Sustainability Commons^™

Hydrothermal Carbonization Of Biomass Wastes: Sustainability And Geochemistry, Michael A. Kruge, Teresa A. Centeno, Alvaro Amado-Fierro, José Manuel González-Lafuente, Ruben Forjan-Castro, José Luis Gallego

Department of Earth and Environmental Studies Faculty Scholarship and Creative Works

Introduction. To reduce the stream of solid waste going to landfills, innovative means for beneficial use are essential. The diversity and volume of organic wastes pose singular problems and opportunities for recovery and circularity. Common processes for organics include conversion to biofuels and carbonization to biochar, typically done by torrefaction (dry pyrolysis). Research on biochar explores its potential as pollutant adsorbent, agricultural or polluted soil amendment, biofuel (directly or as feedstock), and for carbon sequestration (Ighalo et al., 2022; Cavali et al., 2023). Recently, other processes at lower temperatures such as hydrothermal carbonization (HTC) offer new possibilities (Seshadri et al., …

Water-Energy-Food Linkages In Community Smallholder Irrigation Schemes: Center Pivot Irrigation In Rwanda, Ankit Chandra, Derek M. Heeren, Lameck O. Odhiambo, N. Brozovic

Daugherty Water for Food Global Institute: Faculty Publications

Water, energy, and food are linked in intricate ways in irrigated agriculture and understanding the interplay of these components is crucial for sustainable and profitable crop production, particularly in smallholder setting such as in sub-Saharan Africa. This study evaluates water-energy-food linkages, engineering and economic performance, irrigation decision making, and challenges faced around water management in a community-based mechanized irrigation scheme in Rwanda. The research is the first to analyze such as scheme, which uses technology typically used by large farmers in a smallholder setting. The study investigates the variation in water requirements and the relationship and impacts of this variability …

Reaction Steps In Heterogeneous Photocatalytic Oxidation Of Toluene In Gas Phase—A Review, Yerzhigit Tulebekov, Zhandos Orazov, Bagdat Satybaldiyev, Daniel D. Snow, Raphaël Schneider, Bolat Uralbekov

Nebraska Water Center: Faculty Publications

A review of the current literature shows there is no clear consensus regarding the reaction mechanisms of air-borne aromatic compounds such as toluene by photocatalytic oxidation. Potential oxidation reactions over TiO₂ or TiO₂-based catalysts under ultraviolet and visible (UV/VIS) illumination are most commonly considered for removal of these pollutants. Along the pathways from a model pollutant, toluene, to final mineralization products (CO₂ and H₂O), the formation of several intermediates via specific reactions include parallel oxidation reactions and formation of less-reactive intermediates on the TiO₂ surface. The latter may occupy active adsorption sites and …

Design Of Stormwater Bmps For Surface And Groundwater Protection Based On Site-Scale Soil Properties: Phase I, Kelly Kibler, Lisa Chambers, Melanie Beazley

Florida DOT

Much of Earth’s nutrient cycling takes place in soils. Characteristics of soils control physical, chemical, and biological processes that determine rates of nutrient fluxes, storage, or transformation. As remediation of excess nutrients in stormwater runoff is one function of stormwater Best Management Practices (BMPs), the soil profile constitutes one of the most important factors of BMP design. Variation observed in BMP effectiveness (e.g., why one BMP design works effectively in one place and not another) can often be explained by variations in the soil profile, either through direct means or by a soil’s influence on hydraulics of stormwater flow through …

Towards Sustainable Water Management: Soil Analysis, Modeling, And Sensor Implementation On A Micro-Basin Chile's Los Lagos Region, Tammy N. Huynh

Civil Engineering ETDs

The Los Lagos region of Chile is experiencing ecological and socioeconomic challenges because of climate change. Despite efforts by the agricultural sector to understand and manage water resources, the lack of basic water quantification data affects their ability to effectively plan and implement water management strategies. This research aims to address this critical issue through three key objectives. First, characterize soil properties related to texture and structure in a micro-basin of the Los Lagos region. Secondly, it aims to investigate the hydrologic budget of the micro-basin with an emphasis on soil moisture using the Soil Moisture Routing model (SMR). Lastly, …

Biocrude Production From Lignin In Hydrothermal Medium: Effect Of Rapid Heating And Short Residence Time, Kyoko Hirayama

Civil & Environmental Engineering Theses & Dissertations

This study aims to address knowledge gaps in the production of valuable products from waste streams generated during lignocellulosic biofuel production. The primary objective is to develop a process that converts lignin, a byproduct of bioethanol refineries, into a sustainable biolubricant.

