Environmental Monitoring Commons^™

Mixture Effects On Metal Accumulation In The Asian Clam, Corbicula Fluminea, Mark A. Huff

Electronic Theses and Dissertations

Field collected Corbicula fluminea were exposed to trace level copper, lead, and zinc with the aim of examining the preferential accumulation between the soft tissue and shell. Metal levels were based on those in a permitted industrial effluent. At 1X effluent and 2X effluent exposure levels, copper was found to preferentially accumulate in the clam soft tissue, lead was found to preferentially accumulate in the clam shell, and zinc was found to excrete back into the diluent after preferentially accumulating in the clam soft tissue. When exposed as a mixture at 1X effluent levels, copper and lead were found to …

Bioremediation Of Effluent Water In A Coal Ash Disposal Area: Optimizing Microbial Sulfate Reduction, Ryka Shea

Electronic Theses and Dissertations

Coal combustion residues (CCR) pose a serious environmental threat, even long after they are disposed of in specialized landfills, due to their complex composition and potential for leaching into waterways. This study focuses on the issue of elevated sulfate concentrations at the Martin Lake Steam Electric Station (MLSES) A-I Disposal Area in Panola County, Texas, where CCR are disposed of in a permanent landfill. Currently, this site is exceeding its regulatory limit of sulfate concentrations in its effluent and is in need of a cost-effective and sustainable solution to this problem. This research utilized benchtop experiments to investigate sulfate reducing …

Landslide Inventory And Unstable Slope Monitoring Along Highways In Eastern Tennessee, Robert Mcsweeney

Electronic Theses and Dissertations

This research introduces an unstable slope management program (USMP) for Tennessee based on federal slope management standards, along with improved methods for landslide monitoring with unmanned aerial systems (UAS) lidar and photogrammetry. In mountainous regions, monitoring slope hazards is a critical function of transportation management. A mobile field assessment form created with Survey123 was used to collect 22 unstable slope ratings in eastern Tennessee. Location points were appended with photographs, notes, and site information. Landslide scores ranged from 325 (Fair) to 1005 (Poor). UAS monitoring of a slow-moving soil landslide along I-40 near Rockwood, TN, produced high-resolution lidar and photogrammetry …

A Geospatial And Machine Learning Framework For Forecasting Ground Level Ozone Pollution, William J. Keenan

Electronic Theses and Dissertations

The major detrimental health effects of ground-level ozone (GLO) pollution make it imperative that both policy makers and ordinary citizens have access to high accuracy, high-resolution forecasts of their local area. Recently, advancements in computing power have made it possible to apply artificial intelligence (AI) techniques to a variety of big data modelling problems, including GLO forecasting and estimation. Of these AI methods, deep neural networks (DNN) have demonstrated the highest accuracy due to their ability extract non-linear relationships from high dimensional, noisy data inputs.

This research effort uses novel data sources, namely NOAA’s High Resolution Rapid Refresh (HRRR) meteorology …

Surface Water Quality Assessment Of Mingo Creek County Park: The Impacts Of Extractive Industries, Mikayla J. Bayto

Electronic Theses and Dissertations

Historical and current extraction operations and infrastructure, including natural gas pipelines, conventional and unconventional oil and natural gas drilling, longwall coal mining, and strip coal mining, occur throughout the Mingo Creek watershed of Washington County, Pennsylvania, including Mingo Creek County Park. Mingo Creek and several associated tributaries flow through Mingo Creek County Park, eventually discharging into the Monongahela River. An independent water quality study was conducted from June 2020 through July 2023 in Mingo Creek County Park to determine if historical and current extraction activities impact Mingo Creek and its associated tributaries. Weekly sampling of Mingo Creek and associated tributaries …

Assessing Sustainability Within The Brewing Industry: A Literature Review And Benchmarking Analysis., Elijah Thomas Miller

Electronic Theses and Dissertations

The goals of this study were twofold: to further examine sustainability within the brewing industry through a literature analysis across four academic journals, and a benchmarking analysis of a Louisville, Kentucky brewery’s resource consumption and emissions production. Publications related to the brewing industry were examined for the presence of sustainability keywords: “efficiency, sustainability, carbon footprint, climate change and greenhouse gas”. Benchmarking examined the local brewery’s primary production facility to determine their performance compared to other surveyed breweries pursuing sustainability across the country. Literature examination found noticeable discrepancies between the appearance of sustainability topics within article abstracts and their discussion within …

Near-Real-Time Monitoring Of Crop Progress At Field Scales By Fusing Observations From Both Polar-Orbiting And Geostationary Satellites, Yu Shen

Electronic Theses and Dissertations

No abstract provided.

