Geology Commons^™

Oxidation Of Dibenzothiophene To Dibenzothiophene Using Metal Nanoparticles Supported On Silica, Karina Castillo

Open Access Theses & Dissertations

Silica and nanoparticles of Pt, Au, and Ag supported on silica were tested for the ability to oxidize dibenzothiophene (DBT) to sulfone. High performance liquid chromatography was used to study the removal of DBT from solution. In addition, X- ray diffraction, infrared spectroscopy and Raman Spectroscopy were used to characterize the product of the oxidation reaction. Further studies involved the use X-ray absorption spectroscopy to characterize the nanoparticle catalysts before and after the oxidation reaction.

To better understand the reaction, silica was synthesized at different pHs using three different acids. The acids used to synthesize the silica were HCl, HNO3, …

Controlling Features And Processes For Radionuclide Release From Unsaturated Zone Geological Repositories, Lubna K. Hamdan

Open Access Theses & Dissertations

In the long run, nuclear waste packages will fail gradually due to localized and general corrosion and radionuclides will be transported to the accessible environment by ground water.

Two main failure scenarios are expected for the waste packages: Flow-through model and bathtub model; in the flow-through model water flows through the waste container, while in the bathtub model water pools inside the waste package. The Department of Energy, in their performance assessment of the proposed repository at Yucca Mountain, excluded the bathtub model from their analysis and assumed the diffusion and advection to be in the same direction in the …

Application Of Copper And Zinc Isotopes To Fingerprint Metal Sources And Identify Attenuation Mechanisms In The Abandoned Waldorf Mine Area, Clear Creek County, Colorado, Suzan Aranda Luna

Open Access Theses & Dissertations

Acid rock drainage (ARD) is caused by the oxidative weathering of sulfide minerals. Sulfur is oxidized by dissolved oxygen or Fe(III) and sulfate ions, metals, and protons are released into the environment. Hence, the pH of nearby water and soils often decreases in response to ARD while metal concentrations increase. Because a large part of the Rocky Mountains of Colorado are highly mineralized (i.e., the Colorado Mineral Belt), ARD is a serious problem in this region. Moreover, the many abandoned mining areas in the Rocky Mountains that include waste rock piles, tailings impoundments, and surface disturbances add to the problem …

Investigations Of Grade Control, Macarthur Mine, Yerington, Nevada: An Oxidized Porphyry Copper System, Joseph Daniel Louis Lori

Open Access Theses & Dissertations

Supergene enriched, low-grade oxidized porphyry copper deposits are of great economic value. Oxidized porphyry sections are economic targets because even low-grade prospects have the potential to produce low-cost copper in an environmentally friendly fashion due to easy leachability and high recovery rates of the oxide mineralization. The MacArthur Mine, in the historic Yerington mining district of Nevada, is the focus of this study. The MacArthur is a tilted oxidized porphyry deposit, partially mined by open pit methods, hosted in the Jurassic Bear Quartz Monzonite of the Yerington batholith. The objective of the study is to define controls of copper oxide …

Results Of New Petrologic And Remote Sensing Studies In The Big Bend Region, Stevan Christian Benker

Open Access Theses & Dissertations

The initial section of this manuscript involves the South Rim Formation, a series of 32.2-32 Ma comenditic quartz trachytic-rhyolitic volcanics and associated intrusives, erupted and was emplaced in Big Bend National Park, Texas. Magmatic parameters have only been interpreted for one of the two diverse petrogenetic suites comprising this formation. Here, new mineralogic data for the South Rim Formation rocks are presented. Magmatic parameters interpreted from these data assist in deciphering lithospheric characteristics during the mid-Tertiary.

Results indicate low temperatures (< 750 °C), reduced conditions (generally below the FMQ buffer), and low pressures (≤ 100 MPa) associated with South Rim Formation magmatism with slight conditional differences between the two suites. Newly discovered fayalite microphenocrysts allowed determination of oxygen fugacity values (between -0.14 and -0.25 ΔFMQ over temperature ranges of 680-700 °C), via mineral equilibria based QUILF95 calculations, for Emory Peak Suite.

Petrologic information is correlated with structural evidence from Trans-Pecos Texas and adjacent regions to evaluate debated timing of tectonic …

Characterizing The Deformation Of Reservoirs Using Interferometry, Gravity, And Seismic Analyses, Cara Schiek

Open Access Theses & Dissertations

In this Dissertation, I characterize how reservoirs deform using surface and subsurface techniques. The surface technique I employ is radar interferometry, also known as InSAR (Interferometric Synthetic Aperture Radar). The subsurface analyses I explore include gravity modeling and seismic techniques consisting of determining earthquake locations from a small-temporary seismic network of six seismometers. These techniques were used in two different projects to determine how reservoirs deform in the subsurface and how this deformation relates to its remotely sensed surface deformation.