The first chapter examines recent advancements in synthesizing biolubricants and investigates their scalability. It explores innovative materials, catalysts, chemical modification approaches, and additives that have emerged in the field. A particular hurdle is the oxidative stability of biolubricants derived from plant oils, which are prone to autooxidation due to their C=C bonds. To overcome this, the study aims to …

Adsorptive–Photocatalytic Performance For Antibiotic And Personal Care Product Using Cu0.5Mn0.5Fe2O4, Chanat Chokejaroenrat, Chainarong Sakulthaew, Athaphon Angkaew, Apiladda Pattanateeradetch, Wuttinun Raksajit, Kanokwan Teingtham, Piyaporn Phansak, Pawee Klongvessa, Daniel D. Snow, Clifford E. Harris, Steven Comfort

Nebraska Water Center: Faculty Publications

The amount of antibiotics and personal care products entering local sewage systems and ultimately natural waters is increasing and raising concerns about long-term human health effects. We developed an adsorptive photocatalyst, Cu_0.5Mn_0.5Fe₂O₄ nanoparticles, utilizing co-precipitation and calcination with melamine, and quantified its efficacy in removing paraben and oxytetracycline (OTC). During melamine calcination, Cu_0.5Mn_0.5Fe₂O₄ recrystallized, improving material crystallinity and purity for the adsorptive–photocatalytic reaction. Kinetic experiments showed that all four parabens and OTC were removed within 120 and 45 min. We found that contaminant adsorption and reaction …

Optimizing The Membrane-Assisted Recovery Of Solids (Mars) Technology For Nutrient Removal And Recovery From Concentrated Waste Streams, Ben Yamin Hoque

USF Tampa Graduate Theses and Dissertations

The effective management of nutrients, such as nitrogen and phosphorus, in decentralizedwastewater treatment environments is a pressing challenge. These nutrients pose significant risks to the environment and public health when discharged into water bodies, while their recovery and reuse can help alleviate nutrient shortages in various industries, including agriculture. Conventional biological treatment methods used in centralized facilities are not suitable for decentralized systems due to operational complexities and space limitations. Chemical treatment mechanisms, such as adsorption, ion exchange, precipitation, and air-stripping, offer potential solutions but are accompanied by challenges like high costs and logistical issues. Therefore, finding a sustainable and …

Incorporation Of Carbon Dioxide Production And Transport Module Into A Soil-Plant-Atmosphere Continuum Model, Sahila Beegum, Wenguang Sun, Dennis Timlin, Zhuangji Wang, David Fleisher, Vangimalla R. Reddy, Chittaranjan Ray

Nebraska Water Center: Faculty Publications

Carbon dioxide release from agricultural soils is influenced by multiple factors, including soil (soil properties, soil-microbial respiration, water content, temperature, soil diffusivity), plant (carbon assimilation, rhizosphere respiration), atmosphere (climate, atmospheric carbon dioxide), etc. Accurate estimation of the carbon dioxide (CO₂) fluxes in the soil and soil respiration (CO₂ flux between soil and atmosphere) requires a process-based modeling approach that accounts for the influence of all these factors. In this study, a module for CO₂ production via root and microbial respiration and diffusion-based carbon dioxide transport is developed and integrated with MAIZSIM (a process-based maize crop growth …

The Association Between Drought Exposure And Respiratory-Related Mortality In The United States From 2000 To 2018, Yeongjin Gwon, Yuanyuan Ji, Jesse E. Bell, Azar M. Abadi, Jesse D. Berman, Austin Rau, Ronald D. Leeper, Jared Rennie

