Environmental Sciences Commons^™

Using Uranium And Strontium Isotopes To Identify Water Flow Paths And Solute Sources In Agricultural Upper Snake-Rock Watershed In Idaho: Understanding Agrohydrology Processes Of Dryland Critical Zone, Jennifer Herrera

Open Access Theses & Dissertations

Irrigation in agricultural systems alters hydrological cycles by redistributing surface water and groundwater, modifying Critical Zone elemental cycles, and impacting water quality and availability. Here, I focus on understanding agrohydrologic processes in Dryland Critical Zones and the impacts of land-use changes and climate variability in the extensively irrigated agricultural Upper Snake-Rock Watershed in semi-arid south-central Idaho. The Snake River originates in Wyoming and flows across southern and central Idaho. The Snake River supplies irrigation water to the Kimberly and Twin Falls areas of Idaho, the focus of this study, which is characterized by intensive agricultural activity. With the increasing pressure …

A Half Century Of Biophysical Change In Polygonized Tundra On The Coastal Plain Of Northern Alaska, Mariana Mora

Open Access Theses & Dissertations

Climate change is amplified in the Arctic. As a result, Arctic tundra landscapes are undergoing physical changes through accelerated thaw and ice-wedge degradation. Understanding the magnitude and direction of these changes in the Arctic is a necessary step toward understanding the response of the Arctic to climate change and feedbacks to the Climate System. Through repeat measurements collected from 1973 through 2018, we were able to assess decadal time scale changes in polygon geomorphology, thaw depth, land surface compression and expansion, and vertical elevation within a highly polygonized tundra system, and their implications when scaled to a regional level. This …

Temporal Partitioning And Coexistence Among Four Sympatric Felid Species In The Northern Jaguar Reserve, Kylie Marie Rezendes

Open Access Theses & Dissertations

Coexistence among sympatric carnivores is shaped by behavioral strategies that mediate competition and mortality risk in heterogeneous landscapes. Understanding how sympatric carnivores, such as felids, use space and time in relation to one another requires models that account for both spatial and temporal overlap across landscapes. Models incorporating time-to-event probabilities provide a powerful framework for detecting behavioral dynamics across shared landscapes. This study evaluated the spatiotemporal responses of two apex predators â?? the jaguar (Panthera onca) and mountain lion (Puma concolor) - and two mesopredators - bobcat (Lynx rufus) and ocelot (Leopardus pardalis) - across five years of camera trap …

Experimental Investigation Of Photovoltaic Soiling Losses And Aerosol Absorption And Scattering Related To Dust In The Chihuahuan Desert Region, German Rodriguez Ortiz

Open Access Theses & Dissertations

This dissertation explores the interaction between mineral dust and solar radiation in the Chihuahuan Desert, one of the dustiest areas in North America. I focused on two main aspects: (1) the characterization of atmospheric aerosol optical properties during dust events, and (2) the effects of dust deposition (soiling) on the performance of photovoltaic (PV) modules. I characterized the intrinsic optical properties of aerosols in El Paso, Texas during the peak of the 2021 dust season. Ground-level, high-resolution optical and meteorological data were collected at the Black and Brown Carbon (BC^2) study site, whereas particulate matter and additional meteorological parameters were …

Electrochemistry Behind Pfas: Mechanistic And Analytical Approach For Sensing And Degradation Strategies, Jonathan Josue Calvillo Solis

Open Access Theses & Dissertations

Understanding the fundamental electrochemistry of perfluoroalkyl substances (PFAS) is key to developing effective water remediation and sensing strategies. This work explores the thermodynamics and kinetics of perfluorooctanoic acid (PFOA) electroreduction, focusing on C-F bond cleavage. These insights were applied to design a highly sensitive electrochemical sensor for detecting trace levels of PFOA in water. This dissertation focuses on the electrochemical investigation of the reduction reaction of PFOA in aqueous and organic media employing different electrode materials. This exploration allows to understand the defluorination reaction of PFAS to further propose potential strategies for water treatment and PFOA electrosensing. Through electrochemical, spectroscopical …

Electrodeposition Of Gallium Nitride_Unraveling The Role Of Precursors, Deposition Conditions, And Substrate Effects For Semiconductor Applications, Mauricio Azier Leyva Aranzabal

