Geology Commons^™

Boron Adsorption In Clay Minerals: Implications For Martian Groundwater Chemistry And Prebiotic Processes, Matthew A. Nellessen, Laura Crossey, Patrick J. Gasda, Horton Newsom, Abdulmehdi Ali, Eric J. Peterson, Nina Lanza, Adriana Reyes-Newell, Dorothea Delapp, Chris Yeager, Andrea Labouriau, Roger C. Wiens, Samuel Clegg, Shelbie Legett, Debarati Das

Earth and Planetary Sciences ETDs

Boron has been detected on Mars [Gasda et al., 2017, Das et al., 2019, 2020] within calciumsulfate veins found within clay-rich rocks on Mars by the Mars Science Laboratory (MSL) rover using Laser Induced Breakdown Spectroscopy (LIBS) analysis. Boron plays a vital role in stabilizing ribose on Earth and has been suggested as a key requirement for life [Scorei et al., 2006, 2012; Furukawa et al., 2013, 2017; Becker et al., 2019]. Additionally, boron readily adsorbs to phyllosilicate clay minerals and is often associated with biologic processes in clay soils. The discovery of boron on Mars in proximity to phyllosilicate …

Plio-Pleistocene Antarctic Ice-Ocean Interactions In The Ross Sea, Catherine Prunella

USF Tampa Graduate Theses and Dissertations

Warm, intermediate-depth Southern Ocean waters are implicated in recent Antarctic ice mass loss. Direct observations of Antarctic Ice Sheet (AIS) retreat are temporally limited, necessitating paleoceanographic records of ocean-ice interactions during past warm climate intervals. Deepsea and ice-proximal sediments record orbitally-paced glacial-interglacial fluctuations in AIS volume during the Plio-Pleistocene (last 5 million years; Ma), but the total contribution of the AIS and the role of ocean heat in these fluctuations remain unresolved. To address the response of Antarctica’s ice sheets to changing ocean temperatures during the Plio-Pleistocene, International Ocean Discovery Program (IODP) Expedition 374 recovered sediments from the Ross Sea …

Interpretations Of Lava Flow Properties From Radar Remote Sensing Data, Gavin Douglas Tolometti, Catherine Neish, Gordon R. Osinski, Scott S. Hughes, Shannon E. Kobs-Nawotniak

Earth Sciences Publications

The surface morphology and roughness of a lava flow provides insight on its lava properties and emplacement processes. This is essential information for understanding the eruption history of lava fields, and magmatic processes beneath the surface of Earth and other planetary bodies such as the Moon. The surface morphology is influenced by lava properties such as viscosity, temperature, composition, and rate of shear. In this work, we seek to understand how we can interpret the emplacement processes and lava properties of lava flows using remote sensing data. Craters of the Moon (COTM) National Monument and Preserve in Idaho hosts a …

Geochemical Characterization Of Base Metals In Stream Water And Sediments In The Caddo Lake Watershed, Cass, Harrison, And Marion Counties, Texas, Melinda S. Faulkner, Melanie L. Ertons, Joseph D. Watkins

Faculty Publications

The Caddo Lake watershed is located in northeastern Texas and encompasses much of Cass, Harrison, and Marion counties. The watershed is drained by major streams and tributaries flowing in an easterly direction over Eocene-aged rocks and sediments of the Wilcox and Claiborne groups, and empty into the western arm of Caddo Lake. Since 1995, Caddo Lake and some of its tributaries have been included on the State of Texas Clean Water Act 303(d) list by the Texas Commission on Environmental Quality (TCEQ) for impairment due to mercury content in edible tissue, depressed dissolved oxygen, base metal concentrations, and low pH …

A Geochemical And Statistical Investigation Of The Big Four Springs Region In Southern Missouri, Jordan Jasso Vega

