Water Resource Management Commons^™

Comparing Hydrogen Peroxide And Sodium Perborate Ultraviolet Advanced Oxidation Processes For 1,4-Dioxane Removal From Wastewater Effluent, Tulsi Shukla

Electronic Theses and Dissertations, 2020-2023

Ultraviolet advanced oxidation processes were compared using sodium perborate (UV/NaBO3 AOP) or hydrogen peroxide (UV/H2O2 AOP) for 1,4-dioxane removal from tertiary wastewater effluent. Both UV/H2O2 and UV/NaBO3 AOPs were also tested with the addition of acetic acid. Results revealed that sodium perborate performed similarly to hydrogen peroxide – the UV/NaBO3 AOP with 6 milligrams per liter (mg/L) as H2O2 resulted in 43.9 percent 1,4-dioxane removal, while an equivalent UV/H2O2 AOP showed 42.8 percent removal. Although the oxidants performed similarly, NaBO3 is an average of 3.3 times more expensive than H2O2. However, the solid form of NaBO3 can provide a major …

Exploring A Lab-Scale Cascade Upflow Bioreactor System For Nitrogen Removal Via Biosorption Activated Media, Alejandra Robles Lecompte

Graduate Thesis and Dissertation 2023-2024

Many Best Management Practices (BMPs) have been developed to reduce excessive nutrients in stormwater runoff and mitigate harmful algal blooms in downstream receiving water bodies. This study demonstrates a new BMP by comparing two green sorption media (i.e., specialty adsorbents) for nutrient removal in cascade upflow biofiltration systems operated in parallel. The proposed filtration technology can control hydraulic gradients, prevent clogging and settlements, and increase hydraulic loading while removing more nutrients in an integrated physicochemical and microbiological treatment process. The two green sorption media being tested in this study include zero-valent-iron and perlite-based green sorption media (ZIPGEM) and biochar, iron, …

Comparing Phosphorus Removal Efficiencies And Mechanisms Via Two Cost-Effective Specialty Adsorbents In A Cascade Upflow Filtration System, Sydney Kilgus-Vesely

Honors Undergraduate Theses

Finding solutions to treat water that contains phosphorus is an important effort due to the harmful impacts it presents to both human health and the environment. Phosphorus is considered a limiting factor in water oftentimes and therefore controls the growth of algal bloom in a water body. The increase of algal populations due to wastewater effluent, stormwater runoff, and agricultural discharge in Florida waters has a direct link to the event of harmful algal blooms such as red tide in coastal regions, eutrophication of waterbodies, and fish kills. Finding low cost, energy efficient, and low maintenance green sorption media (GSM) …

Developing Cost-Effective Specialty Adsorbents To Meet The Emerging Challenges Of Pollutant Removal In Surface Water Systems, Diana Ordonez

Electronic Theses and Dissertations, 2020-2023

The production of clean water is emphasized under the United Nations goals for sustainable development (SDGs), enlightening the acute need of developing new sustainable technologies in all disciplines. SDGs have urged all engineers in the 21st century to mitigate pollution of drinking water sources and prevent all receiving waterbodies from the impact of agriculture discharge, wastewater effluent, and stormwater runoff. Current water matrix constituents of concern include traditional pollutants (i.e., total nitrogen and total phosphate), natural organic matters (i.e., total organic carbon (TOC), tannic acid), heavy metals (i.e., copper, calcium), and harmful algae toxins (i.e., microcystin), as well as contaminants …

Low-Head Dams (Aka Drowning Machines) Are Deadly: An Analysis Of Liability For Landowners And States, And Recommendations For Legislation And Warning Signs, Forrest R. Hansen, Rollin H. Hotchkiss

Kentucky Journal of Equine, Agriculture, & Natural Resources Law

No abstract provided.

