Oil, Gas, and Energy Commons^™

The Utilization Of Dry Scrubber Material For The Production Of Calcium Sulfoaluminate Clinkers And Cements, Tristana Y. Duvallet, Robert B. Jewell, Anne E. Oberlink, Thomas L. Robl

World of Coal Ash Proceedings

No abstract provided.

Two Bottom Ash Management/Handling System Enhancement Case Studies – From Technology Evaluation And Design Through Construction And Performance Verification, George Mckenzie, Aaron Davis, Chris Pickelmann, Jason Obermeyer

World of Coal Ash Proceedings

No abstract provided.

Slurry-Trench Cutoff Walls For The Containment Of The Coal Combustion Residuals (Ccr) Impacted Groundwater: Evaluation Of Hydraulic Conductivity And Consolidation Properties Of Soil-Bentonite Backfills, Y.L. Yang, Krishna Reddy, Y.J. Du, R.D. Fan

World of Coal Ash Proceedings

No abstract provided.

Challenges Met In Using Bottom Ash As A Landfill Drainage Media, William M. Strachan

World of Coal Ash Proceedings

No abstract provided.

Ccp Beneficial Use Risk Assessment: Case Studies For Three Different Applications, Andrew Bittner, Ari Lewis

World of Coal Ash Proceedings

No abstract provided.

Corrective Measures/Corrective Action (Cm/Ca) Strategies That Effectively Integrate Engineered Pond Closures And Short/Long-Term Groundwater Management With Case Study Examples, Steve Putrich

World of Coal Ash Proceedings

No abstract provided.

Experimental Test Method To Determine The Reactivity Of Fly Ash For Use In Concrete Mixture Proportioning, Antara Choudry, Deborah Glosser, O. Burkan Isgor, W. Jason Weiss

World of Coal Ash Proceedings

No abstract provided.

Overview Of Epri Research On Environmental Issues And Beneficial Use Of Coal Combustion Products, Bruce Hensel, Ken Ladwig

World of Coal Ash Proceedings

No abstract provided.

Is My Site A Candidate For A Groundwater Natural Attenuation Remedy? A Geochemist’S Perspective, Bob Glazier

World of Coal Ash Proceedings

No abstract provided.

Panel On Liquefaction Of Ponded Fly Ash: From Laboratory To Practice, Tarunjit S. Butalia

World of Coal Ash Proceedings

No abstract provided.

Managing Landfill Leachate In A World Without Ash Basins: Lessons Learned And Practical Considerations, Evan Andrews, Michael Lazar

World of Coal Ash Proceedings

No abstract provided.

Developing Enhanced Monitored Natural Attenuation Strategies Using Reactive Transport Models, Pj Nolan, Hugh Davies, Greg Hebeler, Rens Verburg

World of Coal Ash Proceedings

No abstract provided.

Impoundment Closure Enhancement Measures To Support Groundwater Compliance, John Hesemann, Wayne Weber, Eric Dulle

World of Coal Ash Proceedings

No abstract provided.

Enhancing Coal Ash Impoundment Closure Using Value Engineering, Holt Wheeler, Trey Mangers, Paul Lear

World of Coal Ash Proceedings

No abstract provided.

Reduction Of Amine Emissions From An Aqueous Amine Carbon Dioxide Capture System Using Charged Colloidal Gas Aphrons, Xiaobing Li, Jesse G. Thompson, Kunlei Liu

Center for Applied Energy Research Faculty Patents

The present invention includes a system and process to reduce amine mist emissions (or MEA) from carbon capture systems using colloidal gas aphrons (CGA), and includes a method for separating and recovering an amine solvent (e.g., in the form of entrained droplets/mist and/or fine aerosol particles) from a carbon dioxide scrubbed flue gas stream exiting a carbon capture system (e.g., oil-fired power plants, coal-fired power plants, and/or natural gas combined cycle plants).