Open Access Theses & Dissertations

Gallium nitride (GaN) is a wide-bandgap semiconductor noted for its remarkable optoelectronic and structural characteristics, rendering it a potential material for high-power, high-frequency, and optoelectronic device applications. This dissertation investigates the electrochemical synthesis of GaN thin films by potentiostatic and galvanostatic electrodeposition techniques using aqueous solutions of gallium nitrate (Ga(NO3)3), ammonium nitrate (NH4NO3), and auxiliary agents like potassium nitrate and urea. The main aim is to examine the essential elements affecting nitrogen incorporation and film shape while assessing electrochemical performance on various conductive substrates.A thorough investigation was performed to evaluate the impacts of electrodeposition duration, electrolyte pH, precursor molar concentrations, …

Development Of Porous Separators For Lithium-Ion Batteries Via 3d Printing And Thermally Induced Phase Separation, Abraham Enchinton

Open Access Theses & Dissertations

Additive manufacturing processes allow the development of custom-shape rechargeable batteries, but research in custom filaments for fused deposition modeling (FDM) of battery separators has remained limited until now. This study discusses the development and optimization of a composite thermoplastic filament feedstock to 3D print separator membranes. A number of post-processing steps - leveraging the thermally induced phase separation (TIPS) of the composite filament - are introduced in tandem with FDM to promote microporosity formation through the removal of the sacrificial diluent phase within 3D printed samples. Three distinct compositions of varying polymer/diluent ratios were developed and thoroughly investigated through thermogravimetric …

The New Anthropocentrism: The Problem Of Water Conservation And Water Justice, Benjamin Stuart Milam

Open Access Theses & Dissertations

My objective with my thesis is to argue for and reinforce a type of anthropocentrism that is both environmentally conscious and consumable for an audience that is not necessarily well versed in philosophical literature. In the first chapter I go over philosophical frameworks, such as Anthropocentrism and Biocentrism, and why I believe they do not meet both of those criteria listed. After that I discuss New Anthropocentrism, coined by Clive Hamilton, and why I believe that a slightly modified version possesses qualities that I believe are needed for the crisis at hand. In chapter 2 I use that framework and …

Using The Schism Model And Hf Radar Data To Study Surface Currents In Texas Bays: A Case Study Of Sabine Lake (Sl) And Galveston Bay (Gb)., Cletus Ozoemena Ogbodo

Open Access Theses & Dissertations

Surface currents study provides invaluable understanding into the physical dynamics of oceans, bays, estuaries, and nearshore environments, offering critical insights about water movement and related coastal processes. These currents play a fundamental role in understanding the state of estuarine and marine systems, such as their effects on sediment transport, heat distribution and climate change, nutrient distribution, and pollutant dispersal. In addition, surface current data provides significant economic and ecological implications for coastal communities essential for managing resources effectively and ensuring the resilience of coastal regions against environmental and anthropogenic pressures. This study was driven by the need to address the …

The United States National Security And Policy Implications Of Desertification, Eric Olvera

Open Access Theses & Dissertations

Contemporary climate security literature reveals that desertification appears to be overlooked as a climate change security threat to the United States (US). This investigation demonstrates that an inequity exists between sea-level-rise- and desertification-based climate security literature. This inequity may reveal that the US may be ignoring desertification at a time when land use in some dryland areas is reaching a critical point where it can no longer support human activity. Due to the interdisciplinary nature (science and security) of this work, a review of the terminology used in the article is provided to establish a baseline understanding of “desertification” and …

Thermal Inequity Along The Us-Mexico Border: An Analysis Of El Paso, Texas, Mia Alexandra Trevino

Open Access Theses & Dissertations

The Urban Heat Island effect (UHI) combined with rising average global temperatures invariably results in thermal inequality, the unequal distribution of temperature patterns by different socioeconomic and sociodemographic groups, resulting in an array of negative public health impacts. This thesis research focused on the historical factors that contribute to UHI and tree cover in historically underserved neighborhoods in El Paso, Texas. The impact of maps from 1933-1954 created by the Home Ownerâ??s Loan Corporation (HOLC), a federal selective lending program, resulted in decades of disinvestment and inequality especially in redlined areas. Geospatial analyses of environmental and socioeconomic indicators such as …

Optimization And Purification Of Magnesium Borides Fabricated By Combustion Synthesis And By High-Temperature Sintering, Miguel Joaquin Camarena

Open Access Theses & Dissertations

Hydrogen as a fuel provides several benefits over the use of fossil fuels; however, one challenge in utilizing hydrogen as an energy carrier revolves around its storage. Achieving sufficient volumetric hydrogen density in a storage solution will facilitate hydrogenâ??s adoption for use in both stationary and mobile applications. Solid-state hydrogen storage provides a promising pathway to solving this problem. However, the hydrogenation of these materials is characterized by slow kinetics and extreme thermodynamic conditions. Magnesium borohydride (Mg(BH4)2) is a promising material in hydrogen storage due to its reversible properties and a theoretical hydrogen capacity of 14.9 wt.%. To synthesize this …