Bench- And Pilot-Scale Corrosion Control Inhibitor Effectiveness Studies For A Community's Blended Surficial And Brackish Groundwater Supply, Paula Campesino

Electronic Theses and Dissertations, 2020-2023

The United States Environmental Protection Agency regulates the lead and copper content of a public water system's finished water at the consumer's tap, through the Safe Drinking Water Act's Lead and Copper Rule (LCR), promulgated in 1991. This rule was recently changed through the LCR Revisions (LCRR), that took effect in 2021. The more stringent requirements of the LCRR motivated the City of Sarasota, Florida (City), to work with the University of Central Florida (UCF) on a study of the municipality's finished water corrosivity. Initially, this evaluation investigated the City's existing finished water corrosivity using linear polarization resistance (LPR) measurements …

Electron Beam Treatment For The Removal Of 1,4-Dioxane In Water And Wastewater, Robert Pearce, Xi Li, John Vennekate, Gianluigi Ciovati, Charles Bott

Electrical & Computer Engineering Faculty Publications

Electron beam (e-beam) treatment uses accelerated electrons to form oxidizing and reducing radicals when applied to water without the use of external chemicals. In this study, electron beam treatment was used to degrade 1,4-dioxane in several water matrices. Removal improved in the progressively cleaner water matrices and removals as high as 94% to 99% were observed at a dose of 2.3 kGy in secondary effluent. 1,4-dioxane removal was confirmed to be primarily through hydroxyl radical oxidation. The calculated electrical energy per order was found to be 0.53, 0.26, and 0.08 kWh/m³/order for secondary effluent (Avg. total organic carbon …

Elevation-Distributed Multistage Reverse Osmosis Desalination With Seawater Pumped Storage, Hani E. Elsayed-Ali

Electrical & Computer Engineering Faculty Publications

A seawater reverse osmosis (RO) plant layout based on multistage RO with stages located at different elevations above sea level is described. The plant uses the weight of a seawater column from pumped storage as head pressure for RO (gravity-driven multistage RO) or to supplement high-pressure pumps used in RO (gravity-assisted multistage RO). The use of gravitational force reduces the specific energy for RO compared to using high-pressure pumps. By locating the RO stages at different elevations based on demand sites, the total specific energy consumption for RO and permeate transport to different elevations above sea level is reduced from …

Labile Carbon And Soil Texture Control Nitrogen Transformation In Deep Vadose Zone, Lidong Li, Jordan Shields, Daniel D. Snow, Michael Kaiser, Arindam Malakar

Daugherty Water for Food Global Institute: Faculty Publications

Understanding transient nitrogen (N) storage and transformation in the deep vadose zone is critical for controlling groundwater contamination by nitrate. The occurrence of organic and inorganic forms of carbon (C) and nitrogen and their importance in the deep vadose zone is not well characterized due to difficulty in sampling and the limited number of studies. We sampled and characterized these pools beneath 27 croplands with different vadose zone thicknesses (6–45 m). We measured nitrate and ammonium in different depths for the 27 sites to evaluate inorganic N storage. We measured total Kjeldahl nitrogen (TKN), hot-water extractable organic carbon (EOC), soil …

Impact Of Eastern Redcedar Encroachment On Water Resources In The Nebraska Sandhills, Yaser Kishawi, Aaron R. Mittelstet, Troy E. Gilmore, Dirac Twidwell, Tirthankar Roy, Nawaraj Shrestha

Department of Agricultural and Biological Systems Engineering: Faculty Publications

Worldwide, tree or shrub dominated woodlands have encroached into herbaceous dominated grasslands. While very few studies have evaluated the impact of Eastern Redcedar (redcedar) encroachment on the water budget, none have analyzed the impact on water quality. In this study, we evaluated the impact of redcedar encroachment on the water budget in the Nebraska Sand Hills and how the decreased streamflow would increase nitrate and atrazine concentrations in the Platte River. We calibrated a Soil and Water Assessment Tool (SWAT model) for streamflow, recharge, and evapotranspiration. Using a moving window with a dilate morphological filter, encroachment scenarios of 11.9%, 16.1%, …

Winter Dynamics Of Storm Water Management Ponds And Winter Tolerance In Three Aquatic Plant Species, Patrick Strzalkowski

Theses and Dissertations (Comprehensive)

