Oil, Gas, and Energy Commons^™

Synthesis Of Palladium And Palladium-Copper Nanostructures As Electrocatalysts, Haibin Wu

Graduate Theses and Dissertations

Pd and its alloys are alternatives of Pt as promising catalysts and electrocatalysts for many reactions. Size controlled synthesis of nanoparticles remains a major research subject, since smaller size particles show better catalytic performance. In this work, we developed a modified chemical wet method to prepare Pd and Pd-Cu nanostructures with uniform small size. Different sizes and shapes of Pd nanostructures were successfully synthesized by using the two reducing agents (i.e., L-ascorbyl-6-palmitate or phenylphosphinic acid). The reducing agents play a role to control the final morphologies and sizes of particles. The use of L-ascorbyl-6-palmitate favors to form irregular branch shapes …

Transformation Of Swine Manure And Algal Consortia To Value-Added Products, Mahmoud A. Sharara

Graduate Theses and Dissertations

The swine production sector is projected to grow globally. In the past, this growth manifested itself in increased herd sizes and geographically concentrated production. Although economically sound, these trends had negative consequences on surrounding ecosystems. Over-application of manure resulted in water quality degradation, while long-term storage of manure slurries was found to promote release of potent GHG emissions. There is a need for innovative approaches for swine manure management that are compatible with current scales of production, and increasingly strict environmental regulations.

This study aims to investigate the potential for incorporating gasification as part of a novel swine manure management …

The Power Behind The Controversy: Understanding Local Policy Elites' Perceptions On The Benefits And Risks Associated With High Voltage Power Line Installation In The State Of Arkansas, Rachael Marie Moyer

Graduate Theses and Dissertations

Following a proposal for the installation of high voltage power lines in northwest Arkansas, a controversial policy debate emerged. Proponents of the transmission line argue that such an installation is inevitable and necessary to efficiently and reliably support the identified electric load in the region. Opponents claim that the lines will degrade the natural environment and hamper the tourism-based local economy in affected regions, notably in Ozark Mountain areas. This study seeks to understand how local policy elites perceive the benefits and risks associated with proposed transmission lines, which is a critical step in comprehending the formation and changes of …

Enhancement Of The Performance Of Gaas Based Solar Cells By Using Plasmonic, Anti-Reflection Coating And Hydrophobic Effects, Yahia Fayiz Makableh

Graduate Theses and Dissertations

Investigation of renewable energy resources is gaining huge momentum in recent years due to the limited fossil fuels, and their detriment impact on the environment. Solar energy is promising to meet the increased energy demand. In order to achieve this goal, solar energy has to be harvested efficiently at low cost. Therefore, higher efficiency solar cells are the primary focus of research worldwide. Photovoltaics based on InAs/GaAs intermediate band solar cells and their device performance enhancements are investigated in this dissertation. The device enhancement is carried out by surface modification methods. The dissertation work is inspired by the need of …

Experimental Verification And Integration Of A Next Generation Smart Power Management System, Tavis Clemmer

Graduate Theses and Dissertations

With the increase in energy demand by the residential community in this country and the diminishing fossil fuel resources being used for electric energy production there is a need for a system to efficiently manage power within a residence. The Smart Green Power Node (SGPN) is a next generation energy management system that automates on-site energy production, storage, consumption, and grid usage to yield the most savings for both the utility and the consumer. Such a system automatically manages on-site distributed generation sources such as a PhotoVoltaic (PV) input and battery storage to curtail grid energy usage when the price …

Incorporating Environmental And Social Factors Into Decision-Making Of An Oil And Gas Industry To Improve Sustainability, Gaurav Dabhadkar

Graduate Theses and Dissertations

The energy industry (including the oil and gas industry) is facing unparalleled scrutiny and demands from stakeholders including investors, regulators (industry and environmental), communities, and other stakeholders. Sustainable development is one of the major concerns of the oil and gas industry. Companies are seeking to increase sustainability of their operations by considering environmental and Social concerns in addition to economic concerns. Oil and gas companies need to take decisions at different stages of the product life cycle (e.g. planning, design, exploration, production, and clean-up) which have direct or indirect impact on the organization's objectives. Addressing economic, technical, Social, and environmental …

Top-Down Aluminum Induced Crystallization For Photovoltaics, Seth Daniel Shumate

Graduate Theses and Dissertations

Passivating silicon solar cell surfaces is critical to fabricating very high efficiency and low cost photovoltaic devices. The sun-facing surface of the solar cell, known as the emitter, is particularly important when designing a solar cell. This work focused first on an alternative method of forming the emitter of silicon solar cells, and secondly on a method for improving the surface passivation of both these non-traditional and standard n-type solar cells.

