Hydrology Commons^™

Low-Level Pharmaceuticals And Personal Care Products In The Waters Of Michigan, Lisa M. Anderson

Dissertations

The results of this research are the product of a two year study funded by the Michigan Department of Environmental Quality with monies from the Clean Michigan Initiative. Low-level (part per billion range) pharmaceuticals and personal care products (PPCPs) in the waters of Michigan were investigated. Five rivers in the State were sampled; including the Clinton, Grand, Kalamazoo, Muskegon, and Saginaw. Groundwater samples were obtained from two shallow municipal water wells also; one on the Grand River and one on the Kalamazoo River. The wells were sampled to determine if PPCPs in the river water were being drawn in by …

Sedimentology And Stratigraphy Of The Pennsylvanian Saginaw Aquifer, Central Lower Michigan, U.S.A., Niah B. H. Venable

Masters Theses

The Saginaw Aquifer is an important bedrock aquifer serving the needs of over 400,000 people in the Tri-County area of the Central Lower Peninsula of Michigan. The aquifer is comprised of the Pennsylvanian Grand River and Saginaw Formations. This study focuses on expanding existing knowledge of the general sedimentologic and stratigraphic characteristics of these units using conventional geological methods including core analysis, local log to core correlation, local and regional log to log correlation, and biostratigraphy. Analysis of new core from the study area examines facies and depositional environments given cursory coverage in outcrop studies by past researchers.

Incised valley …

Geoelectrical Response Of An Aged Lnapl Plume: Implications For Monitoring Natural Attenuation, Douglas D. Werkema Jr.

Dissertations

The geoelectric stratigraphy at a site impacted with light non-aqueous phase liquids (LNAPLs) is investigated for its link to natural biodegradation, its contribution to the conductive model for aged (i.e. mature) LNAPL contaminated sites, and the relationship to the natural hydrologic regime. The highest conductivities (lowest resistivities) were observed in portions o f soils where LNAPL was in residual and free phase. Corroborating evidence from bacteria enumeration from soil close to the vertical resistivity probe (VRP) installations show orders-of-magnitude increase in both heterotrophic and oil degrading microbes at the depths where the conductivity was at a maximum. The coincidence o …

Chemical, Isotopic, And Hydrogeologic Investigations Of An Agriculturally Impacted Area, Nottawa Creek Watershed, Calhoun County, Michigan, Gerald A. Unterreiner

Dissertations

A 4 km2 agricultural area within the somewhat poorly drained Nottawa Creek Watershed, south central Michigan, was investigated to help understand transport and transformation processes of nutrients and herbicides to surface water. Geology o f the study area is comprised of a thin glacial drift cover overlying shale bedrock. A one layer, two-dimensional numerical triangular finite element groundwater flow model was developed to evaluate regional groundwater flow. Selected horizontal hydraulic conductivities ranged from 3 x 10‘3 m/day to 107 m/day. Field-scale infiltration modeling with the computer program GLEAMS, substantiated with water level measurements, suggest significant recharge events occur during summer, …

A Comprehensive Approach For Evaluation Of Groundwater Vulnerability To Contamination, Shafiul H. Chowdhury

Dissertations

Groundwater vulnerability to contamination from surface sources was evaluated for Nottawa Creek Watershed, Calhoun County Michigan using AQUIPRO and DRASTIC vulnerability methods. A geographic information system (GIS) was used to analyze and map the data. Forty groundwater samples were collected following a statistical sampling protocol from private wells. Samples were analyzed for nitrate-N and atrazine. Atrazine was not detected (detection limit 0.1 ppb) in any of the samples. Five samples contained detectable nitrate-N (detection limit 0.05 mg/L). Due to insufficient chemical data, the relative AQUIPRO and DRASTIC vulnerability scores could not be compared with the frequency of occurrences o f …

Systematics Of Stable Isotopes And Radionuclides In Precipitation At Kalamazoo, Michigan, Usa, Madhav V. Machavaram

Dissertations

Precipitation samples were collected at Kalamazoo from June 1992 to March 1995. The samples were analyzed for their 8D and 8lgO values. The 5D - 5I80 relationship is comparable to that of Meteoric Water Line (MWL). The monthly mean isotopic values in precipitation exhibited strong seasonality, being higher in summer and lower in winter months. This behavior is apparently a direct consequence of the temperature effect on isotope fractionation.

