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Articles 1 - 11 of 11
Full-Text Articles in Physics
Three-Body Analytical Potential For Interacting Helium Atoms, Carol A. Parish, Clifford E. Dykstra
Three-Body Analytical Potential For Interacting Helium Atoms, Carol A. Parish, Clifford E. Dykstra
Chemistry Faculty Publications
Large basis set ab initio calculations have been carried out for a dense grid of points on the He, potential energy surface. Three-body contributions were extracted at every point, and a number of concise functional representations for the three-body potential surface were then examined. Three-body multipolar dispersion terms and other radial and angular terms were used in the representations, and an assessment of relative importance of the different terms is presented. Combined with a two-body He-He potential, the results of this work should offer a high quality interaction potential for simulations of aggregated helium.
A Magnetic, Neutron Diffraction, And Mössbauer Spectral Study Of The Nd₂Fe₁₇₋ₓalₓ Solid Solutions, Gary J. Long, Gaya Kanishka Marasinghe, Sanjay R. Mishra, Oran Allan Pringle, Zhongbo Hu, William B. Yelon, D. P. Middleton, K. H. J. Buschow, Fernande Grandjean
A Magnetic, Neutron Diffraction, And Mössbauer Spectral Study Of The Nd₂Fe₁₇₋ₓalₓ Solid Solutions, Gary J. Long, Gaya Kanishka Marasinghe, Sanjay R. Mishra, Oran Allan Pringle, Zhongbo Hu, William B. Yelon, D. P. Middleton, K. H. J. Buschow, Fernande Grandjean
Chemistry Faculty Research & Creative Works
The magnetic properties of a series of Nd2Fe17-xAlx solid solutions, with x equal to 2.04, 4.01, 5.97, 7.94, and 9.06, have been studied by magnetic measurements, neutron diffraction, and Mössbauer spectroscopy. Magnetization studies indicate that the Curie temperature increases from 330 K in Nd2Fe17 to a maximum of ~470 K at an x of 3.5. The compounds crystallize in the Th2Zn17 structure with lattice parameters and unit cell volumes which increase linearly with increasing aluminum content. The neutron diffraction results indicate that aluminum atoms are excluded from the 9d …
Neutron Diffraction And Mössbauer Effect Study Of Several Nd₂Fe₁₇₋ₓalₓ Solid Solutions, William B. Yelon, H. Xie, Gary J. Long, Oran Allan Pringle, Fernande Grandjean, K. H. J. Buschow
Neutron Diffraction And Mössbauer Effect Study Of Several Nd₂Fe₁₇₋ₓalₓ Solid Solutions, William B. Yelon, H. Xie, Gary J. Long, Oran Allan Pringle, Fernande Grandjean, K. H. J. Buschow
Physics Faculty Research & Creative Works
Aluminum-substituted Nd2Fe17-xAlx solid solutions with x=2.30, 4.44, 6.13, 8.00, and 9.40 have been studied by neutron diffraction and Mössbauer spectroscopy. A Rietveld analysis of the neutron scattering indicates that the aluminum atoms have a high initial affinity for the 18h site, show a high affinity for the 6c site at high aluminum concentrations, and are absent from the 9d site at all aluminum concentrations. The Mössbauer spectra show a maximum in both the maximum and weighted average hyperfine field for x≅2. This indicates that the lattice expansion which occurs with aluminum substitution is sufficient, at …
Neutron-Diffraction And Mössbauer Effect Study Of The Tb₂Fe₁₇₋ₓalₓ Solid Solutions, Gaya Kanishka Marasinghe, Sanjay R. Mishra, Oran Allan Pringle, Gary J. Long, Zhong Bo Hu, William B. Yelon, Fernande Grandjean, D. P. Middleton, K. H. J. Buschow
