Hydrology Commons^™

Rare Earth Element Transport In The Yucca Mountain Region, Liqiong Zhang

UNLV Theses, Dissertations, Professional Papers, and Capstones

In sync with environmental pollution of solutes in nature, from source, process to consequence, geochemical processes (leaching and sorption) and hydraulic transportation of the rare earth elements (REEs) have been investigated at Yucca Mountain (YM), Nevada. This research includes the leaching behavior of trace elements (including REEs) from aquifer rocks, the surface complexation reactions of REEs in synthetic groundwater, and transportation of reactive REEs in the local-scale groundwater system of YM. This dissertation includes three projects. These studies indicate that surface complexation reactions may retard the transportation of REEs along groundwater paths in YM, which suggests a similar behavior of …

Identification Of Geochemical Facies Through Major Ion Data And Additional Parameters From Shallow Groundwater Utilizing A Comparison Of Geomathematics And Traditional Methods In Las Vegas Valley, Nevada, Eric Dano

UNLV Theses, Dissertations, Professional Papers, and Capstones

There has been little exploration to identify geochemical facies in shallow groundwater in the Las Vegas Valley in Clark County, Nevada. Identification of hydrochemical facies in Las Vegas Valley is important for assessing the extent and nature of a potential groundwater resource. The identification of facies could be complicated by the possibility that secondary recharge constitutes a hydrochemical facies of its own. To identify geochemical facies, groundwater samples for major ions, stable isotopes and some municipal tracers were collected from 35 wells in an established network of monitor wells. Wells were purged with a bailer or 12V pump and EC, …

Assessment Of Impacts To Hydroclimatology And River Operations Due To Climate Change Over The Colorado River Basin, William Paul Miller

UNLV Theses, Dissertations, Professional Papers, and Capstones

This dissertation investigated the impacts of climate change to the hydroclimatology and river and reservoir management operations within the Colorado River Basin. Preliminary research indicated observed warming trends throughout the Colorado River Basin and corresponding seasonal trends to the magnitude and timing of runoff in the Colorado River Basin. Subsequent research investigated the changing character of precipitation and corresponding impacts to streamflow over the Colorado River Basin. Analysis of snowpack telemetry (SNOTEL) stations over the American West and Colorado River Basin indicated decreasing trends in annual snowpack, often at least at the 95% confidence interval. A shorter snowpack season was …

Uncertainty, Sensitivity And Geostatistical Studies Of Flow And Contaminant Transport In Heterogeneous Unsaturated Zone, Feng Pan

UNLV Theses, Dissertations, Professional Papers, and Capstones

The objectives of this study are: (1) to develop a methodology of estimating probability density functions (PDFs) of unsaturated hydraulic parameters when field samples are sparse, (2) to evaluate the predictive uncertainties in flow and contaminant transport due to parameter uncertainties in the layer- and local-scale heterogeneities of hydraulic parameters in unsaturated zone (UZ), (3) to investigate the contributions of the parameter uncertainties to the flow and transport uncertainties, and (4) to estimate the spatial correlation structures of hydraulic parameters by incorporating prior information and site measurements.

At layer scale, the uncertainty assessment of flow and contaminant transport in UZ …

Uncertainty In Recharge From Subsidence Craters At Frenchman Flat, Nevada Test Site: Impacts Of Initial And Boundary Conditions And Media Properties, David Matthew Ely

UNLV Theses, Dissertations, Professional Papers, and Capstones

The Nevada Test Site has over 400 subsidence craters formed by the collapse of overlying rock following underground nuclear tests. Under natural conditions, infiltration and recharge would not be considered likely due to infrequent precipitation events and extreme evapotranspiration. Crater U5a in Frenchman Flat was chosen for study because it intercepts significantly more drainage than surrounding craters. Vadose zone modeling was conducted to test the sensitivity of water movement to boundary and initial conditions. The effects of ponding depth was negligible but depth of wetting front movement was highly dependent on the lateral extent of the ponds. The model was …

The Use Of Spectrofluorimetry And Capillary Electrophoresis/Laser-Induced Fluorescence For The Detection Of Fluorescent Dyes In Groundwater Migration Studies, Patrick Ferguson

UNLV Theses, Dissertations, Professional Papers, and Capstones

This thesis involves work that was accomplished during a two-year internship at the Environmental Protection Agency's (EPA), Environmental Chemistry Branch. The research is an application of trace level determination of fluorescein dyes used as groundwater tracers. The work was performed to determine whether groundwater could migrate from a Resource Conservation Recovery Act (RCRA) site to an adjacent Superfund site. The research involved using Spectrofluorimetry and a new technique called capillary electrophoresis/laser induced fluorescence (CE/LIF) to determine tracer dyes that were injected at the RCRA site and monitored at the Superfund site. Results from Spectrofluorimetry were compared to those of CE/LIF. …

Hydrostratigraphy And Allostratigraphy Of The Cenozoic Alluvium In The Northwestern Part Of Las Vegas Valley, Clark County, Nevada, David J. Donovan

UNLV Theses, Dissertations, Professional Papers, and Capstones

This investigation was conducted to determine the location, nature, and boundaries of the most permeable unit within the alluvial aquifer material in Las Vegas Valley. It was prompted by declines in specific capacity of about 90% at the Las Vegas Valley Water District's West Central Well Field. It was hypothesized that the decline in specific capacity resulted from dewatering of the most permeable interval of the alluvium. Lithologic descriptions from wells and aquifer test information were analyzed for geologic and hydrogeologic variability. New information, in the form of detailed unpublished lithologic and hydrologic information, was available from twenty water wells …

