Other Environmental Sciences Commons^™

Applications For The Quasi-Atomic Orbital And Constrained Density Functional Theory Methods On Catalytic Reactions, Alvaro David Loaiza Orduz

LSU Doctoral Dissertations

Selective activation of C–O, C–H, and C–C bonds underpins biomass upgrading, alkane functionalization, and CO₂ conversion. Despite their importance, the electronic factors governing catalytic performance remain incompletely understood, and many industrial processes still rely on empirical trends or material-specific observations. This dissertation addresses this gap by applying density functional theory (DFT), thermodynamic decomposition, and electronic-structure analysis to identify unifying principles of reactivity across transition-metal phosphides, vanadate oxides, copper-based electrocatalysts, and mixed IrO₂–RuO₂ layers. This work examines how charge transfer, orbital localization, and ligand-induced perturbations control reaction pathways in diverse catalytic systems. C–O bond scission in 2-methyltetrahydrofuran (MTHF) and methanol was …

Establishing A Framework Of Best Management Practices For Sustainable Water Quality: Integration Of Technology And Remote Sensing, Mason L. Marcantel

LSU Master's Theses

Water quality security is a complex management issue that is constantly challenged by factors of seasonal variability in climate change, urban population growth, and agricultural intensification. These factors warrant the need for innovative technological adaptations to management practices that integrate remote monitoring, predictive modeling, and sustainable resource utilization. This study establishes a framework for sustainable water quality practices through the integration of remote sensing technology for urban wastewater treatment and agricultural irrigation systems. This dual-site research study explores seasonal water quality dynamics and technological interventions to create a more proactive approach to water quality security.

In the first study, water …

Effects Of Hydrological Connectivity On Created Marsh Sustainability, Katie Swann

LSU Master's Theses

While efforts are being made to curb the high rate of coastal land loss in Louisiana, and even to restore ecosystem services and functions, it is generally accepted that restoration of these areas and functions is not a one-to-one value. It may take decadal time scales to reach efficient functional processing of nutrients and carbon storage rates, which may never reach true capacity comparable to similar naturally-organized systems. Although it is imperative to preserve these areas, restoration of ecosystem services and biogeochemical processes of coastal wetlands are preferable to future without action scenarios. Effectively directing the use of the limited …

Coastal Sedimentary Records Of Extreme Events And Human Activity: Examples From Hurricanes And Microplastics, Nicholas T. Culligan

LSU Doctoral Dissertations

Coastal regions are uniquely vulnerable to a myriad of natural and anthropogenically caused stresses such as hurricane strikes and chronic microplastic pollution. Both hurricanes and microplastics have major negative effects on global coastlines and are forecast to become more damaging in the future. However, current model trends are based on limited modern data and may not provide an accurate or comprehensive view of the future. Therefore, this dissertation investigates coastal stratigraphic records to determine long-term past trends of these presses and pulses so that researchers, stakeholders, and policy makers can use them to enact strategies to mitigate damages from worsening …

From Biowaste To Product: The Functionalization Of Biochar For Agricultural And Environmental Applications, Baoyue Zhou

LSU Doctoral Dissertations

Biochar is a porous carbonated substance that is manufactured through pyrolysis of biomass feedstocks in an oxygen-deficiency environment. The production of biochar from agricultural waste materials provides a potential solution for eliminating pollution while improving carbon sequestration. While biochar is shown to provide multiple benefits to soil health and fertility, its use in environmental remediation has been hampered by its low affinity for hazardous anionic species and the difficulty in isolating from water phase. To overcome these obstacles, various efforts have been made to modify biochar surface chemistry and morphology.