Neutron-Diffraction And Mössbauer Effect Study Of The Tb₂Fe₁₇₋ₓalₓ Solid Solutions, Gaya Kanishka Marasinghe, Sanjay R. Mishra, Oran Allan Pringle, Gary J. Long, Zhong Bo Hu, William B. Yelon, Fernande Grandjean, D. P. Middleton, K. H. J. Buschow
Physics Faculty Research & Creative Works
The magnetic properties of a series of Tb2Fe17-xAlx solid solutions, with nominal x compositions of 0, 2, 3, 4, 5, 6, 7, and 8, have been studied by neutron diffraction and Mössbauer spectroscopy. Neutron-diffraction data indicate that the compounds all crystallize with the Th2Zn17 structure and that the aluminum atoms are excluded from the 9d site and show a distinct preference for the 6c site only for an aluminum content greater than 6. The unit-cell volume increases by approximately 1% per aluminum atom substituted in the formula unit. The magnetic moment per …
36th Rocky Mountain Conference On Analytical Chemistry
36th Rocky Mountain Conference On Analytical Chemistry
Rocky Mountain Conference on Magnetic Resonance
Program, abstracts, and information about the 36th annual meeting of the Rocky Mountain Conference on Analytical Chemistry, co-sponsored by the Colorado Section of the American Chemical Society and the Rocky Mountain Section of the Society for Applied Spectroscopy. Held in Denver, Colorado, July 31 - August 5, 1994.
Surface-Induced Ordering In Asymmetric Block Copolymers, Y. Liu, W. Zhao, X. Zheng, Alexander H. King, A. Sing, M. H. Rafailovich, J. Sokolov, K. H. Dai, E. J. Kramer, S. A. Schwarz, O. Gebizlioglu, S. K. Sinha
Surface-Induced Ordering In Asymmetric Block Copolymers, Y. Liu, W. Zhao, X. Zheng, Alexander H. King, A. Sing, M. H. Rafailovich, J. Sokolov, K. H. Dai, E. J. Kramer, S. A. Schwarz, O. Gebizlioglu, S. K. Sinha
Alexander H. King
The surface-induced ordering in thin films of asymmetric deuterated polystyrene (dPS)- poly(viny1pyridine) (PVP) diblock and triblock copolymers of comparable polymerization index and PVP volume fraction - 0.25) was studied using transmission electron microscopy, atomic force microscopy, secondary ion massspectrometry, and neutron reflectivity. The morphology of both di- and triblock copolymer films was found to be cylindrical except for the layer adjacent to the silicon oxide surface, which due to the strong interaction of silica with PVP, was lamellar. The spacing between adjacent cylindrical layers was found to be consistent with mean field theory predictions. In the triblock copolymer films the …
A Magnetic, Neutron Diffraction, And Mössbauer Spectral Study Of Nd₂Fe₁₅Ga₂ And The Tb₂Fe₁₇₋ₓgaₓ Solid Solutions, Zhong Bo Hu, William B. Yelon, Sanjay R. Mishra, Gary J. Long, Oran Allan Pringle, D. P. Middleton, K. H. J. Buschow, Fernande Grandjean
A Magnetic, Neutron Diffraction, And Mössbauer Spectral Study Of Nd₂Fe₁₅Ga₂ And The Tb₂Fe₁₇₋ₓgaₓ Solid Solutions, Zhong Bo Hu, William B. Yelon, Sanjay R. Mishra, Gary J. Long, Oran Allan Pringle, D. P. Middleton, K. H. J. Buschow, Fernande Grandjean
Physics Faculty Research & Creative Works
An x-ray diffraction study of the substitution of gallium in Tb 2Fe17 to form the Tb2Fe17-xGax solid solutions indicates that the compounds adopt the rhombohedral Th2Zn17 structure. The unit cell volume and the a-axis lattice parameter increase linearly with increasing gallium content. The c-axis lattice parameter increases linearly from x=0 to 6 and then decreases between x=7 and 8. Magnetic studies show the Curie temperature increases by ~150° above that of Tb2Fe17 to reach a maximum between x=3 and 4, and then decreases with further increases in …
