Geology Commons^™

Rhyolite And Trachyte Formation At Lake City Caldera: Insight From Quantitative Textural And Geochemical Analyses, Jordan Lubbers

Dissertations, Master's Theses and Master's Reports

Lake City Caldera (22.93 ± 0.02 Ma) is the youngest of 15 Tertiary calderas found within the Southern Rocky Mountain Volcanic Field (SRMVF). Extreme topographical relief of the area reveals the three dimensional exposure of a complex, high-k calc-alkaline, magmatic system, which provides us with the opportunity to study, in detail, how large silicic magmas evolve in the subsurface. The Lake City igneous system is comprised of two major units: a resurgent syenite intrusion and the Sunshine Peak Tuff (Lower, Middle, and Upper). Bulk-rock analyses indicate that the Lower and Middle Sunshine Peak tuff are crystal poor and rhyolitic in …

Geochemical Evidence For Seasonal Controls On The Transportation Of Holocene Loess, Matanuska Valley, Southern Alaska, Usa, Daniel R. Muhs, James R. Budahn, Gary Skipp, John P. Mcgeehin

United States Geological Survey: Staff Publications

Loess is a widespread Quaternary deposit in Alaska and loess accretion occurs today in some regions, such as the Matanuska Valley. The source of loess in the Matanuska Valley has been debated for more than seven decades, with the Knik River and the Matanuska River, both to the east, being the leading candidates and the Susitna River, to the west, as a less favorable source. We report here new stratigraphic, mineralogic, and geochemical data that test the competing hypotheses of these river sources. Loess thickness data are consistent with previous studies that show that a source or sources lay to …

Geochemistry Of Upper Cretaceous Sediments Of Bozeş Formation (Apuseni Mts., Romania) – Provenance Implications, Luminiţa Zaharia, Romona Bălc, Cosmin C. Stremţan, Adriana Socaciu

School of Geosciences Faculty and Staff Publications

A whole-rock geochemical study was carried out on sandstones from the Upper Cretaceous Bozeş Formation in the southeastern part of the Apuseni Mountains (Romania) in order to constrain their provenance and depositional setting. The geochemical results were compared and integrated with previously reported provenance indicators, such as framework composition and heavy mineral assemblages. The chemical composition is similar for all samples investigated, with limited ranges for both major oxides and trace elements. The sandstones are potassic (Na₂O/K₂O < 1) and can be classified mainly as arenites with a few greywackes. Their immature to relatively mature character is revealed by the SiO₂/Al₂O₃ ratios, ranging between 3.90 and 11.25, as well as their high Sr/Rb ratios. The …

Metal Mobilization In Groundwater, Bauxite, Ar, Steven Alexander Hamlin

Graduate Theses and Dissertations

The Wilcox Aquifer of Bauxite, AR contains bauxite ore deposits that may contribute heavy metals to groundwater. Twenty-four wells were sampled for aluminum, iron, manganese, zinc, lead, barium, nitrate, sulfate, sodium, alkalinity, calcium, magnesium, chloride, pH, total organic carbon, and total dissolved solids. A Wilcoxon Rank-Sum compared the similarity of the three geographic areas covered in the study. All parameters for wells in Bauxite and Sardis failed to reject the null hypothesis, signifying that wells all occupy the Saline Formation. 2/3rds of the parameters from BFI261 and the Bauxite region did not agree, suggesting the two areas do not occupy …

Nwa 8614: The Least Heated Winonaite, Karla Farley, Alexander M. Ruzicka, Katherine Armstrong

Student Research Symposium

Northwest Africa 8614 is classified as a winonaite on the basis of oxygen isotope ratios, mineralogy, and highly reduced chemistry. Unlike other winonaites, it contains numerous and readily apparent chondrules. Here we discuss various features of NWA 8614 and the possible significance of the meteorite.

Petrological and chemical analyses were performed using optical microscopy with a DM2500 Leica petrographic microscope and a Zeiss Sigma VP-FEG scanning electron microscope (SEM) with a high-efficiency energy dispersive spectrometer (EDS). Oxygen isotopes were analyzed by Karen Ziegler at the University of New Mexico on acid-washed samples to remove terrestrial weathering products.