The summer precipitation at Kalamazoo is derived predominantly from the water vapor originated in the Gulf of Mexico. A box model calculation showed that a Rayleigh type distillation with Gulf moisture …

Groundwater-Kalamazoo River Interaction Near The Parchment City Wellfield, Parchment, Michigan, W. Richard Laton

Dissertations

A detailed hydrogeologic study of the Kalamazoo River and its interaction with the groundwater was completed near Parchment, Michigan. The Kalamazoo River between Portage Creek and Allegan Dam is a Federal superfund site due to PCB contamination trapped in its sediments. The City of Parchment pumps all of its drinking water from a glacial aquifer 850 feet from the Kalamazoo River. This study focused on the hydrogeology and groundwater/surface interaction of the area through the use of surface and downhole geophysics, installation of monitoring wells and peizometers, seepage meters and chemical sampling. It was determined that the Kalamazoo River is …

A Study On The Causes Of Variations In Transmissivity And Storativity During Pump Tests At Asylum Lake, Paul Joseph Pare

Masters Theses

Over a two year period, Western Michigan University ran a number of pump tests in the Asylum Lake Area in Kalamazoo, Michigan. The transmissivities and storativities calculated from these tests differed significantly from well to well in any particular test, and from pump test to pump test. Utilizing the computer programs AQTESOLV 3.0 and Aquifer Parameter Estimator, a number of T and S values were calculated. After analysis of the results, the following conclusion was drawn. The main reason for the deviations in the T and S values arose from the mixing of the results of numerous methods (some of …

Geological And Hydrogeological Characterization Of The Schoolcraft Aquifer, Schoolcraft, Michigan, William K. Steinmann

Masters Theses

Newly installed monitoring wells, county well logs, gamma-ray logs, head measurements, flow nets, slug tests, and full aquifer pumping tests were utilized to characterize the geologic and hydrogeologic conditions of the area. Evaluation of the geologic conditions indicate that the study area is best described as a glacially generated, humid type, alluvial fan. A hydrogeologic facies model concept aided in the initial evaluation of the hydrogeologic conditions and was utilized for the placement of several vertically nested monitoring wells. Further evaluation indicates an unconfined aquifer comprised of two separate flow systems: a shallow, local flow system interacting with flow-through surface …

Hydrogeology And Hydrogeochemistry Of Government Marsh, North St. Joseph County, Michigan, Michael C. Kasenow

Dissertations

A hydrogeologic and hydrogeochemical investigation was conducted at Government Marsh located in St. Joseph County, Michigan from May, 1988, to November, 1993. Information on glacial geology, topography, drainage patterns, hydraulic conductivity, vegetation, water chemistry, and static water table elevations has been collected and analyzed. Data were collected in order to determine directions of ground water flow and areas of recharge and discharge. Bail-down tests, grain-size analysis, and permeameters were used to determine hydraulic conductivity adjacent to and within the wetland. Water table elevations and chemistry were analyzed from wells adjacent to the wetland perimeter and within the boundaries of the …

Precipitation Dynamics In Kalamazoo, Sw Michigan: A Stable Isotope Perspective, Madhav V. Machavaram

Masters Theses

No abstract provided.

The Hydrogeology Of Bonnie Castle And Dustin Lakes And Its Relationship To Groundwater Contamination From The Kl Avenue Landfill, Kalamazoo County, Michigan, Joseph S. Hobin

Masters Theses

The objectives of this investigation were to explain the hydrogeology of Bonnie Castle and Dustin Lakes and to assess the water quality of the lake environments with respect to possible impact from the KL Avenue Landfill.

The surface water/groundwater relationship was determined by the installation of mini-piezometer nests and seepage meters at selected study stations along the shoreline of each lake. Field data were augmented with groundwater and surface water chemical analyses, lake depth profiles and geologic cross-sections.