Quantifying Current Soil Brine Contamination Within The Smackover Oil Field In Arkansas Using Multispectral Digital Imagery, Victoria Williams

Electronic Theses and Dissertations

A remote sensing study was performed to quantify current soil brine contamination across the historic Smackover Oil Field in south-central Arkansas, United States. The oil field was established in 1922 and was not subject to the future waste regulations created by the Arkansas Oil and Gas Commission. Brine is a waste product of oil manufacturing which contains water with high salt levels. The storage and transport of brine in the oil field created landscape scarring across the study area.

Landsat 9 multispectral digital imagery was utilized to create supervised classification maps based on earthen pits and creek scarring across the …

Investigating The Impact On Private Water Supply Of Hydraulic Fracturing Communication With An Abandoned Conventional Gas Well In New Freeport, Pa, Kiley Miller

Electronic Theses and Dissertations

In June of 2022 a “frac out” occurred in New Freeport, PA when an unconventional gas well under development by hydraulic fracturing, communicated with an abandoned gas well to the surface. An initial “zone of impact” encompassed much of the town’s main thoroughfare. Water samples were obtained from 17 private water wells, 5 springs and 1 pond (31 total samples) and analyzed for cations, anions, and light hydrocarbons. Methane was found in 18 of the samples, both located within and outside of the “zone of impact”. Mass ratio analyses indicated contamination from both unconventional and conventional wells. Interferometric Synthetic Aperture …

Development Of Standard Operating Procedure With Modified Method To Quantify Benzene And Other Volatile Organic Compounds In Air Samples Using Gas Chromatography, Heather Hall

Electronic Theses and Dissertations

Stephen F. Austin State University (SFASU) Department of Environmental Science has recently invested in a gas chromatograph which can be used to analyze air samples for volatile organic compounds (VOCs) such as benzene, toluene, ethylbenzene, and xylenes (BTEX). The goal of this project was to develop a standard operating procedure (SOP) and modify the current method for the detection of VOCs associated with oil and gas drilling activity to accommodate the equipment and capabilities of SFASU Environmental Assessment Lab. This study aims to provide the framework for future research in air quality monitoring in the Eagle Ford Shale area. An …

Using An Inventory Of Unstable Slopes To Prioritize Probabilistic Rockfall Modeling And Acid Base Accounting In Great Smoky Mountains National Park, Thomas A. O'Shea

Electronic Theses and Dissertations

An inventory of unstable slopes along transportation corridors and performance modeling are important components of geotechnical asset management in Great Smoky Mountains National Park (GRSM). Hazards and risk were assessed for 285 unstable slopes along 151 miles of roadway. A multi-criteria model was created to select fourteen sites for two-dimensional probabilistic rockfall simulations and Acid Base Accounting (ABA) tests. Simulations indicate that rock material would likely enter the roadway at all fourteen sites. ABA test results indicate that influence of significant acid-producing potential is generally confined to slaty rocks of the Anakeesta Formation and graphitic schist of the Wehutty Formation. …

Accurate Quantitation Of Hexavalent Chromium For Reference Standard Certification And Quality Control Testing Using Speciated Isotope Dilution Mass Spectrometry, James E. Henderson

Electronic Theses and Dissertations

The ability to perform accurate, repeatable, and defensible elemental and molecular speciated analysis is immensely significant for measurements that support human health, environmental science, and industry. This is especially true since trivalent chromium [Cr(III)] is necessary for proper nutrition, while hexavalent chromium [Cr(VI)] is extremely toxic, genotoxic, and carcinogenic. The main challenges associated with speciated analysis are related to reactive species that are continuously transformed or converted to other species during sample processing. Accurate determination of Cr(III) and Cr(VI) species require a method that is capable of monitoring and correcting for interconversion, bias, and instrumental error. Traditional quantitative methods, such …

Tree Canopy Effects On Roof-Harvested Rainwater In East Texas, Kimberly Gamez

Electronic Theses and Dissertations

Nine experimental metal roofs with rainwater harvesting systems were constructed and water quality parameters were measured in 2016-2017 in order to evaluate the effects of arboreal overhang on roof-harvested rainwater quality collected in East Texas. Three treatments were evaluated: Rainwater collected from roofs without any overhanging tree vegetation, rainwater collected from roofs under predominantly Southern yellow pine tree cover, and rainwater collected from roofs under predominantly hardwood tree cover. Rainwater was collected from these roofs for one year. The effects of canopy cover on water quality parameters, comparison to drinking water standards, first-flush efficiency, and seasonal effects were evaluated.

