Environmental Health and Protection Commons^™

Regulation Of Dissolved Arsenic Using Zero-Valent Iron With Gypsum And Sulfate Reducing Bacteria: Laboratory Microcosm And Column Studies, Ying Liu

Dissertations, Theses, and Capstone Projects

Bench scale microcosm incubation was first conducted in two stages to examine the removal of arsenic (As) by zero-valent iron (ZVI) in the presence of sulfate reducing bacteria, gypsum as well as organic substrates under anaerobic condition. About 98% of dissolved As was removed from solution within 20 days with concurrent decrease of dissolved sulfate and growth of bacterial population. Mineralogy analysis using SEM-EDS found the formation of iron sulfide and Fourier-transformed infrared (FTIR) spectroscopy analysis indicates that some As is associated with pyrite. The main iron corrosion product was found as ferrihydrite with traces of lepidocrocite. Sequential leaching shows …

Including Farmer Irrigation Behavior In A Sociohydrological Modeling Framework With Application In North India, Jimmy O’Keeffe, Simon Moulds, Emma Bergin, Nick Brozovic, Ana Mijic, Wouter Buytaert

Daugherty Water for Food Global Institute: Faculty Publications

Understanding water user behavior and its potential outcomes is important for the development of suitable water resource management options. Computational models are commonly used to assist water resource management decision making; however, while natural processes are increasingly well modeled, the inclusion of human behavior has lagged behind. Improved representation of irrigation water user behavior within models can provide more accurate and relevant information for irrigation management in the agricultural sector. This paper outlines a model that conceptualizes and proceduralizes observed farmer irrigation practices, highlighting impacts and interactions between the environment and behavior. It is developed using a bottom-up approach, informed …

The Effects Of Continuous Diazinon Exposure On Growth And Reproduction In Japanese Medaka Using A Modified Medaka Extended One Generation Reproduction Test (Meogrt), Kevin Flynn, Doug Lothenbach, Frank Whiteman, Dean Hammermeister, Joe Swintek, Matthew Etterson, Rodney Johnson

United States Environmental Protection Agency: Publications

The Medaka Extended One Generation Reproduction Test (MEOGRT) is a Tier 2 test within U.S. Environmental Protection Agency's (USEPA) Endocrine Disruptor Screening Program (EDSP), designed to characterize the potential adverse effects to fish of exposure to chemical that can cause disruption of the endocrine system. The MEOGRT focuses primarily on adverse effects to reproduction while collecting information regarding effects on growth, survival, and endocrine-related endpoints. However, the risk assessment process for fish, as mandated by legislation such as the Federal Insecticide, Fungicide, and Rodenticide Act (FIFRA) or the Toxic Substances Control Act (TSCA), could benefit from a more detailed assessment …

Review Of Curbing Catastrophe: Natural Hazards And Risk Reduction In The Modern World, Kira H. Hamman

Numeracy

Timothy H. Dixon. 2017. Curbing Catastrophe: Natural Hazards and Risk Reduction in the Modern World. (New York, NY: Cambridge University Press) 300 pp. ISBN 978-1108113663.

In Curbing Catastrophe, Timothy H. Dixon explores commonalities among natural disasters like Hurricane Katrina, the 2010 earthquake in Haiti, and the meltdown at Fukushima. He identifies communication failure between scientists and policy makers as a major culprit in the devastation that results from such events and offers strategies for improving that communication. He includes optional in-depth scientific and quantitative examinations of the events and the resulting devastation, making the book appropriate for use …

Coupling Toxicokinetic–Toxicodynamic And Population Models For Assessing Aquatic Ecological Risks To Time-Varying Pesticide Exposures, Glen Thursby, Keith Sappington, Matthew Etterson

United States Environmental Protection Agency: Publications

Population modeling evaluations of pesticide exposure time series were compared with aspects of a currently used risk assessment process. The US Environmental Protection Agency’s Office of Pesticide Programs models daily aquatic 30-yr pesticide exposure distributions in its risk assessments, but does not routinely make full use of the information in such time series.We used mysid shrimp Americamysis bahia toxicity and demographic data to demonstrate the value of a toxicokinetic– toxicodynamic model coupled with a series of matrix population models in risk assessment refinements. This species is a small epibenthic marine crustacean routinely used in regulatory toxicity tests. We demonstrate how …