Graduate Theses/Dissertations

The Big Four Springs region hosts four major first-order magnitude springs in southern Missouri and northern Arkansas. These springs are Big Spring (Carter County, MO), Greer Spring (Oregon County, MO), Mammoth Spring (Fulton County, AR), and Hodgson Mill Spring (Ozark County, MO). Based on historic dye traces and hydrogeological investigations, these springs drain an area of approximately 1500 square miles and collectively discharge an average of 780 million gallons of water per day. The rocks from youngest to oldest that are found in Big Four Springs region are the Cotter and Jefferson City Dolomite (Ordovician), Roubidoux Formation (Ordovician), Gasconade Dolomite …

Chemostratigraphy Of Carbonate Gravity Flows Of The Wolfcamp Formation In Crockett County, Midland Basin, Texas, Alex Blizzard, Julie Bloxson

Electronic Theses and Dissertations

Sediment gravity flows into deep-water environments are important stratigraphic traps in lithologically diverse reservoirs generating multiple plays for hydrocarbon exploration. These highly heterogeneous deposits can be studied by utilizing chemostratigraphy and higher-order sequence stratigraphy; being an accurate method for reservoir characterization. Studying these gravity flows along a carbonate platform’s slope can further expand an understanding of the stratigraphy that is filling adjacent basins. The application of elemental analyses can support in identifying mineralogy that impact reservoir quality, especially when conventional testing cannot be applied.

This study utilizes five cores containing the Wolfcamp Formation from the southeastern slope of the Central …

Geochemistry Of The Lazufre Volcanic Complex: Determining The Geometries And Processes Of The Magmatic Sources In The Central Andean Volcanic Zone, Brooke Erin Benz

Graduate Theses/Dissertations

The Central Andes in South America contain many active volcanoes and volcano complexes due to constant subduction producing extrusive rocks varying in composition. The Lazufre Complex, Chile-Argentina border, consists of two Pleistocene volcanic centers, Lastarria and Cordon del Azufre andesite and dacite lava flows and domes. Whole-rock K-Ar dates of lavas from Cordon del Azufre place the most recent eruptions at 0.6-0.3 Ma ±0.3 Ma. Major-element data of plagioclase and pyroxene show homogeneous compositions between the centers, which is consistent with whole rock major- and trace-element compositions. The primary composition of the pyroxenes are augite and diopsides for cpx and …

Pumice Compositions And Mineral Chemistry From Lascar Volcano, Chile, Madelaine M. Stearn

Graduate Theses/Dissertations

Lascar volcano is one the most active volcano in the Central Volcanic Zone of the Andean Cordillera, with 36 Holocene eruptions including a VEI 4 eruption in April 1993. Activity has not been consistent throughout time, and therefore, the processes behind it are poorly understood. Lascar volcano has cyclic behavior and has had four stages of activity, each of which had a unique eruptive style and product composition. Stage I (<43 >ka) had primarily mafic andesite lavas erupted effusively from a stratocone. Stage II initiated with dome building events ESE of the original vent and culminated in the 26.45 ka …

Geochemical Analysis And Heat-Treatment Of Natural Sapphires From Madagascar And Tanzania In Oxidizing And Reducing Conditions, Lukas Karuza, Dr. Michael B. Wolf, Brian Konecke Phd

Geology: Student Scholarship & Creative Works

Natural or synthetic sapphires can be heat-treated to improve the clarity by removing “silk” (inclusions) and to change color by introducing color-inducing elements (i.e., chromophores) into the lattice structure or changing their valency. Due to these reasons, sapphires can be heat-treated to increase their monetary value. Twenty natural blue (C1), 20 green (C2), and 20 clear (C3) sapphires from Madagascar and Tanzania were heat-treated in a muffle furnace in oxidizing and reducing conditions, from 1200 to 1600℃, for 10-hour soak time. In total, 5 experiments were conducted in which soak time remained constant: experiment 1 was performed at 1200℃, exp. …

Isotopic And Geochemical Tracers Of Groundwater Flow In The Shivwits Plateau, Grand Canyon National Park, Jonathan W. Wilson

Theses and Dissertations--Earth and Environmental Sciences

As the impacts of global climate change on water resources continue to become more apparent, proper understanding and management of groundwater resources will be needed as supplies become more strained. Traditional methods of characterizing groundwater systems are time-intensive, costly, and can be difficult to complete in remote areas. Using ambient geochemical tracers from discrete sampling could aid in characterizing spring systems through determining flow paths, recharge areas, and carbon cycling. However, using discrete seasonal samples to understand the hydrogeology of complex, mixed-lithology aquifers has not been extensively examined. Here we explore using δ¹³C of dissolved organic carbon (DOC), …