Top-down aluminum induced crystallization (TAIC) was used for forming a polycrystalline silicon layer from amorphous silicon using aluminum to catalyze the crystallization at much lower temperatures than otherwise possible. …

Characterization Of Cellulase Enzyme Inhibitors Formed During The Chemical Pretreatments Of Rice Straw, Kalavathy Rajan

Graduate Theses and Dissertations

Production of fuels and chemicals from a renewable and inexpensive resource such as lignocellulosic biomass is a lucrative and sustainable option for the advanced biofuel and bio-based chemical platform. Agricultural residues constitute the bulk of potential feedstock available for cellulosic fuel production. On a global scale, rice straw is the largest source of agricultural residues and is therefore an ideal crop model for biomass deconstruction studies. Lignocellulosic biofuel production involves the processes of biomass conditioning, enzymatic saccharification, microbial fermentation and ethanol distillation, and one of the major factors affecting its techno-economic feasibility is the biomass recalcitrance to enzymatic saccharification. Preconditioning …

Life Cycle Assessment Projection Of Photovoltaic Cells: A Case Study On Energy Demand Of Quantum Wire Based Photovoltaic Technology Research, Shilpi Mukherjee

Graduate Theses and Dissertations

With increasing clean-energy demand, photovoltaic (PV) technologies have gained attention as potential long-term alternative to fossil fuel energy. However, PV research and manufacture still utilize fossil fuel-powered grid electricity. With continuous enhancement of solar conversion efficiency, it is imperative to assess whether overall life cycle efficiency is also being enhanced. Many new-material PV technologies are still in their research phase, and life cycle analyses of these technologies have not yet been performed. For best results, grid dependency must be minimized for PV research, and this can be accomplished by an analytical instrument called Life Cycle Assessment (LCA).

LCA is the …

Identifying, Monitoring, Quantifying And Converting Algae To Bio-Fuels In Bio-Reactors, Alice C. Jernigan

Graduate Theses and Dissertations

Growing algae as a source for bio-fuels has become an area of interest due to concerns about global warming and the reliability and ecology of the production of fossil fuels. Dried algae harvested from a pilot water quality improvement technology at the Rockaway Wastewater Treatment Facility in New York were examined as a source of carbohydrates and lipids for the production of bio-fuels in bio-reactors. The length of storage time, storage conditions, sugar and lipid extraction processes, and fuel production were studied. The results show that if the algae is stored dry (0.015 g/g algae even after a year in …

Awareness, Use, And Perceptions Of Biodiesel: A Comparison Of Consumers In Belgium And The United States, Maggie Jo Pruitt, Leslie D. Edgar, Donald M. Johnson

Discovery, The Student Journal of Dale Bumpers College of Agricultural, Food and Life Sciences

Belgian (N = 61) and American (N = 134) fuel consumers were interviewed in the summer of 2012 to determine their awareness, use, and perceptions of biodiesel. Consumers who were aware of biodiesel were asked their perceptions. A significantly P < 0.0001) higher percentage of Belgian consumers (78.7%) reported owning or driving a diesel vehicle compared to American consumers (9.0%). Belgian and American consumers moderately agreed biodiesel is a high-quality fuel. For both Belgian and American consumers, there was no significant association between owning a diesel vehicle and being aware of biodiesel or having purchased biodiesel. Although Belgian and American consumers agreed that using non-food crops for biodiesel is justified, Belgians were significantly less supportive than American consumers of using food crops for biodiesel. Both Belgian and American consumers disagreed with the statement “I would never use biodiesel”, and the two sets of consumers moderately disagreed that diesel engines would not run properly on biodiesel. Belgian and American consumers agreed that global warming is increasing; however, American consumers were more positive about the potential of biodiesel to reduce harmful exhaust emissions and global warming. Belgian consumers moderately agreed and American consumers agreed that biodiesel is better to use because it is made from renewable resources. Belgian and American consumers generally show similar perceptions of biodiesel, with the exception that American consumers were more positive toward the environmental and renewable aspects of biodiesel use. Recommendations for further research include gaining a better understanding of the potential positive influences that impact consumers’ perceptions of biodiesel.