Fischer–Tropsch: Product Selectivity–The Fingerprint Of Synthetic Fuels, Wilson D. Shafer, Muthu Kumaran Gnanamani, Uschi M. Graham, Jia Yang, Cornelius M. Masuku, Gary Jacobs, Burtron H. Davis

Center for Applied Energy Research Faculty and Staff Publications

The bulk of the products that were synthesized from Fischer–Tropsch synthesis (FTS) is a wide range (C₁–C₇₀₊) of hydrocarbons, primarily straight-chained paraffins. Additional hydrocarbon products, which can also be a majority, are linear olefins, specifically: 1-olefin, trans-2-olefin, and cis-2-olefin. Minor hydrocarbon products can include isomerized hydrocarbons, predominantly methyl-branched paraffin, cyclic hydrocarbons mainly derived from high-temperature FTS and internal olefins. Combined, these products provide 80–95% of the total products (excluding CO₂) generated from syngas. A vast number of different oxygenated species, such as aldehydes, ketones, acids, and alcohols, are also embedded in this product range. …

Method Of Increasing Mass Transfer Rate Of Acid Gas Scrubbing Solvents, Joseph E. Remias, Cameron A. Lippert, Kunlei Liu

Center for Applied Energy Research Faculty Patents

A method of increasing the overall mass transfer rate of acid gas scrubbing solids is disclosed. Various catalyst compounds for that purpose are also disclosed.

Effect Of Pt Promotion On The Ni-Catalyzed Deoxygenation Of Tristearin To Fuel-Like Hydrocarbons, Ryan Loe, Kelsey Huff, Morgan Walli, Tonya Morgan, Dali Qian, Robert Pace, Yang Song, Mark Isaacs, Eduardo Santillan-Jimenez, Mark Crocker

Center for Applied Energy Research Faculty and Staff Publications

Pt represents an effective promoter of supported Ni catalysts in the transformation of tristearin to green diesel via decarbonylation/decarboxylation (deCO_x), conversion increasing from 2% over 20% Ni/Al₂O₃ to 100% over 20% Ni-0.5% Pt/Al₂O₃ at 260 °C. Catalyst characterization reveals that the superior activity of Ni-Pt relative to Ni-only catalysts is not a result of Ni particle size effects or surface area differences, but rather stems from several other phenomena, including the improved reducibility of NiO when Pt is present. Indeed, the addition of a small amount of Pt to the supported Ni …

Continuous Catalytic Deoxygenation Of Waste Free Fatty Acid-Based Feeds To Fuel-Like Hydrocarbons Over A Supported Ni-Cu Catalyst, Ryan Loe, Yasmeen Lavoignat, Miranda Maier, Mohanad Abdallah, Tonya Morgan, Dali Qian, Robert Pace, Eduardo Santillan-Jimenez, Mark Crocker

Center for Applied Energy Research Faculty and Staff Publications

While commercial hydrodeoxygenation (HDO) processes convert fats, oils, and grease (FOG) to fuel-like hydrocarbons, alternative processes based on decarboxylation/decarbonylation (deCO_x) continue to attract interest. In this contribution, the activity of 20% Ni-5% Cu/Al₂O₃ in the deCO_x of waste free fatty acid (FFA)-based feeds—including brown grease (BG) and an FFA feed obtained by steam stripping a biodiesel feedstock—was investigated, along with the structure-activity relationships responsible for Ni promotion by Cu and the structural evolution of catalysts during use and regeneration. In eight-hour experiments, near quantitative conversion of the aforementioned feeds to diesel-like hydrocarbons was achieved. …

Fractionation And Characterization Of Lignin Streams From Unique High-Lignin Content Endocarp Feedstocks, Wenqi Li, Kirtley Amos, Mi Li, Yunqiao Pu, Seth Debolt, Arthur J. Ragauskas, Jian Shi

Biosystems and Agricultural Engineering Faculty Publications

Background: Lignin is a promising source of building blocks for upgrading to valuable aromatic chemicals and materials. Endocarp biomass represents a non-edible crop residue in an existing agricultural setting which cannot be used as animal feed nor soil amendment. With significantly higher lignin content and bulk energy density, endo-carps have significant advantages to be converted into both biofuel and bioproducts as compared to other biomass resources. Deep eutectic solvent (DES) is highly effective in fractionating lignin from a variety of biomass feedstocks with high yield and purity while at lower cost comparing to certain ionic liquids.