Daugherty Water for Food Global Institute: Faculty Publications

Climate change has brought increasing attention to the assessment of health risks associated with climate and extreme events. Drought is a complex climate phenomenon that has been increasing in frequency and severity both locally and globally due to climate change. However, the health risks of drought are often overlooked, especially in places such as the United States, as the pathways to health impacts are complex and indirect. This study aims to conduct a comprehensive assessment of the effects of monthly drought exposure on respiratory mortality for NOAA climate regions in the United States from 2000 to 2018. A two-stage model …

Attainable And Sustainable Home Building Solutions, Katrina Matthews

Construction Management

Sustainability has fortunately been a recent concern in the construction industry as climate change continues to impose potentially insurmountable threats to the global environment. Although many new methods have been adopted in efforts to lessen the adverse environmental effects of construction-related activities, as a society, we still have much room for growth as the built environment accounts for almost 50% of global emissions. Many changes and standards must be adopted to make these solutions efficiently beneficial. To set industry standards, we must start with the most basic form of construction- residential building. This report covers two attainable framing solutions for …

Exploring The Potential Of Pavegen’S Kinetic Energy Generating Floor For Sustainable Energy Solutions: A Proposal For Cal Poly Slo, Brandon J. Cuneo

Construction Management

This paper proposes the installation of Pavegen's kinetic energy generating floors at Cal Poly’s campus as a sustainable energy solution. Pavegen has developed a pioneering technology that converts footsteps into clean and renewable energy. The versatility of these floors is demonstrated through successful implementations in various settings, such as transportation hubs and public spaces, generating power from foot traffic. Collaborations with Schneider Electric, installation at Dupont Circle, and integration at Heathrow Airport showcase the potential for sustainable urban infrastructure. This paper outlines research conducted on Pavegen and similar solutions, including communication with company representatives and examining proposed installation locations at …

Improving The Cotton Simulation Model, Gossym, For Soil, Photosynthesis, And Transpiration Processes, Sahila Beegum, Dennis Timlin, Kambham Raja Reddy, Vangimalla Reddy, Wenguang Sun, Zhuangji Wang, David Fleisher, Chittaranjan Ray

Nebraska Water Center: Faculty Publications

GOSSYM, a mechanistic, process-level cotton crop simulation model, has a two-dimensional (2D) gridded soil model called Rhizos that simulates the below-ground processes daily. Water movement is based on gradients of water content and not hydraulic heads. In GOSSYM, photosynthesis is calculated using a daily empirical light response function that requires calibration for response to elevated carbon dioxide ( CO₂). This report discusses improvements made to the GOSSYM model for soil, photosynthesis, and transpiration processes. GOSSYM’s predictions of below-ground processes using Rhizos are improved by replacing it with 2DSOIL, a mechanistic 2D finite element soil process model. The photosynthesis …

Downstream Hydrochemistry And Irrigation Water Quality Of The Syr Darya, Aral Sea Basin, South Kazakhstan, Bagdat Satybaldiyev, Baimurat Ismailov, Nurbek Nurpeisov, Kairat Kenges, Daniel D. Snow, Arindam Malakar, Omirzhan Taukebayev, Bolat Uralbekov

Daugherty Water for Food Global Institute: Faculty Publications

New hydrochemical measurements from the Syr Darya provide insights into factors affecting the composition and quality of a major freshwater source replenishing the Aral Sea. This river is heavily used for power and irrigation and crosses territories of four Central Asia republics. It is intensely managed, draining several major tributaries, many reservoirs, and numerous irrigation distribution systems and canals. Analysis of seasonal changes in dissolved ion concentrations using geochemical diagrams, elemental ratios, statistical correlation, and equilibrium modeling allowed the characterization of mineral formation processes that control the dissolved chemical composition. Measured water hydrochemistry and composition type differs substantially from previous …

Occurrence Of Radionuclides And Hazardous Elements In The Transboundary River Basin Kyrgyzstan–Kazakhstan, Mariya A. Severinenko, Vladimir P. Solodukhin, Bekmamat M. Djenbaev, The National Academy Of Science Of The Kyrgyz Republic G. Lennik, Baktiyar T. Zholboldiev, Daniel D. Snow