Advancing Grid Modernization Through Data-Driven Resilience Modeling And Hosting Capacity Of Distributed Energy Resources, Oscar Samuel Acosta

Open Access Theses & Dissertations

This Ph.D. dissertation focuses on advancing the integration of distributed energy resources (DERs) through concepts surrounding their impacts on power system stability, resilience, and hosting capacity (HC). This dissertation addresses crucial topics in renewable energy deployment, transient fault response, and dynamic modeling. The work begins with the development of renewable energy source (RES) models tailored for offsetting residential heating, ventilation, and air conditioning~(HVAC) and commercial cooling loads. These models utilize solar photovoltaic (PV) and wind energy systems to produce scalable frameworks adapted across diverse climates and building types in application of a partial-load targeting methodology. The dissertation then transitions from …

Environmental Impact Assessments (Eia): Analysis Of Transboundary Environmental Impact Assessments For The Development Of A Uniform Teia Model, Nicolas Chapa

Open Access Theses & Dissertations

This dissertation investigates the evolution, processes, and importance of Environmental Impact Assessments (EIAs), focusing on transboundary EIAs and the need for a uniform framework. Originating from the National Environmental Policy Act (NEPA) of 1969 in the U.S., EIAs have become globally adopted instruments for assessing and mitigating environmental impacts of development projects. This work reiterates historical milestones, strengths, and current limitations of EIAs. Research also included a review of environmental regulations from Mexico, such as the General Law on Ecological Equilibrium and Environmental Protection (LGEEPA). Through several case studies requiring the use of transboundary EIAs, where shared resources and concerns …

A Machine Learning Approach For Estimating Evapotranspiration For Urban Landscaping Vegetation In Semi-Arid Regions, Damian Lorenzo Gallegos Espinoza

Open Access Theses & Dissertations

Water management is important for residents in semi-arid urban areas due to increasing demand, water scarcity, and rising costs. It is estimated that in semi-arid regions, 40-70% of the household water consumption is used in landscaping. Therefore, urban landscaping water use can substantially contribute to water conservation. This work aims to estimate the water needs of urban landscaping vegetation to inform residents in semi-arid regions.Evapotranspiration indicates water and energy exchange between the atmosphere, soil, and vegetation. This interaction depends on solar radiation, evaporation, transpiration, and other biophysical parameters. Evapotranspiration has become a reference for water management in agriculture (e.g., crop …

Redefining Approaches For Measuring Landscape Subsidence And Permafrost Degradation In Arctic Tundra Environments, Tabatha Lynn Fuson

Open Access Theses & Dissertations

As climate change accelerates in the Arctic, the degradation of permafrost is leading to significant landscape transformation in tundra landscapes. This dissertation investigates the multifaceted responses of permafrost systems to warming, focusing on the dynamics of surface elevation changes and active layer thickness (ALT) across the North Slope of Alaska. In this study, I explore the capacity of repeat Terrestrial Laser Scanning (TLS) technology for modeling tundra features and detecting surface subsidence, specifically how different climate and landscape conditions during scanning impact TLS model precision. We also compare TLS model precision estimates to TLS model accuracy by comparing elevation values …

An Integrated Study Of Aerosol Concentrations And Meteorological Conditions In El Paso Airshed Using Modeling And Instrumentation, Joscelyne Guzman-Gonzalez

Open Access Theses & Dissertations

Atmospheric aerosols are solid or liquid particles suspended in the atmosphere. Aerosols can be primary, which are directly emitted into the atmosphere, or secondary, which are formed when emitted gases undergo complex chemical reactions. Atmospheric aerosols can range from a few nanometers to tens of microns in diameter. Atmospheric aerosols play a significant role in climate; they can absorb or reflect heat, influencing temperature and weather patterns. Air quality is also affected by aerosols, which can have detrimental effects on human health, contributing to respiratory issues and other health problems. El Paso Texas is located at the south of the …

Upscaling Sapflow Measurements To Footprint Transpiration Estimations In The Jornada Experimental Range, New Mexico, Usa, Habibur R. Howlider

Open Access Theses & Dissertations

This study proposes a new method for computing transpiration across an eddy covariance footprint using field observations of plant sap flow, phytomorphology sampling, uncrewed aerial system (UAS) digital image processing, and eddy covariance micrometeorological measurements. The method is applied to the Jornada Experimental Range, New Mexico where we address three key questions: (1) How do daily summer transpiration rates of Mesquite (Prosopis glandulosa) and Creosote (Larrea tridentate) individuals of different ages compare? (2) How can the contributions of plants of varying sizes and ages be integrated for terrain-wide transpiration estimates? (3) What is the contribution of transpiration to total evapotranspiration …

