Geology Commons^™

Volatile Cycling And Metasomatism In Flat-Slab Subduction Zones Of The Central Andes, Coleman Hiett

All Graduate Theses and Dissertations, Spring 1920 to Summer 2023

Flat-slab subduction, where an oceanic plate subducts horizontally below a continental margin for hundreds of kilometers, is an enigmatic but prevalent tectonic configuration in which chemical cycling and alteration of the continental plate is poorly constrained. Geochemical investigations in regions of modern and ancient flat-slab subduction in the Central Andes afford an opportunity to study this process. Certain elements naturally occur with varying number of neutrons in their nuclei (isotopes), and measurements of isotope ratios within geologic materials inform on chemical sources and geologic processes. This research leverages stable isotope analyses and other geochemical tools to investigate volatiles and other …

First-Row Transition Element Distribution Across The Blueschist-Eclogite Transition: A Case Study From New Caledonia, Natalie M. Harmon

Electronic Theses and Dissertations

The first-row transition elements (FRTE), namely Sc, Ti, V, Cr, Mn, Fe, Co, Ni, Cu, and Zn, are potential redox tracers in the solid Earth due to their general compatibility during crustal processes, and the redox-sensitive nature of certain elements. Despite widespread interest in the FRTEs, their distribution and behavior in subduction zones, particularly across the blueschist-eclogite transition, are still poorly constrained. New Caledonia preserves a prograde subduction zone with largely coherent continuous progression in metamorphic grade. Although the metamorphic sequence has been disrupted to some extent, this is the closest natural example of blueschist and eclogite that was sourced …

The Role Of Slow Slip Events In The Cascadia Subduction Zone Earthquake Cycle, Juliette P. Saux, Elias G. Molitors Bergman, Eileen L. Evans, John P. Loveless

Geosciences: Faculty Publications

Slow slip events (SSEs) detected on the Cascadia Subduction Zone interface at 30–50 km depth imply a release of accumulated strain. However, studies of interseismic deformation in Cascadia typically find coupling on the upper 30 km of the interface, which is generally accepted as defining the seismogenic zone. Estimates of coupling using net interseismic velocities (including SSE effects) and restricting coupling to the shallow interface may underestimate slip deficit accumulation at depths >30 km. Here, we detect reversals in GPS motion as indications of SSEs, then use SSE displacements to estimate cumulative slow slip from 2007 to 2021. We calculate …

Seismic Anisotropy And Mantle Deformation Beneath The Central Sunda Plate, Wenkai Song, Youqiang Yu, Stephen S. Gao, Kelly H. Liu, Yifang Fu

Geosciences and Geological and Petroleum Engineering Faculty Research & Creative Works

The central Sunda plate, which forms the core of Southeast Asia, has been extensively studied based on analyses of data mainly from surface geological observations. In contrast, largely due to the limited coverage by seismic stations in the area, a number of key issues associated with mantle structure and dynamics remain enigmatic. These can possibly be constrained by investigating seismic azimuthal anisotropy in the upper mantle. Here we employ the shear wave splitting technique on three P-to-S converted phases from the core-mantle boundary (PKS, SKKS, and SKS) recorded by 11 stations to systematically explore the spatial variation of azimuthal anisotropy …

Analyzing Slab Holes In Subduction Zones And Their Impacts Through Numerical Simulations, Taylor M. Arrowood

Theses and Dissertations--Earth and Environmental Sciences

Subduction zones form as higher density oceanic lithosphere is forced beneath an over-riding, lower density, continental or oceanic plate; a process driven by contrasts in buoyancy throughout this system. We seek to explore subduction zones in which the subducting lithosphere is discontinuous after passing through the trench, forming a slab gap. The main research objective is to determine the effect of slab gaps on surface topography in a subduction-related orogen and asthenospheric flow into the mantle wedge using two and three-dimensional numerical mechanical models. We obtain results from 24+ models that suggest a connection between slab gaps/holes and the magnitude …

Petrology Of An Oxidized Blueschist Cobble From The San Onofre Breccia, California, Usa, Alaina A. Helm