Significant …

Aerial Mineral And Organic Particulate Deposition In East Texas, Sarah Caton, Sarah Caton

Electronic Theses and Dissertations

This study determined the monthly amount, particle size distribution, and chemical composition of particulate deposition in East Texas over a one-year period. It also recognized the seasonal patterns of this deposition as well as its primary origins as either mineral or organic particulate deposition.

The study recorded the monthly mass of deposition, particle size distribution, and the chemical makeup of deposition throughout a period of twelve months at seven sampling locations. SEM-EDS technology was used in conjunction with PCI programming to measure the sizes of depositional particles throughout this time period and identify their chemical composition.

The total yearly deposition …

The Persistence Of Acid Mine Drainage At An East Texas Coal Mine, Sarah Zagurski

Electronic Theses and Dissertations

The objective of this study was to estimate the time it will take for acid forming materials (pyrite) to be weathered to a state of equilibrium and thus cease to produce acid in ground and surface waters within Oak Hill Mine. This was accomplished using an ex-situ kinetic leaching study incorporating a humidity cell in a controlled laboratory setting. Leaching was conducted on soil cores obtained from the vadose zone at Oak Hill Mine and the humidity cell was used to accelerate oxidation of the pyrite within the cores.

An in-situ field study was also conducted that monitored groundwater conditions …

Applications Of Digital Remote Sensing To Quantify Glacier Change In Glacier And Mount Rainier National Parks, Brianna Clark

Electronic Theses and Dissertations

Digital remote sensing and geographic information systems were employed in performing area and volume calculations on glacial landscapes. Characteristics of glaciers from two geographic regions, the Intermountain Region (between the Rocky Mountain and Cascade Ranges) and the Pacific Northwest, were estimated for the years 1985, 2000, and 2015. Glacier National Park was studied for the Intermountain Region whereas Mount Rainier National Park was representative of the glaciers in the Pacific Northwest. Within the thirty year period of the study, the glaciers in Glacier National Park decreased in area by 27.5 percent while those on Mount Rainier only decreased by 5.7 …

Analyzing The Effects Of Of Seasonal Land Cover And Precipitation On The Sediment Delivery Ratio Of An Agriculture Dominated Watershed., Jonah Liebman

Electronic Theses and Dissertations

Soil erosion is of escalating importance as increasing population and climate change have put increasing pressures on agricultural food production. Vegetation and precipitation are two factors that control the amount of soil erosion extant within a region. Sediment delivery ratios (SDRs) assess the ratio of soil eroded from a watershed system that is permanently removed from the system through stream sediment discharge. Using 1) river discharge and sediment concentration data and 2) the Revised Universal Soil Loss Equation (RUSLE), this thesis analyzes fluctuations in monthly SDRs for an average hydroclimatological crop-harvest season for the Senachwine Creek watershed, IL. Through calculating …

Storm Sampling To Assess Inclement Weather Impacts On Water Quality In A Karst Watershed: Sinking Creek, Watauga Watershed, East Tennessee, Porcha Mccurdy

Electronic Theses and Dissertations

Escherichia coli changes in Sinking Creek, an impaired water body in the Watauga watershed of northeast Tennessee, were assessed during storm events using water samples collected with ISCO automated samplers during eight storms at two locations. Turbidity and electrical conductivity (EC) data loggers were deployed in the creek, and dissolved oxygen (DO) was measured in situ to test the stream’s water quality and reaction to inclement weather. Cotton fabric was deployed at both locations and sent to an external lab to test for the presence of Optical Brighteners (OB), which are indicators of residential wastewater. E. coli and turbidity at …

Changes In Land Use Land Cover (Lulc), Surface Water Quality And Modelling Surface Discharge In Beaver Creek Watershed, Northeast Tennessee And Southwest Virginia, Tosin James

Electronic Theses and Dissertations

Beaver Creek is an impaired streams that is not supporting its designated use for recreation due to Escherichia coli (E.coli), and sediment. To address this problem, this thesis was divided into two studies.