Nebraska Water Center: Faculty Publications

Important for irrigation, the transboundary river basin between Kyrgyzstan and Kazakhstan is vulnerable to geochemical and anthropogenic sources of pollution. The use of water use indices, together with measurements of the elemental and radionuclide composition of the water and bottom sediments, provides a means for evaluating the continued use of the water from this region. Recent monitoring shows the highest concentrations of hazardous contaminants include lead and thorium contained in the bottom and banks of the Kichi-Kemin River. These contaminants are likely remnants of an accidental spill at the Aktyuz tailing dump in 1964. The specific activity of the Th-232 …

Historic Downtown Streetscape Plan Price City, Utah, Patricia Beckert

All Graduate Plan B and other Reports, Spring 1920 to Spring 2023

The idea of a small-town Main Street has profound meaning within the American culture that has prevailed for the past two centuries. Historically, Main Street serves as the beating heart of a community, a place where economic, social, cultural, and civic activities are centered (Francaviglia, 1996; Main Street America, n.d.). Since the beginning of the 19th century, many factors have led to the decline of Main Streets, and despite a variety of efforts from different stakeholders, that decline has only intensified in recent decades (Isenberg, 2008; Orvell, 2014 Howard, 2015). In 1980, after a three-year project conducted by the National …

Unleash The Heat: Exploring Geothermal Energy Perspectives And Energy Literacy In São Miguel, Azores, Lena Mcdonough

Independent Study Project (ISP) Collection

The green energy transition is moving ahead in EU countries at very different paces, and there are some key challenges that all regions currently face in trying to phase fossil fuels out of their energy mixes. One of these challenges is that most regions simply cannot harness enough renewable energy sources and simultaneously have the storage technology for creating a baseload power source as reliable as oil, coal and natural gas. That is, unless you sit in the middle of the Atlantic Ocean on the boundary of three tectonic plates, with a continuous and reliable renewable energy source beneath your …

Urban Mass Transit: New York State And The Mta Sustainability Initiatives On Greenhouse Gas Emission Reduction, Omosehin Moyebi

Sustainability Research & Practice Seminar Presentations

Dr. Omosehin Moyebi, Health - Urban Mass Transit: New York State and the MTA Sustainability Initiatives on Greenhouse Gas Emission Reduction

Projected Long-Term Climate Trends Reveal The Critical Role Of Vapor Pressure Deficit For Soybean Yields In The Us Midwest, Wenguang Sun, David Fleisher, Dennis Timlin, Chittaranjan Ray, Zhuangji Wang, Sahila Beegum, Vangimalla Reddy

Nebraska Water Center: Faculty Publications

Extreme climate events including heat waves and droughts are projected to become more frequent under future climate change conditions. However, the mechanisms between soybean yields and climate factors, specifically involving variable rainfall and high heat episodes, are still unclear, particularly with respect to spatial trends in the United States (US) Midwest. A recently modified version of the model GLYCIM was used to evaluate rainfed soybean production across 12 states at a 10 km spatial resolution for three time periods (2011–2020, 2051–2060, 2091–2099) under Representative Concentration Pathway (RCP) scenarios 4.5 and 8.5. Results showed that except for the northernmost Midwest counties, …

Pan-Arctic Soil Moisture Control On Tundra Carbon Sequestration And Plant Productivity, Donatella Zona, Peter M. Lafleur, Koen Hufkens, Beniamino Gioli, Barbara Bailey, George Burba, Eugénie S. Euskirchen, Jennifer D. Watts, Kyle A. Arndt, Mary Farina, John S. Kimball, Martin Heimann, Mathias Göckede, Martijn Pallandt, Torben R. Christensen, Mikhail Mastepanov, Efrén López-Blanco, Albertus J. Dolman, Roisin Commane, Charles E. Miller, Josh Hashemi, Lars Kutzbach, David Holl, Julia Boike, Christian Wille, Torsten Sachs, Aram Kalhori, Elyn R. Humphreys, Oliver Sonnentag, Gesa Meyer, Gabriel H. Gosselin, Philip Marsh, Walter C. Oechel

Daugherty Water for Food Global Institute: Faculty Publications

Long-term atmospheric CO₂ concentration records have suggested a reduction in the positive effect of warming on high-latitude carbon uptake since the 1990s. A variety of mechanisms have been proposed to explain the reduced net carbon sink of northern ecosystems with increased air temperature, including water stress on vegetation and increased respiration over recent decades. However, the lack of consistent long-term carbon flux and in situ soil moisture data has severely limited our ability to identify the mechanisms responsible for the recent reduced carbon sink strength. In this study, we used a record of nearly 100 site-years of eddy covariance …

Collaboration Between Science And Art Through A Special International Symposium For Ecosystem Health And Sustainability, Changwoo Ahn Dr.