Results: In the present …

Detection And Characterization Of The Tin Dihydride (Snh2 And Snd2) Molecule In The Gas Phase, Tony C. Smith, Dennis J. Clouthier

Chemistry Faculty Publications

The SnH₂ and SnD₂ molecules have been detected for the first time in the gas phase by laser-induced fluorescence (LIF) and emission spectroscopic techniques through the ùB₁–X̃¹A₁ electronic transition. These reactive species were prepared in a pulsed electric discharge jet using (CH₃)₄Sn or SnH₄/SnD₄ precursors diluted in high pressure argon. Transitions to the electronic excited state of the jet-cooled molecules were probed with LIF, and the ground state energy levels were measured from single rovibronic level emission spectra. The LIF spectrum of SnD_{2 …}

Asymmetric Price Volatility Transmission Between U.S. Biofuel, Corn, And Oil Markets, Sayed Saghaian, Mehdi Nemati, Cory Walters, Bo Chen

Agricultural Economics Faculty Publications

Linkages between agricultural commodity and energy prices have become more complex with increased ethanol production. The concern is whether the new corn–ethanol links lead to volatility-spillover transmission between food and energy prices. We investigate asymmetric volatility spillovers between oil, corn, and ethanol prices using a BEKK-multivariate-GARCH approach. Additionally, we use daily, weekly, and monthly futures prices to examine whether the use of different-frequency data leads to inconsistent results. The results support the existence of asymmetric volatility transmission between corn and ethanol prices. Furthermore, the volatility-spillover effects are different for the different-frequency prices, and positive and negative price changes generate inconsistent …

Synergistic Interactions Of H2 And N2 With Molten Gallium In The Presence Of Plasma, Maria L. Carreon, Daniel F. Jaramillo-Cabanzo, Indira Chaudhuri, Madhu Menon, Mahendra K. Sunkara

Physics and Astronomy Faculty Publications

The present study examines the interaction of hydrogen and nitrogen plasmas with gallium in an effort to gain insights into the mechanisms behind the synergetic effect of plasma and a catalytic metal. Absorption/desorption experiments were performed, accompanied by theoretical-computational calculations. Experiments were carried out in a plasma-enhanced, Ga-packed, batch reactor and entailed monitoring the change in pressure at different temperatures. The results indicated a rapid adsorption/dissolution of the gas into the molten metal when gallium was exposed to plasma, even at a low temperature of 100 °C. The experimental observations, when hydrogen was used, indicate that gallium acts as a …

Assessment Of Thermal Maturity Trends In Devonian–Mississippian Source Rocks Using Raman Spectroscopy: Limitations Of Peak-Fitting Method, Jason S. Lupoi, Luke P. Fritz, Thomas M. Parris, Paul C. Hackley, Logan Solotky, Courtland F. Eble, Steve Schlaegle

Faculty, Staff, and Affiliated Publications--KGS

The thermal maturity of shale is often measured by vitrinite reflectance (VRo). VRo measurements for the Devonian–Mississippian black shale source rocks evaluated herein predicted thermal immaturity in areas where associated reservoir rocks are oil-producing. This limitation of the VRo method led to the current evaluation of Raman spectroscopy as a suitable alternative for developing correlations between thermal maturity and Raman spectra. In this study, Raman spectra of Devonian–Mississippian black shale source rocks were regressed against measured VRo or sample-depth. Attempts were made to develop quantitative correlations of thermal maturity. Using sample-depth as a proxy for thermal maturity is not without …

Catalytic Oxidation And Depolymerization Of Lignin In Aqueous Ionic Liquid, Lalitendu Das, Siquan Xu, Jian Shi

Biosystems and Agricultural Engineering Faculty Publications

Lignin is an integral part of the plant cell wall, which provides rigidity to plants, also contributes to the recalcitrance of the lignocellulosic biomass to biochemical and biological deconstruction. Lignin is a promising renewable feedstock for aromatic chemicals; however, an efficient and economic lignin depolymerization method needs to be developed to enable the conversion. In this study, we investigated the depolymerization of alkaline lignin in aqueous 1-ethyl-3-methylimidazolium acetate [C₂C₁Im][OAc] under oxidizing conditions. Seven different transition metal catalysts were screened in presence of H₂O₂ as oxidizing agent in a batch reactor. CoCl₂ and …

Enhancements In Mass Transfer For Carbon Capture Solvents Part I: Homogeneous Catalyst, Leland R. Widger, Moushumi Sarma, Jonathan J. Bryant, David S. Mannel, Jesse G. Thompson, Cameron A. Lippert, Kunlei Liu