Comparative Mössbauer Effect Study Of Several R₂Fe₁₇ And R₂Fe₁₇Nₓ Compounds, Gary J. Long, Sanjay R. Mishra, Oran Allan Pringle, Fernande Grandjean, K. H. Buschow
Comparative Mössbauer Effect Study Of Several R₂Fe₁₇ And R₂Fe₁₇Nₓ Compounds, Gary J. Long, Sanjay R. Mishra, Oran Allan Pringle, Fernande Grandjean, K. H. Buschow
Chemistry Faculty Research & Creative Works
The Mössbauer spectra of Sm2Fe17 and Ho 2Fe17 and their nitrides have been measured between 295 and 85 K and analyzed with a model which is consistent with our earlier work on R2Fe17 and R2Fe17Nx compounds, where R is Pr, Nd, and Th. This model is completely consistent throughout these rare-earth compounds and is in agreement with the crystallographic changes occurring upon nitrogenation and with the prediction of band structure calculations. The dramatic increase in Curie temperature in the nitrides results from the expansion of the crystallographic …
Structure And Phase Transition Of The 6,5-Annulene Isomer Of C_{61}H_{2}, Andrea N. Lommen, Paul A. Heiney, Gavin B. M. Vaughan, Peter W. Stephens, Dengfa Liu, Dayin Li, Allan L. Smith, Andrew R. Mcghie, Robert M. Strongin, Laurent Brard, Amos B. Smith Iii
Structure And Phase Transition Of The 6,5-Annulene Isomer Of C_{61}H_{2}, Andrea N. Lommen, Paul A. Heiney, Gavin B. M. Vaughan, Peter W. Stephens, Dengfa Liu, Dayin Li, Allan L. Smith, Andrew R. Mcghie, Robert M. Strongin, Laurent Brard, Amos B. Smith Iii
Chemistry Faculty Publications and Presentations
We have used differential scanning calorimetry and x-ray diffraction to study the crystalline phases of the 6,5-annulene isomer of C61H2. At 308 K the methylenated fullerenes are orientationally disordered in a face-centered cubic lattice with lattice parameter 14.19±0.02 Å. Below Tc=290 K the symmetry is lowered to Pa3¯, a simple-cubic structure. At 20 K the lattice parameter is 14.06±0.02 Å, with substantial statistical disorder remaining. The transition temperature in C61H2 is slightly higher than in C60O and higher still than in C60, but the three compounds exhibit orientationally …
A Mössbauer Effect Study Of The Microscopic Magnetic Properties Of Th₂Fe₁₇ And Its Nitride, Th₂Fe₁₇N₂.₆, Gary J. Long, Oran Allan Pringle, Fernande Grandjean, T. H. Jacobs, K. H. Buschow
A Mössbauer Effect Study Of The Microscopic Magnetic Properties Of Th₂Fe₁₇ And Its Nitride, Th₂Fe₁₇N₂.₆, Gary J. Long, Oran Allan Pringle, Fernande Grandjean, T. H. Jacobs, K. H. Buschow
Chemistry Faculty Research & Creative Works
The Mössbauer spectra of Th2Fe17 and Th2Fe17N2.6 have been measured at various temperatures between 85 and 295 K and analyzed with a model that is based on the Wigner-Seitz cell environment of each iron site, the orientation of the magnetization, and the magnetic moments as determined from either neutron-diffraction measurements or band-structure calculations. Upon nitrogenation of Th2Fe17, the 85 K weighted average isomer shift increases from 0.037 to 0.156 mm/s and further the isomer shifts of the four crystallographically distinct sites increase in agreement with the increase observed …
Determination Of Plasma Parameters In A Dc Arcjet Diamond Reactor: Part 1, Scott Reeve, Wayne Weimer
Determination Of Plasma Parameters In A Dc Arcjet Diamond Reactor: Part 1, Scott Reeve, Wayne Weimer
Scott Reeve
No abstract provided.