Owing to the …

Geochemical Analysis Of Surface Materials Surrounding The Bautsch-Gray Mine Superfund Site Near Galena, Illinois, Ryan Plath

Geology: Student Scholarship & Creative Works

The Bautsch-Gray zinc and lead mine, near Galena, IL, was in operation from the early 1900s until closing in 1975. The mine’s tailings pile has documented elevated lead and zinc concentrations in the surface materials surrounding the site. Numerous floods have caused contaminated sediment to migrate off the mine tailings pile, across Blackjack Road and into an outwash basin, and towards Smallpox Creek. Since this site was designated an EPA priority list Superfund site in 2010, the EPA has conducted numerous remediation efforts. This study attempts to develop a better understanding of the contamination within the soils of the outwash …

Sequence Stratigraphy, Depositional Environments And Geochemistry Of The Middle Cambrian Bloomington Formation In Northern Utah, Christopher Ryan Jensen

All Graduate Theses and Dissertations, Spring 1920 to Summer 2023

The Bloomington Formation (~425 m thick) is a latest Middle Cambrian (~506.5-505 Ma.), mixed warm water, carbonate and shale unit on the Cordilleran passive margin in northern Utah and southern Idaho. The Hodges Shale and Calls Fort Shale Members are shale dominated and the Middle Limestone Member is a thick carbonate. Fossil diversity and abundance is surprisingly low for a Middle Cambrian carbonate/shale formation. Present, however, are 10-50 cm thrombolite mud mounds, associated with Girvanella oncoliths. These mud mounds represent shallow water carbonates that experienced a small flooding event that gives the mud mounds time and proper conditions to build …

Modeling Background Radiation Using Geochemical Data, Kara Marsac

UNLV Theses, Dissertations, Professional Papers, and Capstones

Aerial gamma ray surveys have many applications in geology and science in general, such as locating mining prospects, defining radioactive plumes, and detecting nuclear weapons. Unfortunately there is currently no simple way to separate the natural gamma radiation of soil and rocks from that of contaminants such as radioactive plumes. This project used geochemical data (uranium, potassium and thorium concentrations) collected from national databases, private companies, and the NURE (National Uranium Resource Evaluation) Survey, to create forward models of exposure rates measured by aerial gamma ray surveys. We developed these techniques using an area in north central Arizona known as …

Composition, Alteration, And Texture Of Fault-Related Rocks From Safod Core And Surface Outcrop Analogs: Evidence For Deformation Processes And Fluid-Rock Interactions, Kelly Keighley Bradbury, Colter R. Davis, John W. Shervais, Susanne U. Janecke, James P. Evans

Geosciences Faculty Publications

We examine the fine-scale variations in mineralogical composition, geochemical alteration, and texture of the fault-related rocks from the Phase 3 whole-rock core sampled between 3,187.4 and 3,301.4 m measured depth within the San Andreas Fault Observatory at Depth (SAFOD) borehole near Parkfield, California. This work provides insight into the physical and chemical properties, structural architecture, and fluid-rock interactions associated with the actively deforming traces of the San Andreas Fault zone at depth. Exhumed outcrops within the SAF system comprised of serpentinite-bearing protolith are examined for comparison at San Simeon, Goat Rock State Park, and Nelson Creek, California. In the Phase …

Carbon Cycling Dynamics Inferred From Carbon Isotope Sourcing In A Mid-Latitude Karst-Influenced River, Kegan N. Mcclanahan

Masters Theses & Specialist Projects

As ever-increasing levels of carbon dioxide alter the chemistry of the Earth’s atmosphere, understanding the global carbon cycle becomes increasingly important. A particularly important component is the riverine carbon cycle, as rivers are the primary conduits for dissolved inorganic carbon from terrestrial watersheds to ocean basins. Stable carbon isotopes (13C/12C) were collected weekly and input into the mixing model IsoSource to delineate seasonal carbon sourcing along two nested basins in the upper Green River System, Kentucky. In the more siliciclastic upstream catchment, dissolved inorganic carbon (DIC) was primarily derived from soil respiration (34%). Groundwater dissolving carbonate bedrock and carbonate dissolution/precipitation …

