocities were expressed in terms of dispersive coefficients under certain simplifying constraints. Frequency domains were found to exist around resonances where group and phase velocities are in opposition, implying possible negative index behavior.

In this paper, we incorporate in the derived equations physical models (including Debye, Lorentz and Condon) for material dispersion in permittivity, permeability and chirality in order to further examine the consequences of second-order dispersion leading to negative index for practical cases, and also …


Information Encryption, Transmission, And Retrieval Via Chaotic Modulation In A Hybrid Acousto-Optic Bragg Cell Under Profiled Beam Illumination, Monish Ranjan Chatterjee, Fares S. Almehmadi Aug 2014

Information Encryption, Transmission, And Retrieval Via Chaotic Modulation In A Hybrid Acousto-Optic Bragg Cell Under Profiled Beam Illumination, Monish Ranjan Chatterjee, Fares S. Almehmadi

Electrical and Computer Engineering Faculty Publications

In recent work, the propagation of a profiled optical beam through an open-loop acousto-optic Bragg cell was examined using a transfer function formalism. The device was also studied under closed-loop via intensity feedback, and shown to exhibit more extended chaotic band responses, thereby potentially increasing the dynamic range and parameter sensitivities of any applied signal and the device operation respectively.

In this paper, simple low- to mid-RF signals (periodic waveforms and low BW audio) are transmitted through the closed-loop system and the resulting encryption and recovery at the receiver are examined especially from the perspective of overall robustness of the …


Particle Image Velocimetry Of Transverse Jets In Crossflow, Jesse K. Tsai, Kayla Kuzmich, David Forliti, Kriss Vanderhyde, Nils Sedano Aug 2014

Particle Image Velocimetry Of Transverse Jets In Crossflow, Jesse K. Tsai, Kayla Kuzmich, David Forliti, Kriss Vanderhyde, Nils Sedano

STAR Program Research Presentations

The jet in crossflow (JICF) has been an ongoing study for the past several decades with applications in the field of fluid mechanics. This particular flow field produces vortical structures tied to the entrainment and mixing of two separate fluids. Research of the JICF seeks to determine a model and trajectory scaling law for future designs. This will help future designers to optimize the mixing and homogeneity of the two fluids to decrease emissions from pollutants, make ignition easier, and improve combustion efficiency of rockets.

Our experiment will employ Particle Image Velocimetry (PIV) to determine the fluid motion of the …


Does A Plastron Improve Heat Transfer?, Madani A. Khan, Jeffrey Alston, Andrew Guenthner Aug 2014

Does A Plastron Improve Heat Transfer?, Madani A. Khan, Jeffrey Alston, Andrew Guenthner

STAR Program Research Presentations

Superamphiphobic surfaces strongly repel both water and oils. In this work, aluminum coupons are processed by sanding with various grit of sand paper to impart microscale roughness. Subsequent submersion of the aluminum substrate in boiling water grows nanoscale grass-like structures. The oxide layer of Al is slightly soluble in water. During a fast diffusion/equilibrium, Al2O3 nanograss grows on the surface. A low energy coating is then deposited on the surface. The micro and nanoscale features create re-entrant structures that trap air enabling contact liquid to be in a Cassie-Baxter state. Superamphiphobicity of the samples were confirmed by …


A Soft Condensed Matter Approach Towards Mathematical Modelling Of Mass Transport And Swelling In Food Grains, Michael Chapwanya, N. Misra Aug 2014

A Soft Condensed Matter Approach Towards Mathematical Modelling Of Mass Transport And Swelling In Food Grains, Michael Chapwanya, N. Misra

Articles

Soft condensed matter (SCM) physics has recently gained importance for a large class of engineering materials. The treatment of food materials from a soft matter perspective, however, is only at the surface and is gaining importance for understanding the complex phenomena and structure of foods. In this work, we present a theoretical treatment of navy beans from a SCM perspective to describe the hydration kinetics. We solve the transport equations within a porous matrix and employ the Flory–Huggin’s equation for polymer–solvent mixture to balance the osmotic pressure. The swelling of the legume seed is modelled as a moving boundary with …