Mineral Compositions Of Meteorite Samples Alha 77005, Nwa 7397, Nwa 5480, And Ausson: Implications For Geodynamic Processes On Their Parent Bodies And Meteorite Reclassification, Kaylin Agnata Tunnell

Masters Theses

“This study investigates the major, minor, and trace element compositions of minerals from a series of meteorites which represent different stages of planetary evolution including two sample from Mars (ALHA 77005 and NWA 7397), one sample from Vesta (NWA 5480), and one ordinary chondrite (Ausson). The goal of this study is to investigate if petrogenetic tracers commonly employed to understand terrestrial samples can also be applied to extraterrestrial samples. The data presented here show that mineral trace element data allow for novel insight into the magmatic history of meteorite samples. For example, V/Sc and Fe/Mn ratios in olivine provide insight …

Applying Garnet And Zircon Ree Linkages To Determine Timing Of P-T Conditions And Tectonic Implications For Uhp Eclogites And Hp Granulites, Dulan Uhp Terrane, China, Wesley Weisberg

All Master's Theses

The Dulan ultrahigh-pressure (UHP) terrane in western China hosts rocks that record continental collision, however; the timing of peak P-T conditions in UHP eclogites and HP granulites, and the tectonic significance of their spatial relationship within the Dulan UHP terrane are not well understood. This study, (1) evaluates rare earth element (REE) equilibrium between garnet and zircon, to assess coeval growth; (2) links timing (from zircon) to the P-T history (from garnet) to constrain the P-T-t path of the Dulan UHP terrane and interpret implications for zircon growth; (3) refines P-T conditions for HP granulite; and (4) evaluates the tectonic …

Development Of A Synthesis Method For O2-Releasing Compound For Microbiological Experiments, Danae Greco

Williams Honors College, Honors Research Projects

Many celestial bodies within our solar system may have habitable environments due to the presence of liquid water. Europa, one of Jupiter’s moons, may be habitable because of its liquid ocean and other potentially biologically favorable conditions. The ocean on Europa is hypothesized to contain large amounts of oxidants and low pH due to the radiolytically processed icy ocean shell. This suspected environment on Europa is similar to the composition of acid mine drainage on Earth, which can house microbial communities in environments of extreme acidity. Similar chemical reactions in Europa’s ocean may occur to produce the appropriate reduction-oxidation gradients …

Physical And Chemical Properties Of Clastic Sediments From Two Caves In The Northern Karst Region Of Puerto Rico, Autum R. Downey

Graduate Theses, Dissertations, and Problem Reports (ETD)

Geochemical properties and organic characteristics are essential to understanding the general depositional dynamics of a cave. Most work on clastic cave sediments focuses on physical properties of sediments. Little work has been done on bulk organic matter and geochemical properties.

This project reports physical and geochemical characterization of cave sediments from two caves in the northern karst region of Puerto Rico: El Tallonal Cave and Cueva Clara. Core and grab samples were collected and analyzed for particle size, total organic carbon, total nitrogen, organic matter characteristics using fluorescence spectroscopy, and major and minor elements using X-ray fluorescence (XRF). The sediments …

Effects Of Reservoir Conditions And Trace Co-Contaminant Gases On Geological Carbon Sequestration, Ram Kumar

USF Tampa Graduate Theses and Dissertations

Geological carbon sequestration in a saline formation is a promising technology for large-scale carbon dioxide (CO2) mitigation. Several factors such as temperature, pressure, salinity, hydraulic conductivity, and mineralogy of a formation affect the CO2 sequestration in saline formations. These factors can vary widely depending upon the type of formation or the degree of heterogeneity within a formation. In addition to these properties of the repositories, the CO2-rich flue gas streams captured from point sources often contains small amounts of impurities such as sulfur oxides (SOx) and nitrogen oxides (NOx), which may have serious implications on the chemistry of the repositories …

