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Full-Text Articles in Physics

The Weakest Bond: Experimental Observation Of Helium Dimer, Fei Luo, George C. Mcbane, Geunsik Kim, Clayton F. Giese, W. Ronald Gentry Dec 1992

The Weakest Bond: Experimental Observation Of Helium Dimer, Fei Luo, George C. Mcbane, Geunsik Kim, Clayton F. Giese, W. Ronald Gentry

Peer Reviewed Articles

Helium dimer ion was observed after electron impact ionization of a supersonic expansion of helium with translational temperature near 1 mK. The dependence of the ion signal on source pressure, distance from the source, and electron kinetic energy was measured. The signal was determined to arise from ionization of neutral helium dimer.


Angular Distributions For Near-Threshold (E,2E) Processes For H, He, And Other Rare-Gas Targets, Cheng Pan, Anthony F. Starace Apr 1992

Angular Distributions For Near-Threshold (E,2E) Processes For H, He, And Other Rare-Gas Targets, Cheng Pan, Anthony F. Starace

Anthony F. Starace Publications

Distorted-wave calculations of the triply differential cross sections for electron-impact ionization of H, He, Ne, Ar, Kr, and Xe are presented for final-state electrons sharing ≤4 eV excess energy and for the coplanar, θ12=π geometry. Results for H and He targets, presented briefly elsewhere [C. Pan and A. F. Starace, Phys. Rev. Lett. 67, 185 (1991)], are analyzed in greater detail and compared with available experimental and other theoretical results. In particular, for He targets the effects of exchange and of second-order capture processes are exhibited. These are shown to be of lesser importance than other short-range effects …


A Theoretical Investigation Of The Ground And Low‐Lying Excited States Of Butadiene Radical Cation, Robert J. Cave, Michael G. Perrott '90 Mar 1992

A Theoretical Investigation Of The Ground And Low‐Lying Excited States Of Butadiene Radical Cation, Robert J. Cave, Michael G. Perrott '90

All HMC Faculty Publications and Research

Results are presented from ab initio calculations on the ground and several low‐lying excited states of the butadiene radical cation. In particular, we have calculated geometries for the ground and several excited states at the multiconfiguration self‐consistent field level and characterized the planar stationary points. The vertical ionization potentials from the neutral molecule ground state and vertical excitation energies at the computed equilibrium geometry of the cation were also examined. A variety of methods were tested for the calculation of ionization potentials and excitation energies, including multiconfiguration self‐consistent field, multireference singles and doubles configuration interaction (with and without size‐consistency correction), …