Design Of Engineered Nanomaterials For Pfas Adsorption And Catalytic Degradation From Relevant Environmental Conditions, Sheng Yin

Open Access Theses & Dissertations

Poly- and per-fluoroalkyl substances (PFAS) are a class of artificially made chemicals whose carbon chains are fully or partially fluorinated. Due to their persistent and pervasive distribution and their adverse effects on human health, the removal of PFAS from the environment has been the focus of current research. This project explores the use of engineered nanomaterials for the effective removal of PFAS through various adsorption and catalytic degradation methods. First, a comprehensive review of recent studies highlights the significant potential of various nanomaterials, including carbon-based, non-metal, single-metal, and multi-metal nanomaterials, for PFAS remediation. These materials are evaluated for their performance, …

Analyzing The Impact Of Oil And Gas-Contaminated Fluids On Soil In Eddy And Lea Counties Using Sequential Extraction, Mary Adu-Gyamfi

Open Access Theses & Dissertations

The study investigates the impacts of oil and gas-contaminated fluids on soil within the context of Eddy and Lea Counties in New Mexico, the United States. The increase in oil and gas operations has led to enormous wastewater production that is handled, stored, and transported, leading to thousands of spills yearly. The continuous and accidental release of this wastewater poses several risks to the environment due to its high levels of hazardous pollutants. Several studies were conducted on how to reduce the contaminants; however, the impact caused on the environment and the fate of the spilled fluids is unclear due …

Promoting Social Sustainability: Implementing A Dynamic Stem Driven Framework To Empower Underrepresented Communities In West Texas Schools, Raquel Haggerty

Open Access Theses & Dissertations

This dissertation explores how environmental engineering can utilize STEM education as a strategic tool, enhancing social sustainability and thereby empowering underserved Hispanic communities in West Texas. Responding to significant educational and resource disparities, this research introduces an innovative interdisciplinary framework that combines instruction-initiated resource activation (I2RA), culturally attuned parent engagement (CAPE), and community- centered STEM education (CCSE). This approach uniquely addresses the challenges faced by these communities, integrating environmental solutions with educational advancements to forge a path toward equitable STEM access and achievement.

Additionally, the "Elevate and Empower" case study exemplifies the practical application of this comprehensive framework, demonstrating its …

Dispersal And Population Structure Of Euchlanis Chihuahuaensis Via Anemochory In The Chihuahuan Desert, Tristan Chavez-Poeschel

Open Access Theses & Dissertations

Desert ecosystems present challenges for aquatic organisms as habitats are fragmented, both in space and time; however, diapausing stages of rotifers can travel hundreds of kilometers during wind events. I used the rotifer Euchlanis chihuahuaensis as a model species to investigate the influence of wind dispersal on gene flow and population genetics in Chihuahuan Desert populations. I hypothesized that anemochory facilitates gene flow from source populations in the Northern Chihuahuan Desert in Mexico and the western United States to habitats in the Trans-Pecos region via delineated wind corridors. To test this hypothesis, the genetic diversity of populations from both inside …

Investigating Changes In Surface Water Chemistry Across The Llano Uplift And The Balcones Fault Zone In Central Texas Using Strontium And Uranium Isotopes, Hao Tuan Pham

Open Access Theses & Dissertations

The landscape of central Texas is shaped by over one billion years of Earth's history. An array of lithology lies within central Texas along with two large geological structures. The Llano Uplift, characterized by Proterozoic metamorphic and igneous rocks dating back to 1.37 billion years ago, is encircled by Paleozoic and Mesozoic sedimentary rocks. To the southeast of the Llano Uplift lies the Balcones Fault Zone (BFZ), an extensional structural system of mostly normal faults that delineates the transition between Paleozoic-Mesozoic sedimentary rocks and Cenozoic sedimentary cover, which are influential to the regional hydrogeology. This study investigates the hydrogeological dynamics …

Resource Scarcity Caused By Environmental Changes: Driving Factor In Terrorism Attacks In Afghanistan, Pakistan, Syria, Amaris Bustamante

Open Access Theses & Dissertations

Climate change, resource scarcity, and terrorist attacks are ever-growing crises that disproportionately impact different states. They are crises that can impact the stability and resilience of humanity in the following decades if they are not addressed and mitigated. This study addresses the impact of resource scarcity caused by climate change that can then serve as a driving force in terrorist attacks in climate-sensitive and conflict-prone states. The objective of this mixed-methods study is to identify the correlation between climate changes that lead to resource scarcity such as rainfall and surface temperatures with terrorist attacks when taking into consideration other demographic, …