Geochemistry And Stable Isotopes Of Surface Water And Groundwater In The Continental Pit In Butte, Montana, Usa, Amber Mcgivern

Graduate Theses & Non-Theses

The Continental porphyry Cu‐Mo mine, located 2 km east of the famous Berkeley Pit lake of Butte, Montana, contains two small lakes that vary in size depending on mining activity. In contrast to the acidic Berkeley Pit lake, the Continental Pit waters have near-neutral pH and relatively low metal concentrations. The main reason is geological: whereas the Berkeley Pit mined highly‐altered granite rich in pyrite with no neutralizing potential, the Continental Pit is mining weakly‐altered granite with lower pyrite concentrations and up to 1‐2% hydrothermal calcite. The purpose of this study was to gather and interpret information that bears on …

Contact Zone Mineralogy And Geochemistry Of The Mt. Mica Pegmatite, Oxford County, Maine, Kimberly T. Clark

LSU New Orleans Theses and Dissertations

This study focuses on exocontact mineral assemblages to determine composition, thermal signatures, and the extent of exomorphism that occurred between the Mt. Mica pegmatite and the migmatite host rock at the contact. Biotite-garnet thermometry of country rock samples resulted in an average temperature estimate of 630 °C. Measured biotite Fe/(Fe+Mg) ratios were used to calculate an fO2 of -18. The results indicate that the country rock and pegmatite formed under similar oxidizing conditions near the quartz-fayalite-magnetite (QFM) equilibria buffer. Whole rock (REE) analysis indicates an interaction trend between the country rock and pegmatite. Exomorphism does not appear to have …

Linking Instrumental Neutron Activation Analysis (Inaa) With Geology In The Ancestral Caddo Region, Robert Z. Selden Jr.

CRHR: Archaeology

This poster illustrates the success of a novel method of INAA that was employed to reveal geochemical signatures in Caddo ceramic vessel sherds that correlate with local surficial geology. The geochemical data from the sherd assemblage were used within an exploration of potential ceramic provenance, which was successful at demarcating sherds from ceramic vessels made from clays in either the Claiborne or Wilcox Groups. Further geochemical segregation was also apparent between the Recklaw Formation in the Claiborne Group, and the Weches Formation in the Wilcox Group. These results point to a high degree of geochemical variability within the East Texas …

At The Confluence Of Gis And Geochemistry: Identifying Geochemical Correlates Of Ripley Engraved Caddo Ceramics, Robert Z. Selden Jr., Timothy K. Perttula

CRHR: Archaeology

In this poster, we discuss a new approach to the identification and definition of spatial trends in archeologically-recovered ceramics associated with geochemical results produced using instrumental neutron activation analysis (INAA). Using all of the Ripley Engraved INAA samples, we posit that clays in the Claiborne and Wilcox Groups can be successfully demarcated by sodium (Na), cerium (Ce), and zinc (Zn). Using a subset of those data from the Big Cypress Creek basin, we find that ceramics manufactured in three different Caddo political communities can be successfully demarcated based upon differential concentrations of arsenic (As), iron (Fe), and vanadium (V) found …

Sources Of Co2 Controlling The Carbonate Chemistry Of The Logsdon River, Mammoth Cave, Kentucky, Bruce Elliott Hatcher

Masters Theses & Specialist Projects

Logsdon River is a major, base-level stream within the Turnhole Bend Drainage basin of the Mammoth Cave System. The Logsdon River system has provided a unique opportunity to examine the geochemical evolution of a stream flowing through a major karst conduit that can be traversed for 10 km. This study examines CO₂ inputs at the upstream portion of the river, which provide major control for the river’s hydrochemistry. Samples were collected from the upstream portion of Logsdon River at what is referred to as the S-188 sump and also nearby at Crowbar Dome over the course of 44 weeks …