The Transdisciplinary STEAM+ Journal

The collaborations between ecosystem restoration and art practices was epitomized by the eco-artist Jackie Brookner who said: “it is not a matter of the scientists providing the hard-core research and artists the soft outreach; rather, the dynamics engendered in the space between disciplines is full of information necessary to solve complex problems at the systemic level”. This paper reviews and summaries the goals, activities, and lessons learned from a special symposium, which was held at the 12^th INTECOL (International Congress of Ecology) conference in Beijing, China, August 21 through 25, 2017, where about 3000 people attended from 70 countries. …

Importance Of Snowmelt On Soil Nitrate Leaching To Groundwater – A Model Study, Sahila Beegum, Arindam Malakar, Chittaranjan Ray, Daniel D. Snow

Nebraska Water Center: Faculty Publications

The movement of nitrate to surface water bodies during snow accumulation and melting has been extensively studied, but there are only limited studies on the influence of snow processes on nitrate leaching to groundwater. The present study investigated the impact of snow processes on nitrate leaching to groundwater based on a simulation modeling approach using HYDRUS-1D. HYDRUS-1D model has a temperature threshold-based snow model in addition to water, solute, and heat simulation components. The snow component in HYDRUS-1D was previously not applied to snow simulation studies since the method does not consider a detailed physical and process-based representation of snow …

Process Intensification Strategies For Green Solvent Mediated Biomass Pretreatment, Ahamed Ullah, Yuxuan Zhang, Can Liu, Qi Qiao, Qing Shao, Jian Shi

Markey Cancer Center Faculty Publications

Demonstrated to be highly effective for lignocellulosic biomass pretreatment, deep eutectic solvent (DES) has attracted increasing attention owing to its advantages of simple synthesis, relatively low chemical cost, and better biocompatibility as compared to certain ionic liquids. Here we provide a critical review of the status of the design/selection of DES for the pretreatment of biomass feedstocks with an emphasis on the process intensification strategies: 1) integration of microwave, ultrasound, and high solid extrusion for pretreating biomass, 2) one-pot DES pretreatment, enzymatic hydrolysis, and fermentation, 3) strategies for DES recycling and product recovery; and 4) recent progress on molecular simulations …

Time Domain Reflectometry Waveform Interpretation With Convolutional Neural Networks, Zhuangji Wang, Shan Hua, Dennis Timlin, Yuki Kojima, Songtao Lu, Wenguang Sun, David Fleisher, Robert Horton, Vangimalla R. Reddy, Katherine Tully

Nebraska Water Center: Faculty Publications

Interpreting time domain reflectometry (TDR) waveforms obtained in soils with non-uniform water content is an open question. We design a new TDR waveform interpretation model based on convolutional neural networks (CNNs) that can reveal the spatial variations of soil relative permittivity and water content along a TDR sensor. The proposed model, namely TDR-CNN, is constructed with three modules. First, the geometrical features of the TDR waveforms are extracted with a simplified version of VGG16 network. Second, the reflection positions in a TDR waveform are traced using a 1D version of the region proposal network. Finally, the soil relative permittivity values …

Globally Scalable Approach To Estimate Net Ecosystem Exchange Based On Remote Sensing, Meteorological Data, And Direct Measurements Of Eddy Covariance Sites, Ruslan Zhuravlev, Andrey Dara, André Luís Diniz Dos Santos, Oleg Demidov, George Burba