Honors Papers

The mid-Miocene San Onofre Breccia (SOB) found along the southern California borderlands contains clasts of several lithologies including high-pressure metamorphic rocks commonly thought to be shed from the Catalina Schist. Sorensen concluded the San Onofre Schist was part of the Franciscan Complex, although at that time the Catalina subduction was considered to be part of the Franciscan Complex. In this study, a ~10 cm cobble collected from the San Onofre type locality was studied to describe its mineralogy and estimate its conditions of metamorphism. The cobble is composed of glaucophane (35%) + epidote (15%) + garnet (13%) + phengite (12%) …

Sulfur And Trace Metal Cycling At Convergent Margins, Jesse B. Walters

Electronic Theses and Dissertations

Subduction zones are the site of long-term chemical exchange between Earth’s surface and interior geochemical reservoirs. Subducting slabs are progressively depleted in volatiles and other mobile elements through dehydration and melting reactions. These elements are then introduced to the mantle wedge and volcanic arc. One consequence of this cycle is that volcanic arcs produce the most oxidized magmas on Earth. Sulfur, which exhibits a range in valence states from S^2- to S⁶⁺, is one of the few elements in the subducting slab capable of oxidizing the arc and mantle wedge. Sulfides in the slab may also act …

Boron Variation And The Subducted Sediment Component In The Volcanics From The Bifurcated Portion Of The Lesser Antilles Island Arc (Laia), Ami Margret Ngo Ward

USF Tampa Graduate Theses and Dissertations

North of Martinique island the Lesser Antilles volcanic arc bifurcates, creating a double arc. Here volcanic activity has migrated up to 50 km westward with time, resulting in two volcanic lines that are distinct in age. The eastern line, commonly referred to as the old arc, was active from Early Eocene to Mid-Miocene (Nagle, 1971; Nagle et al., 1976; Westercamp and Tazieff, 1980; Andreieff et al., 1988). The western line, commonly referred to as the recent arc, has been active since the late Pliocene, ~6 Ma ago (Nagle, 1971; Nagle et al., 1976; Westercamp and Tazieff, 1980; Andreieff et al., …

Fluid-Mobile Trace Element Variability Of Serpentinites And Entrained Crustal Rocks Across The Mariana Forearc System, Raymond M. Johnston

USF Tampa Graduate Theses and Dissertations

In the Mariana subduction system, active serpentinite mud volcanoes are associated with the subduction of the Pacific plate beneath the Philippine plate in a non-accretionary convergent plate margin. This location offers a unique opportunity to study the subduction zone interface with little crustal contamination. The systematics of fluid-mobile trace elements (FME) (As, Cs, Rb, Sb, Tl, Pb, and Sr) in erupted serpentinite muds and entrained serpentinized ultramafic and mafic clasts can place constraints on the release of slab-derived fluids from the downgoing plate, and ultimately the pressure/temperature (P/TC°) conditions at which these fluids are mobilized.

The samples analyzed in this …

Investigating Cascade Magmatism Through Dating And Chemical Analysis Of The Hatchet Mountain And Pe Ell Formations, Sw Wa, Robyn Organ, Jeffery Tepper, Wesely Von Dassow, Tabor Reedy

Summer Research

Modern Cascade arc magmatism began ~45 Ma, shortly after accretion of the Siletzia terrane culminated at ~50 Ma. The earliest expressions of this magmatism are several petrologically-diverse volcanic units in SW Washington including: (1) the Goble Volcanics (GV) / Hatchet Mountain Formation (HM), (2) the Pe Ell Formation (PE), and (3) scattered exposures of unnamed basalts (UB). These rocks, all dominantly subaerial lavas, occur west of the modern arc where they are interbedded with marine and deltaic sedimentary units, suggesting eruption in a forearc or volcanic front setting. Goals of this study are: (1) to characterize the elemental and Sr-Nd …

Characteristics Of The Mantle Flow System Beneath The Indochina Peninsula Revealed By Teleseismic Shear Wave Splitting Analysis, Youqiang Yu, Stephen S. Gao, Kelly H. Liu, Ting Yang, Mei Xue, Khanh Phon Le, Jinyao Gao

Geosciences and Geological and Petroleum Engineering Faculty Research & Creative Works