The vast majority of the research into the performance of stormwater management ponds (SWMPs) has been performed in warm regions or during the warmer seasons in temperate regions. It is presumed that SWMPs are inactive in the winter as any potential stormwater is trapped in snow and ice. The main goal of this thesis was to test this presumption and to study the dynamics and performance of three SWMPs during the winter. Remote water level loggers were installed into the three SWMPs and daily grab samples from the influents and effluents were taken and analyzed for total phosphorus (TP), chloride, …

Ex-Ante Cost-Benefit Analysis Of High-End And Low-Cost Wireless Sensor Network (Wsn) Technology Packages For Efficient Irrigation Water Management In The Philippines, Marielle Q. Aringo, Victor B. Ella, Camille G. Martinez, Gamiello S. Pereira

Journal of Economics, Management and Agricultural Development

Four wireless sensor network (WSN) technology packages developed for efficient irrigation water management in the Philippines were subjected to ex-ante cost-benefit analysis (CBA) to assess their financial viability. The WSN technologies include high-end and low-cost wireless sensors for upland crop production with drip irrigation system and lowland crop production with alternate wetting and drying (AWD). Results showed that the high-end WSN technology packages are only viable for high-value crops such as red onion, bell pepper, and hot pepper. The low-cost WSN technology packages are viable for all selected crops except sweet corn. Minimum areas were also generated for each crop …

Earlier Snowmelt May Lead To Late Season Declines In Plant Productivity And Carbon Sequestration In Arctic Tundra Ecosystems, Donatella Zona, Peter M. Lafleur, Koen Hufkens, Barbara Bailey, Beniamino Gioli, George Burba, Jordan P. Goodrich, Anna K. Liljedahl, Eugénie S. Euskirchen, Jennifer D. Watts, Mary Farina, John S. Kimball, Martin Heimann, Mathias Göckede, Martijn Pallandt, Torben R. Christensen, Mikhail Mastepanov, Efrén López-Blanco, Marcin Jackowicz-Korczynski, Albertus J. Dolman, Luca Belelli Marchesini, Roisin Commane, Steven C. Wofsy, Charles E. Miller, David A. Lipson, Josh Hashemi, Kyle A. Arndt, Lars Kutzbach, David Holl, Julia Boike, Christian Wille, Torsten Sachs, Aram Kalhori, Xia Song

Daugherty Water for Food Global Institute: Faculty Publications

Arctic warming is affecting snow cover and soil hydrology, with consequences for carbon sequestration in tundra ecosystems. The scarcity of observations in the Arctic has limited our understanding of the impact of covarying environmental drivers on the carbon balance of tundra ecosystems. In this study, we address some of these uncertainties through a novel record of 119 site-years of summer data from eddy covariance towers representing dominant tundra vegetation types located on continuous permafrost in the Arctic. Here we found that earlier snowmelt was associated with more tundra net CO2 sequestration and higher gross primary productivity (GPP) only in June …

Sulfonated Styrene Grafted Sebs/Abs Made By Additive Manufacturing For Ion Exchange Applications, Avianna Elaine Gallegos

Open Access Theses & Dissertations

An interpenetrating polymer network (IPN) for cation exchange applications was synthesized from a blend of styrene-ethylene/butylene-styrene (SEBS) and acrylonitrile butadiene styrene (ABS), which was 3D printed, grafted with crosslinked polystyrene (PS), and sulfonated. A method for styrene grafting was applied to reduce the damage to polymer phases caused by the sulfonation reaction. Styrene and divinylbenzene monomers were introduced to the IPN and induced with heat treatment to polymerize in situ. The graft copolymerization reaction was enhanced with varying quantities of benzoyl peroxide as a chemical initiator. The samples were subsequently sulfonated with chlorosulfonic acid in dichloroethane and functionalized for ion …

Life Cycle Assessment Of Novel Electrochemical Struvite Recovery In Municipal Wastewater Treatment At The Plant And U.S. Watershed Scales, Karla Morrissey

Graduate Theses and Dissertations

As the supply of phosphorus decreases, nutrient recovery in municipal wastewater treatment has become an important area of research. Recovery methods for phosphorus-containing fertilizers, such as struvite, and other products are currently being developed and assessed for their efficiency and economic feasibility. Potential environmental impacts from nutrient recovery are also being assessed as design for the environment is important, especially with regards to the eutrophying potential of phosphorus in phosphorus-limited freshwater aquatic systems. Life cycle assessment (LCA) is a tool that can be used to estimate potential environmental impacts of a product or service focusing on its entire life cycle. …

Quantifying A 21-Year Surface Water And Groundwater Interaction In A Ridge And Valley Lake Environment Using A Highly Constrained Modeling Approach, Richard T. Bowers Jr.