Design Of A Pretreatment And Enzymatic Saccharification Scheme Of Understory From Managed Pine Forest For A Biochemical-Refinery Platform: The Example Of The Sweetgum Tree, Angele Djioleu

Graduate Theses and Dissertations

The possibility of using sweetgum from southern pine dominated forests as a biobased refinery feedstock was investigated. First, a baseline hydrolysis scheme for sweetgum wood and bark was designed. Sweetgum wood and bark were pretreated with 0.98% (v/v) sulfuric acid at 140°C for 30, 40, 50, 60 or 70 min and at 160°C for 30, 40, 50 or 60 min. The water insoluble solid (WIS) fraction was hydrolyzed with a cellulase enzyme cocktail. Results showed that maximum xylose and glucose yields from the wood were 82 and 86%, respectively. Similarly, the respective maximum yields of xylose and glucose from the …

The Development Of A High Performance Concrete To Store Thermal Energy For Concentrating Solar Power Plants, Emerson Esmond John

Graduate Theses and Dissertations

In recent years, due to rising energy costs as well as an increased awareness of the environmental effects of greenhouse gas emissions produced through traditional forms of energy production, there is great interest in developing alternative sources of energy. One of the most viable alternative energy sources is solar energy. In particular, concentrating solar power (CSP) technologies have been identified as an option for meeting utility needs in the U.S. Southwest. These systems are required to produce electricity not only during periods of high solar radiation but also during times of reduced radiation due to cloud cover, and even extend …

Energy Consumption And Greenhouse Gas Emissions From Commercial And Manufacturing Sectors Specific Studies On Hvac Equipment And Dairy Processing, Aik Jong Tan

Graduate Theses and Dissertations

Commercial and manufacturing sectors in United States consumed approximately 50% of the total End use energy in 2010. In 2009, 81.5% of the greenhouse gas (GHG) emitted in the United States was energy related. From the broad aspects of commercial and manufacturing sectors; two relatively narrow and specific topics, commercial building's HVAC equipment and dairy processing were chosen to increase the understanding of the energy use and GHG emission in these two sectors. Few published studies related to these two specific areas are available. The first study in this thesis discussed the energy use and GHG emissions by HVAC equipment …

Biological Strategies And Mathematical Approaches For Limiting Bacterial Contaminants And Chemical Pollutants In Bioethanol Fermentations, Alia Chahed Ep Limayem

Graduate Theses and Dissertations

During the most recent decades increased interest in fuel from biomass in the United States and worldwide has emerged each time petroleum derived-gasoline registered well publicized spikes in price. The willingness of the U.S. government to face the issues of more heavily high-priced foreign oil and climate change has led to more investment on plant-derived sustainable biofuel sources. Biomass derived from corn has become one of the primary feedstocks for bioethanol production for the past several years in the U.S. However, the argument of whether to use food as biofuel has led to a search for alternative non-food sources. Consequently, …

Mathematical Modeling Of Fluid Spills In Hydraulically Fractured Well Sites, Oluwafemi Michael Taiwo

Graduate Theses and Dissertations

Improved drilling technology and favorable energy prices have contributed to the rapid pace at which the exploitation of unconventional natural gas is taking place across the United States. As a natural gas well is being drilled, reserve pits are constructed to hold the drilling fluids and other materials returned from the drilling process. These reserve pits can fail, and when they do, plant and animal life of the surrounding area may be adversely affected. This project develops a screening tool for a suitable location for a reserve pit. This work will be a critical piece of the Infrastructure Placement Analysis …

Identifying Optimal Cellulosic Biomass Feedstock Supply Areas For Potential Biorefineries In Arkansas, Mark Cooper

Graduate Theses and Dissertations

In February 2010, the U.S. Environmental Protection Agency released the revised Renewable Fuel Standard (RFS2), mandating at least 36 billion gallons of renewable fuels to be produced annually in America, and blended into all on/off road, locomotive, and marine gasoline and diesel by the year 2022. America's existing biorefineries fall significantly short of being able to meet this mandate, resulting in the need for rapid expansion in the near future if this goal is to be met. The state of Arkansas has abundant resources to offer the renewable energy industry, if properly utilized. The goal of this thesis is to …

Effects Of Diesel And Biodiesel Blends On Engine Performance And Efficiency, Christopher Hunt, Donald Johnson, Don Edgar

Discovery, The Student Journal of Dale Bumpers College of Agricultural, Food and Life Sciences