Numerical Investigation Of The Nonlinear Dynamics Of A Hybrid Acousto-Optic Bragg Cell With A Variable Feedback Gain, Monish Ranjan Chatterjee, Hao Zhou Aug 2014

Numerical Investigation Of The Nonlinear Dynamics Of A Hybrid Acousto-Optic Bragg Cell With A Variable Feedback Gain, Monish Ranjan Chatterjee, Hao Zhou

Electrical and Computer Engineering Faculty Publications

Since around 1979, the operation of an acousto-optic Bragg cell under positive first-order feedback via amplification and delay in the loop has been studied extensively by several groups [1-3]. In recent work, the analysis of the nonlinear dynamics (NLD) of the system was extended to include bistable maps and Lyapunov exponents, and application of the chaos for signal encryption and decryption for uniform plane waves. The present work originated with the problem of a variable photodetector aperture opening relative to the first-order light. This potentially complex problem is simplified by assuming instead a variable feedback gain ( β ~ (t)), …


A Low Temperature Nonlinear Optical Rotational Anisotropy Spectrometer For The Determination Of Crystallographic And Electronic Symmetries, Darius H. Torchinsky, Hao Chu, Tongfei Qi, Gang Cao, David Hsieh Aug 2014

A Low Temperature Nonlinear Optical Rotational Anisotropy Spectrometer For The Determination Of Crystallographic And Electronic Symmetries, Darius H. Torchinsky, Hao Chu, Tongfei Qi, Gang Cao, David Hsieh

Center for Advanced Materials Faculty Publications

Nonlinear optical generation from a crystalline material can reveal the symmetries of both its lattice structure and underlying ordered electronic phases and can therefore be exploited as a complementary technique to diffraction based scattering probes. Although this technique has been successfully used to study the lattice and magnetic structures of systems such as semiconductor surfaces, multiferroic crystals, magnetic thin films, and multilayers, challenging technical requirements have prevented its application to the plethora of complex electronic phases found in strongly correlated electron systems. These requirements include an ability to probe small bulk single crystals at the μm length scale, a need …


Variable Viscosity Condition In The Modeling Of A Slider Bearing, Kedar Nath Uprety, S.C. Mancas Jul 2014

Variable Viscosity Condition In The Modeling Of A Slider Bearing, Kedar Nath Uprety, S.C. Mancas

Publications

To reduce tear and wear of machinery lubrication is essential. Lubricants form a layer between two surfaces preventing direct contact and reduce friction between moving parts and hence reduce wear. In this short letter the lubrication of two slider bearings with parallel and nonparallel is studied. First, we show that bearings with parallel plates cannot support any load. For bearings with nonparallel plates we are interested on how constant and temperature dependent viscosity affects the properties of the bearings. Also, a critical temperature for which the bearings would fail due to excess in temperature is found for both latter cases. …


Transparent Conducting Oxides: A Δ-Doped Superlattice Approach, Valentino R. Cooper, Sung S. Ambrose Seo, Suyoun Lee, Jun Sung Kim, Woo Seok Choi, Satoshi Okamoto, Ho Nyung Lee Jul 2014

Transparent Conducting Oxides: A Δ-Doped Superlattice Approach, Valentino R. Cooper, Sung S. Ambrose Seo, Suyoun Lee, Jun Sung Kim, Woo Seok Choi, Satoshi Okamoto, Ho Nyung Lee

Physics and Astronomy Faculty Publications

Metallic states appearing at interfaces between dissimilar insulating oxides exhibit intriguing phenomena such as superconductivity and magnetism. Despite tremendous progress in understanding their origins, very little is known about how to control the conduction pathways and the distribution of charge carriers. Using optical spectroscopic measurements and density-functional theory (DFT) simulations, we examine the effect of SrTiO3 (STO) spacer layer thickness on the optical transparency and carrier distribution in La δ-doped STO superlattices. We experimentally observe that these metallic superlattices remain highly transparent to visible light; a direct consequence of the appropriately large gap between the O 2p and Ti 3d …


Nonlocal And Quantum-Tunneling Contributions To Harmonic Generation In Nanostructures: Electron-Cloud-Screening Effects, Michael Scalora, Maria Antonietta Vincenti, Domenico De Ceglia, Joseph W. Haus Jul 2014