USF Tampa Graduate Theses and Dissertations

Karst lakes are ubiquitous in ridge terrain settings in limestone aquifer coastal plain environments. In west-central Florida, these lakes are frequently connected to the Upper Floridan aquifer and have unique aquifer recharge characteristics. They have been selectively studied because they commonly have no or very limited surface water discharge and limited drainage areas, have appreciable surface water and groundwater interaction and leak to the deep aquifer. An innovative modeling approach was developed to collectively understand and more precisely quantify this vertical leakage, both from a lake-specific and regional water budget standpoint, for a 21-year study period (2000-2020). A unique, calibrated …

Optimizing Lake Okeechobee Watershed Management And Reservoir Operations For Water Quality Improvement, Osama Mahrous Mossad Tarabih

USF Tampa Graduate Theses and Dissertations

Rivers around the globe have been altered as people have constructed water resources infrastructure to store water for different human needs, causing negative impacts on ecosystem processes and functions. Environmental flows have been introduced to restore deteriorated riverine ecosystems; however, environmental flows have not always been practical or adequate to restore environment conditions in rivers globally. Lake Okeechobee is a large subtropical lake that plays a pivotal role in South Florida water system providing various water demands for the surrounding communities as well as providing crucial services to the ecosystem of South Florida. However, hydrologic alterations and nutrient (phosphorus and …

Population Health Metrics During The Early Stages Of The Covid-19 Pandemic: Correlative Pilot Study, Marie A. Severson, David A. Cassada, Victor C. Huber, Daniel D. Snow, Lisa M. Mcfadden

Nebraska Water Center: Faculty Publications

Background: COVID-19 has caused nearly 1 million deaths in the United States, not to mention job losses, business and school closures, stay-at-home orders, and mask mandates. Many people have suffered increased anxiety and depression since the pandemic began. Not only have mental health symptoms become more prevalent, but alcohol consumption has also increased during this time. Helplines offer important insight into both physical and mental wellness of a population by offering immediate, anonymous, cheap, and accessible resources for health and substance use disorders (SUD) that was unobstructed by many of the mandates of the pandemic. Further, the pandemic also …

Enrofloxacin And Sulfamethoxazole Sorption On Carbonized Leonardite: Kinetics, Isotherms, Influential Effects, And Antibacterial Activity Toward S. Aureus Atcc 25923, Chanat Chokejaroenrat, Chainarong Sakulthaew, Khomson Satchasataporn, Daniel D. Snow, Tarik E. Ali, Mohammed A. Assiri, Apichon Watcharenwong, Saksit Imman, Nopparat Suriyachai, Torpong Kreetachat

Nebraska Water Center: Faculty Publications

Excessive antibiotic use in veterinary applications has resulted in water contamination and potentially poses a serious threat to aquatic environments and human health. The objective of the current study was to quantify carbonized leonardite (cLND) adsorption capabilities to remove sulfamethoxazole (SMX)- and enrofloxacin (ENR)-contaminated water and to determine the microbial activity of ENR residuals on cLND following adsorption. The cLND samples prepared at 450^oC and 850^oC (cLND450 and cLND550, respectively) were evaluated for structural and physical characteristics and adsorption capabilities based on adsorption kinetics and isotherm studies. The low pyrolysis temperature of cLND resulted in a …

Warming Of The Willamette River, 1850–Present: The Effects Of Climate Change And Direct Human Interventions, Stefan Talke, David Jay, Heida Diefenderfer