A Metasomatized Lithospheric Mantle Control On The Metallogenic Signature Of Post-Subduction Magmatism, David A. Holwell, Marco Fiorentini, Iain Mcdonald, Yongjun Lu, Andrea Giuliani, Daniel J. Smith, Manuel Keith, Marek Locmelis

Geosciences and Geological and Petroleum Engineering Faculty Research & Creative Works

Ore deposits are loci on Earth where energy and mass flux are greatly enhanced and focussed, acting as magnifying lenses into metal transport, fractionation and concentration mechanisms through the lithosphere. Here we show that the metallogenic architecture of the lithosphere is illuminated by the geochemical signatures of metasomatised mantle rocks and post-subduction magmatic-hydrothermal mineral systems. Our data reveal that anomalously gold and tellurium rich magmatic sulfides in mantle-derived magmas emplaced in the lower crust share a common metallogenic signature with upper crustal porphyry-epithermal ore systems. We propose that a trans-lithospheric continuum exists whereby post-subduction magmas transporting metal-rich sulfide cargoes play …

The Paleozoic Sedimentary Rocks Of The Ouachita Mountains And Their Genetic Relationship To The Mississippi Valley-Type Mineralization In The Southern Ozark Region: Insights From Radiogenic Pb Isotopes And Trace Elements Studies, Christophe Wakamya Simbo

Graduate Theses and Dissertations

Cluster of Pb and/or Zn deposits of the well-known Tri-State and Northern Arkansas Mississippi Valley Type (MVT) districts located north of the Arkoma basin and the Ouachita fold-thrust belt in north America are genetically connected to the Pennsylvanian-Permian Ouachita orogeny which triggered a South-North topographic gradient flow of basinal brines, leaching metal rich sediments en route. The objective of the research is twofold. First, to ascertain whether the organic-rich shales and sandstones from the study area provided metals during the mineralization event, which was coeval with the Ouachita orogeny. Second, to assess the depositional environment of the potential source rocks, …

Evaluating Sources Of Hydrochemical Variability And Mixing In The Upper Gila River, New Mexico, Pavel Vakhlamov

Earth and Planetary Sciences ETDs

This study of the upper reaches of the Gila River basin in southwestern New Mexico reveals both spatial and seasonal patterns in physical and hydrochemical parameters. Monsoonal precipitation, temporal variability in water chemistry of streams in the upper Gila watershed is significantly impacted by surface runoff due to variability in landscape cover features, as well as surface area of the catchment. However, during base flow regimes spring inputs are the dominant drivers of solute concentrations and chemical variability.

Geothermal sources play a major role in salinization of the southwestern stream systems. Prolonged water/rock interaction combined with high temperature, pressure result …

Natural Salinization Of The Jemez River, New Mexico: An Insight From Trace Element Geochemistry, Jon K. Golla

Earth and Planetary Sciences ETDs

The Jemez River, a tributary of the Rio Grande in north-central New Mexico, receives thermal water input from the geofluids of the Valles Caldera, an active, high-temperature, liquid-dominated geothermal system. We focus on a ∼50-km portion of the northern Jemez River. This research extends previous decadal work (Crossey et al., in prep., 2013) on major chemistry in the river by characterizing the response of 16 trace elements to geochemical contributions from geothermal waters (McCauley, Spence, Soda Dam, and Jemez Springs springs and San Ysidro mineral waters), an area with copious hydrothermal degassing (Hummingbird), and two major tributaries (Rio San Antonio …

Extreme Oxygen Isotope Zoning In Garnet And Zircon From A Metachert Block In Melange Reveals Metasomatism At The Peak Of Subduction Metamorphism, F. Zeb Page, Emilia M. Cameron, Clara Margaret Flood, Jeffrey W. Dobbins, Michael J. Spicuzza, Kouki Kitajima, Ariel Strickland, Takayuki Ushikubo, Christopher G. Mattinson, John W. Valley