Daugherty Water for Food Global Institute: Faculty Publications

Despite a rapid development of Nature-Based Solutions (NBS) for carbon removal in recent years, the methods for evaluating NBS still have certain gaps. We propose an approach based on a combination of remote sensing data and meteorological variables to reconstruct the spatiotemporal variation of net ecosystem exchange from eddy-covariance stations. A Lagrangian particle dispersion model was used for upscaling satellite images and flux towers. We trained data-driven models based on kernel methods separately for each selected land-cover class. The results suggest that the proposed approach to quantifying carbon exchange on a medium-to-large scale by blending eddy covariance flux data with …

Role Of Social Determinants Of Health In Differential Respiratory Exposure And Health Outcomes Among Children, Jagadeesh Puvvula, Jill A. Poole, Yeongjin Gwon, Eleanor G. Rogan, Jesse E. Bell

Daugherty Water for Food Global Institute: Faculty Publications

Background Attributes defining the Social Determinants of Health (SDoH) are associated with disproportionate exposures to environmental hazards and differential health outcomes among communities. The dynamics between SDoH, disproportionate environmental exposures, and differential health outcomes are often specific to micro-geographic areas.

Methods This study focused on children less than 20 years of age who lived in Douglas County, Nebraska, during 2016–2019. To assess the role of SDoH in differential exposures, we evaluated the association between SDoH metrics and criteria pollutant concentrations and the association between SDoH and pediatric asthma exacerbations to quantify the role of SDoH in differential pediatric asthma outcomes. …

Survey Data: Optimising Retrofitted Insulation For Irish Residential Building Walls, Rakshit D. Muddu, Aimee Byrne, Anthony Robinson Dr.

Datasets

A survey was conducted to determine the preferred set point temperature and heating pattern among Irish households. The survey was sent to 237 people living across Ireland, out of which 32 respondents skipped the survey and 9 surveys were found to be incomplete. Amongst the counties in Ireland 71.1% respondents were from Dublin, 6.34% from Kildare, 5% from Meath, 5% from Wicklow and in all the remaining counties response rate was below 2%. Part 1: This section of the survey recorded information regarding characteristics of the building such as house type, wall type, insulation type, period the house was built. …

Rainwater Catchment System In Public Sector Housing, Araceli Peña, Muhammad Yanzar Sarin

2023 REYES Proceedings

Water is a universal right for all living beings on the planet, but today it has become a commercial good. It costs significantly to extract water from increasingly distant storage sources. For these reasons and many more the fight for water has become increasingly intense. Precisely, an alternative to avoid more dam construction is the implementation of public politic with actions focused on the integral solution of water, that is to say, that it be distributed fairly and equitably to all users, avoiding more concessions to great industries like as soft drinks and breweries, which are the main consumers and …

Development Of A Framework To Support Community-Scale Nutrient Recovery For Local Crop Fertilization And Production, Scott A. Lopez

Graduate Theses, Dissertations, and Problem Reports (ETD)

Nutrient and resource recovery (NRR) has become increasingly crucial as regions face deteriorating sanitation infrastructures, limited support, and growing environmental challenges. Implementing region-specific NRR technologies and systems could provide effective circular economy insights into addressing these challenges. Because of the multidisciplinary challenges associated with the design and implementation of NRR strategies, various government and local decision-makers need to collaborate effectively in the decision-making process. Structured decision-making (SDM) methodologies are practical when determining the most appropriate NRR strategy for nutrient-rich waste streams. However, applications of computational SDM limited because of the vast amounts of data that are needed to analyze the …

Labile Carbon And Soil Texture Control Nitrogen Transformation In Deep Vadose Zone, Lidong Li, Jordan Shields, Daniel D. Snow, Michael Kaiser, Arindam Malakar

Daugherty Water for Food Global Institute: Faculty Publications

Understanding transient nitrogen (N) storage and transformation in the deep vadose zone is critical for controlling groundwater contamination by nitrate. The occurrence of organic and inorganic forms of carbon (C) and nitrogen and their importance in the deep vadose zone is not well characterized due to difficulty in sampling and the limited number of studies. We sampled and characterized these pools beneath 27 croplands with different vadose zone thicknesses (6–45 m). We measured nitrate and ammonium in different depths for the 27 sites to evaluate inorganic N storage. We measured total Kjeldahl nitrogen (TKN), hot-water extractable organic carbon (EOC), soil …