Fe/Mg co-doped biochar composites from sugarcane harvest residue were prepared …

Sediment Buffering And Recycling On An Annual To Centennial Scale Along The Mississippi River, Nikki E. Neubeck

LSU Master's Theses

Although the Mississippi River and its tributaries have been investigated for many years, the alteration of the river through dams, levees, and diversions has affected how sediment is transported from source to sink (>10³ y). Previous provenance research using detrital zircon U-Pb dating indicates a slow transport time from source-to-sink, but recent anthropogenic alterations of the river may potentially diminish the transportation time of heavy minerals due to an increase in flow efficiency. The objective of this study is to analyze the degree of buffering and recycling of Mississippi River sediment over a range of short time scales, …

Seasonal Transport Of Dissolved Inorganic Carbon And Total Alkalinity Across The Louisiana Shelf, Michelle M. Anderson

LSU Master's Theses

Rivers and wetlands are a major source of terrestrial derived carbon for coastal ocean margins. Unfortunately, Louisiana’s wetlands are threatened by ongoing high rates of erosion, deterioration, and unprecedented rates of river water discharge that changes seasonally, leading to a net loss of terrestrial carbon into the northern Gulf of Mexico (nGOM). There exists a current lack of understanding about the distribution of dissolved inorganic carbon (DIC) and total alkalinity (TAlk) within the shallowest regions of the Louisiana shelf. Even less is known about how the transport of DIC alters seasonally with changes in river outflow and shelf currents. Quantifying …

An Ecopath With Ecosim Analysis On Offshore Petroleum Platform Influences On Gulf Of Mexico Red Snapper, Valentin Gomez

LSU Master's Theses

Offshore oil and gas platforms have had a significant presence in the Gulf of Mexico since the 1950s. An important secondary function of these structures is that they provide artificial habitat to fisheries, most notably Red snapper. Policy changes intended to reduce the risk associated with aging infrastructure have reduced the number of standing platforms from 4044 to 1867 from 2001 to 2018. The effect this loss of habitat has on Red snapper was tested by creating three scenarios of platform changes and modeling the perturbation from 2005 to 2050. The simulation was accomplished using the ecological model Ecopath with …

Breaking Coastal Hypoxia: Destratification Of Gulf Of Mexico Deadzone To Encourage Oxygen Transport Downwards To Maintain Marine Fauna, Veda Thipparthi

LSU Master's Theses

As a consequence of seasonal eutrophication and human input, a vast hypoxic area termed The Dead Zone develops every year in the Gulf of Mexico (GOM) during summer along the Louisiana coastline characterized by vertical seawater density-stratification with oxygen concentrations less than 2 mg.l^-1 at the seafloor. It poses a threat to bottom-dwelling faunae and their environment which has negative ecological and economic consequences. This project aims to mitigate hypoxia by employing mechanical impellers placed at strategic water depths and locations in the Gulf. Enhanced transport of oxygen results by mixing oxygen-enriched seawater at the surface, downward into the …

Sources And Chemical Stability Of Soil Organic Carbon Along A Salinity Gradient And A Chronosequence Of Created Brackish Marshes In Coastal Louisiana, Megan L. Kelsall

LSU Master's Theses

Tidal marshes have been recognized for providing a number of important ecological services including soil carbon sequestration. However, the loss of tidal marsh habitat due to climate change and anthropogenic stressors exposes previously stored soil organic carbon (SOC) to oxidation. The vulnerability of SOC to oxidation depends on its chemical stability and environmental conditions limiting decomposition. Labile organic carbon (LC), decomposes quickly unless abiotic conditions limit decomposition. Recalcitrant organic carbon (RC) decomposes slower and is stored for longer time periods. Predicting long-term storage of SOC is complicated by the potential for multiple SOC sources, differences in chemical stability, and variation …

Matrix Recharge In A Shrink-Swell Floodplain Forest Soil, Savannah R. Morales

LSU Master's Theses

Despite the global distribution of fine-grained Vertisols, the hydrology of these floodplain soils is still not well understood. Vertisols shrink and swell depending on soil moisture leading to a range of soil pore sizes, from large macropore cracks to smaller micropores, and consequently a range of hydraulic conductivities. Despite the plethora of research indicating the importance of both flooding and soil moisture in floodplain ecosystems, the specific role that flooding plays in soil moisture recharge has been less widely studied and remains of interest. Blue food dye and deuterated water were used as tracers to determine the role of the …

Deltaic Wetland Dynamics From Seasonal To Centennial Scales, Giancarlo A. Restreppo