Faculty & Staff Scholarship

A tectonic block of garnet quartzite in the amphibolite-facies melange of the Catalina Schist (Santa Catalina Island, California, USA) records the metasomatic pre-treatment of high-delta O-18 sediments as they enter the subduction zone. The block is primarily quartz, but contains two generations of garnet that record extreme oxygen isotope disequilibrium and inverse fractionations between garnet cores and matrix quartz. Rare millimeter-scale garnet crystals record prograde cation zoning patterns, whereas more abundant similar to 200-mu m-diameter crystals have the same composition as rims on the larger garnets. Garnets of both generations have high-delta O-18 cores (20.8 parts per thousand-26.3 parts per …

Geochemical Analysis Of The Chinchín Formation In Southern Ecuador, Katherine Ludwig

Celebration of Learning

The subduction of the Nazca Plate under the South American Plate has led to the uplift of the majority of the Andes Mountains, but in Ecuador, the Nazca Plate subducts underneath the North Andes Plate, which then collides with the South American Plate. This tectonic setting has formed two parallel mountain chains as well as a complex series of basins between them. However, the formations that make up these basins are poorly understood. This study focuses on the Chinchín Formation, an ~3.5 km thick, volcanic formation that serves as the bedrock of the Quingeo Basin in southern Ecuador. This study …

Petrogenesis Of The El Rechuelos Rhyolite, Jemez Mountains Volcanic Field, New Mexico, Usa, Kelsy Jo Konkright

UNLV Theses, Dissertations, Professional Papers, and Capstones

The El Rechuelos Rhyolite represents volcanic activity preceding the multiple caldera collapse events of the Jemez Mountains volcanic field (JMVF) in northern New Mexico. This study focuses on seven rhyolitic units clustered north of the Valles caldera. These units have been studied in order to interpret their relationships to one another and the eruptive history of the JMVF. Additionally, this study adds to the research on the relationships between effusive and explosive rhyolitic volcanism, and understanding how caldera-forming eruptions develop from silicic systems.

Limited previous research includes K/Ar dates and a few inconsistent 40Ar/39Ar dates, in addition to whole rock …

Structural Control Of Thermal Fluid Circulation And Geochemistry In A Flat-Slab Subduction Zone, Peru, Brandt E. Scott

All Graduate Theses and Dissertations, Spring 1920 to Summer 2023

Hot spring geochemistry from the Peruvian Andes provide insight on how faults, or fractures in the Earth's crust, are capable of influencing fluid circulation. Faults can either promote or inhibit fluid flow and the goal of this study is test the role of a major fault, such as the Cordillera Blanca detachment, as a channel for transporting deep fluids to the surface. Hot springs are abundant in the Cordillera Blanca and Huayhuash ranges in Peru, and several springs issue along the Cordillera Blanca detachment, making this region an ideal setting for our study. To test the role of the Cordillera …

Variability In Groundwater Flow And Chemistry In The Houzhai Karst Basin, Guizhou Province, China, Joshua M. Barna

Theses and Dissertations--Earth and Environmental Sciences

Understanding how karst aquifers store and transmit water and contaminants is an ongoing problem in hydrogeology. Flowpath and recharge heterogeneity contribute to the complexity of these systems. This thesis explores karst-conduit connectivity and water chemistry variability in the Houzhai catchment in Guizhou province, China. Artificial tracer tests were conducted during both the monsoon and dry seasons to understand temporal variability in connectivity and water velocity between karst features. Multiple flowpaths through the catchment are activated during the monsoon season and partially abandoned during the dry season. Additionally, gradient reversals during monsoonal high-flow events and as a result of pumping can …

The Medicine Hat Block And The Assembly Of Laurentia: New Interpretations From Single-Grain Zircon Analyses, Blake Oswell Ladouceur

Electronic Theses and Dissertations

The Medicine Hat Block (MHB) is one of the core cratonic elements that amalgamated in the Paleoproterozoic to form Laurentia. However the role of the MHB in the formation of Laurentia is poorly constrained due to virtually all of the MHB being concealed by Proterozoic and younger supracrustal sequences limiting availability of data. The primary sources of samples from the MHB are 1) xenoliths of variable metamorphic grade including gneisses amphibolites and meta-plutonic rocks collected from Eocene volcanic rock; and 2) similar lithologies recovered from boreholes that penetrate to the MHB basement. Previous work on samples from the MHB yielded …