Tests were conducted during the summer of 2009 on a John Deere 3203 diesel tractor to determine differences in specific fuel consumption (sfc), power take-off (PTO) torque (Nm), and PTO power (kW), between ultralow sulfur No. 2 Diesel (D2), 20% biodiesel (B20), 50% biodiesel (B50), and100% biodiesel (B100). Four 1-hr tests were conducted with D2, while three 1-hr tests were conducted with B20, B50, and B100. The results indicated that there was no significant (p < 0.05) difference between D2 and B20 for power or torque. Fueling with B50 resulted in significantly lower power and torque than fueling with D2 or B20, but significantly higher power and torque than fueling with B100. There were significant differences between each fuel in sfc; as the biodiesel blend increased, sfc also increased. Based on these data, B20 appears to be the optimal biodiesel blend for this and similar compact utility tractors since fueling with B20 resulted in no significant loss in power or torque (compared to D2) and only a slight increase in fuel consumption.

Describing The Economic Impact Of The Oil And Gas Industry In Arkansas, Katherine A. Deck, Viktoria Riiman

Publications and Presentations

The Arkansas oil and natural gas industries are increasingly important to the state’s economic vitality. As global demand for energy increases, domestic production is put into the spotlight. This study describes the economic impact of the oil and gas industries in Arkansas, focusing on the sector’s economic output, employment, and tax revenues.

E-85 Vs. Regular Gasoline: Effects On Engine Performance, Fuel Efficiency, And Exhaust Emissions, Jordan W. Steinhaus, Donald M. Johnson, George W. Wardlow

Discovery, The Student Journal of Dale Bumpers College of Agricultural, Food and Life Sciences

This study compared the performance, fuel efficiency, and exhaust emissions of a 2.61 kW engine fueled with regular unleaded gasoline (87 octane) and an 85% ethanol blend (E85) under two load conditions. Four 1-h tests were conducted with each fuel at both governor’s maximum (3400 rpm) and peak torque (2800 rpm) conditions for a total of 16 tests. At governor’s maximum engine speed, there were no significant differences (p>0.05) between fuels for engine torque, power, specific carbon dioxide (sCO2 ), specific carbon monoxide (sCO), specific hydrocarbons (sHC), or specific oxides of nitrogen (sNOX) emissions. However, there was a significant …

Measurement Of Transient Smoke Emissions From Diesel And Biodiesel Fuel Blends In An Agricultural Tractor, Kristin M. Pennington, Sonia R. Munoz, Donald M. Johnson, George Wardlow

Discovery, The Student Journal of Dale Bumpers College of Agricultural, Food and Life Sciences

Transient smoke emissions pose potential hazards to human health and the environment. With the increased popularity of biodiesel, there is a need to determine if these fuels produce different levels of particulate matter in exhaust emissions. This study examined the transient smoke emissions of three fuels: No. 2 petroleum diesel fuel (D2, ASTM D 975), a blend of 20% biodiesel and 80% petroleum diesel (B20, ASTM 6751), and a 100% pure biodiesel derived from animal fats (B100, ASTM D 6751). Measurements of smoke emissions were taken using the SAE J1677 snap acceleration test procedure on a John Deere 3203 compact …

Economic Impacts Of Future Biorefineries In The State Of Arkansas: An Input-Output Analysis, Sayeed R. Mehmood, M. H. Pelkki

Journal of the Arkansas Academy of Science

No abstract provided.

Projecting The Economic Impact Of The Fayetteville Shale Play For 2008-2012, Katherine A. Deck

Publications and Presentations

In 2006, the Center for Business and Economic Research released an economic impact study of the newly developing natural gas industry related to the Fayetteville Shale. The Fayetteville Shale is an unconventional gas reservoir located on the Arkansas side of the Arkoma Basin, ranging in thickness from 50 to 325 feet and ranging in depth from 1,500 to 6,500 feet. That study concluded that from 2005 to 2008, economic output of over $5.5 billion and 9,683 jobs would be generated as a result of investments in the Fayetteville Shale. Those estimates were based on the best information available when the …

Using Biosolids To Enhance Phytoremediation Of Oil-Contaminated Soil, Heather N. Markway, Duane C. Wolf, Kaaron J. Davis, Edward E. Gbur

Discovery, The Student Journal of Dale Bumpers College of Agricultural, Food and Life Sciences

