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Ab Initio Study Of The Effects Of Humidity On Perovskite Based Hybrid Solar Cell Interfaces, Shantanu Rajendra Rachalwar

Browse all Theses and Dissertations

Despite the impressive success of perovskite-based hybrid solar cells, their widespread usage has been limited partially owing to stability issues under working environmental conditions. Among these, the effects of humidity are some of the most significant. Water intercalation generally degrades the material, shortens its useful life, and reduces the efficiency of photovoltaic energy conversion. Understanding the reasons for these effects can be achieved through detailed and accurate atomic-scale analysis. Here, we study water intercalation at the interfaces of perovskite-based hybrid solar cell material and TiO2 electrode. Accurate ab initio computer simulations are used to obtain structural and electronic properties. We …

Study Of Periodical Flow Heat Transfer In An Internal Combustion Engine, Xi Luo

Wayne State University Dissertations

In-cylinder heat transfer is one of the most critical physical behaviors which has a direct influence on engine out emission and thermal efficiency for IC engine. In-cylinder wall temperature has to be precisely controlled to achieve high efficiency and low emission. However, this cannot be done without knowing gas-to-wall heat flux. This study reports on the development of a technique suitable for engine in-cylinder surface temperature measurement, as the traditional method is “hard to reach.” A laser induced phosphorescence technique was used to study in-cylinder wall temperature effects on engine out unburned hydrocarbons during the engine transitional period (warm up). …

Development Of A Dynamic Cfd Model For Offshore Oscillating Water Columns With Non-Linear Interactions, Ken O'Connell

Theses

This thesis focuses on the development of a state of the art modelling technique for offshore Oscillating Water Column (OWC) type Wave Energy Converters (WEC) using Computational Fluid Dynamics (CFD). Current literature indicates a limited amount of work has been completed on studying these devices containing non-linear time dependent flow phenomenon. Initially, a 2D Numerical Wave Tank (NWT) is studied to reduce discretisation error in order to reproduce accurately propagating waves. Further development into a 3D domain permits the geometrical requirements of an OWC type spar buoy to be included.

In parallel, a single Degree of Freedom (DOF) model is …

Structure Stability And Optical Response Of Lead Halide Hybrid Perovskite Photovoltaic Materials: A First-Principles Simulation Study, Siddharth Narendrakumar Rathod

Browse all Theses and Dissertations

A third-generation of solar cell is based on organic-inorganic hybrid perovskite materials. These have reached up to 22.1% conversion efficiency through exponential growth just within the last decade, compared to much longer improvement times for other photovoltaic technologies. Lead halide perovskites are among the most commonly used materials in this context. Despite the relatively large number of available works on some of these materials, in particular CH3NH3PbI3, others are less investigated. Here, we focused on CH3NH3PbCl3, CH3NH3PbBr3 and CH3NH3PbI3 for assessing structure stability and optical response. Using quantum-mechanics-based first principles approaches, we calculated the optimized structures of these three materials …

Mathematical Modeling Of A P-N Junction Solar Cell Using The Transport Equations, Surjeet Singh

Browse all Theses and Dissertations

While analytical models are limited in the situations that they can simulate, they are generally easier to implement than numerical models and provide a rapid view of the variables which affect a certain quantity. Analytical models are also very useful in educational situations; such as a graduate class on photovoltaics. The modeling of the interior workings of a solar cell can be complex and involved; and some of the equations can become quite lengthy. A focus of this thesis work is the derivation of the minority carrier density and minority current density equations for a p-n junction solar cell. The …

Configuration And Electronic Properties Of The Interface Between Lead Iodide Hybrid Perovskite And Self-Assembled Monolayers In Solar Cells, Parin Divya Amlani

Browse all Theses and Dissertations

Hybrid perovskite photovoltaic materials are currently the most promising functional materials for solar cell applications with efficiency reaching to those of more conventional materials such as silicon. Using self-assembled monolayers between photovoltaic materials and electrodes is a method for improving the stability and functionality. Recent experiments have shown that using 4-mercaptobenzoic acid and pentafluorobenzenethiol monolayers bridging lead iodide hybrid perovskite photovoltaic materials and electrodes result in improved stability and efficiency. The details of monolayer assembly, molecular adsorption configuration, and resulting modification of electronic properties are important characteristics related to solar cell performance. These characteristics can be obtained through accurate computer …

