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2020

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Articles 1 - 13 of 13

Full-Text Articles in Mineral Physics

Optimizing Raman Spectral Collection For Quartz And Zircon Crystals For Elastic Geothermobarometry, Mayara F. Cizina Dec 2020

Optimizing Raman Spectral Collection For Quartz And Zircon Crystals For Elastic Geothermobarometry, Mayara F. Cizina

Boise State University Theses and Dissertations

Raman microspectroscopy is widely used to identify and characterize organic and inorganic compounds. In the geosciences, Raman microspectroscopy has been used to identify mineral and fluid inclusions in host crystals, as well as to calculate pressure-temperature (P-T) conditions using mineral inclusions in host crystals, such as quartz-in-garnet barometry (QuiG). For thermobarometric applications, the reproducibility of Raman peak position measurements is crucial to obtain accurate P-T estimates. In this study, we explored how to optimize Raman spectral collection of quartz and zircon inclusions and reference crystals by monitoring machine stability and by varying spectral parameters. We also monitored a reference Hg …


Structure Analysis Of Natural Wangdaodeite—Linbo3-Type Fetio3, Oliver Tschauner, Chi Ma, Matthew G. Newville, Antonio Lanzirotti Dec 2020

Structure Analysis Of Natural Wangdaodeite—Linbo3-Type Fetio3, Oliver Tschauner, Chi Ma, Matthew G. Newville, Antonio Lanzirotti

Geoscience Faculty Research

© 2020 by the authors. Licensee MDPI, Basel, Switzerland. This paper reports the first structure refinement of natural wangdaodeite, LiNbO3-type FeTiO3 from the Ries impact structure. Wangdaodeite occurs together with recrystallized ilmenite clasts in shock melt veins which have experienced peak shock pressures of between 17 and 22 GPa. Comparison of natural and synthetic wangdaodeite points toward a correlation between the distortion of ferrate-and titanate-polyhedra and the c/a ratio of the unit cell. The Raman spectrum of wangdaodeite is calculated based on the refined structure. Comparison to the reported spectrum of the type-material shows that the Raman peak at 738–740 …


Framework Grain Composition And Texture Of The Wedington Sandstone Member, Fayetteville Shale, As A Provenance And Sediment Dispersal Indicator For Clastic Depositional Systems Across The Northern Arkansas Structural Platform During The Late Mississippian, Tanner Wayne Corbin Dec 2020

Framework Grain Composition And Texture Of The Wedington Sandstone Member, Fayetteville Shale, As A Provenance And Sediment Dispersal Indicator For Clastic Depositional Systems Across The Northern Arkansas Structural Platform During The Late Mississippian, Tanner Wayne Corbin

Graduate Theses and Dissertations

The Wedington Sandstone Member of the Fayetteville Shale is a constructive delta complex in the Chesterian section of the Late Mississippian record in Northwest Arkansas. A comparative analysis of framework grain composition between the Wedington and two other stratigraphically proximal Carboniferous sandstones: the Batesville Sandstone (older) and the Basal Atoka-Spiro Sandstone (younger) has addressed three questions: 1) Is there similarity in sediment provenance for the three sandstones? 2) Do these three sandstone units have a similar sediment dispersal vector? 3) What are likely sediment source terrains for the Wedington Sandstone? Wedington samples overwhelmingly plot as quartzarenites with fewer samples plotting …


Foliar Application Of Low Concentrations Of Titanium Dioxide And Zinc Oxide Nanoparticles To The Common Sunflower Under Field Conditions, Marek Kolenčík, Dávid Ernst, Martin Urík, Ľuba Ďurišová, Marek Bujdoš, Martin Šebesta, Edmund Dobročka, Samuel Kšiňan, Ramakanth Illa, Qian Yu, Huan Feng, Ivan Černý, Veronika Holišová, Gabriela Kratošová Aug 2020

Foliar Application Of Low Concentrations Of Titanium Dioxide And Zinc Oxide Nanoparticles To The Common Sunflower Under Field Conditions, Marek Kolenčík, Dávid Ernst, Martin Urík, Ľuba Ďurišová, Marek Bujdoš, Martin Šebesta, Edmund Dobročka, Samuel Kšiňan, Ramakanth Illa, Qian Yu, Huan Feng, Ivan Černý, Veronika Holišová, Gabriela Kratošová

Department of Earth and Environmental Studies Faculty Scholarship and Creative Works

Nano-fertilisers have only recently been introduced to intensify plant production, and there still remains inadequate scientific knowledge on their plant-related effects. This paper therefore compares the effects of two nano-fertilisers on common sunflower production under field conditions. The benefits arising from the foliar application of micronutrient-based zinc oxide fertiliser were compared with those from the titanium dioxide plant-growth enhancer. Both the zinc oxide (ZnO) and titanium dioxide (TiO2) were delivered by foliar application in nano-size at a concentration of 2.6 mg·L−1. The foliar-applied nanoparticles (NPs) had good crystallinity and a mean size distribution under 30 nm. …