LSU Doctoral Dissertations

The lower plain of the Mississippi River Delta contains approximately five coastal sedimentary basins that are topographically defined, and one shelf-crossing depocenter (the Birds Foot Delta). These depositional systems receive varying quantities of sediment from fluvial and marine sources and have rates of coastal land loss that are roughly inversely proportional to fluvial sediment supply. To combat land loss along these regions, Louisiana has launched a historic campaign to sustain and regrow coastal lands using, in part, river sediment diversions. Fine sediments constitute the majority of sediment load in the Mississippi River, but are under-studied with respect to dispersal processes, …

Evaluating Seasonal Nutrient Fluxes In Emerging And Eroding Wetlands Of The Louisiana Delta Plain, Kiran Upreti

LSU Doctoral Dissertations

Deltaic wetlands can ameliorate high NO₃^- loads via denitrification, a dominant NO₃^- reduction pathway in inland and coastal habitats. Dissimilatory Nitrate Reduction to Ammonia (DNRA), in contrast to denitrification, conserves N within the system and has been found to be favored over denitrification with increase in salinity and temperature. There are no studies in the Louisiana Deltaic plain with simultaneous estimation of denitrification and DNRA. Increased P availability has been shown to increase denitrification so it is essential to understand P biogeochemistry when studying N cycle. Here, we evaluated net denitrification using N₂:Ar and …

Longitudinal Study Of The Attitudes And Behaviors Of Environmental Education Program Participants., Kasie R. Dugas

LSU Master's Theses

The goal of this longitudinal study was to measure the attitudes and behaviors of participants of the Marsh Maneuvers program over the course of the last 25 years. The goal of the Marsh Maneuvers program is to educate students into becoming environmentally literate adults. Environmental literacy is considered herein to be people possessing knowledge about and positive attitudes and behaviors towards the environment. Although students learn basic science and environmental knowledge in the classroom, true environmental literacy is believed to require more hands-on understanding of the material. To evaluate the effectiveness of the program, the following three objectives were completed. …

Influence Of Salinity, Sunlight, And Sediment On The Toxicity Of Pesticides In Three Non-Target Organisms, Emily Noelle Vebrosky

LSU Doctoral Dissertations

Pesticides used in the United States must undergo registration by the United States Environmental Protection Agency (USEPA), after a multitude of analyses ranging from environmental fate to aquatic toxicological impacts to human risk exposure. Testing varies for each chemical, some requiring more testing than others. In many cases, environmental factors are restricted in the analysis of chemical behavior and organismal testing is limited to larvae. Many pesticides are formulated to breakdown in the environment by means of photolysis, hydrolysis, or oxidation, either to ensure low-persistence, limited transport, or to form the active ingredient (pro-pesticides). Environmental influences on chemical behaviors include …

Perils Of The Fungal Kingdom: Mycotoxins In Food And Feed, Adrianna Isobel Pribil

LSU Master's Theses

Humans and fungi have a complex relationship, especially in regards to the many fungal secondary metabolites that can be produced. When secondary metabolites are toxic to animals and humans they are defined as mycotoxins. Fungi can grow on crops pre-harvest and post-harvest, and have the potential to produce mycotoxins which occur regularly in animal feed and food for human consumption. In high doses, mycotoxins cause variety of problems that result in economic losses and extreme health issues. However, multiple mycotoxins will co-occur in nature and commonly occur in low doses. Thus chronic low daily doses of multiple mycotoxins overtime may …

Assessment Of Mercury Content In Louisiana's Freshwater Fish And Its Association To Se Concentrations, Alexander David Reyes-Avila

LSU Master's Theses

Ample evidence has demonstrated the neurotoxic properties of organic Hg to humans. However, recent studies have proposed the protective effects of Se against organic Hg detected in marine fish. Louisiana’s freshwater bodies are exploited by recreational anglers that enjoy fishing as recreational activity and food source. Thus, testing of Hg in Louisiana was resumed in 2017 to update the state advisories. However, before drawing conclusions based solely on organic Hg, it might be useful to see how much Se is present in freshwater fish. The main objective of this study was to determine the Se:Hg molar ratio in Louisiana’s freshwater …