Geology Commons^™

Gypsum-Carbonate Speleothems From Cueva De Las Espadas (Naica Mine, Mexico): Mineralogy And Palaeohydrogeological Implications, Fernando Gázquez, Jose Maria Calaforra, Paolo Forti, Fernando Rull, Jesús Martínez-Frías

International Journal of Speleology

Some of the most outstanding hypogenic gypsum speleothems worldwide have been recently discovered in the Naica mines. The Cueva de las Espadas (Swords Cave), which lies at 120 m depth, hosts a rare type of speleothem called “espada” (“sword”). This study contributes to the understanding of the mineralogical composition of these singular speleothems, by means of their examination using micro-Raman spectroscopy, FT-IR spectroscopy and EDX microprobe. Our data revealed a complex mineralogy comprising a high-purity selenite core covered by several layers of calcite, aragonite and gypsum. Solid inclusions of polymetallic oxides (Mn-Pb-Zn) and graphite were also detected. The position of …

2d And 3d Imaging Of The Metamorphic Carbonates At Omalos Plateau/Polje, Crete, Greece By Employing Independent And Joint Inversion On Resistivity And Seismic Data, Hamdan Ali Hamdan Dr, Nikos Economou, Giorgos Kritikakis, Nikos Andronikidis, Emmanuil Manoutsoglou, Antonis Vafidis, Pangratis Pangratis, Georgina Apostolidou

International Journal of Speleology

A geophysical survey carried out at Omalos plateau in Chania, Western Crete, Greece employed seismic as well as electrical tomography methods in order to image karstic structures and the metamorphic carbonates (Tripali unit and Plattenkalk group) which are covered by post-Mesozoic deposits (terra rossa, clays, sands and gravels). The geoelectrical sections image the metamorphic carbonates which exhibit a highly irregular relief. At the central part of the plateau the thickness of post-Mesozoic deposits (terra rossa, clays, sands and gravels) ranges from 40-130 m. A 3D resistivity image was generated by inverting resistivity data collected on a grid to the south …

Diagenesis Of A Drapery Speleothem From Castañar Cave: From Dissolution To Dolomitization, Andrea Martín-Pérez, Rebeca Martín-García, Ana M. Alonso-Zarza

International Journal of Speleology

A drapery speleothem (DRA-1) from Castañar Cave in Spain was subjected to a detailed petrographical study in order to identify its primary and diagenetic features. The drapery’s present day characteristics are the result of the combined effects of the primary and diagenetic processes that DRA-1 underwent. Its primary minerals are calcite, aragonite and huntite. Calcite is the main constituent of the speleothem, whereas aragonite forms as frostwork over the calcite. Huntite is the main mineral of moonmilk which covers the tips of aragonite. These primary minerals have undergone a set of diagenetic processes, which include: 1) partial dissolution or corrosion …

Provenance And Geological Significance Of Red Mud And Other Clastic Sediments Of The Mugnano Cave (Montagnola Senese, Italy), Francesco Iacoviello, Ivan Martini

International Journal of Speleology

The Mugnano cave is characterized by a thick clastic sedimentary fill showing a great variability of sedimentary facies, ranging from clay to coarse-grained sand deposits. This paper deals with combined sedimentological and mineralogical (XRD and SEM) studies of these sediments and bedrock insoluble residues in order to understand the origin and geological significance of cave deposits, with particular attention to red mud sediments, often considered as the residue of host rock dissolution. Three different sedimentary facies were recognized: i) YS, yellow sand with occasionally shell fragments, testifying the arrival of sediments from the surrounding landscape; ii) RS, red laminated mud; …

Petrographic And Isotopic Evidence For Late-Stage Processes In Sulfuric Acid Caves Of The Guadalupe Mountains, New Mexico, Usa, Margaret V. Palmer, Arthur N. Palmer

