Oil, Gas, and Energy Commons^™

Design Concepts And Process Analysis For Transmuter Fuel Manufacturing, Georg F. Mauer

Fuels Campaign (TRP)

The safe and effective manufacturing of actinide-bearing fuels for any transmutation strategy requires that the entire manufacturing process be contained within a shielded hot cell environment. To ensure that the fabrication process is feasible, the entire process must be designed for remote operation. The equipment must be reliable enough to perform over several decades, and also easy to maintain or repair remotely. The facility must also be designed to facilitate its own decontamination and decommissioning. In addition to these design factors, the potential viability of any fuel fabrication process will also be impacted by a number of variables, such as …

Impact Of The Synthesis Process On Structure Properties For Afci Fuel Candidates, Kenneth Czerwinski

Fuels Campaign (TRP)

Synthesis of actinium mononitrides using carbothermic reduction of the corresponding oxides has a few outstanding issues, including the formation of secondary phases such as oxides and carbides and low densities of the final product. Furthermore the requirement of a high process temperature at 1700°C, for more than 12 hours is also a drawback particularly for Americium-bearing samples. Therefore, it is important to explore the use of other possible routes to synthesize actinide mononitrides.

A low temperature process is used in this research to produce actinide mononitrides using a fluoride route in which the first step is to mix the actinide …

Solution-Based Synthesis Of Nitride Fuels, Tyler A. Sullens, Kenneth Czerwinski

Fuels Campaign (TRP)

The preliminary studies into the synthesis of actinide nitride fuels through a low temperature, liquid ammonia based synthesis route have been conducted on the uranium containing system, and there is good indication for the success of synthesizing uranium (III) nitride. The dissolution of iodine in ammonia is a rapid process, resulting in a pale green solution, which does not result in any observable oxidation of iodine. The cannula transfer of dissolved iodine into the reaction vessel containing U metal has been conducted with little to no residual iodine remaining in the original flask. The metal being used for these reactions …

Evaluation Of Fluorapatite As A Waste-Form Material, Dennis W. Lindle, Oliver Hemmers, Dale L. Perry

Separations Campaign (TRP)

Argonne National Laboratory has proposed a new extraction procedure to handle TRISO-coated fuels, the Fluoride Extraction Process, or FLEX. The FLEX process is designed to separate the uranium in the fuel from the actinides and most fission products by taking advantage of the unique properties of uranium hexafluoride (UF₆). In the FLEX process, the used TRISO fuel is reacted with zirconium fluoride salt, forming UF₆ and the fluoride salts of the actinides and fission products. At process temperatures, the UF₆ volatizes into a gas, and is released from the molten salt mixture. This leaves behind the …

Economic Analysis Of Cellulase Production Methods For Bio-Ethanol, Jun Zhuang, Mary A. Marchant, Sue E. Nokes, Herbert J. Strobel

Biosystems and Agricultural Engineering Faculty Publications

The cost of cellulase enzymes has limited the feasibility of producing ethanol from fibrous biomass. Traditional submerged fermentation (SmF) was compared to an alternative method of producing cellulase, solid state cultivation (SSC). Results from an economic analysis indicated that the unit costs for cellulase enzyme production were $15.67 (The prices are all 2004 prices in this article, except otherwise stated. We deflated newer prices to 2004 prices using a deflation factor 0.9 per year and inflated older prices to 2004 prices using an inflation factor 1.1.) per kilogram ($/kg) and $40.36/kg, for the SSC and SmF methods, respectively, while the …

Hadron Models And Related New Energy Issues, Florentin Smarandache

Branch Mathematics and Statistics Faculty and Staff Publications

The present book covers a wide-range of issues from alternative hadron models to their likely implications in New Energy research, including alternative interpretation of lowenergy reaction (coldfusion) phenomena. The authors explored some new approaches to describe novel phenomena in particle physics. M Pitkanen introduces his nuclear string hypothesis derived from his Topological Geometrodynamics theory, while E. Goldfain discusses a number of nonlinear dynamics methods, including bifurcation, pattern formation (complex GinzburgLandau equation) to describe elementary particle masses. Fu Yuhua discusses a plausible method for prediction of phenomena related to New Energy development. F. Smarandache discusses his unmatter hypothesis, and A. Yefremov …

Dissolution, Reactor, And Environmental Behavior Of Zro2-Mgo Inert Fuel Matrix, Kenneth Czerwinski

Fuels Campaign (TRP)

This project will examine inert fuels containing ZrO₂ and MgO as the inert matrix. Ceramics with this inert matrix, Ce, U and eventually Pu will be synthesized and examined. While the Advanced Fuel Cycle Initiative focus is on inert fuels with Pu as the fissile component, this task will perform initial laboratory experiments with Ce and U. The initial work with Ce will be performed early in the project with results used as a basis for U studies. Reactor physics calculations will be used to examine suitable quantities of burnable poisons from the candidate elements Gd, Er, or Hf. …

Interaction Between Metal Fission Products And Triso Coating Materials, Clemens Heske

Fuels Campaign (TRP)

This project focuses on the chemical bonding and interface formation of metal fission products with the coating materials used in tri-isotropic (TRISO) fuel particles for gas-cooled reactors. By combining surface- and bulk-sensitive spectroscopic methods, intermediate chemical phases at the interface, intermixing/ diffusion behavior, and the electronic interface structure as a function of material (metal and coating materials) and temperature are examined.