Water Sufficiency For Organismal Function In Dryland Critical Zones, Lindsey Dacey

Open Access Theses & Dissertations

Water availability is crucial for organismal survival and growth in dryland environments, affecting both ecological interactions and carbon dynamics. The goal of this thesis is to develop soil water release curves (SWRCs) that link soil water potentials (Ψ) to soil water content (θ). Using the SWRCs, temporal soil water sufficiency curves are developed, which quantify the amount of time that dryland critical zones have enough water to sustain the physiology of organisms. These curves allow for effectively indicating water availability across different species, coverage types, and soil conditions, enhancing our understanding of water dynamics in drylands and contributing important parameters …

Assessing Urban Tree Coverage Along The U.S.-Mexico Border: A Gis Analysis Of Paso Del Norte, Melanie Escobar

Open Access Theses & Dissertations

In recent years, researchers have extensively studied the spatial distribution of social demographics and urban tree canopy (UTC) in urban cities, but very few, to this date, address U.S.-Mexico border cities. To date, there is no research that assesses the distribution of urban tree canopy (UTC) in the city of El Paso, Texas, and Ciudad Juarez, Chihuahua, along the U.S.- Mexico border. Leveraging advanced mapping techniques and GIS tools, the study performs comparisons between countries (Juárez vs. El Paso urbanized areas and intra-country (within each country). It compares land cover classifications, assesses variations in UTC distribution across census tracts and …

Assessing Nordihydroguaiaretic Acid Properties And Its Potential Therapeutic Effect For Glioblastoma, Jose Arturo Guerrero

Open Access Theses & Dissertations

This study employs a combination of theoretical and experimental analysis to spectroscopically investigate the biomechanistic structure relationship and therapeutic effects of the Nordihydroguaiaretic Acid (NDGA) chemical derived from the Larrea Tridentata plant. These relationships are crucial for understanding NDGA's efficacy in disease prevention, treatment, and potential toxicological effects. While the medicinal and antiviral properties of the NDGA have been studied extensively, there remains a gap in optically identifying and reporting its structural changes. The current research successfully reveals evident trends in NDGA's vibrational signatures, particularly highlighting the absence of the Raman feature at 780 〖cm〗^(-1) as indicative of a fully …

Predictive Understanding Of Lake Water Temperature And Dissolved Oxygen Profiles Across The Red River Basin Through Interpretable Machine Learning, Isabela Suaza Sierra

Open Access Theses & Dissertations

Accurately predicting lake water temperature (LWT) and dissolved oxygen (DO) is crucial for determining threshold values of fish survivability under warmer global conditions, with recreational fishing in reservoirs significantly contributing to regional economies, such as $779 million and $1,891 million annually to the economies of Oklahoma and Texas, respectively. Current mathematical models for temperature and oxygen profiles, which incorporate multi-layer and turbulent mixing equations, are complex and challenging to parameterize, particularly due to uncertainties in acquiring sufficient data for training and validation. Leveraging the flexibility and information extraction power of machine learning (ML) methods, this master thesis aimed to set …

Niobate Nanosheet Catalysts For Cationic Dye Intercalation And Solar-Driven Water Photolysis, Cassandra Idona Monárrez-Grendahl

Open Access Theses & Dissertations

With the goal of creating efficient visible light photocatalysts for water photolysis, in this work we are exploring the synthesis of new porous oxide materials derived from potassium triniobate (KNb3O8) and titanium niobium oxide (KTiNbO5), which are layered wide band gap semiconductors. Generating hydrogen via direct water photolysis holds promise as a way to lower the cost of hydrogen gas production so it can be used as a renewable and clean alternative fuel. My group has demonstrated that layered semiconductor materials have the potential to enable the synthesis of new types of photocatalyst composites with customizable characteristics. In this work, …

Bitcoin's Technical Foundation And Its Potential For A Decentralized And Environmentally Friendly Future, Iqtiar Md Siddique

Open Access Theses & Dissertations

This research examines a systematic analysis of Bitcoin, employing a Coefficient of Variation (CV) approach to gauge its degree of decentralization. Bitcoin, an innovative decentralized digital currency, has received much attention for its potential to revolutionize traditional financial systems. This study employs the Coefficient of Variation (CV) to acquire insights into the wealth distribution and concentration among Bitcoin users. This research demonstrates how decentralized the network of Bitcoin is. The methodology uses real data on Bitcoin addresses and their holdings to compute the Coefficient of Variation (CV). This approach provides valuable insights into the ongoing discourse surrounding Bitcoin's decentralization, offering …