International Journal of Speleology

Caves of the Guadalupe Mountains have experienced many modifications since their final phase of sulfuric acid speleogenesis several million years ago. Petrographic and geochemical data reveal details of the change from H₂SO₄ to CO₂-dominated reactions. The H₂SO₄ dissolution front acquired a coating of replacement gypsum with local pockets of anhydrite and by-products of altered clay, including Fe-Mn oxides. Alteration of bedrock beneath the gypsum produced a white micritized rind with small negative shifts in δ¹³C and δ¹⁸O. Solution basins contain records of the earliest post-speleogenetic processes: corroded bedrock, …

Secondary Halite Deposits In The Iranian Salt Karst: General Description And Origin, Michal Filippi, Jiří Bruthans, Lukáš Palatinus, Mohammad Zare, Naser Asadi

International Journal of Speleology

This paper summaries 12 years of documentation of secondary halite deposits in the Iranian salt karst.

A variety of secondary halite deposits was distinguished and classified into several groups, on the basis of the site and mechanism of their origin. Deposits formed: i) via crystallization in/on streams and pools, ii) from dripping, splashing and aerosol water, iii) from evaporation of seepage and capillary water, and iv) other types of deposits. The following examples of halite forms were distinguished in each of the above mentioned group: i) euhedral crystals, floating rafts (raft cones), thin brine surface crusts and films; ii) straw …

Mineralogy Of Iza Cave (Rodnei Mountains, N. Romania), Tudor Tămaş, Ferenc Kristály, Lucian Barbu-Tudoran

International Journal of Speleology

The secondary minerals from Iza Cave result from the interactions of karst water and/or cave atmosphere over a variety of sedimentary and metamorphic rocks. The cave passages expose at various extents Eocene limestones and conglomerates, Oligocene black shales, Upper Precambrian micaschists, marble and dolomitic marble and associated ore deposits.

Twelve secondary minerals identified in the cave (carbonates, sulfates, phosphates, oxides and hydroxides, and silicates) are presented in this study. Calcite, aragonite, gypsum, brushite and hydroxylapatite are the components of common speleothems in the limestone, dolomite and conglomerate areas of the cave. Ankerite crusts are related to areas with pyrite mineralization …

The First Cave Occurrence Of Orpiment (As₂S₃) From The Sulfuric Acid Caves Of Aghia Paraskevi (Kassandra Peninsula, N. Greece), Georgios Lazaridis, Vasilios Melfos, Lambrini Papadopoulou

International Journal of Speleology

Orpiment, tamarugite and pickeringite occur in close association above the surface of thermal water cave pools in the active sulfuric acid caves of Aghia Paraskevi on the Kassandra peninsula, northern Greece. Gypsum also occurs as small interstitial crystals or encrustations. Orpiment is of high significance since it has not previously been reported as a cave mineral. In addition, tamarugite and pickeringite rarely occur in karst caves. Water from a borehole and a spring is of Na-Cl type and contains traces of CO₂ and H₂S. The B/Cl ratios indicate seawater participation with a possible mixing with geothermal water …

Trace Element And Stable Isotope Data From A Flowstone In A Natural Cave Of The Mining District Of Sw Sardinia (Italy): Evidence For Zn²⁺-Induced Aragonite Precipitation In Comparatively Wet Climatic Conditions, Guglielmo Angelo Caddeo, Jo De Waele, Franco Frau, Loren Bruce Railsback

International Journal of Speleology

A speleothem from Crovassa Azzurra, a mine cave in SW Sardinia (Italy), has been analysed for mineralogy, minor and trace elements and stable isotopes. It is composed of layers of primary calcite and aragonite, with a region of secondary calcite. The primary carbonate is strikingly rich in Zn and Pb, presumably as the result of transport in solution from overlying Pb-Zn deposits. Immediately below the transition between calcite and aragonite, concentrations of Zn, Cd and P increase. At the transition between aragonite and Pb-rich aragonite, concentrations of Pb and P increase. Stable isotopes indicate an evolution toward more humid periods …

Minerals And Speleothems Of The József-Hegy Cave (Budapest, Hungary), Szabolcs Leél-Őssy, Gyöngyvér Szanyi, Gergely Surányi