In the past year, emphasis was placed on a detailed analysis and description of the Cs/SiC interface formation process.

Criticality Studies For Urex Processes, Denis Beller

Separations Campaign (TRP)

The completion of criticality experiments for mixtures of transuranic actinides (TRU–includes Np, Pu, Am, and Cm) that will be created during the separation of used nuclear fuel may be a requirement in order to construct prototype plants for the Global Nuclear Energy Partnership. In this program and the Advanced Fuel Cycle Research and Development (AFC R&D) program that supports it, economic and environmental methods are being developed to reduce the impact of waste from commercial nuclear fuel cycles.

Recycling of used fuel by chemically separating it into U, fission products, and TRU would be the first step in this new …

The Potential For Ch4-Enriched Biogas As A Transport Fuel In Ireland, Niamh Power

Theses

Ireland needs a biofuel industry- to aid compliance with the Kyoto Protocol, the Biofuels Directive and to secure its energ>' supply. The overall aim of this work is to assess the potential of CH4-enriched biogas as a transport fuel in Ireland. Biogas is produced during the anaerobic digestion of biomass. This work investigates biogas production from two different feedstocks; biodegradable municipal waste and agricultural crops. To assess the potential for biogas as a transport fuel the alternatives to biogas are investigated and compared. Thus digestion and composting of biodegradable municipal waste, and biogas and ethanol production from agricultural crops …

Anaerobic Digestion: Decision Support Software, Marco Poliafico

Theses

Ireland has significant quantities of livestock; meat exportation is a vibrant sector of the economy. Environmental management of animal wastes has therefore become an important concern. On the other hand in the last decade, national and EU policy debate has highlighted the need to investigate alternative energy: in particular energy for transport.

This study investigates the quantities of animal wastes produced in Ireland and their potential treatment using Anaerobic Digestion technologies. In 2005 Ireland had over 8 millions animals (cattle and pigs) and the annual slaughter accounted for over 4.2 million of these creatures. These animals have been responsible for …

Pto Performance And Nox Emissions With D2, B20, And B100 Fuels In A John Deere 3203 Compact Tractor, Matthew Hardin, Tonya Brown, Melanie Roller, Donald Johnson, George Wardlow

Discovery, The Student Journal of Dale Bumpers College of Agricultural, Food and Life Sciences

Tests were conducted in fall 2006 on a John Deere 3203 diesel tractor to determine differences in specific fuel consumption, power take-off (PTO) torque, PTO power, thermal efficiency, and oxides of nitrogen (NOx) emissions between No. 2 diesel (D2), 20% biodiesel (B20), and 100% biodiesel (B100). Four 1-hour tests were conducted on each fuel. The results indicated no statistically significant differences (p≤.05) between D2 or B20 on any variable of interest. However, B100 resulted in significantly (p≤.05) increased, specific fuel consumption and thermal efficiency and decreased PTO torque and PTO power over both D2 and B20. These data suggest that …

Multi-Phase Flow Analysis In Oil And Gas Engineering Systems And Its Modelling, Orlando F. Ayala, Luis F. Ayala, Orlando M. Ayala

Engineering Technology Faculty Publications

[Introduction] Two-phase flow is very common in industrial processes and its applications were already in use in ages as remote as the era of Archimedes. At the present time, many industrial processes rely on multi-phase phenomena for the transport of energy and mass or for material processing. During the last century, the nuclear, chemical and petroleum industries propelled intense research activity in the area. Their efforts have been aimed at the demystification of the mechanisms taking place during this complex flow situation.

An Institutional Analysis Of Oil And Gas Sector Development And Environmental Management In The Yukon Territory, Jason C. May

Theses and Dissertations (Comprehensive)

This thesis investigates the ways in which oil and gas development priorities and concern for the environment are integrated within strategic planning and management frameworks, and how associated conflict is addressed, in a case study of the Yukon. Because substantial ground-based oil and gas activity is yet to occur in the territory, a thorough understanding of the institutions and institutional arrangements set to govern future oil and gas development is a valuable tool for gauging the capacity to integrate these priorities. Therefore, this thesis employs the Institutional Analysis and Development (IAD) framework to analyze the legislation, regulations, policies, and institutions …