Physics Commons^™

Photoluminescence Study Of Gan Implanted With Erbium And Erbium-Oxygen, Lori R. Everitt

Theses and Dissertations

Erbium emits at 1540 nm, which propagates well through fiber optic cables. This work studies the photoluminescence (PL) from GaN, GaN implanted with Er alone, and GaN implanted with both Er and O as functions of excitation laser energy and sample temperature. When the exciton bound to a neutral donor recombined, a photon was emitted at 3.47 eV. A photon emitted at 3.457 eV may have been evidence of the recombination of an exciton bound to a neutral acceptor. Second, the Er-ion transitions were observed in two groups around 0.805 and 1.25 eV. The PL intensity was measured at four …

Collisional Broadening Of Spectral Lines In The X → B System Of O2 And The First Vibrational Band Of No By The Noble Gases, John J. Cornicelli

Theses and Dissertations

Collisional broadening of the rotational spectral lines of the X to b system of O₂ and the first vibrational band of NO by the noble gases is examined by Fourier transform spectroscopy. Peaks of the individual rotational lines are modeled with a Voigt function, from which Lorentzian half widths are extracted. Lorentzian widths are plotted vs. pressure of foreign gas, from which the pressure broadening coefficients and pressure broadening cross sections are calculated. The pressure broadening coefficients are compared to theoretical values determined by past research for O₂. NO coefficients are compared to similar research using N …

Time Resolved Photoluminescence Spectra Of A Mid-Infrared Multiple Quantum Well Semiconductor Laser, Anthony L. Franz

Theses and Dissertations

Recombination mechanisms in mid-IR semiconductor lasers are strongly dependent on the carrier density of the active region. The objective of this research is to improve previous carrier density estimates through the incorporation of spectral information. One hundred photoluminescence (PL) spectra were calculated for a variety of carrier densities. Calculations were made for an InAsSb/InAlAsSb multiple quantum well laser sample assuming parabolic bands. The widths of the calculated spectral profiles were tabulated as a function of carrier density. Actual spectra were measured using the Ultrafast Mid-Infrared Photoluminescence System, which uses upconversion to measure the PL intensity in time steps smaller than …

Reactive Quantum Scattering In Two Dimensions, Roy S. Calfas

Theses and Dissertations

In an effort to develop a more efficient time dependent approach for calculating scattering matrix elements, absorbing boundary conditions are combined together with the channel packet method. As an introduction to scattering, scattering matrix elements are presented for a one-dimensional square well and a one-dimensional potential consisting of a Gaussian well with symmetric Gaussian barriers. Next, the combination of the channel packet method together with absorbing boundary conditions yields an order of magnitude savings in the time necessary to compute the correlation function for the collinear H+H

Hybrid Quantum And Molecular Mechanics Embedded Cluster Models For Chemistry On Silicon And Silicon Carbide Surfaces, James R. Shoemaker

Theses and Dissertations

Fabrication of silicon carbide SiC semiconductor devices are of interest for aerospace applications because of their high-temperature tolerance. Growth of an insulating SiO₂ layer on SiC is a poorly understood process, and sometimes produces interface defects that degrade device performance. Accurate theoretical models of surface chemistry, using quantum mechanics QM, do not exist because of the huge computational cost of solving Schroedingers equation for a molecular cluster large enough to represent a surface. Molecular mechanics MM, which describes a molecule as a collection of atoms interacting through classical potentials, is a fast computational method, good at predicting molecular structure, …

Kinetics And Spectroscopy Of Brno, Patrick E. Godfrey

Theses and Dissertations

The infrared spectra and photochemistry of nitrosyl bromide, BrNO, are important to characterizing the performance of a recently demonstrated Br(²P_1/2)-NO(v=2 → v=1) transfer laser pumped by photolysis of iodine molecules. This wavelength agile, mid-infrared laser may be a desirable source for remote sensing and infrared countermeasures missions. Nitrosyl bromide also plays a role in the destruction of stratospheric ozone. The kinetics of BrNO formation and destruction were examined using time-resolved photolysis techniques. The equilibrium constant for the dark reaction Br₂ + 2NO (reversible reaction) 2BrNO was determined as K_eq 168 ± 23 /atm and …