Column Tests Of Nitrate Breakthrough Behavior In Subsurface Sediments To Understand Transport In The Root-Zone, Rebecca Sally Haworth, Emma Rose Goodwin

Natural Resources Management and Environmental Sciences

Nitrate has become an increasingly ubiquitous pollutant in surface and groundwater, posing a threat to hu- man health and ecosystems. Nitrogen is a necessary nutrient for plant growth and is limiting in many soils. As a result, farmers often add nitrogen to soil in a usable form such as nitrate, nitrite, or ammonia through the addition of fertilizer.

A Quantitative Analysis Of The Effects Of Urbanization, Mesophication And Prescribed Burns On Oak Woodlands In The Chicago Metropolitan Area, Chad Populorum

Celebration of Learning

Urban expansion has had devastating impacts on forest ecosystems, especially within the past century. Human attempts to dominate nature have diminished natural disturbance regimes, which have maintained the biodiversity and historic composition of these ecosystems. Fires have been a prominent force in maintaining the structure of oak, hickory and other heliophytic (sun loving and fire-adapted) forest systems. Human induced fire suppression has led to mesophication across North America. Mesophication is the transition from drier conditions with open canopies to wetter conditions with closed canopies. These new conditions decrease the survival rates of these important species and begin to favor mesophytic …

Radical Social Ecology As Deep Pragmatism: A Call To The Abolition Of Systemic Dissonance And The Minimization Of Entropic Chaos, Arielle Brender

Student Theses 2015-Present

This paper aims to shed light on the dissonance caused by the superimposition of Dominant Human Systems on Natural Systems. I highlight the synthetic nature of Dominant Human Systems as egoic and linguistic phenomenon manufactured by a mere portion of the human population, which renders them inherently oppressive unto peoples and landscapes whose wisdom were barred from the design process. In pursuing a radical pragmatic approach to mending the simultaneous oppression and destruction of the human being and the earth, I highlight the necessity of minimizing entropic chaos caused by excess energy expenditure, an essential feature of systems that aim …

Analysis Of Surface Soil Lead Contamination In Urban Neighborhoods Of Davenport, Ia, Joseph Teresi

Geology: Student Scholarship & Creative Works

Davenport, IA, is a typical Midwestern city with a population of ~102,600 residents and is characterized by aging infrastructure and housing stock. Consequently, alarmingly high rates of child lead poisoning—as a result of deteriorating lead paint—constitute a major public health concern in some urban neighborhoods. Augustana College’s Upper Mississippi Center is an organization that helps urban and rural communities solve sustainability challenges by mobilizing the college’s resources. In conjunction with their Sustainable Working Landscapes Initiative (SWLI), a research team conducted free home lead screenings in vulnerable Davenport neighborhoods to better understand the severity of the problem. Via appointment, 27 homes …

Spatial Analysis Of Air Particulate Pollution Distributions And Its Relation To Real Property Value In Beijing, China, Yingyu Zhang

Great Lakes Center Masters Theses

Air particulate pollution contributes the major air pollution in Beijing, China. In this research, concentrations of air particulate pollutants were measured at a total of twenty-three field locations in the urban districts of Beijing applying a laser particle counter in June and December 2015. Geographic Information System (GIS) was utilized to study the two and three-dimensional spatial distributions of air particulate pollution (PM0.5, PM1.0, PM2.5, PM5.0, PM10). Geostatistical or spatial statistical models were applied to interpolate the spatial distributions of air particulate pollution and real property values in the study area. Geographically Weighted Regression (GWR) was applied to analyze the …

Advancing The Understanding Of Environmental Transformations, Bioavailability And Effects Of Nanomaterials, An International Us Environmental Protection Agency—Uk Environmental Nanoscience Initiative Joint Program, Mitch M. Lasat, Kian Fan Chung, Jamie Lead, Steve Mcgrath, Richard J. Owen, Sophie Rocks, Jason M. Unrine, Junfeng Zhang