Numerous geoscientific investigations have been conducted on the southeastern Tibetan Plateau and adjacent areas for understanding crustal and mantle deformation associated with the indentation of the Indian Plate into Eurasia. A number of key issues, such as the causes of a sudden change of fast polarization orientations from N-S to almost E-W at approximately 26°N revealed by shear wave splitting (SWS) studies, and the geodynamic implications of the transition still remain enigmatic, partially due to the lack of sufficient SWS measurements on the Indochina Peninsula. Here we employ the SWS technique to systematically illuminate upper mantle anisotropy beneath the Indochina …

Contrasting Sediment Melt And Fluid Signatures For Magma Components In The Aeolian Arc: Implications For Numerical Modeling Of Subduction Systems, Denis Zamboni, Esteban Gazel, Jeffrey G. Ryan, Claudia Cannatelli, Federico Lucchi, Zachary D. Atlas, Jarek Trela, Sarah E. Mazza, Benedetto De Vivo

Geosciences: Faculty Publications

The complex geodynamic evolution of Aeolian Arc in the southern Tyrrhenian Sea resulted in melts with some of the most pronounced along the arc geochemical variation in incompatible trace elements and radiogenic isotopes worldwide, likely reflecting variations in arc magma source components. Here we elucidate the effects of subducted components on magma sources along different sections of the Aeolian Arc by evaluating systematics of elements depleted in the upper mantle but enriched in the subducting slab, focusing on a new set of B, Be, As, and Li measurements. Based on our new results, we suggest that both hydrous fluids and …

Fluid Release During Eclogite Formation, North Qaidam Terrane, Western China, Jake M. Meyer

All Master's Theses

Ultrahigh-pressure (UHP, depths ≳100 km) eclogite samples from the Dulan area of the North Qaidam Terrane, western China, preserve evidence of fluid release along a prograde pressure-temperature (P-T) path. Eclogite sample D126A, Grt + Omp + Qtz + Zo + Amp + Phe + minor Rt + Hem, contains garnet porphyroblasts that preserve strong Ca zoning, recording higher core values (Grs₃₄), lower inner mantle values (Grs₂₅), increasing outer mantle values (Grs₂₈), and lower rim values (Grs₂₆). Isochemical phase diagrams (pseudosections), assuming H₂O saturation, produce a P-T path constrained by multiple …

Seismic Anisotropy And Subduction-Induced Mantle Fabrics Beneath The Arabian And Nubian Plates Adjacent To The Red Sea, Ahmed A. Elsheikh, Stephen S. Gao, Kelly H. Liu, Abdelnasser A. Mohamed, Youqiang Yu, Raafat E. Fat-Helbary

Geosciences and Geological and Petroleum Engineering Faculty Research & Creative Works

For most continental areas, the mechanisms leading to mantle fabrics responsible for the observed anisotropy remain ambiguous, partially due to the lack of sufficient spatial coverage of reliable seismological observations. Here we report the first joint analysis of shear-wave splitting measurements obtained at stations on the Arabian and Nubian Plates adjacent to the Red Sea. More than 1100 pairs of high-quality splitting parameters show dominantly N-S fast orientations at all 47 stations and larger-than-normal splitting times beneath the Afro-Arabian Dome (AAD). The uniformly N-S fast orientations and large splitting times up to 1.5 s are inconsistent with significant contributions from …

A Geochemical Study Of Crustal Plutonic Rocks From The Southern Mariana Trench Forearc: Relationship To Volcanic Rocks Erupted During Subduction Initiation, Julie A. Johnson

FIU Electronic Theses and Dissertations

Two suites of intermediate-felsic plutonic rocks were recovered by dredges RD63 and RD64 (R/V KK81-06-26) from the northern wall of the Mariana trench near Guam, which is located in the southern part of the Izu-Bonin-Mariana (IBM) island arc system. The locations of the dredges are significant as the area contains volcanic rocks (forearc basalts and boninites) that have been pivotal in explaining processes that occur when one lithospheric plate initially begins to subduct beneath another. The plutonic rocks have been classified based on petrologic and geochemical analyses, which provides insight to their origin and evolution in context of the surrounding …

Eclogites And Eclogites: Oxygen Isotope Evidence Of A Shared Subduction Origin For Franciscan Eclogites And Moses Rock Eclogite Xenoliths, William F. Hoover