Angle-Resolved Study Of Ar 2p₁/₂,₃/₂⁻1Ns,D Resonant Auger Decay, Marc Andrew Humphrey

Honors Theses

Angle-resolved measurements of the Ar 2p_1/2,3/2^-14s,3d,4d and 2p_3/2^-14s,3d,4d resonant Auger transitions have been carried out using photons from an undulator beamline at the Advanced Light Source of Lawrence Berkeley National Laboratory. The intensity distributions and angular distribution anisotropy (β) parameters have been reported for nearly all of the possible 3p⁴nl final ionic states. These results further verify the predictions of the spectator model for the 2p_1/2,3/2^-14s resonances and the subsequent breakdown of this model for the 2p_1/2,3/2^-13d and 2p_1/2,3/2^-14d relative intensities. This work …

Collision-Induced Secondary Electron And Negative Ion Emission From Metallic Surfaces, John Christopher Tucek

Dissertations, Theses, and Masters Projects

Absolute yields of negative ions and secondary electrons resulting from collisions of positive sodium ions (Na{dollar}\sp{lcub}+{rcub}){dollar} with polycrystalline aluminum (Al) and molybdenum (Mo) surfaces and the Mo (100) surface have been measured as a function of the oxygen (O) coverage, from none up to several monolayers, for impact energies, E {dollar}<{dollar} 500 eV. Negative oxygen ions (O{dollar}\sp{lcub}-{rcub}){dollar} are found to be the dominant sputtered negative ions and for the three surfaces at all O coverages and Na{dollar}\sp{lcub}+{rcub}{dollar} impact energies. The O{dollar}\sp{lcub}-{rcub}{dollar} and secondary electron yields share a common impact energy threshold at {dollar}\rm E\sb{lcub}th{rcub}\approx 50{dollar} eV, and both have a strong dependence on the oxygen coverage of the surface.;The kinetic energy distributions of the secondary electrons and sputtered O{dollar}\sp{lcub}-{rcub}{dollar} were determined as functions of O coverages and impact energies. The O{dollar}\sp{lcub}-{rcub}{dollar} distributions are characterized by a narrow, low energy peak (at {dollar}\sim{dollar}1-2 eV) followed by a low level, high energy tail. The secondary electrons have a narrow (FWHM {dollar}\sim{dollar} 1-2 eV) kinetic energy distribution, centered essentially at the same most probable kinetic energy as the ions. The shapes of the respective distributions and the most probable kinetic energies are essentially invariant with the impact energy, O coverage and the metal surface.;The results were analyzed in terms of conventional collision cascade model, but the calculation could not be fitted to the experimental results. An electronic excitation mechanism is proposed to augment the collision cascade and to provide a mechanism for secondary electron emission. In the model, adsorbed O, which resides on the surface essentially as O{dollar}\sp{lcub}-{rcub},{dollar} is collisionally excited into an (MO{dollar}\sp{lcub}-{rcub})\sp*{dollar} repulsive state, and as the O{dollar}\sp{lcub}-{rcub}{dollar} exits the surface along the surface potential energy curve, it can decay by emission of an electron to the metal or to the vacuum, or it can survive as an ion. The parameters of this model can be adjusted such that the calculated kinetic energy distribution, together with that of the collision cascade, can reasonably reproduce the experimental observations for the ions and provide a reasonable fit to the corresponding electron kinetic energy distributions as well.

Characterization Of Iron Oxides And Atmospheric Corrosion Of Steel, Sei Jin Oh

Physics Theses & Dissertations

The study of corrosion behavior was performed using three different analytical techniques, which provided information on the formation, development and layering of iron oxides on the corrosion products as a function of atmospheric conditions, exposure time and type of steel. In particular, the protective layer formed on weathering steel was investigated as a function of different amounts of alloying elements in the steel, atmospheric conditions and exposure times. Combined together, the results provided a better understanding of the atmospheric corrosion behavior of steel, and formed a part of database of the atmospheric corrosion characteristics.

Accurate characterization of the iron oxides …