The first study explored changes in Land Use Land Cover (LULC), and its impact on surface water quality. Changes in E.coli load between 1997-2001 and 2014-2018 were analyzed. Also, Landsat data of 2001, and 2018 were examined in Terrset 18.31. Mann-Whitney test only showed a significant reduction in E.coli for one site. Negative correlation was established between E.coli load, and Developed LULC, Forest LULC, and …

A Study Of Chloride Levels In Pine Creek, Allegheny County, Pa, Selina Prettner

Electronic Theses and Dissertations

Pine Creek is a 22.8-mile long tributary to the Allegheny River draining over 67 square miles of northern Allegheny County, PA. The main stem runs along Route 8 and receives extensive runoff from road salt from deicing. A site near Etna, PA sampled biweekly in 2013 consistently showed elevated conductivity that correlated with increased chloride levels. Winter road deicing runoff produced acute chloride concentrations up to 678 mg/L. Chloride fluctuated in the summer and autumn months but did not exceed the USEPA Secondary Drinking Water Standard (250 mg/L) or the aquatic life criterion for chronic concentrations (230 mg/L). Sampling throughout …

The Effects Of Constructed Wetlands On Metal Solubilization And Bioavailability In Passive Mine Remediation, Elizabeth Cochran

Electronic Theses and Dissertations

The legacy of coal mining in Appalachia has left many watersheds impacted by abandoned mine drainage. The drainage degrades streams, groundwater and habitats with acidity and toxic heavy metals. The Lowber Passive Remediation System has been in operation since 2004 to remediate high amounts of dissolved Fe, SO₄, Al, and Mn. The site consists of six settling ponds and an extensive wetlands at the finish. This study investigated the resolubilization of Fe and Mn in the wetlands and the role of bacteria in resolubilization. During three seasons, field measurements of water quality and lab analysis of Fe, Mn, …

Water Quality Assessment Of Deer Lakes County Park Before, During And After Unconventional Shale Gas Drilling, Daniel Robinson

Electronic Theses and Dissertations

Allegheny County, Pennsylvania, signed a lease to allow unconventional natural gas extraction from Marcellus Shale beneath Deer Lakes County Park in 2014. The park has three man-made lakes and four waterways that eventually flow into the Allegheny River. Drilling commenced in early 2016, and there are now five producing wells. The park has an extensive abandoned coal mine network and several abandoned oil and gas wells. Thus, an independent water quality study was undertaken beginning in July 2015. Samples from seven different sites in the park were used to establish a water quality baseline prior to the drilling. Monthly sampling …

Mercury In Big Cypress Bayou And Caddo Lake Watersheds In Marion And Harrison Counties Texas, Joseph Watkins

Electronic Theses and Dissertations

Caddo Lake has been included on the Texas Commission on Environmental Quality 303(d) list for impairment due to mercury (Hg) content since 1996. One of the primary tributaries, Big Cypress Bayou, flows across Eocene-aged rocks and sediments associated with the Wilcox Group; the Wilcox is of interest because it contains lignite coal, which has a direct link to mercury. Previous research has focused on dry deposition from fossil fuel combustion as the primary source of mercury but has not addressed the potential watershed contribution to mercury concentrations in Caddo Lake.

Big Cypress Bayou flows through Harrison and Marion counties in …

Groundwater Hydrogeolgy And Hydrochemistry Of Karst Springs In The Eastern Peninsula Of Fort Hood Military Installation, William Scribner Welles

Electronic Theses and Dissertations

The eastern peninsula of Fort Hood Military Installation is underlain by a complex karst spring network. These springs are a primary water source in a protected habitat for endangered songbirds, which has only recently begun to be fully investigated. These Fredericksburg Group springs express both epigenetic and hypogenetic karst signatures. The study area is part of a paleo reef trend, a hydraulically disconnected segment of the northern section of the Edwards Aquifer. This study utilized standard ion index values, repeated measures, and principal component analyses on the chemical profiles of six perennial springs to classify spring water sources and their …

Effectiveness Of Prescribed Fire On Meeting Fuel Load And Wildlife Habitat Management Objectives In East Texas National Forests, Trey Wall