Plant and Soil Sciences Faculty Publications

Nanotechnology has significant economic, health, and environmental benefits, including renewable energy and innovative environmental solutions. Manufactured nanoparticles have been incorporated into new materials and products because of their novel or enhanced properties. These very same properties also have prompted concerns about the potential environmental and human health hazard and risk posed by the manufactured nanomaterials. Appropriate risk management responses require the development of models capable of predicting the environmental and human health effects of the nanomaterials. Development of predictive models has been hampered by a lack of information concerning the environmental fate, behavior and effects of manufactured nanoparticles. The United …

An Assessment Of Atmospheric And Meteorological Factors Regulating Red Sea Phytoplankton Growth, Wenzhao Li, Hesham El-Askary, Mohamed A. Qurban, Emmanouil Proestakis, Michael J. Garay, Olga V. Kalishnikova, Vassilis Amiridis, Antonis Gkikas, Eleni Marinou, Thomas Piechota, K. P. Manikandan

Mathematics, Physics, and Computer Science Faculty Articles and Research

This study considers the various factors that regulate nutrients supply in the Red Sea. Multi-sensor observation and reanalysis datasets are used to examine the relationships among dust deposition, sea surface temperature (SST), and wind speed, as they may contribute to anomalous phytoplankton blooms, through time-series and correlation analyses. A positive correlation was found at 0–3 months lag between chlorophyll-a (Chl-a) anomalies and dust anomalies over the Red Sea regions. Dust deposition process was further examined with dust aerosols’ vertical distribution using satellite lidar data. Conversely, a negative correlation was found at 0–3 months lag between SST anomalies …

Imidacloprid Sorption And Transport In Cropland, Grass Buffer, And Riparian Buffer Soils, Laura E. Satkowski, Keith W. Goyne, Stephen H. Anderson, Robert N. Lerch, Elisabeth B. Webb, Daniel D. Snow

Daugherty Water for Food Global Institute: Faculty Publications

An understanding of neonicotinoid sorption and transport in soil is critical for determining and mitigating environmental risk associated with the most widely used class of insecticides. The objective of this study was to evaluate mobility and transport of the neonicotinoid imidacloprid (ICD) in soils collected from cropland, grass vegetative buffer strip (VBS), and riparian VBS soils. Soils were collected at six randomly chosen sites within grids that encompassed all three land uses. Single-point equilibrium batch sorption experiments were conducted using radio-labeled (¹⁴C) ICD to determine solid–solution partition coefficients (K_d). Column experiments were conducted using soils collected …

Cuando La Vida Era Tranquila: Land Use And Livelihood Changes Following The Construction Of The Chan 75 Dam In Nance Del Risco, Bocas Del Toro, Patrick Mckenzie

Independent Study Project (ISP) Collection

The Ngobe are Panama’s most populous indigenous group. While the Ngobe that live in the comarca have land and resource rights, those that live immediately outside of it do not. This issue has been exacerbated by the creation of Palo Seco Forest Reserve which has removed all land rights from the Ngobe living within it. In order to meet its growing demand for energy, Panama is expanding its hydroelectric sector. One such hydroelectric dam built by AES is Chan 75. However, Chan 75 has had a controversial history, especially regarding its treatment of the Ngobe people of the corregimiento Nance …

High-Resolution Water Footprints Of Production Of The United States

Daugherty Water for Food Global Institute: Faculty Publications

The United States is the largest producer of goods and services in the world. Rainfall, surface water supplies, and groundwater aquifers represent a fundamental input to economic production. Despite the importance of water resources to economic activity, we do not have consistent information on water use for specific locations and economic sectors. A national, spatially detailed database of water use by sector would provide insight into U.S. utilization and dependence on water resources for economic production. To this end, we calculate the water footprint of over 500 food, energy, mining, services, and manufacturing industries and goods produced in the United …

Sensitivity Analyses For Simulating Pesticide Impacts On Honey Bee Colonies, A. Carmen Kuan, Gloria Degrandi-Hoffman, Robert J. Curry, Kristina V. Garber, Andrew R. Kanarek, Marcia N. Snyder, Kurt L. Wolfe, S. Thomas Purucker