Civil and Environmental Engineering Faculty Publications and Presentations

Using archival research methods, we found and combined data from multiple sources to produce a unique, 140 year record of daily water temperature (Tw) in the lower Willamette River, Oregon (1881–1890, 1941–present). Additional daily weather and river flow records from the 1850s onwards are used to develop and validate a statistical regression model of Tw for 1850–2020. The model simulates the time-lagged response of Tw to air temperature and river flow, and is calibrated for three distinct time periods: the late 19th, mid 20th, and early 21st centuries. Results show that Tw has trended upwards at ~1.1 °C …

Permafrost Landscape History Shapes Fluvial Chemistry, Ecosystem Carbon Balance, And Potential Trajectories Of Future Change, Scott Zolkos, Suzanne E. Tank, Steven V. Kokelj, Robert G. Striegl, Sarah Shakil, Carolina Voigt, Oliver Sonnentag, William L. Quinton, Edward A.G. Schuur, Donatella Zona, Peter M. Lafleur, Ryan C. Sullivan, Masahito Ueyama, David Billesbach, David Cook, Elyn R. Humphreys, Philip Marsh

Daugherty Water for Food Global Institute: Faculty Publications

Intensifying permafrost thaw alters carbon cycling by mobilizing large amounts of terrestrial substrate into aquatic ecosystems. Yet, few studies have measured aquatic carbon fluxes and constrained drivers of ecosystem carbon balance across heterogeneous Arctic landscapes. Here, we characterized hydrochemical and landscape controls on fluvial carbon cycling, quantified fluvial carbon fluxes, and estimated fluvial contributions to ecosystem carbon balance across 33 watersheds in four ecoregions in the continuous permafrost zone of the western Canadian Arctic: unglaciated uplands, ice-rich moraine, and organic-rich lowlands and till plains. Major ions, stable isotopes, and carbon speciation and fluxes revealed patterns in carbon cycling across ecoregions …

The Effect Of Water Management And Ratoon Rice Cropping On Methane Emissions And Harvest Yield In Arkansas, Marguerita Leavitt

Graduate Theses and Dissertations

Sustainable intensification of rice farming is crucial to meeting human food needs while reducing environmental impacts. Rice produces 8% of all anthropogenic CH4, which is a potent greenhouse gas. CH4 emissions can potentially be reduced by cultivation practices that minimize the number of days the fields are saturated, such as dry-seeding instead of water-seeding and irrigation using the alternate wetting and drying (AWD) technique instead of delayed, continuous flooding (DF). Ratoon cropping, wherein a second crop of rice is grown from the harvested stubble of the first crop, can be used to produce additional yield with minimal labor, but may …

Tree Ring Reconstructions Of Streamflow For The Lower Rio Grande Valley Of Texas, Adedolapo Mutiyat Adeyanju

Theses and Dissertations

The Rio Grande River is a major water source for people living within the USA-Mexico border. The Rio Grande River has its headwaters in the San Juan Mountains in Colorado and the Sierra Madre Occidental in Mexico before flowing into Texas through El-Paso. The water supply issues facing the Lower Rio Grande Basin (LRGB) are extremely complex from international restrictions to severe climate change. The river shares its flow between the U.S.A and Mexico based on the provisions of the 1944 treaty between the U.S.A and Mexico. The LRGB flow is regulated by releases from Falcon and Amistad Reservoirs managed …

Tap Water Disinfection In The Electrochemical Precipitation Process By Using Novel Conductive Concrete, Md Shoriful Islam

Theses and Dissertations

Electrochemical precipitation (EP) is tested to learn about its impact on disinfectants in tap water. The EP process involves applying electricity through electrodes submerged in water to precipitate dissolved metals like water hardness out without chemical additives. In the study, tap water was tested to learn about EP’s impact on disinfectants. Tap water contains not only hardness but also residual disinfectants. It is very essential for the safety of drinking water against the potential ingress of pathogens before the water reaches the end-users. USEPA mandates that the free chlorine level in drinking water should be 0.2mg/L to 4 mg/L. …

An Unmanned Surface Vehicle: Autonomous Sensor Integration System For Bathymetric Surveys, Fernando Sotelo Torres

Open Access Theses & Dissertations

Unmanned Surface Vehicles (USVs) have been applied to earth sciences, with only a few studies conducted in water environments, as these systems provide autonomous measurement capabilities and transferability to other environmental settings. In this thesis, a reliable, yet economical, USV has been developed for bathymetric surveying of lakes. The system combines an autonomous navigation framework, environmental sensors and a multibeam echosounder to collect submerged topography, temperature, windspeed and monitor the vehicle status during prescribed path planning missions.