The first project uses InSAR to determine land subsidence in the Mimbres basin near Deming, NM. The land subsidence measurements …

Suswa Volcano, Kenya Rift: Evidence Of Magma Mixing, Na-F Complexing And Eruptions Triggered By Recharge, Vanessa Veronica Espejel Garcia

Open Access Theses & Dissertations

The Cenozoic East African rift system (EARS) is a sequence of grabens, intraplate transforms, accommodation zones, and abundant magmatism. The Central Kenya Peralkaline Province (CKPP) includes a variety of volcanic rocks -trachyte, pantellerite, comendite, phonolite, trachy-basalt, basaltic trachy-andesite, and basalt- which erupted from volcanoes including: Mount Kenya; Eburru and the Greater Olkaria volcanic complexes; Longonot, Menengai, and Suswa volcanoes; and Ndabibi, Elmenteita, and Tandamara mafic volcanic fields. Only two of the volcanoes, Mount Kenya (on the flank of the central graben) and Suswa (the southernmost of the CKPP volcanoes), have phonolites as part of their assemblage.

The evolution of Suswa …

Insight Into The Physics Of Rupture: Dynamic Triggering Seismicity, Hector Gonzalez-Huizar

Open Access Theses & Dissertations

Seismic waves can trigger earthquakes and tremor at large distances from the causable event. Dynamic triggering occurs when the surface waves from large earthquakes change the stresses conditions on previously overstressed faults, promoting failure. To understand the causative stresses and environments behind dynamic triggering, we model the change in the stress field that the passing of Rayleigh and Love waves cause on a fault plane of arbitrary orientation relative to the direction of propagation of the waves, and apply a Coulomb failure criterion to calculate the potential of these stress changes to trigger seismicity. We apply our model to three …

Two-Dimensional Gravity Modeling Of The Rattlesnake Springs Watershed, Carlsbad Caverns National Park, New Mexico, Nikolay D. Boykov

Open Access Theses & Dissertations

A series of non-invasive geophysical investigations at the Rattlesnake Springs part of Carlsbad Caverns National Park, New Mexico, were performed in an effort to better delineate the watershed of the springs. The goal of this project is to determine possible locations of fractures and faults that may control the distribution of groundwater that feeds Rattlesnake Springs. Once the water flow paths are identified, the park will be able to better protect Rattlesnake Springs from environmental hazards, such as oil and gas drilling, as well as from upstream water development. As part of this effort I conducted a precision gravity survey …

Magnitude Of Right-Lateral Offset On The Southern Death Valley Fault Zone From Miocene Volcanic Assemblages, Sabrina Michelle Canalda

Open Access Theses & Dissertations

In this study correlation of Miocene volcanic and sedimentary rocks in southern Death Valley is used to constrain the total amount of slip on the southern Death Valley fault. The tertiary volcanic section near Ibex Pass is correlated to rocks ~35 km to the northwest, in the Wingate Wash region (Luckow et al., 2005). Geochronology by Luckow et al. (2005) in Wingate Wash and the Owlshead Mountains has the region divided into two basic periods: an early interval (~14-13.4Ma), and a later phase (~13-12.5Ma). One date from the volcanic sequence in Ibex Pass has been reported (Calzia, 2000) suggesting that …

The Pluvial Lake Palomas - Samalayuca Dunes System, Miguel Dominguez Acosta

Open Access Theses & Dissertations

A lacustro-aeolian system formed by the Pluvial Lake Palomas (PLP), the Samalayuca Dunes (SMD) and a connecting aeolian corridor is found in the central Chihuahuan Desert of North America approximately 50 km upwind (SW) of the binational Paso del Norte metroplex. The system is described by its three individual components. They comprise one of the largest paleo-lacustrine (Pleistocene) environments in the Chihuahuan Desert (PLP), one of the largest and least-studied sand seas of North America (SMD), and a newly described and geomorphically heterogeneous aeolian corridor connecting the two.

The Chihuahuan Desert has been a major and underappreciated dust production region …

Temporal And Geochemical Insights Related To Volcanic And Plutonic Activity Within Big Bend National Park, Texas, Daniel Paul Miggins

Open Access Theses & Dissertations

Big Bend National Park located in the southeastern part of the Trans-Pecos Magmatic Province in west Texas contains a diverse suite of volcanic and intrusive rocks. Ongoing geologic mapping, geochronology, and geochemical studies have focused on the timing and geological relationships associated with these volcanic and intrusive rocks. Igneous activity within Big Bend National Park occurred from 46.5 to 22.0 Ma. Precise 40Ar/39Ar and U-Pb zircon geochronology has resolved the timing of this activity into five discrete episodes: 1) eruption and emplacement of both intrusive and volcanic mafic rocks at 46.5 Ma followed by ~42.0 Ma mafic volcanic pulse; 2) …