United States Environmental Protection Agency: Publications

We employ Monte Carlo simulation and sensitivity analysis techniques to describe the population dynamics of pesticide exposure to a honey bee colony using the VarroaPop+Pesticide model. Simulations are performed of hive population trajectories with and without pesticide exposure to determine the effects of weather, queen strength, foraging activity, colony resources, and Varroa populations on colony growth and survival. The daily resolution of the model allows us to conditionally identify sensitivity metrics. Simulations indicate queen strength and forager lifespan are consistent, critical inputs for colony dynamics in both the control and exposed conditions. Adult contact toxicity, application rate and nectar load …

Reproductive Success And Contaminant Associations In Tree Swallows (Tachycineta Bicolor) Used To Assess A Beneficial Use Impairment In U.S. And Binational Great Lakes’ Areas Of Concern, Christine M. Custer, Thomas W. Custer, Matthew A. Etterson, Paul M. Dummer, Diana Goldberg, J. Christian Franson

United States Environmental Protection Agency: Publications

During 2010-2014, tree swallow (Tachycineta bicolor) reproductive success was monitored at 68 sites across all 5 Great Lakes, including 58 sites located within Great Lakes Areas of Concern (AOCs) and 10 non-AOCs. Sample eggs were collected from tree swallow clutches and analyzed for contaminants including polychlorinated biphenyls (PCBs), dioxins and furans, polybrominated diphenyl ethers, and 34 other organic compounds. Contaminant data were available for 360 of the clutches monitored. Markov chain multistate modeling was used to assess the importance of 5 ecological variables and 11 of the dominant contaminants in explaining the pattern of egg and nestling failure …

Nutrient Export From A Proximal Intermittent Stream Draining Eku Meadowbrook Farm, Madison County, Kentucky, James Scott Winter, Walter S. Borowski, Jonathan M. Malzone

EKU Faculty and Staff Scholarship

Agricultural activities contribute significant amounts of nutrients that contaminate surface and subsurface water. Eastern Kentucky University (EKU) Meadowbrook Farm (Madison County, Kentucky) seeks to decrease its export of nutrients to Muddy Creek using sequestration techniques. The first step in the overall process is to determine nutrient export at present, before sequestration efforts take place. Here we estimate the export of phosphate, nitrate, and ammonium during Tropical Storm Cindy (July 22 to 24, 2017) from a proximal, intermittent stream, named the BRC. This stream drains a representative portion the Farm, receiving water from a dairy complex, pasture, and cropland.

To estimate …

Nutrient Contamination From An Agricultural Non-Point Source And Its Mitigation: A Case Study Of Eku Meadowbrook Farm, Madison County, Kentucky, Walter S. Borowski, Reid E. Buskirk, James Scott Winter, Jonathan Malzone Dr.

EKU Faculty and Staff Scholarship

Non-point sources are now responsible for most nutrient contamination in surface water and groundwater, leading to eutrophication and decreased water quality. Because of fertilizer use and animal husbandry, agricultural areas are prime sources for nutrient contamination. Consequently, it is advisable to mitigate entry of nutrients into watersheds from agricultural runoff and groundwater flow. Eastern Kentucky University (EKU) Meadowbrook Farm (Madison County, Kentucky) seeks to decrease its export of nutrients to Muddy Creek, which is tributary of the Kentucky River. To demonstrate the efficacy of any sequestration strategies, nutrient export must be measured both before and after sequestration efforts are implemented. …

Estimates Of Present And Future Flood Risk In The Conterminous United States, Oliver E.J. Wing, Paul D. Bates, Andrew M. Smith, Christopher C. Sampson, Kris A. Johnson, Joseph Fargione, Philip Morefield