Nonlocal And Quantum-Tunneling Contributions To Harmonic Generation In Nanostructures: Electron-Cloud-Screening Effects, Michael Scalora, Maria Antonietta Vincenti, Domenico De Ceglia, Joseph W. Haus

Electrical and Computer Engineering Faculty Publications

Our theoretical examination of second- and third-harmonic generation from metal-based nanostructures predicts that nonlocal and quantum-tunneling phenomena can significantly exceed expectations based solely on local, classical electromagnetism. Mindful that the diameter of typical transition-metal atoms is approximately 3 Å, we adopt a theoretical model that treats nanometer-size features and/or subnanometer-size gaps or spacers by taking into account (i) the limits imposed by atomic size to fulfill the requirements of continuum electrodynamics, (ii) spillage of the nearly free electron cloud into the surrounding vacuum, and (iii) the increased probability of quantum tunneling as objects are placed in close proximity.

Our approach …


Effect Of Z1/2, Eh5, And Ci1 Deep Defects On The Performance Of N-Type 4h-Sic Epitaxial Layers Schottky Detectors: Alpha Spectroscopy And Deep Level Transient Spectroscopy Studies, M. A. Mannan, S. K. Chaudhuri, K. V. Nguyen, K. C. Mandal Jun 2014

Effect Of Z1/2, Eh5, And Ci1 Deep Defects On The Performance Of N-Type 4h-Sic Epitaxial Layers Schottky Detectors: Alpha Spectroscopy And Deep Level Transient Spectroscopy Studies, M. A. Mannan, S. K. Chaudhuri, K. V. Nguyen, K. C. Mandal

Faculty Publications

No abstract provided.


Copper Doping Of Zno Crystals By Transmutation Of 64Zn To 65Cu: An Electron Paramagnetic Resonance And Gamma Spectroscopy Study, Matthew C. Recker, John W. Mcclory, Maurio S. Holston, Eric M. Golden, Nancy C. Giles, Larry E. Halliburton Jun 2014

Copper Doping Of Zno Crystals By Transmutation Of 64Zn To 65Cu: An Electron Paramagnetic Resonance And Gamma Spectroscopy Study, Matthew C. Recker, John W. Mcclory, Maurio S. Holston, Eric M. Golden, Nancy C. Giles, Larry E. Halliburton

Faculty Publications

Transmutation of 64Zn to 65Cu has been observed in a ZnO crystal irradiated with neutrons. The crystal was characterized with electron paramagnetic resonance (EPR) before and after the irradiation and with gamma spectroscopy after the irradiation. Major features in the gamma spectrum of the neutron-irradiated crystal included the primary 1115.5 keV gamma ray from the 65Zn decay and the positron annihilation peak at 511 keV. Their presence confirmed the successful transmutation of 64Zn nuclei to 65Cu. Additional direct evidence for transmutation was obtained from the EPR of Cu2+ ions (where 63Cu and 65 …


Ferromagnetic Resonance Study Of Eightfold Artificial Ferromagnetic Quasicrystals, Vinayak Shantaram Bhat, J. Sklenar, J. Woods, B. Farmer, J. B. Ketterson, Jeffrey Todd Hastings, Lance E. De Long May 2014

Ferromagnetic Resonance Study Of Eightfold Artificial Ferromagnetic Quasicrystals, Vinayak Shantaram Bhat, J. Sklenar, J. Woods, B. Farmer, J. B. Ketterson, Jeffrey Todd Hastings, Lance E. De Long

Physics and Astronomy Faculty Publications

We have performed broadband (10 MHz–18 GHz) and narrowband (9.7 GHz) ferromagnetic resonance (FMR) measurements on permalloy thin films patterned with quasiperiodic Ammann tilings having eightfold rotational symmetry. We observed highly reproducible mode structures in the low-frequency, hysteretic regime in which domain walls and unsaturated magnetization textures exist. A minimum of 10 robust modes were observed in patterned samples, compared to the single uniform mode observed in unpatterned permalloy films. The field dependence and approximate eightfold rotational symmetry of the FMR spectra are in good agreement with micromagnetic simulations that confirm the importance of patterning for controlling static and dynamic …