The result of this research was the characterization of Bonnie Castle Lake as a perched recharge lake and Dustin Lake as a …

Laboratory Studies Of Filter Pack Grain-Size Distributions And Hydrophobic Treatments To Enhance The Recovery Of Free-Phase Floating Hydrocarbons, Hugh Garret Heuvelhorst

Masters Theses

Experiments were conducted in laboratory sand tanks to evaluate filter pack design criteria in an effort to improve free-product hydrocarbon recovery from sand aquifers. Filter sands were prepared and installed in the test tanks to examine the relative efficiency of two different grain sizes and two different grain-size distributions to imbibe kerosene from the formation sand and release it to their respective wells. Treatments of different chemical products were applied to other filter sands to create a hydrophobic coating on the grains. The hydrophobic coatings were tested on filter sands of different grain sizes and grain-size distributions and compared to …

The Effects Of Composting Of Yard Wastes On The Ground-Water Quality: Wmu Farms Site, Kalamazoo, Michigan, Bryan Kirk Allen

Masters Theses

In the rush to find alternatives to landfilling of yard waste, federal and state agencies have identified composting as the main solution. There is therefore a need to address the possible environmental problems which could be associated with such composting operations. Compost may contain nutrients, organic acids, pesticides, and metals which could leach through soils to the ground water posing a potential contamination problem.

At the WMU Farms Site, two sites have been used for the composting of leaves by the City of Kalamazoo. The physical and chemical hydrogeology of these sites were characterized.

The results suggest that the presence …

Groundwater Chemistry Analysis Of The Saginaw Formation In Delhi Township, Michigan, Sam L. Kitchin

Masters Theses

Groundwater chemistry and well data provided by the Ingham County (Michigan) Health Department were used to evaluate the distribution of inorganic chemical constituents in the groundwater flow system of the Saginaw Formation, in Delhi Township, Michigan. The data also were used to study the distribution of chemical constituents with respect to different rock types of the Saginaw Formation. The data were analyzed to examine if variations in the concentrations of the chemical constituents and the values of other chemical parameters relate to rock-water interactions, groundwater flow systems, or groundwater contamination.

The results indicate that patterns of increasing or decreasing concentrations …

Ground-Water Contamination By Volatile Organic Compounds: Sources Of Error, Temporal And Spatial Variability, Gary Thomas Blinkiewicz

Masters Theses

Data on the distributions of VOC’s (volatile organic compounds), principally trichloroethane and dichloroethylenes, in a shallow sand and gravel aquifer near Rockford, IL have been collected for a number of years. Synoptic sampling events from a dense monitoring well network within a greater than 4 mi^2 area, provide the basis for the evaluation of sources of variability in concentrations in space and time. Sampling, and analysis-related variability in these data contribute less than 10% of total variance. Spatial and temporal variability over periods of months to years are significant Results suggest that contaminant distributions can be resolved best by using …

Improved Filter-Pack Design For Hydrocarbon Recovery Wells In Unconsolidated Aquifers, Thomas R. Barrett

Masters Theses

Laboratory sand tank experiments and two field studies were conducted to determine filter-pack designs that would increase the hydrocarbon flow rate into hydrocarbon recovery wells. Previous laboratory experiments have shown that using filter-packs of Teflon chips or sands treated with a water repellent spray will increase the rate of hydrocarbon recovery into wells in laboratory bail down test experiments.

The results of the laboratory investigations suggest that using a hydrophobic filter-pack with a median grain-size of 2.5-3.5 greater than that of the aquifer will provide the greatest rate of hydrocarbon recovery.

In two field studies, wells constructed with a hydrophobic …

A Study Of Ground-Water Quality In A Priority Agricultural And Livestock Watershed, Cass County, Michigan, Matthew Alan Stuk

Masters Theses

A study of ground-water contamination in a shallow, sandy, glacial drift aquifer was performed in a watershed dominated by swine feedlots and crop fields in Cass County, Michigan. Monitoring wells were installed and sampled to study the flow pattern, chemistry, and contamination of ground water.

Results of chemical analyses show contamination from fertilizers and other soil-applied chemicals as well as the infiltration of breakdown products from pig waste. Shallow wells in impacted areas show potassium and nitrate from the breakdown of fertilizers, calcium from field application of lime, and additional nitrate from pig waste. Elevated calcium, potassium, and nitrate concentrations …

Hydrogeologic Characterization Of A Multi-Aquifer System At Station 11 In Kalamazoo, Michigan, Linda G. Jones

Masters Theses

The purpose of this study was to determine the hydraulic connection between the upper and lower confined glacial drift aquifers. The results of this study are based primarily upon the geologic profiles, a comparison of the head differences within each aquifer, potentiometric surfaces and different lag times for precipitation to reach each aquifer.