International Journal of Speleology

With the discovery of the József-hegy Cave, a cave of hydrothermal origin with an abundance of minerals unknown so far in Hungary came to light. Diversity and the frequency of the occurrence of crystals make this cave similar to the Lechuguilla Cave, even if the dimensions of the mineral precipitations and the passages do not compare in scale. The variety and mass of carbonates and sulphates are surprising. This paper describes the minerals and speleothems of the József-hegy Cave, their occurrence and genesis, including determined ages. The 41 U/Th measurements suggest that speleothems begun to develop in the upper level …

Tracer Tests In Karst Hydrogeology And Speleology, Nico Goldscheider, Joe Meiman, Michiel Pronk, Christopher Smart

International Journal of Speleology

This article presents an introduction to the fundamentals of tracing techniques and their application in cave and karst environments, illustrated by case studies from the Mammoth Cave, USA, and a small experimental site in Switzerland. The properties and limitations of the most important artificial tracers are discussed, and the available methods of tracer injection, sampling, online monitoring and laboratory analysis are presented. Fully quantitative tracer experiments result in continuous or discrete concentration-time data series, i.e. breakthrough curves, and concomitant discharge data, which make it possible to obtain detailed information about groundwater flow and contaminant transport. Within the frame of speleological …

Hydrodynamic Aspect Of Caves, Mitja Prelovšek, Janez Turk, Franci Gabrovšek

International Journal of Speleology

From a hydrological point of view, active caves are a series of connected conduits which drain water through an aquifer. Water tends to choose the easiest way through the system but different geological and morphological barriers act as flow restrictions. The number and characteristics of restrictions depends on the particular speleogenetic environment, which is a function of geological, geomorphological, climatological and hydrological settings. Such a variety and heterogeneity of underground systems has presented a challenge for human understanding for many centuries. Access to many underground passages, theoretical knowledge and recent methods (modeling, water pressure-resistant dataloggers, precise sensors etc.) give us …

Contribution Of Artificial Galleries To The Knowledge Of Karstic System Behaviour In Addition To Natural Cavern Data, Benjamin Garry, Thibaut Blondel, Christophe Emblanch, Christophe Sudre, Séverine Bilgot, Alain Cavaillou, Daniel Boyer, Michel Auguste

International Journal of Speleology

The study of karstic systems is mainly based on hydrodynamic and hydrochemical data collected at system inlets (rainfall) and outlets (springs). Indeed, some complementary data base coming from speleological and hydrogeological explorations of natural cavities exist. However, they are not completely representative of all the types of flows. These kinds of flow which have a large part in general hydrodynamics of a system are already the result of a structured organization of karst due to complex phenomena of limestone dissolution. Artificial galleries have the advantage to be easily accessible. Moreover, they cut randomly flows which are much less structured or …

Groundwater Contamination In Caves: Four Case Studies In Spain, Monserrat Jiménez-Sánchez, Heather Stoll, Iñaki Vadillo, Manolo López-Chicano, María Domínguez-Cuesta, Wenceslao Martín-Rosales, Mónica Meléndez-Asensio

International Journal of Speleology

Groundwater quality was monitored in four Spanish caves using concentrations of nitrate, potassium, phosphorus and in some cases total organic carbon. Three of the caves are located in NW Spain and contain prehistoric cave paintings and hence have special conservation interest. Of these, two are open show caves (Tito Bustillo and Pindal Caves), while the other one (Herrerías Cave) is not managed for tours and is partially closed off to public access. The fourth cave (Las Maravillas Cave) is located in SW Spain and is opened to the public because of its geological features and natural beauty. In this paper, …

Some Applications Of Geochemical And Isotopic Techniques To Hydrogeology Of The Caves After Research In Two Sites (Nerja Cave-S Spain And Fourbanne System-French Jura), Jacques Mudry, Bartolomé Andreo, Arnaud Charmoille, Cristina Liñán, Francisco Carrasco

International Journal of Speleology

Caves constitute privileged sampling spots to investigate the hydrochemical behaviour of infiltration, but the representative nature of samples can limit their reach. Taking this into account many results can be obtained from chemistry of water sampled in the caves. Carbonate tracers enable to reconstruct the ‘history’ of drip water water, including rainfall and temperatures. Moreover, permanent drip waters prove durability of water stored in the unsaturated zone over the cave, and lags between rain inputs and drip output enable to evaluate transit time through the unsaturated zone. The comparison of input/output concentrations can also contribute to estimate the local water …