Renewable Energy Systems Optimization Using Monte Carlo Simulation And Evolutionary Algorithms, Nicolas Lopez

Open Access Theses & Dissertations

This Dissertation explores the Renewable Energy Integration Problem, and proposes a Genetic Algorithm embedded with a Monte Carlo simulation to solve large instances of the problem that are impractical to solve via full enumeration. The Renewable Energy Integration Problem is defined as finding the optimum set of components to supply the electric demand to a hybrid

microgrid. The components considered are solar panels, wind turbines, diesel generators, electric batteries, connections to the power grid and converters, which can be inverters and/or rectifiers. The methodology developed is explained as well as the combinatorial formulation. In addition, 2 case studies of a …

Genesis Of Unique Carbonate Fans In A Pre-Salt Reservoir Analogue, Indio Mountains, West Texas, Andre Llanos

Open Access Theses & Dissertations

Hydrocarbon exploration in pre-salt sediments of rift basins on the South Atlantic Margin have proven to be successful major oil plays. Located on the western margin of the rift, the Brazilian pre-salt reservoirs of the Santos, Campos, and Espirito Santo Basins are hosted by lacustrine/marine-influenced carbonates that comprise laterally extensive, laminated microbialite facies. The Indio Mountains, located in West Texas, provide well-exposed outcrops of Lower Cretaceous marine and non-marine rift basin strata that can be considered a reservoir-analog to the South Atlantic Margin pre-salt facies. Of particular interest for hydrocarbon exploration are unique carbonate features that have been discovered in …

Depositional Controls And Sequence Stratigraphy Of Lacustrine To Marine Transgressive Deposits In A Rift Basin, Lower Cretaceous Bluff Mesa, Indio Mountains, West Texas, Andrew Anderson

Open Access Theses & Dissertations

Successful hydrocarbon exploration in former rift basins of the South Atlantic pre-salt has generated interest in understanding depositional, diagenetic, and stratigraphic controls on pre-salt deposits. However, most studies to date have focused on attributes and controls on presalt lacustrine carbonate reservoir systems and little work has been done on the overlying marine sealing facies. Currently our standard sequence stratigraphic model of marine transgression of rift systems involves a single pulse of marine flooding over fluvially-incised valleys resulting in backstepping of fluvial and estuarine siliciclastic facies within the erosionally confined zone of an incised valley. However, the pre-salt systems of the …

Forward Osmosis For Wastewater Treatment And Energy Recovery: A Techno-Economic Analysis, Patrick William Buckwalter

Cal Poly Humboldt theses and projects

A novel wastewater treatment system was investigated using forward osmosis membranes to treat municipal wastewater. Treatment by forward osmosis was determined to cost $10 million per million gallons per day (MGD) of wastewater capacity over a 20-year lifetime, with an energy consumption of 870 kWh per million gallons. A case study at the Arcata Wastewater Treatment Plant was conducted to investigate a treatment system that combines energy recovery from algae biomass with forward osmosis membrane treatment using local seawater as a draw solution. Total system cost was calculated to be $29.7 million over a 20-year lifetime with a 2.3 MGD …

Technological Modernization And Its Impact On Agriculture, Fisheries And Fossil Fuel Utilization In The Asia Pacific Countries With Emphasis On Sustainability Perspective, Rajee Olaganathan, Kathleen Quigley

Publications

Modernization is a process that moves towards efficiency. This affects most of the fields such as agriculture, fisheries, forestry, urban planning, policy, fossil fuel usage, manufacturing, technology, economic growth etc. This process plays a major role in moving forward making things faster, better and basically more efficient. The effects of modernization on all these fields bring about the major changes to aspects such as social, economic and the environment. The level of operation has increased from a domestic level; small family scale business to large commercial levels. As the level of operation increased, the utilization of natural resources increased gradually …

More Than Food: An Analysis Of Multidimensional Relationships In Our Food System, Jessica Erin Newnan