United States Environmental Protection Agency: Publications

Past attempts to estimate rainfall-driven flood risk across the US either have incomplete coverage, coarse resolution or use overly simplified models of the flooding process. In this paper, we use a new 30m resolution model of the entire conterminous US with a 2D representation of flood physics to produce estimates of flood hazard, which match to within 90% accuracy the skill of local models built with detailed data. These flood depths are combined with exposure datasets of commensurate resolution to calculate current and future flood risk. Our data show that the total US population exposed to serious flooding is 2.6–3.1 …

Global Anthropogenic Phosphorus Loads To Freshwater And Associated Grey Water Footprints And Water Pollution Levels: A High-Resolution Global Study, Mesfin Mekonnen, Arjen Y. Hoekstra

Daugherty Water for Food Global Institute: Faculty Publications

We estimate the global anthropogenic phosphorus (P) loads to freshwater and the associated grey water footprints (GWFs) for the period 2002–2010, at a spatial resolution of 5 3 5 arc min, and com- pare the GWF per river basin to runoff to assess the P-related water pollution level (WPL). The global anthro- pogenic P load to freshwater systems from both diffuse and point sources is estimated at 1.5 Tg/yr. More than half of this total load was in Asia, followed by Europe (19%) and Latin America and the Caribbean (13%). The domestic sector contributed 54% to the total, agriculture 38%, …

The Future Of Groundwater In California: Lessons In Sustainable Management From Across The West, Christina Hoffman Babbitt, Katherine E. B. Gibson, Scott Sellers, Nicholas Brozovic, Anthony Saracino, Ann Hayden, Maurice Hall, Sandi Zellmer

Daugherty Water for Food Global Institute: Faculty Publications

The 2014 Sustainable Groundwater Management Act (SGMA) created, for the first time and on an unprecedented scale, a mandate to change how groundwater is managed statewide in California. While enacting SGMA was a tremendous step forward, communities and water districts now face the considerable challenge of creating successful groundwater management programs. This report is aimed at helping California’s water managers, public water agencies, county commissioners, city planners, and others better understand the suite of tools and approaches that can be used to enhance the sustainable management of groundwater. Specifically, we consider four categories of management tools—regulatory, incentive-based, agency supply augmentation …

Sustainability At Sit: A Look At The Past, A Plan For The Future, Taliesin Haugh

Capstone Collection

Climate change threatens our world and way of life. Intelligent development and investment could mitigate the worst threats of climate change, while simultaneously providing continuous growth for the global economy. The New Climate Economy proposes efforts to combat this ecological collapse that would result in $30 trillion in new annual economic growth by 2030. Stockholm Resilience Center agrees, giving a framework based on global ecological systems that calls for five critical tasks that can bring growth and stability: Renewable energy

Sustainable local food production

New development models, based on what has worked globally

Reduction of wealth inequity

Education, health, and …

Conservation Limnogeology And Benthic Habitat Mapping In Central Lake Tanganyika (Tanzania), Joseph S. Lucas

Theses and Dissertations--Earth and Environmental Sciences

Small scale protected zones are valuable for helping the health and productivity of fisheries at Lake Tanganyika (East Africa). Spatial placement of protected areas relies on accurate maps of benthic habitats, consisting of detailed bathymetry data and information on lake-floor substrates. This information is unknown for most of Lake Tanganyika. Fish diversity is known to correlate with rocky substrates in ≤ 30 m water depth, which provide spawning grounds for littoral and pelagic species. These benthic habitats form important targets for protected areas, if they can be precisely located.

At the NMVA, echosounding defined the position of the 30-m isobath …

Evaluating The Effectiveness Of Biochar For Treating Wsu Parking Lot Runoff, Alan-Christian Thomas

Research Opportunities for Engineering Undergraduates (ROEU) Program 2017-18

Various pollutants including pesticides, herbicides, automotive fluids, and excess nutrients from fertilizers are found in high concentrations in urban runoff. There are many technologies that can be used to control and redirect the water flow such as retention basins, constructed wetlands, and rain gardens; however, these methods are specifically focused on controlling water and not necessarily the nutrients and contaminants in the water. There has recently been an increased interest in the potential for using additional materials (e.g., compost, charcoal) to enhance the pollution treatment ability by either adding them to the soil or by engineering prefilters to remove pollutants …