Microfiber Coupler Based Label-Free Immunosensor, Lin Bo, Christy Charlton O'Mahony, Yuliya Semenova, Niamh Gilmartin, Pengfei Wang, Gerald Farrell Apr 2014

Microfiber Coupler Based Label-Free Immunosensor, Lin Bo, Christy Charlton O'Mahony, Yuliya Semenova, Niamh Gilmartin, Pengfei Wang, Gerald Farrell

Articles

Optical microfibers and related structures which incorporate large evanescent field and minimal size offer new opportunities for biosensing applications. In this paper we report the development of an immunosensor based on a tapered microfiber coupler embedded in a low refractive index polymer. Biomolecules adsorbed on the microfiber coupler surface modify the surrounding refractive index. By immobilizing antigens on the surface of the sensing area, the microfiber coupler was able to operate as a label-free immunosensor to detect specific antibodies. We experimentally demonstrated for the first time the sensing ability of this sensor using a fibrinogen antigen-antibody pair. By monitoring the …


Numerical Examination Of The Nonlinear Dynamics Of A Hybrid Acousto-Optic Bragg Cell With Positive Feedback Under Profiled Beam Propagation, Fares S. Almehmadi, Monish Ranjan Chatterjee Apr 2014

Numerical Examination Of The Nonlinear Dynamics Of A Hybrid Acousto-Optic Bragg Cell With Positive Feedback Under Profiled Beam Propagation, Fares S. Almehmadi, Monish Ranjan Chatterjee

Electrical and Computer Engineering Faculty Publications

In standard weak interaction theory, acousto-optic Bragg analysis typically assumes that the incident light and sound beams are uniform plane waves. Acousto-optic Bragg diffraction with nonuniform profiled input beams is numerically examined under open loop via a transfer function formalism. Unexpected deviations in the first-order diffracted beam from the standard theory are observed for high �� values. These deviations are significant because the corresponding closed-loop system is sensitive to input amplitudes and initial conditions, and the overall impact on the dynamical behavior has not been studied previously in standard analyses. To explore the effect of such nonuniform output profiles on …


Multiframe Adaptive Wiener Filter Super-Resolution With Jpeg2000-Compressed Images, Barath Narayanan Narayanan, Russell C. Hardie, Eric J. Balster Apr 2014

Multiframe Adaptive Wiener Filter Super-Resolution With Jpeg2000-Compressed Images, Barath Narayanan Narayanan, Russell C. Hardie, Eric J. Balster

Electrical and Computer Engineering Faculty Publications

Historically, Joint Photographic Experts Group 2000 (JPEG2000) image compression and multiframe super-resolution (SR) image processing techniques have evolved separately. In this paper, we propose and compare novel processing architectures for applying multiframe SR with JPEG2000 compression. We propose a modified adaptive Wiener filter (AWF) SR method and study its performance as JPEG2000 is incorporated in different ways. In particular, we perform compression prior to SR and compare this to compression after SR. We also compare both independent-frame compression and difference-frame compression approaches. We find that some of the SR artifacts that result from compression can be reduced by decreasing the …


Numerical Analysis Of First-Order Acousto-Optic Bragg Diffraction Of Profiled Optical Beams Using Open-Loop Transfer Functions, Monish Ranjan Chatterjee, Fares S. Almehmadi Mar 2014

Numerical Analysis Of First-Order Acousto-Optic Bragg Diffraction Of Profiled Optical Beams Using Open-Loop Transfer Functions, Monish Ranjan Chatterjee, Fares S. Almehmadi

Electrical and Computer Engineering Faculty Publications

In standard acousto-optic Bragg analysis, the incident light and sound beams are assumed to be uniform plane waves (with constant profiles) leading to the results based on standard weak interaction theory. As a follow-up to earlier work dealing with nonuniform incident optical beams, we revisit the problem of Bragg diffraction under nonuniform profiles, and include Gaussian, third-order Hermite–Gaussian, and zeroth-order Bessel profiles in our investigation, along with a few others. The first-order diffracted beam is examined (using a transfer function formalism based on angular spectra) under several parametric limits [such as the Klein–Cook parameter Q, the effective profile width, and …