Results of the aquifer test showed that the upper confining layer pinches out in the western part of the well field. This area also provided significant recharge to the well field during the aquifer test. Data collected during the aquifer test and the increases in water levels …

Fractures In The Jacobsville Sandstone And The Precambrian “W” Rocks In Eastern Marquette County, Michigan, Leonard Paul Belliveau

Masters Theses

The major fracture systems in the Jacobsville sandstone likely originated by reverse faulting on the Keweenaw fault and by glacially produced thrusting. Fracture orientations, apertures, and spacings are uniform in the Jacobsville sandstone and Lighthouse Point member of the Mona Schist, and are variable in the Lower member of the Mona schist and Compeau Creek gneiss. Fracture sets in the Compeau Creek gneiss exist in domains separated by metadiabase dikes. The metadiabase dikes relieved the strain produced by the Penokean orogeny by fracturing. Fractures present in inclusions, quartz veins, metadiabase and diabase dikes can be used to temporally evaluate the …

An Analysis Of Hydrogeologic Factors Affecting Aquifer Vulnerability In Southwestern Michigan, Steven E. Benton

Masters Theses

In southwestern Michigan aquifers are threatened by human activities. Parameter/factor weighting systems are used to rate aquifer vulnerability. Hydrogeologic factors affecting aquifer vulnerability were investigated in this study.

Well records, soil surveys, hydrogeologic reports, and partial chemical analyses were used to obtain data on the aquifers, soil types, glacial sediments, and types of contaminants. Data analysis included comparisons of means and medians, factor analysis, and Pearson and Spearman Correlation analysis.

The results indicate that the aquifers in Kalamazoo County are not protected. Depending on the type of glacial sediment, hydrogeologic factors that protect aquifers are clay thickness and the depth …

A Hydrogeochemical Characterization Of A Glacial-Drift Aquifer System In Southwest Michigan, Patrick G. Barrese

Masters Theses

A hydrogeochemical investigation of the Schoolcraft Aquifer, an unconfined, glacial-drift aquifer located in southwest Michigan, was undertaken to focus on three topics: (1) the geochemical definition of recharge and discharge zones both vertically and laterally along projected flow paths, (2) the description of the carbonate and redox chemical systems, and (3) groundwater degradation associated with excessive nitrate, ammonium, and chloride concentrations.

The results of the study were inconclusive in defining recharge and discharge zones; however, iron and alkalinity concentrations were identified as possible indices for recharge and discharge conditions. The carbonate analysis indicated that the aquifer is saturated with respect …

A Regional Study Of Ground-Water Quality In Barry County, Michigan, Margene K. Brewer

Masters Theses

A regional study of ground-water quality in Barry County, Michigan was conducted using a computerized database from the Science for Citizens Center at Western Michigan University in Kalamazoo, Michigan. The database, initiated by the Michigan Groundwater Survey, consists of residential well logs and chemical analyses of samples collected from residential wells by the Barry County Health Department. Qualitative and statistical analyses of the data indicate that the glacial drift aquifer is recharging the bedrock aquifer throughout most of the county. Groundwater quality appears to be controlled mainly by the open-system dissolution of carbonate minerals. The water chemistry is also influenced …

Effects Of Capillarity On Dnapl Thickness In Wells And In Adjacent Sands, Timothy V. Adams

Masters Theses

Physical model experiments were used to investigate the behavior of dense non-aqueous phase liquids (DNAPLs) in various geologic media.

The objectives of the laboratory investigations were to (a) compare DNAPL thickness in wells to thickness in adjacent sands, (b) observe and interpret dyed DNAPL migration in unsaturated and saturated sands, and (c) study DNAPLs' effects on clay layers.

Two cylindrical glass columns fitted with various well screens were filled with sand, clay layers, water, and dyed DNAPLs in four experiments. Columns were packed with fine or coarse sand and clay layers. Coarse hydrophobic sand was also used.