Late Holocene Paleoenvironmental Reconstruction In Barbados, Gilman Reno Ouellette

Masters Theses & Specialist Projects

Barbados is the easternmost island in the Caribbean region, and is uniquely situated between the Atlantic Ocean and Caribbean Sea. Being an isolated island with a karstified aquifer providing the majority of the nation’s water resources, Barbados has found itself in water scarce situations in recent years. In order to better understand natural shifts in groundwater recharge (which is determined by shifts in precipitation), longer records of precipitation are needed than are available from modern measurements. This study presents a paleoclimate reconstruction for the late Holocene on Barbados using stable and radiogenic isotope ratios in speleothem lamina as proxies. In …

Cyclic Distributional Model Of The Late Moscovian Fusulinids In The Donets Basin (Ukraine) In Response To Eustatic Sea Level Fluctuations And Its Application In Biostratigraphy And Correlation, Rimma Khodjanyazova

Boise State University Theses and Dissertations

The continuous Pennsylvanian shallow-marine, paralic, siliciclastic succession in the Donets Basin is pivotal for correlation of marine and continental strata in northern Pangaea with coeval shallow-marine mainly carbonate strata in the Moscow Basin, a historical type area of Moscovian Horizons. The details of the history of establishment, lithostratigraphy and current biostratigraphy of Podolskian and Myachkovian Horizons in the Moscow Basin that are not readily available in Western literature are reviewed.

A model of cyclic recurrence (~0.6 —1myr) of three main fusulinid assemblages in the Pennsylvanian siliciclastic-carbonate succession in the Donets Basin is proposed. A Hemifusulina-association (A) indicates the onset …

Assessment And Conceptualization Of Groundwater Flow In The Edwards Aquifer Through The Knippa Gap In Uvalde County, Texas, Jennifer Raye Adkins

Graduate Theses and Dissertations

The Edwards aquifer is one of the major regional karst aquifers in the United States, with an average withdrawal of 950 million liters per day (L/d). This investigation focuses on the connection between the Uvalde pool and the San Antonio pool of the Edwards aquifer, known as the Knippa Gap, west of the San Antonio metropolitan area in Uvalde County. This is a major zone of recharge to the Edwards aquifer and is approximately 6.4 km wide. The Knippa Gap is bounded by northeast trending faults of the Balcones Fault Zone (BFZ) on the north (specifically the Cooks and Trio …

Alluvial Sediment Or Playas: What Is The Dominant Source Of Sand And Silt In Desert Soil Vesicular A Horizons, Southwest Usa, Mark R. Sweeney, Eric V. Mcdonald, Christohper E. Markley

All Faculty Scholarship for the College of the Sciences

Vesicular A (Av) soil horizons form beneath desert pavements from the accretion of aeolian sediment (dust) commonly thought to be derived primarily from desiccating pluvial lakes and playas, with contributions from ephemeral washes and alluvial fans. Particle size distributions of Av horizons are typically bimodal with primary modes of very fine silt and fine sand, suggesting that the horizon matrix is derived from multiple sources. Here we conduct detailed chemical and physical analysis of both Av horizon soil samples and potential sources of aeolian sediment to better constrain the relative contributions of dust associated with the development of Av horizons. …

Epistemology And Synthesis: Instrumental Neutron Activation Analysis And The Caddo Tradition, Robert Z. Selden Jr.

CRHR: Archaeology

The statistical groupings illustrated herein represent the current iteration of Caddo INAA compositional groups based upon the chemical composition of archaeologically-recovered ceramics. For some time, a number of Caddo archaeologists have thought these results to be lacking. This poster symbolizes the first step toward a new interpretation of chemical composition groups, and the initial instancce within which GIS has been employed as an analytical tool.