Triplet Ground State Of The Neutral Oxygen-Vacancy Donor In Rutile Tio2, A. T. Brant, Eric M. Golden, Nancy C. Giles, Shan Yang, M. A. R. Sarker, S. Watauchi, M. Nagao, I. Tanaka, D. A. Tryk, A. Manivannan, Larry E. Halliburton Mar 2014

Triplet Ground State Of The Neutral Oxygen-Vacancy Donor In Rutile Tio2, A. T. Brant, Eric M. Golden, Nancy C. Giles, Shan Yang, M. A. R. Sarker, S. Watauchi, M. Nagao, I. Tanaka, D. A. Tryk, A. Manivannan, Larry E. Halliburton

Faculty Publications

Electron paramagnetic resonance (EPR) is used to investigate the triplet (S = 1) ground state of the neutral oxygen vacancy in bulk rutile TiO2 crystals. This shallow donor consists of an oxygen vacancy with two nearest-neighbor, exchange-coupled 3+ ions located along the [001] direction and equidistant from the vacancy. The spins of the two trapped electrons, one at each 3+ ion, align parallel to give the S = 1 state. These neutral oxygen vacancies are formed near 25 K in as-grown oxidized TiO2 crystals by illuminating with sub-band-gap 442 nm laser light. The angular dependence of the EPR …


Neutral Nitrogen Acceptors In Zno: The 67Zn Hyperfine Interactions, Eric M. Golden, S. M. Evans, Larry E. Halliburton, Nancy C. Giles Mar 2014

Neutral Nitrogen Acceptors In Zno: The 67Zn Hyperfine Interactions, Eric M. Golden, S. M. Evans, Larry E. Halliburton, Nancy C. Giles

Faculty Publications

Electron paramagnetic resonance (EPR) is used to characterize the 67Zn hyperfine interactions associated with neutral nitrogen acceptors in zinc oxide. Data are obtained from an n-type bulk crystal grown by the seeded chemical vapor transport method. Singly ionized nitrogen acceptors (N) initially present in the crystal are converted to their paramagnetic neutral charge state (N0) during exposure at low temperature to 442 or 633 nm laser light. The EPR signals from these N0 acceptors are best observed near 5 K. Nitrogen substitutes for oxygen ions and has four nearest-neighbor cations. The zinc ion …


Tunneling Into The Mott Insulator Sr2Iro4, John A. Nichols, Noah Bray-Ali, Armin Ansary, Gang Cao, Kwok-Wai Ng Feb 2014

Tunneling Into The Mott Insulator Sr2Iro4, John A. Nichols, Noah Bray-Ali, Armin Ansary, Gang Cao, Kwok-Wai Ng

Center for Advanced Materials Faculty Publications

We studied the single-layered iridate Sr2IrO4 with a scanning tunneling microscope. The finite low temperature conductance enables the electronic structure of this antiferromagnetic Mott insulator to be measured by tunneling spectroscopy. We imaged the topography of freshly cleaved surfaces and measured differential tunneling conductance at cryogenic temperatures. We found the Mott gap in the tunneling density of states to be 2Δ=615 meV. Within the Mott gap, additional shoulders are observed which are interpreted as inelastic loss features due to magnons.


In-Package Nonthermal Plasma Degradation Of Pesticides On Fresh Produce, N. Misra, Shashi Pankaj, Tony Walsh, Finbarr O'Regan, Paula Bourke, Patrick Cullen Feb 2014

In-Package Nonthermal Plasma Degradation Of Pesticides On Fresh Produce, N. Misra, Shashi Pankaj, Tony Walsh, Finbarr O'Regan, Paula Bourke, Patrick Cullen

Articles

In-package nonthermal plasma (NTP) technology is a novel technology for the decontamination of foods and biological materials. This study presents the first report on the potential of the technology for the degradation of pesticide residues. A cocktail of pesticides, namely Azoxystrobin, Cyprodinil, Fludioxonil and Pyriproxyfen was tested on strawberries. The concentrations of these pesticides were monitored in priori and post- plasma treatment using GC-MS/MS. An applied voltage and time dependent degradation of the pesticides was observed for treatment voltages of 60, 70 and 80 kV and treatment durations ranging from 1 to 5 min, followed by 24 h in-pack storage. …