Honors Theses and Capstones

Food is an integral part of everyday life for human beings, thus meriting particular attention from research and education. Looking further in depth at the factors that influence food, it becomes apparent that this is a complex topic that is related to several systems within the constructs of society. Here, the food system is approached with the understanding that several systems influence food consumption options and decisions including the agricultural, economic, education, energy, health, and political systems. To identify the relationships more closely, a three-dimensional model was built to represent the food system and depict several key factors, their relationships, …

Plasmonic Luminescent Down Shifting Layers For The Enhancement Of Cdte Mini-Modules Performance, Hind Ahmed, S.J. Mccormack, John Doran

Articles

In this investigation, plasmonic coupling between luminescent species (lumogen yellow, and silver nanoparticles (Ag NPs) has been exploited to produce significant enhancement in absorption and fluorescence emission of lumogen yellow dye luminescent downshifting (LDS) layers. The optimum dye concentration in a poly(methyl,methacrylate) polymer LDS layer of ∼100μm thickness was established. Subsequently, plasmonic coupling with Ag NPs was introduced and optimum concentration has been determined for the composite plasmonic Luminescent Down-Shifting (pLDS) layers. The optimum plasmonic coupling has been observed to produce fluorescence emission enhancement of up to 81% for the dye-pLDS layers. The pLDS layers were deposited on top of …

Strengthening The Development Of The Short-Rotation Plantations Bioenergy Sector: Policy Insights From Six European Countries, Carlos Parra-Lopez, Martin Holley, Kevin Lindegaard, Samir Sayadi, Gonzalo Esteban-Lopez, Victor Duran-Zuazo, Christoph Knauer, Hans-Georg Von Engelbrechten, Ralf Winterber, Annika Henriksson, Annette Lamley, Anders Nylander, Susanne Paulrud, Pauline Leonard, Patrick Daly, Lukasz Drzewaszewski, Wojciech Rzewuski

Articles

This paper, based on a participatory methodological framework involving expert stakeholders and researchers from six European countries (Germany, Ireland, Poland, Spain, Sweden and UK), analyses the priority issues for the development of short-rotation plantations (SRP), and proposes a series of policy strategies to strengthen this development. The results indicate that there is a lack of awareness of the multifaceted benefits of SRP at the level of farmers, policy makers and public authorities. More research is required to put a value on the multifunctionality of SRP and justify its public support. Small-scale projects using established technologies are also required with energy …

Sugar Versus Lipid For Sustainable Biofuels, Yaşar Demirel

Yaşar Demirel Publications

Introduction

First‐generation biofuels, namely, ethanol and biodiesel, have led to far reaching impact on the peoples’ life world‐wide.[1] However, they inter-fere with the food supply chain and may not be sustainable although some of the biomass are converted to biofuels after those biomasses have met the human needs. Still, the first‐generation–based biofuels have proved that sugar and lipid platforms can be an answer to energy security and global warming concerns without the need for new infrastructure for feedstock delivery as well as for biomass‐to‐biofuel conversion tech-nologies. At the same time, we are discovering and assessing the long‐term environmental im-plications on …

Human Resource Local Content In Ghana's Upstream Petroleum Industry, Papa Benin

Walden Dissertations and Doctoral Studies

Enactment of Ghana's Petroleum (Local Content and Local Participation) Regulations, 2013 (L.I. 2204) was intended to regulate the percentage of local products, personnel, financing, and goods and services rendered within Ghana's upstream petroleum industry value chain. Five years after the inception of Ghana's upstream oil and gas industry, a gap is evident between the requirements of L.I. 2204 and professional practice. Drawing on Lewin's change theory, a cross-sectional study was conducted to examine the extent of differences between the prevailing human resource local content and the requirements of L.I. 2204 in Ghana's upstream petroleum industry. The extent to which training …

Effects Of Post Eviction Resettlement On Land-Use And Cover Change In Uganda’S Oil Exploration Areas, Joseph Ssekandi, John Mburu, Oliver Wasonga, Laban Macopiyo, Charles A. Francis

Department of Agronomy and Horticulture: Faculty Publications

Evaluation of the changes in land use and land cover change (LULCC) in respect to oil exploration across the Albertine region in Uganda has been focused around the exploration areas and protected areas, with no attention to the potential impacts of evictees’ activities on resettled areas. This study used LANDSAT images to analyze the land use and land cover changes (LULCC) among the period before eviction (2002 and 2005) at the climax of eviction and resettlements (2005-2011), and during the post-resettlement period (2011-2015) to quantify the impacts of resettlements on the environment. LANDSAT images were processed using ERDAS IMAGINE software …