While the plant rhizosphere and associated microbial processes have been shown to amplify the degradation rate of chemical residues in soils, phytoremediation can be a slow process. The objective of this greenhouse study was to determine if the addition of biosolids as an organic soil amendment would enhance growth of plants in oil-contaminated soil and thus potentially increase effectiveness of phytoremediation. Pearl millet (Pennisetum glaucum (L.) R. Br.) or sudangrass (Sorghum sudanense (Piper) Stapf (Piper)) was grown in a Captina silt loam (finesilty, siliceous, mesic Typic Fragiudults) contaminated with 5% crude oil (v/w) and amended with 24 g biosolids/kg soil. …

Life Cycle Analysis For The Cultivation And Combustion Of Miscanthus For Biofuel Compared With Natural Gas, Amanda Ashworth, Charles West, Michael Popp, Mireille Montrejaud-Vignoles, Caroline Sablayrolles, Gabrielle Benoit

Discovery, The Student Journal of Dale Bumpers College of Agricultural, Food and Life Sciences

As negative environmental and economic impacts of fossil fuels have escalated, so has the importance of renewable bioenergy crops whose feedstocks are noncompetitive with food supplies. Compared with fossil fuels, use of lignocellulosic feedstocks offers potential for greenhouse gas reduction and highly positive net energy returns because of low input demand and high yields per unit of land area, thus making them advantageous for the emerging biofuel industry. The aim of this study was to simulate environmental impacts of producing a biofuel grass for combustion use based on the inventory of inputs and their effects on eutrophication of surface waters; …

Pto Performance And Nox Emissions With D2, B20, And B100 Fuels In A John Deere 3203 Compact Tractor, Matthew Hardin, Tonya Brown, Melanie Roller, Donald Johnson, George Wardlow

Discovery, The Student Journal of Dale Bumpers College of Agricultural, Food and Life Sciences

Tests were conducted in fall 2006 on a John Deere 3203 diesel tractor to determine differences in specific fuel consumption, power take-off (PTO) torque, PTO power, thermal efficiency, and oxides of nitrogen (NOx) emissions between No. 2 diesel (D2), 20% biodiesel (B20), and 100% biodiesel (B100). Four 1-hour tests were conducted on each fuel. The results indicated no statistically significant differences (p≤.05) between D2 or B20 on any variable of interest. However, B100 resulted in significantly (p≤.05) increased, specific fuel consumption and thermal efficiency and decreased PTO torque and PTO power over both D2 and B20. These data suggest that …

Projecting The Economic Impact Of The Fayetteville Shale Play For 2005-2008, Jeffery T. Collins, Katherine A. Deck

Publications and Presentations

This study projects the general economic impact from exploration and development activities related to the Fayetteville Shale. The Fayetteville Shale is an unconventional gas reservoir located on the Arkansas side of the Arkoma Basin, ranging in thickness from 50 to 325 feet and ranging in depth from 1,500 to 6,500 feet. The Fayetteville Shale is aerially extensive and may be present across numerous counties in central and eastern Arkansas, including the counties of Cleburne, Conway, Faulkner, Independence, Johnson, St. Francis, Prairie, Van Buren, White, and Woodruff.

Laboratory-Scale Evaluation Of Incandescent And Compact Florescent Lamps For Poultry House Lighting, Leanne Gabriel, Donald M. Johnson

Discovery, The Student Journal of Dale Bumpers College of Agricultural, Food and Life Sciences

This laboratory-scale study compared 1000- and 2000-h rated 60W incandescent lamps and 6000-h rated 60W-equivalent compact florescent lamps over 6000 h of simulated broiler-house operation. The four original 1000-h incandescent lamps were replaced 22 times and the four 2000-h incandescent lamps were replaced 14 times. None of the four compact florescent lamps failed during the 6000-h experiment, although one was broken due to human error. Both types of incandescent lamps had significantly higher (p < .0001) mean illuminance (lx) than did the compact florescent lamps. The compact florescent lamps used significantly less (p < .0001) power (W) and had significantly higher (p < .0001) efficiency (lx/W) than the incandescent lamps. Despite a higher initial purchase price, the total cost (purchase + replacement + electrical) of operating compact florescent lamps was approximately 36% lower than the total cost of operating either type of incandescent lamp over the 6000 h period. The results of this study indicate that even at a least-cost price for electricity ($0.04/kW/h), growers can reduce total broiler-house lighting costs by replacing incandescent lamps with compact florescent lamps.