Honors Papers

Eclogites can be found in two distinct tectonic settings in the western USA: in the Franciscan Complex as tectonic blocks in a fossil accretionary wedge, and in the Navajo Volcanic Field as xenoliths in diatremes. Intra-crystal oxygen isotope analyses of garnets from these two settings provide important information on the source, composition and timing of fluid interactions in both eclogite settings. Because of the well-documented relationship between Franciscan subduction and the volcanism in the Navajo Volcanic Field, the samples in this study can be directly compared to determine if they share a common origin. The Navajo eclogites in this study …

A Petrologic Study Of The Teanaway Basalt: Eocene Slab Window Volcanism In Central Wa, Liz Roepke

Summer Research

The Teanaway Basalt (TB) includes subaerial basalt to andesite flows, mafic to felsic tuffs, and rhyolite domes in the Central Cascades of Washington State. These volcanics overlie the extensive ~47 Ma Teanaway Dike Swarm (TDS) that cuts the underlying Swauk Formation. Samples were collected from 3 main localities: Easton Ridge (ER) in the west, Liberty Ridge (LR) in the east, and the Middle Fork of the Teanaway River (MF) in the center.

The bimodal TB consists predominantly of basaltic andesite and andesite (45.3–63.1 wt% SiO₂) with subordinate rhyolite (75.9–79.4 wt% SiO₂). The mafic rocks classify as …

Thermobarometric Modeling Of The Catalina Amphibolite Unit: Implications For Tectonic And Metasomatic Models, Henry W. Towbin

Honors Papers

On Santa Catalina Island, Ca high-grade amphibolite units overlie progressively lower- grade blueschist units in an inverted stack structure. This juxtaposition of high grade and low-grade metamorphic units has long been the subject of much debate as to the tectonic origins of the formation and how it relates to California's tectonic evolution. Previous petrography and thermobaromety of blocks in the amphibolite unit estimate pressures and temperatures of ~8-11 kbar and ~640-750 °C (Platt, 1975; Sorensen and Barton 1987). These estimates were calculated before many of the computational advances in modern thermobarometry. Using Equilibrium Assemblage Diagrams (EAD) calculated with Theriak Domino, …

Geochemical Source Components In Seafloor Lavas In The Aleutian Back-Arc, Max Thomas Siegrist

Theses and Dissertations

Whole-rock compositions of seafloor lavas are used to constrain the processes and source characteristics contributing to the formation of geochemically distinctive, primitive magma types located in the Aleutian back-arc. Samples were dredged primarily from small volcanic cones on the seafloor, located between the emergent volcanoes and in the back-arc up to 60 km from the volcanic front. Compositions vary from basalt to dacite, with 48-70 % SiO₂ and 4-13 % MgO. Nearly 30% of the samples are primitive, with Mg/Mg+Fe >0.60. Most primitive samples are basalts, which fall into two groups, based on minor and trace element abundances. Low/med-K …

Tavşanli Zone: The Northern Subducted Margin Of The Anatolidetauride Block, Aral I. Okay

Bulletin of the Mineral Research and Exploration

The Tavşanlı Zone constitutes the northern margin of the Anatolide-Tauride Block that has undergone high pressure-low temperature metamorphism during the Cretaceous. It is bounded in the north by the İzmir-Ankara suture and in the south by the rocks of the Afyon Zone. The Tavşanlı Zone is subdivided into four tectonic units. At the base there is the Orhaneli Group, which shows a regular stratigraphic succession that has underdone metamorphism at ~24 kbar pressure and 430-500 °C temperature during the Late Cretaceous (~80 Ma). From the base upward the Orhaneli Group consists of micaschist, marble and metabasite-metachertphyllite, and is tectonically overlain …

Along-Strike Trace Element And Isotopic Variation In Aleutian Island Arc Basalt: Subduction Melts Sediments And Dehydrates Serpentine, Brad S. Singer, Brian R. Jicha, William P. Leeman, Nick W. Rogers, Matthew F. Thirlwall, Jeffrey G. Ryan, Kirsten E. Nicolaysen

Geology Faculty Publications

Trace element and Sr-Nd-Pb isotope compositions of basaltic lavas from 11 volcanoes spanning 1300 km of the Aleutian Island arc provide new constraints on the recycling of elements in melts and fluids derived from subducted oceanic crust and sediment. Despite a nearly twofold variation in the flux of sediment subducted along the Aleutians, proxies indicating the presence of sediment melt in the magma source, including Th/La and Th/Nd, do not vary systematically along strike. In contrast, ratios including B/La, B/Nb, B/Be, Cs/La, Pb/Ce, and Li/Y suggest that the quantity or composition of fluid transferred from the slab into the mantle …