Storm Surges In The Bohai Sea: The Role Of Waves And Tides, Yuanyi Li, Huan Feng, Guillaume Vigouroux, Dekui Yuan, Guangyu Zhang, Xiaodi Ma, Kun Lei May 2020

Storm Surges In The Bohai Sea: The Role Of Waves And Tides, Yuanyi Li, Huan Feng, Guillaume Vigouroux, Dekui Yuan, Guangyu Zhang, Xiaodi Ma, Kun Lei

Department of Earth and Environmental Studies Faculty Scholarship and Creative Works

A storm surge is a complex phenomenon in which waves, tide and current interact. Even though wind is the predominant force driving the surge, waves and tidal phase are also important factors that influence the mass and momentum transport during the surge. Devastating storm surges often occur in the Bohai Sea, a semi-enclosed shallow sea in North China, due to extreme storms. However, the effects of waves on storm surges in the Bohai Sea have not been quantified and the mechanisms responsible for the higher surges that affect part of the Bohai Sea have not been thoroughly studied. In this …


Comparative Geochemical Analysis Of Ordovician And Mississippian Cherts In Relation To The Northern Arkansas And The Tri-State Mississippi Valley-Type Ore Districts, Jonathan T. Chick May 2020

Comparative Geochemical Analysis Of Ordovician And Mississippian Cherts In Relation To The Northern Arkansas And The Tri-State Mississippi Valley-Type Ore Districts, Jonathan T. Chick

Graduate Theses and Dissertations

It has been hypothesized that Ordovician, Mississippian, and younger carbonate and clastic formations found within the Ouachita Basin of west-central Arkansas and northward onto the Ozark Dome have experienced interaction with hydrothermal fluids due to tectonic forces produced by the Ouachita Orogeny. Lead (Pb) isotope analyses and resulting values produced through previous and concurrent geochemical studies of several formations indicate that the Mississippi Valley-type (MVT) ores were produced from a mixing and cooling of these sedimentary basinal brines by meteoric or connate waters. Reduction of sulfate to sulfide is one of the possible mechanisms by which MVT ore precipitation may …


Structure-Strength Relations Of Distinct Mon Phases From First-Principles Calculations, Cheng Lu, Changfeng Chen Apr 2020

Structure-Strength Relations Of Distinct Mon Phases From First-Principles Calculations, Cheng Lu, Changfeng Chen

Physics & Astronomy Faculty Research

Molybdenum mononitrides (MoN) exhibit superior strength and hardness among the large class of transition-metal light-element compounds, but the underlying atomistic mechanisms for their outstanding mechanical properties and the variations of those properties among various MoN phases adopting different crystal structures remain largely unexplored and require further investigation. Here we report first-principles calculations that examine the stress-strain relations of these materials, and systematically compare results under pure and indentation shear deformations. In particular, we examine the distinct bonding structures and the associated mechanical properties in four different crystal phases of MoN that have been experimentally synthesized and stabilized under various physical …


Indentation-Strain Stiffening In Tungsten Nitrides: Mechanisms And Implications, Cheng Lu, Changfeng Chen Apr 2020

Indentation-Strain Stiffening In Tungsten Nitrides: Mechanisms And Implications, Cheng Lu, Changfeng Chen

Physics & Astronomy Faculty Research

We report on a systematic computational study of ideal strengths, i.e., the lowest stresses needed to destabilize a perfect crystal under a variety of loading conditions for six stable and metastable tungsten nitrides identified by advanced crystal structure search algorithms. We employ first-principles calculations to determine stress-strain relations and examine the corresponding atomistic bonding changes for a microscopic understanding of the structural deformation modes. The obtained results show that, in stark contrast to many previously studied transition-metal borides, carbides, and also most nitrides, the tungsten nitrides exhibit surprisingly broad and common patterns of strain-stiffening effects under indentation strains. These extraordinary …


Riesite, A New High Pressure Polymorph Of Tio2 From The Ries Impact Structure, Tschauner, Chi Ma, Antonio Lanzirotti, Matthew G. Newville Jan 2020

Riesite, A New High Pressure Polymorph Of Tio2 From The Ries Impact Structure, Tschauner, Chi Ma, Antonio Lanzirotti, Matthew G. Newville

Geoscience Faculty Research

This paper describes riesite, a new high-pressure polymorph of TiO2 from the Ries impact structure, Germany. Riesite occurs in shock-induced melt veins within xenoliths of bedrock in suevite. It is structurally closely related to srilankite from which it differs by having two distinct cation sites rather than one and through its monoclinic symmetry. It is indicative that riesite forms only upon release from the shock state upon back transformation from akaogiite.