The main objective of this study is to provide a methodological framework to build a USV, with independent decision-making, efficient control, and long-range …

An Integrated Approach For Dynamic Process Modeling And Optimization Of Wastewater Treatment Facilities, Komal Rathore

USF Tampa Graduate Theses and Dissertations

The subareas of process systems engineering including process modeling, simulation, and optimization are becoming progressively substantial for understanding processes, making decisions, improving efficiency, and complying with stricter environmental and safety legislation. Additionally, the availability of user-friendly flowsheet simulators and computational resources with the current trend of data collection and analysis has allowed for a more accurate representation of complex processes such as wastewater treatment systems. Despite all the progress in the areas of process modeling and simulation, the first-principle mechanistic models for wastewater treatment processes are at best employed during the design stage, and therefore, not used optimally for day-to-day …

Tracing Geochemical Sources And Health Risk Assessment Of Uranium In Groundwater Of Arid Zone Of India, P. Pandit, Atul Saini, Sabarathinam Chidambaram, Vinod Kumar, Banjarani Panda, A. L. Ramanathan, Netrananda Sahu, A. K. Singh, Rohit Mehra

Nebraska Water Center: Faculty Publications

Water quality degradation and metal contamination in groundwater are serious concerns in an arid region with scanty water resources. This study aimed at evaluating the source of uranium (U) and potential health risk assessment in groundwater of the arid region of western Rajasthan and northern Gujarat. The probable source of vanadium (V) and fluorine (F) was also identified. U and trace metal concentration, along with physicochemical characteristics were determined for 265 groundwater samples collected from groundwater of duricrusts and palaeochannels of western Rajasthan and northern Gujarat. The U concentration ranged between 0.6 and 260 μg L⁻¹ with a mean …

Developing A Miniature Smart Boat For Marine Research, Michael Isaac Eirinberg

Computer Engineering

This project examines the development of a smart boat which could serve as a possible marine research apparatus. The smart boat consists of a miniature vessel containing a low-cost microcontroller to live stream a camera feed, GPS telemetry, and compass data through its own WiFi access point. The smart boat also has the potential for autonomous navigation. My project captivated the interest of several members of California Polytechnic State University, San Luis Obispo’s (Cal Poly SLO) Marine Science Department faculty, who proposed a variety of fascinating and valuable smart boat applications.

Effects Of Experimental Scale On The Adsorption Of Two Pharmaceutical Drugs Detected In Municipal Wastewater Effluent, Michael Moore

Master's Theses

Pharmaceutical drugs are being produced and consumed in increasing quantities every year and are poorly treated by conventional wastewater treatment processes, leading to increasing detection of such compounds in surface water, groundwater, and municipal drinking water. Soil aquifer treatment (SAT) is a promising method for treating these emerging compounds through combined adsorption and degradation of target compounds in soil. This thesis examines the consistency of results from typical studies like adsorption isotherms and soil columns utilized in analysis of SAT performance, across varying experimental scales. The adsorption behavior of two pharmaceuticals was investigated as a function of experimental scale and …

Photocatalytic Degradation Of Organic Contaminants By Titania Particles Produced By Flame Spray Pyrolysis, Noah Babik

Theses and Dissertations

Advanced oxidation of organic pollutants with TiO2 photocatalysts is limited due to the wide bandgap of TiO2, 3.2 eV, which requires ultraviolet (UV) radiation. When nanosized TiO2 is modified by carbon doping, charge recombination is inhibited and the bandgap is narrowed, allowing for efficient photodegradation under visible light. Here, we propose a flame spray pyrolysis (FSP) technique to create TiO2. The facile process of FSP has been successful in preparing highly crystalline TiO2 nanoparticles. Using the same procedure to deposit TiO2 onto biochar, the photocatalyst was doped by the carbonaceous material. The morphology, crystalline and electronic structure of the FSP …