At equilibrium, DNAPL …

The Effects Of Urbanization On A Portion Of The Portage Creek Watershed: A Case Study On Surface Water And Groundwater Quality, Susan E. Rezek

Masters Theses

The surface water and groundwater quality in the study area of the Portage Creek watershed was analyzed to determine the possible effects of urbanization. Dry weather and wet weather surface water and groundwater samples were collected from June 1986 to November 1986 at selected stations in the watershed.

Water samples were analyzed for 26 inorganic and organic parameters. Most concentrations were below analytic method detection limits. The analytical data indicate that sodium and chloride are the principal contaminants resulting from urbanization. The probable source of the contamination is deicing salt applied to the City of Portage, Michigan streets.

Overall, the …

A Hydrogeological And Hydrogeochemical Investigation Of Groundwater At A Landfill For Sludge From The Kalamazoo Wastewater Treatment Plant, Richard Howard Christensen

Masters Theses

Major cations and anions were analyzed to determine groundwater chemistry at a site used for the disposal of municipal sludge in the late 1960s and contaminated Portage Creek sedimem dredged in the late 1970s. The disposal site consists of five unlined basins constructed over 50 to 100 feet of stratified sand and gravel outwash underlain by silt and clay. Groundwater in the outwash is unconfined and flows from east to west. A groundwater divide in the center of the site produces local divergent flow to the northwest and southwest. Measurements of chemical constituents indicate that three factors influence groundwater chemistry …

Spatial And Temporal Variations Of Synthetic Organic Compounds In The Contaminant Plume Emanating From The Kl Landfill, Lynn Diane Broede

Masters Theses

Thirty-one synthetic organic compounds have been detected in samples collected from the KL Landfill contaminant plume from March, 1980 to March, 1986. Two groups of organic compounds have been delineated based on their occurrence, concentrations, and persistence throughout the 7-year monitoring period.

Changes in plume geometry and concentration have been studied relative to time, and concentration variations have been related to selected inorganic plume parameters, distance from the landfill, and precipitation. The spatial and temporal distribution of the organic compounds are attributed to biodegradation, three biotransformation sequences, physical properties of the organics and other factors. Three abbreviated anaerobic biotransformation sequences …

Hydrogeology And Hydrogeochemistry Of The Tekonsha Moraine And Adjacent Interlobate Deposits In Charleston Township, Kalamazoo County, Michigan, Victor V. Melbardis

Masters Theses

Hydrogeochemical analyses and hydrogeologic interpretations provide the basis for an understanding of local ground-water flow, in a 12 square mile study area, transected by the Tekonsha Moraine and bound by glaciofluvial deposits. Glacial tills separate an upper and lower aquifer system throughout most of the area.

Degraded and tritiated ground water is present in the lower aquifer system. A negative correlation (-0.62) between tritium concentrations and depth is statistically significant (.04). In this local system, hydrochemical trends are characterized by decreases in sulfate percentages and increases in bicarbonate in the direction of ground-water flow. Statistical evaluation of the hydrochemical data …

Simulation Of Bromide Transport In A Layered Aquifer Using Two-Dimensional And Three-Dimensional Computer Models, Kathleen Michelle Hewitt

Masters Theses

Simulation of a two-well tracer test at a site near Mobile, Alabama was performed and compared with the experimental breakthrough curve. The models used to simulate the test results were the three-dimensional USGS code HST3D and the two-dimensional USGS code MOC. The results of the three-dimensional model were also compared with the results of the two-dimensional model.

The three-dimensional model HST3D predicted the measured breakthrough curve accurately with the exception of early arrival times of the tracer in the withdrawal well. The two-dimensional model MOC did not accurately predict the bromide concentration in the withdrawal well during the two-well test. …

A Laboratory Characterization Of Pulp And Paper Mill Solid Wastes For Potential Use As Hydraulic Barrier Material In Landfill Covers, Carleton Van Maltby

Masters Theses

Fifteen sludges from wastewater treatment systems of pulp and paper mills that encompass major production categories, and eight fly ashes from mill boilers incinerating wood waste, coal, or their combination were characterized for their potential suitability as hydraulic barrier material. Hydraulic conductivity was observed to range over four orders of magnitude for the materials tested.