Trace Element Analysis Of Selected Springs In The Virgin River Basin, Mary A. Yelken

UNLV Theses, Dissertations, Professional Papers, and Capstones

Spring water from 23 springs in and near the Virgin River Basin (southwestern Utah, northwestern Arizona, and southeastern Nevada) was collected and analyzed for chemical concentrations. Trace elements and major ion chemistry was used to determine the potential for utilizing water chemistry to provide information on spring water source and flow pathways. Principal Component Analysis (PCA), rare earth element (REE) normalization patterns, and mineral equilibrium modeling (PHREEQE) techniques were used to analyze the data set. Four major spring water groups were displayed by the PCA, based on similarities in water chemistry. The analyses suggest that spring water chemistry is a …

Residence Time Of Groundwater Issuing From The South Rim Aquifer In The Eastern Grand Canyon, Jim Fitzgerald

UNLV Theses, Dissertations, Professional Papers, and Capstones

In the eastern Grand Canyon, secondary porosity created by north trending faults, folds, and breccia pipes, facilitates groundwater flow through the South Rim carbonate aquifer. Springs associated with the South Rim Aquifer have low ³H concentrations, [Ca²⁺]/[Mg²⁺] rations close to unity, and variable uranium concentrations. For a geochemical comparison, springs are subcategorized on the basis of geology and discharge. Type I springs are associated with high-angle normal faults and have high discharge rates. These springs discharge Ca²⁺ - Mg²⁺, HCO₃^- waters, have ³H concentrations <2 TR, and ²³⁴U/²³⁸U activity …

An Understanding Of Factors Controlling Isotopic Ratios Of Wine As A Potential Surrogate Of Past Precipitation, Eric Alan Caldwell

UNLV Theses, Dissertations, Professional Papers, and Capstones

Precipitation, vapor water, ground water, soil water, grape berry and grape leaf water, grape must, and vintage wines were collected from northern California for stable isotopic analysis. An understanding of factors controlling isotopic ratios of wine allows evaluation of wine as a surrogate of past precipitation. Stable isotopic compositions of grape berry waters collected at Charles Krug Winery in Napa Valley. CA range from -31 to -17 per mil in 8D and +7.2 to +15.3 per mil in 8180, and plot along a transpiration line of slope 2. 7. Grape leaf waters range from -25 to +5 per mil in …

Spectral Analysis Of The Flow Behavior Of Big Spring, Kings Canyon National Park, California, Linda Urzendowski

UNLV Theses, Dissertations, Professional Papers, and Capstones

Big Spring, the resurgence of a karst aquifer in the Lilburn Cave system (Kings Canyon National Park, California), displays the uncommon phenomena of ebb and flow discharge during periods of high runoff.

Hydrograph analyses indicate that the portion of Lilburn Cave between the Z-Room and Big Spring is primarily a conduit flow aquifer. The power spectra strongly indicate a nonlinear system, with evidence of quasi-linear behavior found on a smaller scale. The transfer and kernel function indicate that no additional significant inputs or outputs to the system exist. The bench-scale model built to simulate the ebb and flow cycles in …

Hydrogeology And Hydrogeochemistry Of The Shallow Alluvial Aquifer Zone, Las Vegas Valley, Nevada, Harry Stephen Wild Jr.

UNLV Theses, Dissertations, Professional Papers, and Capstones

In Las Vegas Valley, Nevada, the shallow alluvial aquifer zone is a possible source of contamination to the principal alluvial aquifers that provide 30% of the public drinking water supply for the valley. Development of the principal aquifers has lowered pressure head in the principal aquifers and created the potential for downward seepage from the shallow aquifer zone. This study was undertaken to characterize the hydrogeology and hydrogeochemistry of the shallow alluvial aquifer zone and to compare the hydrogeochemistry of the shallow and principal alluvial aquifer zones.

A 37 well shallow ground water monitoring network was established and water-level, water-quality, …

Spring Flow In A Portion Of Grand Canyon National Park, Arizona, David Bruce Goings

UNLV Theses, Dissertations, Professional Papers, and Capstones

Hermit, Monument, Salt, and Horn Creeks flow through four side canyons of the Colorado River within the Grand Canyon. They lie just west of Grand Canyon Village on the south side of the canyon. Each of these creeks is fed by at least one spring.

Comparisons of flow at each of these springs for a 14 month period, and precipitation on the south rim show a close correlation. The lag period between recharge at the rim and discharge at the springs is less than one month for Hermit Creek and between one and two months for the other three creeks. …

Ground Water Flow Systems Of Central Nevada, G. William Fiero Jr

UNLV Theses, Dissertations, Professional Papers, and Capstones

The U.S. Atomic Energy Commission has been evaluating a large area of central Nevada in order to define a supplemental test site for the underground testing of high-yield nuclear devices. Safety considerations involving the radiocontamination of the ground water in the vicinity of the test site necessitated that research be conducted to determine the direction and rate of flow of the ground water. This investigation defines the ground water flow systems in eighteen valleys comprising 12,000 square miles of central Nevada.

The definition of the systems was made following a compilation of existing hydrologic and geologic data for the area. …