Pyroelectric Ceramics As Temperature Sensors For Energy System Applications, Jorge Luis Silva

Open Access Theses & Dissertations

Temperature is continuously monitored in energy systems to ensure safe operation temperatures, increase efficiency and avoid high emissions. Most of energy systems operate at high temperature and harsh environments to achieve higher efficiencies, therefore temperature sensing devices that can operate under these conditions are highly desired. The interest has increased in temperature sensors capable to operate and in harsh environments and temperature sensors capable to transmit thermal information wirelessly. One of the solutions for developing harsh environment sensors is to use ceramic materials, especially functional ceramics such as pyroelectrics. Pyroelectric ceramics could be used to develop active sensors for both …

Quantifying The Characteristic Length Of A Combustor For An Ionic Liquid Monopropellant Thruster, Kimberly Marie Hogge

Open Access Theses & Dissertations

Ionic liquid monopropellants are currently being researched as a promising alternative to hydrazine in propulsion systems. This report presents a flame study that delineates the flame length of the expected decomposition products from an ionic liquid monopropellant. Through these studies, the characteristic length of a combustion chamber will be defined through calculations and empirical correlations. There is limited information on designing a propulsion system for an ionic liquid monopropellant. Therefore, defining the magnitude for an effective characteristic length serves as beneficial in designing a propulsion system for an ionic liquid monopropellant thruster.

Gypsum, Calcite, And Dolomite Caprock Fabrics And Geochemistry From The Gypsum Valley Salt Diapir, Paradox Basin, Southwestern Colorado, Kevin Lerer

Open Access Theses & Dissertations

Caprocks are found on top of or in a lateral position relative to salt diapirs. The caprocks predominantly comprise sulfate minerals such as anhydrite or gypsum, which presumably accreted during the dissolution of salt from evaporite sediments. In some cases, the sulfate minerals are replaced by carbonate minerals, referred to as "carbonate caprock". Carbonate caprocks associated with salt diapirs are important because they can act as reservoirs or conduits for hydrocarbons, and because they can be easily misidentified as carbonate lithologies belonging to the stratigraphy of the sedimentary sequences adjacent to the diapir, which can jeopardize the accurate interpretation of …

Stop Fighting It Nebraska: Clean Energy Is Here To Stay, Nicholas Underwood

Op-Eds from ENSC230 Energy and the Environment: Economics and Policies

The state of Nebraska and more specifically the Nebraska Public Power District has so far shown a surprising reluctance to incorporate clean or renewable sources of power into its portfolio. The state’s reluctance is exemplified in their support for legal challenges to the Clean Power Plan put forth by the Obama Administration. NPPD in particular has decided to stick with coal as its primary fuel source and has even discouraged the construction of natural gas facilities in the state. The power utilities in this state need to develop a modern, clean energy system to avoid being left behind.

On one …

The Clean Power Plan And How It Will Change History, Abbie Andersen

Op-Eds from ENSC230 Energy and the Environment: Economics and Policies

In a country where 30% of the population still believes that man made climate change is a myth, president Obama has made a daring effort to help fix the damage our country has already inflicted on our planet. By creating The Clean Power Plan (CPP) we’ve taken a step in the right direction as a country. The action that we take to limit our emissions within the next 10 years will likely determine the course of the rest of our existence.

In our current situation humanity has no choice other than to act, and act quickly. We have passed the …

Fossil Fuel Subsides Will Keep The Us In The Stone Age, Alexander Stejskal

Op-Eds from ENSC230 Energy and the Environment: Economics and Policies

Renewable sources will be the future of energy production for the United States. Clean sources of energy like wind and solar have been the topic of conversation for quite some time, and now they’re starting to show their ability to compete economically with fossil fuels.