Zinc And Copper Isotopes As Tracers Of Anthropogenic Contamination In A Sediment Core From An Urban Lake, Anita Thapalia

Open Access Theses & Dissertations

Concentration data alone are often insufficient to resolve metal sources. This study applies stable Zn and Cu isotopes to fingerprint and track the sources of these metals in a sediment core from Lake Ballinger near Seattle, Washington, USA. The base of the Lake Ballinger core pre-dates settlement in the region, while the upper sections record the impact of atmospheric emissions from the nearby Tacoma smelter, as well as Cu and Zn inputs from urban sources. δ⁶⁶Zn and δ⁶⁵Cu varied by 0.42 / and 0.29 /, respectively, over the >300 year core record. Isotopic changes were correlated …

A Multi-Tracer Study Of Saltwater Origin, Cross-Formational Flow, And The Geochemical Evolution Of Groundwater In The Southern High Plains Aquifer Along The Western Caprock Escarpment, East-Central New Mexico, Jeff Langman

Open Access Theses & Dissertations

Sustainable management of groundwater resources requires sufficient knowledge of the distribution of fresh and saline groundwater and the processes affecting saltwater intrusion that may influence the beneficial use of groundwater. A hydrogeologic investigation that coupled various chemical and isotopic tracers, including 3H/3He, 14C, δD, δ18O, 87Sr/86Sr, and δ11B, with the physical characteristics of the aquifer was conducted to determine source waters, the origin of saltwater and its influence through cross-formational flow, and water-rock interactions in the Southern High Plains aquifer along the Western Caprock Escarpment. Sub-aquifers or local flow systems are present along the Western Caprock Escarpment, and the study …

Integrated Geophysical Data Processing And Interpretation Of Crustal Structure In Ethiopia With Emphasis On The Ogaden Basin And Adjacent Areas, Ketsela Tadesse

Open Access Theses & Dissertations

The combined effects of magmatism and stretching due to asthenosphere upwelling modifies the crustal structure of the Earth as seen in the Ethiopian rift and adjacent areas. The Ethiopian rift provides unique opportunities to understand the nature of rifted crust and the intensity of its modification by magmatic processes. I used geological and geophysical data to conduct an integrated study in and around the Ethiopian rift including the northern Kenyan rift and the northern part of the Kenyan dome. New gravity, controlled source seismic, and teleseismic data from the EAGLE (Ethiopia-Afar Geoscientific Lithospheric Experiment) were used as additional constraints in …

Lithospheric Structure Of The Basin And Range Province-Southwestern Colorado Plateau. Southeastern California, Southern Nevada, And Western Arizona, Nigel Oakley Hicks

Open Access Theses & Dissertations

The Basin and Range Province of the western United States is an unusually wide continental rift zone and its structure and evolution have been the topic of much debate. Active source seismic surveys within the Basin and Range Province have delineated a relatively uniform crustal thickness (-30 km) despite varying magnitudes of crustal extension (<10-300 km). Large scale Cenozoic crustal extension has exhumed midcrustal rocks (from 10-20 km depth) along low angle detachment faults to create metamorphic core complexes (exposed lower plate rocks). In contrast to the extreme amounts of extension and internal deformation of the Basin and Range, the Colorado Plateau has remained a relatively rigid block, with a crustal thickness of 40-50 km, apparently resistant to the deformation processes that have shaped the Basin and Range observed today. In general, geophysical surveys reveal a significant contrast in crustal structure between the Basin and Range and it's transition into the Colorado Plateau.

The debate about the origin of the Basin and Range has underscored the need for additional geophysical constraints. Thus in this study, a regional analysis of lithospheric structure in the region of southeastern California, southern Nevada, and western Arizona that includes the Basin and Rangesouthwestern …

Evolution Of Quaternary Intraplate Mafic Lavas Detailed Using Helium-3 Surface Exposure And Argon-40/Argon-39 Dating, And Elemental And Helium, Strontium, Neodymium And Lead Isotopic Signatures: Potrillo Volcanic Field, New Mexico, United States Of America And San Quintin Volcanic Field, Baja California Norte, Mexico, Wendi Joan Whitehead Williams

Open Access Theses & Dissertations

The Pleistocene Potrillo volcanic field (PVF) resides within the southern axis of the Rio Grande Rift, New Mexico, U.S.A., near the eastern extent of the Basin and Range Province. Its alkalic mafic volcanism has resulted in several hundred cones, flows and maars distributed over approximately 4,600 km2. Alignments are segregated into two halves relative to the East Robledo fault system that dissects this field. Three of the five maars have brought peridotitic and lower to upper crustal xenoliths to the surface; several older, non maar-related flows from the west half of the field host ultramafic clots. Stratigraphic relationships, 3He surface …