Statistical Analysis Of Nutrient Loads From The Mississippi-Atchafalaya River Basin (Marb) To The Gulf Of Mexico, Phyllis Okwan, Yi Zhen, Huan Feng, Shinjae Yoo, Murty S. Kambhampati, Abreione Walker, Shayne Boykin, Joe Omojola, Noel Blackburn Jan 2020

Statistical Analysis Of Nutrient Loads From The Mississippi-Atchafalaya River Basin (Marb) To The Gulf Of Mexico, Phyllis Okwan, Yi Zhen, Huan Feng, Shinjae Yoo, Murty S. Kambhampati, Abreione Walker, Shayne Boykin, Joe Omojola, Noel Blackburn

Department of Earth and Environmental Studies Faculty Scholarship and Creative Works

This study investigated the annual and seasonal variations in nutrient loads (NO2− + NO3− and orthophosphate) delivered to the Gulf of Mexico from the Mississippi-Atchafalaya River Basin (MARB) and examined the water quality variations. The results indicate that (1) annually, the mean NO2− + NO3− and orthophosphate loads showed a steady increase during 1996–1999, a persistent level during 2000–2007, and a moderate increase during 2008–2016; (2) seasonally, NO2− + NO3− and orthophosphate in MARB in spring and summer were higher than those in autumn and winter. Analysis of …


Seismic Visibility Of Eclogite In The Earth’S Upper Mantle – Implications From High Pressure-Temperature Single-Crystal Elastic Properties Of Omphacite, Ming Hao, Jin S. Zhang, Wen-Yi Zhou, Qin Wang Jan 2020

Seismic Visibility Of Eclogite In The Earth’S Upper Mantle – Implications From High Pressure-Temperature Single-Crystal Elastic Properties Of Omphacite, Ming Hao, Jin S. Zhang, Wen-Yi Zhou, Qin Wang

Earth and Planetary Sciences Faculty and Staff Publications

Eclogite, constituting the subducted crust, is one of the most important geochemical and geophysical heterogeneities in the Earth’s mantle. As the dominant anisotropic phase in eclogite, precise high pressure-temperature single-crystal elastic properties of omphacite provides the basis for detecting eclogite in the Earth’s upper mantle. In this study, we measured the single-crystal elastic moduli of omphacite up to 18 GPa and 700 K using Brillouin spectroscopy. A least-squares fit to a third-order finite strain equation of state yields KS0’=4.5(1), G0’=1.53(5), ∂KS0/∂T=-0.029(5) GPa/K, ∂G0/∂T=-0.013(5) GPa/K, with ρ0=3.34(1) g/cm3, K …


Analysis Of Deformation Mechanisms That Formed The Shear Zones Found In The Scituate Granite, Rhode Island, Usa, Jacob Waller Jan 2020

Analysis Of Deformation Mechanisms That Formed The Shear Zones Found In The Scituate Granite, Rhode Island, Usa, Jacob Waller

Williams Honors College, Honors Research Projects

The rheology of the ductile middle and lower crust affects the rate and intensity of aftershocks following major seismic events. This ductile deformation in the middle crust is commonly localized in narrow shear zones, which requires a process that causes strain weakening to operate in order to form these shear zones. In order to determine the mechanisms that cause strain localization in a common crustal rock, microstructures were analyzed in and around a shear zone found in a granite, Scituate, RI, deformed during the Alleghenian orogeny. Evolution of shear zone growth was observed through optical and scanning electron microscope (SEM) …


Cobalt Partitioning And Solubility In Low-Temperature Carbonate-Hydrothermal Systems, Seth Kurtis Coursey Jan 2020

Cobalt Partitioning And Solubility In Low-Temperature Carbonate-Hydrothermal Systems, Seth Kurtis Coursey

Graduate Research Theses & Dissertations

Cobalt mineralization has been documented in low temperature Mississippi Valley-type (MVT) deposits in southeast Missouri. Lead and zinc are the most economically important metals in these deposits and are contained within galena (PbS) and sphalerite (ZnS), respectively. Cobalt is also mined in some of the deposits with cobalt-bearing ores, e.g., siegenite ((Ni,Co)3S4) and fletcherite (Cu,(Ni,Co)2S4), occurring stratigraphically below main-stage galena and sphalerite. The hydrothermal fluids responsible for cobalt mineralization are thought to be chemically distinct from the predominant MVT ore-bearing fluids and represent a distinct mineralizing event. Cobalt is likely transported as CoCl2 in hydrothermal fluids and sourced from structures …