Electronic Theses and Dissertations

Using standardized methodology outlined by the United States Forest Service and the National Forests and Grasslands in Texas’ Fire Monitoring Program for data collection, the efficacy of current Forest Service prescribed burn regimes were analyzed for 24 study sites in East Texas National Forests. Study sites were located within Sam Houston, Davy Crockett, and Angelina/Sabine National Forests. Efficacy was determined by comparing defined management objectives established by the Forest Service to the data collected at the study sites. The results conclude that most objectives, as outlined by the Forest Service, are not being met with the current practices. Re-visitation of …

Imidacloprid Persistence, Mobility, And Effect On Ecosystem Function, Joanna Hardin

Electronic Theses and Dissertations

Imidacloprid is a neonicotinoid pesticide used to protect against biting and sucking insects. Land managers rely on its systemic properties, however long-term studies investigating imidacloprid effects on ecosystem function are limited. This study investigated imidacloprid applications to Tsuga caroliniana and Tsuga canadensis over time and compared concentrations to measures of ecosystem function including soil respiration, microbial function, and invertebrate density. Results indicate that imidacloprid is persistent (p0.5). Microbial function and invertebrate density were not significantly different between control and treatment locations nor did imidacloprid concentrations correlate with ecosystem functional indicator activity (p>0.05). It is evident that imidacloprid does not …

Improving Sinkhole Mapping Using Lidar Data And Locating Sinkhole Hotspots In Johnson City, Tn, Kingsley Fasesin

Electronic Theses and Dissertations

Predicting infrastructure damage and economic impact of sinkholes requires high accuracy mapping distribution and development. The study mapped sinkholes and sinkhole hotpsots in Johnson City, TN using LiDAR-derived Digital Elevation Model (DEM) and a database of known sinkholes which were matched to LiDAR-derived depressions. For all matched depressions (n = 404), three metrics were calculated: circularity index, ratio of length to width of the Minimum Bounding Rectangle (MBR) and percent coverage of the MBR by the depression, and 3,634 new sinkholes were identified. Newly developed hotspots were identified in north Johnson City and other areas in the south near the …

Environmental Assessment Of Road Brining And Injection Wells For Disposal Of Oil And Gas Liquid Waste, Marissa Madia

Electronic Theses and Dissertations

The dramatic increase in oil and gas drilling operations in Pennsylvania over the last decade has presented a challenge for their wastewater disposal (e.g., flowback, produced water). Currently, these fluids are treated in permitted brine treatment plants or exported out of state to deep injection well facilities. In Pennsylvania, road brining for dust control is permitted for conventional well brines, and permits for three injection wells for unconventional brines are pending. This study focused on water quality impacts due to road brining in Farmington Township (45 samples) and ground and surface water in Grant Township (41 samples) prior to the …

A Comparison Of Four Wetlands Assessment Procedures Relevant To The Alluvial Valleys Of East Texas, Amy Camp

Electronic Theses and Dissertations

Currently several methods are used by public and private entities to assess wetland functional condition in support of the Section 404 Clean Water Act program. Four of these are: Forested Wetlands in Alluvial Valleys of the Coastal Plain of the Southeastern United States (SEHGM); A Regional Guidebook for Applying the Hydrogeomorphic Approach to the Functional Assessment of Forested Wetlands in Alluvial Valleys of East Texas (ETXHGM); Texas Rapid Assessment Method (TXRAM); and the Wildlife Habitat Appraisal Procedure (WHAP). Little previous research compares wetland functional assessment methods. Results of the SEHGM, ETXHGM, TXRAM, and WHAP methods were compared on five East …

Geophysical Delineation Of Megaporosity And Fluid Migration Pathways For Geohazard Characterization Within The Delaware Basin, Culberson County, Texas, Jonathan David Woodard

Electronic Theses and Dissertations

ABSTRACT

Differential dissolution of gypsum karst within the Delaware Basin poses a significant threat to infrastructure that society depends on. The study area is located in Culberson County, Texas and traverses a distance of approximately 54 kilometers along RM 652 within the Gypsum Plain which is situated on the northern margin of the Chihuahua Desert and includes outcrops of Castile and Rustler strata that host karst geohazards. Regions of karst geohazard potential have been physically surveyed proximal to the study area in evaporites throughout the Castile Formation outcrop; minimal hazards, in comparison to the Castile Formation, have been documented in …