A Framework For Linking Population Model Development With Ecological Risk Assessment Objectives, Sandy Raimondo, Matthew Etterson, Nathan Pollesch, Kristina Garber, Andrew Kanarek, Wade Lehmann, Jill Awkerman

United States Environmental Protection Agency: Publications

The value of models that link organism-level impacts to the responses of a population in ecological risk assessments (ERAs) has been demonstrated extensively over the past few decades. There is little debate about the utility of these models to translate multiple organism-level endpoints into a holistic interpretation of effect to the population; however, there continues to be a struggle for actual application of these models as a common practice in ERA. Although general frameworks for developing models for ERA have been proposed, there is limited guidance on when models should be used, in what form, and how to interpret model …

Assessing The Periodic Groundwater Flow Conditions Of A Perched Aquifer System In The Daniel Boone National Forest, Ethan Sweet

Posters-at-the-Capitol

Assessing the Periodic Groundwater Flow Conditions of a Perched Aquifer System in the Daniel Boone National Forest

Ethan Sweet and Jonathan Malzone

Eastern Kentucky University, Department of Geosciences

Natural ephemeral wetlands situated among the ridge-tops in the Daniel Boone National Forest serve as reservoirs that recharge a shallow groundwater system. Unique interactions between surface and groundwater in these isolated systems provide substantial support for the native ecosystem, serving as a breeding ground for amphibians and as source water for vegetation—especially in periods of drought. Currently it is not understood how groundwater could provide regional biodiversity, a drought buffer, or a …

Patterns Of Nutrient Export For A Typical Non-Point Source, Meadowbrook Farm, Madison County, Kentucky, James Scott Winter, Walter S. Borowski, Jonathan M. Malzone

EKU Faculty and Staff Scholarship

Excess nutrients are found in watersheds originating from active farmland often causing poor water quality and eutrophication in natural waters. Use of fertilizer and animal husbandry can contaminate both surface water and groundwater. Eastern Kentucky University’s Meadowbrook Farm raises crops and livestock and is typical of farms that contribute excess nutrient contaminants to watersheds as non-point sources. An instrumented weir is positioned within a key sub-watershed of the Farm that empties into Muddy Creek, a tributary of the Kentucky River. This drainage is the largest outlet from the Farm that is representative of the Farm’s collective activities.

We measured flow …

Mediation Of Eutrophication Of Surface And Subsurface Water From Non-Point Sources: Nutrient Monitoring At Meadowbrook Farm (Madison County, Kentucky), Walter S. Borowski, Jonathan M. Malzone

EKU Faculty and Staff Scholarship

Non-point sources from various human activities such as farming have replaced industrial point sources as contributors of many contaminants in surface and subsurface waters of the United States. Eastern Kentucky University’s Meadowbrook Farm (720 acres, ~2.9 km²; Madison County, Kentucky) is a teaching facility dedicated to improving farming techniques and discovering best practices for farm operations that include minimizing environmental impacts. Agricultural activities on the Farm contribute nutrients to the Muddy Creek (Kentucky River) watershed that promote eutrophication and degrade water quality. Farm management already uses protocols to mediate drainage of dissolved nitrogen off the Farm, but also …

Nutrient Contamination From Non-Point Sources: Dissolved Nitrate And Ammonium In Surface And Subsurface Waters At Eku Meadowbrook Farm, Madison County, Kentucky, Reid E. Buskirk, Hunter R. Evans, Walter S. Borowski, Jonathan M. Malzone

EKU Faculty and Staff Scholarship

Agricultural activities often contaminate watersheds with excess nutrients leading to poor water quality and eutrophication. We assayed dissolved nutrient levels in surface and subsurface waters of Eastern Kentucky University’s Meadowbrook Farm in order to assess levels of dissolved nutrients leaving its farmland and draining into the Muddy Creek watershed. The Farm raises both crops and livestock so that nutrient sources include fertilizer and manure. We sampled springs, runoff, and subsurface pipe drainage as well as Muddy Creek on six days from May to August 2016 under a variety of weather conditions. Using established, standard colorimetric methods, we measured nitrate (NO …