Geochemical Source Components In Seafloor Lavas In The Aleutian Back-Arc, Max Thomas Siegrist

Theses and Dissertations

Whole-rock compositions of seafloor lavas are used to constrain the processes and source characteristics contributing to the formation of geochemically distinctive, primitive magma types located in the Aleutian back-arc. Samples were dredged primarily from small volcanic cones on the seafloor, located between the emergent volcanoes and in the back-arc up to 60 km from the volcanic front. Compositions vary from basalt to dacite, with 48-70 % SiO₂ and 4-13 % MgO. Nearly 30% of the samples are primitive, with Mg/Mg+Fe >0.60. Most primitive samples are basalts, which fall into two groups, based on minor and trace element abundances. Low/med-K …

Salt Lakes Of The African Rift System: A Valuable Research Opportunity For Insight Into Nature’S Concenrtated Multi-Electrolyte Science, Jyn Philip, Dms Mosha

Tanzania Journal of Science

The Tanzanian rift system salt lakes present significant cultural, ecological, recreational and economical values. Beyond the wealth of minerals, resources of these rift salt lakes include unique wildlife, for instance Lesser Flamingo (Phoenicopterus minor) and Cichlids (Alcolapia spp), which adapted chemically aggressive environments like that of Lake Natron. The general hydrochemical equilibria of these salt lakes is governed by Na+ > K+ >> Ca2+ ~ Mg2+ : (CO32- + HCO3-) > Cl- > SO42-~ F- ionic concentration pattern. Salt accumulation mechanism in these endorheic lakes is considered to base on thermo-mechanical disintegrative stress of the geochemistry sourcing. The rains chemically interact with rift terrains, …

Petrogenesis Of The East Fork Member Rhyolites, Valles Caldera, New Mexico, Usa, Carla Eichler

UNLV Theses, Dissertations, Professional Papers, and Capstones

The most recent volcanism in the Valles caldera is represented by the El Cajete Pyroclastic Beds (ECPB), Battleship Rock Ignimbrite (BRI), and Banco Bonito Flow (BBF) as well as the VC-1 rhyolite, which are collectively known as the East Fork Member (EFM) of the Valles Rhyolite. The EFM was erupted at approximately 55 ka and 40 ka after an approximate 460 ka lull in volcanism. Previous studies suggested a mafic intrusion at depth triggered the eruptions. This thesis represents the first detailed study of the EFM.

Crystal assemblages consist of plagioclase, biotite, clinopyroxene, orthopyroxene, amphibole, sanidine, quartz, and oxides. Electron …

Volcanic Evolution Of The Southern Quinn Canyon Range: Implications For Regional Correlation Of Volcanic Units, Christina Emery

UNLV Theses, Dissertations, Professional Papers, and Capstones

The southern Quinn Canyon Range lies in an area of the Great Basin subjected to large-volume Oligocene-Miocene silicic volcanism and smaller volume basaltic volcanism during the Pliocene. Three major ash-flow tuff units were correlated in the southern Quinn Canyon Range (the Pahranagat Tuff, Clifford Spring Tuff, and the Cow Canyon Tuff) with regional units by utilizing U/Pb and 40 Ar/ 39Ar geochronology, geochemical correlation, and field mapping. Isotopic analysis suggests that basalt in the southern Quinn Canyon Range is part of the Death Valley-Pancake Range Basalt Zone and is similar to Reveille Range Episode 1 and 2 basalts. Further comparison …

Geochemical And 40ar/39ar Constraints On The Evolution Of Volcanism In The Woodlark Rift, Papua New Guinea, Joseph Paul Catalano

Earth & Environmental Sciences - Theses

The tectonic mechanisms producing Pliocene to active volcanism in eastern Papua New Guinea (PNG) have been debated for decades . In order to assess mechanisms that produce volcanism in the Woodlark Rift, we evaluate the evolution of volcanism in eastern PNG using 40Ar/39Ar thermochronology and whole rock geochemistry.