Geochemistry Of Serpentinized Peridotites From The Mariana Forearc Conical Seamount, Odp Leg 125: Implications For The Elemental Recycling At Subduction Zones, Ivan P. Savov, Jeffrey G. Ryan, Massimo D'Antonio, Katherine Kelley, Patrick Mattie

Geology Faculty Publications

Recent examinations of the chemical fluxes through convergent plate margins suggest the existence of significant mass imbalances for many key species: only 20–30% of the to-the-trench inventory of large-ion lithophile elements (LILE) can be accounted for by the magmatic outputs of volcanic arcs. Active serpentinite mud volcanism in the shallow forearc region of the Mariana convergent margin presents a unique opportunity to study a new outflux: the products of shallow-level exchanges between the upper mantle and slab-derived fluids. ODP Leg 125 recovered serpentinized harzburgites and dunites from three sites on the crests and flanks of the active Conical Seamount. These …

Lithium Abundance And Isotope Systematics Of Forearc Serpentinites, Conical Seamount, Mariana Forearc: Insights Into The Mechanics Of Slab-Mantle Exchange During Subduction, Laurie D. Benton, Jeffrey G. Ryan, Ivan P. Savov

Geology Faculty Publications

[1] Variable lithium contents and contrasting Li isotopic signatures are evident in the serpentininite muds and clasts extruded at Conical Seamount in the Mariana forearc. The muds have high Li contents compared to mantle values (3–7 ppm) and a mean δ7Li value of ∼+6‰. The clasts are generally lower in Li, and δ7Li varies from −6‰ to +10‰, with higher δ7Li correlating broadly to higher lithium contents. The diverse δ7Li in the serpentinite clasts suggests Li exchanges between mantle rocks and evolving slab‐derived fluids from different depths, producing a subarc mantle that is zoned in terms of Li abundances and …

Mantle Layering Across Central South America, Kelly H. Liu, Stephen S. Gao, Paul G. Silver, Yongkai K. Zhang

Geosciences and Geological and Petroleum Engineering Faculty Research & Creative Works

Imaging of seismic velocity discontinuities along a 3000 km profile across central South America at 20°S suggests that the depth variations of the 410-km (d410) and 660-km (d660) discontinuities are closely associated with the high-velocity Nazca slab and juxtaposed low-velocity oceanic mantle beneath the slab. The mantle transition zone thickness ranges from 220 km in the oceanic mantle to 270 km in a 600-km-wide area occupied by the deflected Nazca slab. The slab deflection has also been suggested by previous studies of seismic tomography and seismicity. This 50 km difference in the thickness corresponds to a lateral temperature variation of …

Temporal Variation Of Seismic B-Values Beneath Northeastern Japan Island Arc, Aimin Cao, Stephen S. Gao

Geosciences and Geological and Petroleum Engineering Faculty Research & Creative Works

Analysis of a high quality seismic catalog reveals that the average of seismic b-values in the crust beneath most part of northeastern Japan island arc decreased from 0.86 between 1984 and 1990, to 0.73 between 1991 and 1995. The two areas with the largest decrease are found to be in the same areas where the coupling between the North American and the Pacific plates is the highest, as suggested by a recent geodetic study. In the same time period, the annual seismic moment release increased by 10 times. In addition, there seems to be a corresponding increase in volcanic activities …

Subduction Of The Caribbean Plate And Basement Uplifts In The Overriding South American Plate, James N. Kellogg, William E. Bonini

James N Kellogg

Abstract. The new tectonic interpretations presented in this paper are based on geologic field mapping and gravity data supplemented by well logs, seismic profiles, and radiometric and earthquake data. The present Caribbean-South American plate boundary is the South Caribbean marginal fault, where subduction is indicated by folding and thrusting in the deformed belt and a seismic zone that dips 30o to the southeast and terminates 200 km below the Maracaibo Basin. The Caribbean-South American convergence rate is estimated as 1.9 +_. 0.3 cm/yr on the basis of the 390-km length of the seismic zone and a thermal equilibration time of …