Precipitation And Transformation Of Iron-Sulfide Nanoparticles In Low-Temperature Aqueous Environment: Effects Of Reactant Iron And Sulfide Sources, Ezequiel A. Moreno Flores

Open Access Theses & Dissertations

Iron sulfide nanoparticles assume an important role within a wide range of geological settings as indicators of redox environmental conditions and elemental cycling mechanisms. Initial precipitates of iron sulfide are exclusively nanoscale sized in low temperature aqueous conditions and have been reported to go through diverse morphological and phase transformations, possibly leading to the ultimate deposits of pyrite in geologic records of various times. A systematic understanding of how the early-stage nanoparticles of iron sulfide may develop into more crystalline iron sulfide forms is still lacking however. The major goal for this study was to illuminate the effects of the …

Mercury In Big Cypress Bayou And Caddo Lake Watersheds In Marion And Harrison Counties Texas, Joseph Watkins

Electronic Theses and Dissertations

Caddo Lake has been included on the Texas Commission on Environmental Quality 303(d) list for impairment due to mercury (Hg) content since 1996. One of the primary tributaries, Big Cypress Bayou, flows across Eocene-aged rocks and sediments associated with the Wilcox Group; the Wilcox is of interest because it contains lignite coal, which has a direct link to mercury. Previous research has focused on dry deposition from fossil fuel combustion as the primary source of mercury but has not addressed the potential watershed contribution to mercury concentrations in Caddo Lake.

Big Cypress Bayou flows through Harrison and Marion counties in …

Unroofing History Of The Northwestern Ethiopian Plateau: Insights From Low-Temperature Apatite Thermochronology, Shelby Bowden

Masters Theses & Specialist Projects

The geology of Ethiopia is dominated by the Ethiopian Plateau that is similar in elevation to, but aerially larger than, the Colorado Plateau. Several rivers have incised through the plateau, creating gorges that reach up to 1.5 km in depth. The plateau uplifted to its current elevation and was subsequently incised sometime after the Oligocene flood basalt event that signaled the arrival of the African Superplume below Kenya and Ethiopia. Due to its size and extent, published climate modeling has indicated that Late Cenozoic plateau formation could have been a driving force in the East African Cenozoic climate changes. Although …

Chemical And Statistical Analysis Of Karst Groundwater Basin Signatures - Springfield, Mo, Benjamin E. Lockwood

Graduate Theses/Dissertations

Springfield, MO is located on the Springfield Plateau physiographic province. The Springfield plateau contains a number of Mississippian aged units and is mainly capped by the Burlington-Keokuk Formation. The Burlington-Keokuk is a highly fossiliferous limestone with nodular and interbedded chert. Beneath the Burlington-Keokuk lies the Elsey, Reeds Spring, and Pierson Formations respectively which comprise the Springfield Plateau aquifer hydrostratigraphic unit. Within the Springfield Plateau aquifer, a well-developed karst system includes springs, sinkholes, and caves. The Springfield Plateau aquifer is the predominant source for springs and seeps in the Springfield area. The purpose of this study was to understand the differences …

Understanding The Late Mesoproterozoic Earth System From The Oldest Strata In Grand Canyon: C-Isotope Stratigraphy And Facies Analysis Of The 1254 Ma Bass Formation, Grand Canyon Supergroup, Az., Usa, Erin C. Lathrop

All Graduate Theses and Dissertations, Spring 1920 to Summer 2023

Rocks provide insight into ancient times before complex animals existed. The oldest sedimentary rocks in Grand Canyon (the Bass Formation) allow us to glimpse into what things might have been like over a billion years ago. These rocks record the time known as the Mesoproterozoic Era (1.6 to 1.0 billion years ago), otherwise known as the ‘boring billion’. These rocks are thought to be the right age to indicate the end of an oddly stable world when continents were quiet and life was calm, yet they predate younger rocks that record extreme events. The Bass Formation, some of the only …