Active volcanism in southeastern Papua New Guinea occurs on the Papuan Peninsula (Mt. Lamington, Mt. Victory and Waiwa), in the Woodlark Rift (Dobu Island, SE Goodenough Island, and Western Fergusson Island), and in the Woodlark Basin . In the Woodlark Basin, seafloor spreading is active and decompression melting of the upper mantle …

Investigating The Utility Of Detrital Mineral Microchemistry And Radiogenic Isotope Compositions As Provenance Discriminators, Jack Hietpas

Earth & Environmental Sciences - Dissertations

The provenance of clastic sediments remains one of the key tools for understanding the complex dynamic history of the Earth. Detritus shed from ancient orogens may be the only evidence available for determining the timing, evolution, paleogeography, and existence of tectonic events active over the 4.56 Ga of Earth history. The focus of this dissertation research is to assess the strengths and limitations of existing, as well as novel, tools for determining the provenance of siliciclastic sediments.

The utility of detrital monazite crystallization ages was investigated as a provenance indicator in both modern and ancient sedimentary systems. The results from …

The Behavior Of Zircon During Partial Melting In Anatectic Migmatites: Insights To Metamorphism, Deformation And Tectonism In The Central Santa Fe Range, Northern New Mexico, Michelle Renee Stropky

UNLV Theses, Dissertations, Professional Papers, and Capstones

Three lithologic assemblages exposed in the central Santa Fe Range, northern New Mexico include (1) a septum of Proterozoic low temperature (~700oC, 5.5 kbars), semi-pelitic anatectic migmatites surrounded by (2) deformed megacrystic biotite granite that is intruded by (3) discrete plutons of largely undeformed hornblende biotite tonalite. Metamorphic fabrics in the migmatite record three deformation events (D1 - D3); a composite S1/S2 fabric (D1 and D2) that formed contemporaneous with anatexis and is folded about a southwest plunging map-scale (D3) antiform. The megacrystic granite exhibits a pervasive S1 subsolidus foliation that parallels the S1/S2 fabric in the migmatite and is …

Deciphering The Evolution Of Ore Fluids At The Batu Hijau Copper-~Gold Porphyry Deposit, Sumbawa, Indonesia, Jordan Thomas Armstrong

UNLV Theses, Dissertations, Professional Papers, and Capstones

Fluid inclusions contained within quartz veins from the Batu Hijau Cu-Au porphyry deposit in Indonesia were analyzed to track the evolution of fluid temperature, pressure, and composition during the formation of the deposit to better understand the formation of this and other Cu-Au porphyry deposits in order aid future exploration. A combination of petrography, microthermometry, synchrotron x-ray fluorescence, and laser ablation-inductively coupled plasma-mass spectrometry were used to determine the temperature, pressure, and compositional aspects of the deposit.

Four types of fluid inclusions were recognized at Batu Hijau based on the volume percent of the vapor bubble; inclusions were classified as …

Isotope Geochemistry And Geochronology Of Lavas From The Line Islands Chain, Central Pacific Basin: Insight Into The Origin Of The Line Islands, Lauren Storm

Open Access Theses & Dissertations

Geochemical compositions of melts produced in the Earth's mantle provide key data for understanding Earth's internal structure. Particularly, the compositions of unusually large outpourings of basaltic lavas in large igneous provinces involve substantial source volumes, thereby contributing to our understanding of mantle structure and dynamics. Although the origin of such lavas remains enigmatic, geochemically they may originate from Earth's oldest and deepest mantle reservoir, transported by a mantle plume or by entrainment in passive upwelling beneath a fast spreading center. The Pacific Ocean basin hosts several large igneous provinces that formed near a triple junction of three oceanic plates, and …

The Formation History Of Layered Chondrules In Acfer-139 (Cr2), Matt Downen

Mahurin Honors College Capstone Experience/Thesis Projects

Chondrules are spherical grains made of silicates and metal that represent some of the oldest materials our solar system. Acfer-139 (CR) is a carbonaceous chondrite with large multilayered chondrules. The multilayered chondrules are composed of a silicate core surrounded by alternating layers of silicates and metals. Serial sectioning was used to analyze the sample in three dimensions. EMPA and LA-ICP-MS were used to create elemental maps of Acfer-139 (CR2) and determine the geochemistry of different layers in each thick section cut. XRCMT was used to construct a 3-D model of a large multilayered chondrule named Ch-1 with concentric layers of …