Center for Applied Energy Research Faculty and Staff Publications

The novel small molecule carbonic anhydrase (CA) mimic [Co^III(Salphen-COO⁻)Cl]HNEt₃ (1), was synthesized as an additive for increasing CO₂ absorption rates in amine-based post-combustion carbon capture processes (CCS), and its efficacy was verified. 1 was designed for use in a kinetically slow but thermally stable blended solvent, containing the primary amines 1-amino-2-propanol (A2P) and 2-amino-2-methyl-1-propanol (AMP). Together, the A2P/AMP solvent and 1 reduce the overall energy penalty associated with CO₂ capture from coal-derived flue gas, relative to the baseline solvent MEA. 1 is also effective at increasing absorption kinetics of kinetically fast solvents, such …

Solvent Degradation And Emissions From A 0.7mwe Pilot Co2 Capture System With Two-Stage Stripping, Jesse Thompson, Heather Nikolic, Megan Combs, Saloni Bhatnagar, Jonathan Pelgen, Keemia Abad, Kunlei Liu

Center for Applied Energy Research Faculty and Staff Publications

The UKy-CAER team successfully tested an advanced 0.7 MWe post-combustion CO₂ capture system on a coal-fired power plant using a heat integration process combined with two-stage stripping to enhance the CO₂ absorber performance. One of the unique feature of the UKy-CAER integrated process is a two-stage stripping unit for solvent regeneration. The secondary stripper is empowered by the heat rejection from a conventional steam-heated (primary) stripper. The secondary stripper outlet stream at the commercial scale can be used as boiler secondary combustion air, consequently enriching the flue gas with CO₂, resulting in less energy penalty required …

Fischer–Tropsch Synthesis: Effect Of Ammonia On Product Selectivities For A Pt Promoted Co/Alumina Catalyst, Venkat Ramana Rao Pendyala, Wilson D. Shafer, Gary Jacobs, Michela Martinelli, Dennis E. Sparks, Burtron H. Davis

Center for Applied Energy Research Faculty and Staff Publications

The effects of co-fed ammonia in synthesis gas on the activity and product selectivities of a typical cobalt catalyst (0.5% Pt–25% Co/Al₂O₃) were investigated during the Fischer–Tropsch synthesis using a continuously stirred tank reactor (CSTR). The product selectivities were compared at a similar CO conversion level for various concentrations (10–1000 ppmv) of ammonia, as well as clean (un-poisoned) conditions. The addition of 10–1000 ppmv ammonia (concentration of ammonia with respect to the syngas feed) significantly decreased activity; the percentage of deactivation was similar (∼40%) for the various concentrations of ammonia used. At similar CO conversions, the …

Evaluation Of Flocculation, Sedimentation, And Filtration For Dewatering Of Scenedesmus Algae, Nicholas A. Rhea, Jack Groppo, Czarena Crofcheck

Biosystems and Agricultural Engineering Faculty Publications

Algae can be used as a feedstock for agricultural fertilizers, livestock and poultry feeds, anaerobic digestion, and biofuel production. For each end product, the requirements for moisture content (or solids content) vary, such that a desirable water removal strategy needs to be adaptable to varying levels of water removal. Flocculation, sedimentation, and filtration were evaluated as possible strategies for thickening and dewatering of algae. The goal of this study was to validate that algae cells treated by such means could be processed by vacuum belt filters and to determine the conditions under which the solids content could be increased to …

Stratigraphic, Geochemical, And Geochronological Analysis Of The Wolfcamp-D Interval, Midland Basin, Texas, Zachary S. Perlman

Theses and Dissertations--Earth and Environmental Sciences

Subsurface data derived from ~388 ft of drill core from Martin County (TX) were used to understand the depositional setting of the Wolfcamp-D, a petroleum producing interval in the Midland Basin. Elemental geochemistry collected via x-ray fluorescence revealed a highly variable depositional history marked by the deposition of diverse siliciclastic and carbonate lithofacies. Integration of multiple datasets resulted in the interpretation of nine lithofacies, whose deposition appears cyclical. Correlations between molybdenum and total organic carbon indicate slow recharge of bottom waters and anoxic/euxinicconditions within the basin. The presence of phosphatic nodules coinciding with siliceous black mudrocks suggested high levels of …