Even as renewable sources of energy begin to show their gusto, they are still a part of a relatively new industry and new industries always need a little help getting off the ground. There are some forms of aid being provided for renewable sources of energy, like the production tax credit or PTCs, where the …

Solar, Why Not?, Emily Hergenrader

Op-Eds from ENSC230 Energy and the Environment: Economics and Policies

Imagine yourself standing outside for an hour wearing a black shirt on a 90-degree day. Now touch your shirt. Notice how warm it is? This warming is due to the sun’s energy. According to Daniel Nocera, a member of the Division of Chemistry at the Massachusetts Institute of Technology, that same heat from one hour of sun exposure is more energy than all of the energy consumed by humans in an entire year.

Energy is one of the hottest topics debated in our world today. Human existence on Earth depends on energy usage and the availability of its consumption. Due …

Why We Should Keep Worrying About The Atomic Bomb, Eric Davis

Op-Eds from ENSC230 Energy and the Environment: Economics and Policies

“… the members of the Bulletin of the Atomic Scientists Science and Security Board have looked closely at the world situation and found it highly threatening to humanity—so threatening that the hands of the Doomsday Clock must once again be set at three minutes to midnight, two minutes closer to catastrophe than in 2014…Meanwhile, as they slow the pace of disarmament, the nuclear weapon states have given other strong indications that they are committed to retaining nuclear weapons for the indefinite future” - Bulletin of the Atomic Scientists (2015). "Three Minutes and Counting".

Nuclear proliferation and climate change pose the …

Independent Energy, Ian Hall

Op-Eds from ENSC230 Energy and the Environment: Economics and Policies

In the world of energy, an elite selection of the world’s most influential leaders dictates the development of the world. The correlation between petroleum production and global influence is hard to ignore. The world needs energy to move and those with the energy control the movement. Saudi Arabia, Russia, and the US combine to contribute over a third of world oil production. OPEC countries however, dominate the vast energy markets around the world. Well inundated with regional conflict and hostile relations, OPEC countries remain volatile and on top of global energy production.

The energy industry has become extremely productive, fueling …

A Dynamic Power Grid For A Dynamic Age Introducing Les To A Pricing Mechanism That Assesses Demand, And Changes Every Hour, Marvin Christopher Cunningham

Op-Eds from ENSC230 Energy and the Environment: Economics and Policies

Lets say you knew someone who would buy a whole pizza when they were a little bit hungry, left their sink running when they weren’t using it, maxed out their A/C in their house when they were on vacation, and always kept their stove on just in case they wanted to cook something.

You would probably see this as horribly wasteful, and a terrible drain of money. But every time we pay our power bill, our prices assume we share these wasteful habits. The rate that we pay per kilowatt hour assumes customers are eating the whole pizza, even though …

Les To Increase Fixed Price, Nathan Blazek

Op-Eds from ENSC230 Energy and the Environment: Economics and Policies

Lincoln Electric System (LES) plans to increase the fixed amount customers pay each month and decrease the rate it charges for each kWh used.

This shift is claimed to be revenue neutral for LES. But for customers, it means they’ll save less money by turning off lights and buying more efficient appliances.

This policy is a sly and deliberate stab at ongoing conservation efforts. The decreased kilowatt pricing will give customers the perception that it is relatively unnecessary to decrease electricity usage if they are already paying a high price to initially have it. This new policy will even further …

Is Nebraska Really “The Good Life”?, Sarah Porath

Op-Eds from ENSC230 Energy and the Environment: Economics and Policies

For anyone who has ever lived in Nebraska, you know the state is filled with people who resist change. Nebraska is “The Good Life.” Any adjustments or modifications that could disrupt the lifestyle are not welcomed. The people who are elected into office clearly reflect this type of mindset.

It is time for Nebraska to get outside of their comfort zone. We need to move from the good life to the great, healthy, and progressive life by developing a state-wide Energy Efficiency Resource Standard or Goal.

20 states have Mandated Statewide Energy Efficiency Resource Standards and 8 states have Goals …

Fracking Chill, Nick Nardone

Op-Eds from ENSC230 Energy and the Environment: Economics and Policies

Hydraulic Fracturing or commonly known as fracking has caused a big boom in the oil and gas industry making it easier for us to extract oil and gas from the ground, but has serious side effects that as they cause harm to us and our environment. We should slow or stop fracking at once if we want a clean and healthy environment to live in.

Fracking has become widely popular in the last decade and has brought us benefits on the oil and gas side and with little lack of information and support it has been difficult to put restrictions …