Hydrogeochemical Processes As Environmental Indicators In Drip Water: Study Of The Cueva Del Agua (Southern Spain), Angel Fernandez-Cortes, Jose Maria Calaforra, Francisco Sánchez-Martos

International Journal of Speleology

Karst caves exhibit a wide range of hydrological and hydrochemical responses to infiltration events, due to their physical heterogeneity in space and dynamic variability over time, and due to non-Gaussian inputs (rain) and outputs (discharge). This paper reviews different approaches of studying seepage water in caves, in order to understand the infiltration regimen in the non-saturated zone of karst areas. As an illustration, we describe a four-year study of the active carbonate-water system in the Cueva del Agua (Granada, southern Spain) that automatically logs the discharge from a stalactite. The results indicate that: (1) the drip water regime is not …

Epigene And Hypogene Gypsum Karst Manifestations Of The Castile Formation: Eddy County, New Mexico And Culberson County, Texas, Usa, Kevin W. Stafford, Raymond Nance, Laura Rosales-Lagarde, Penelope J. Boston

International Journal of Speleology

Permian evaporites of the Castile Formation crop out over ~1,800 km² in the western Delaware Basin (Eddy County, New Mexico and Culberson County, Texas, USA) with abundant and diverse karst manifestations. Epigene karst occurs as well-developed karren on exposed bedrock, while sinkholes dominate the erosional landscape, including both solutional and collapse forms. Sinkhole analyses suggest that more than half of all sinks are the result of upward stoping of subsurface voids, while many solutional sinks are commonly the result of overprinting of collapsed forms. Epigene caves are laterally limited with rapid aperture decreases away from insurgence, with passages developed …

Surface Corrosion Of An Alpine Karren Field: Recent Measures At Innerbergli (Siebenhengste, Switzerland), Philipp Häuselmann

International Journal of Speleology

29 year old rock paintings in the Alpine karren field of Innerbergli (Siebenhengste, Switzerland) prevented the underlying rock from corrosion, while the surface nearby was corroded. Measurement of the steps indicates an average recent corrosion rate of 0.014 (±0.007) mm/a. This denudation rate is very similar to those observed in other comparable places and with other means.

An Investigation Of Meromixis In Cave Pools, Lechuguilla Cave, New Mexico, David B. Levy

International Journal of Speleology

Chemical characteristics of permanent stratification in cave pools (meromixis) may provide insight into the geochemical origin and evolution of cave pool waters. The objective of this study was to test the hypothesis that some pools in Lechuguilla Cave may be subject to ectogenic meromixis, where permanent chemical stratification is induced by input of relatively saline or fresh water from an external source. However, because organic C concentrations in Lechuguilla waters are low (typically < 1 mg L^-1), biogenic meromixis resulting in O₂(g)-depleted subsurface waters is not expected. Four pools at various depths below ground surface (0 m) were studied: (1) …

Late Pleistocene Cryogenic Calcite Spherolites From The Malachitdom Cave (Ne Rhenish Slate Mountains, Germany): Origin, Unusual Internal Structure And Stable C-O Isotope Composition, Detlev Konrad Richter, Dana Felicitas Christine Riechelmann

International Journal of Speleology

Cryogenic calcites yielded U-series ages in the range from 15.61±0.20 ka to 14.48±0.12 ka, which is the youngest age obtained so far for this type of cryogenic cave carbonates in Europe. Most of these particles of the Malachitdom Cave (NE Brilon, Sauerland, North Rhine-Westphalia) are complex spherolites usually smaller than 1 cm. They show δ¹³C-values between –1 and –5 ‰ VPDB and δ¹⁸O-values ranging from –7 to –16 ‰ VPDB, the δ¹³C-values increase and the δ¹⁸O-values decrease from centre to border. The complex spherolites are interpreted to be formed in slowly freezing …

The Role Of The Epikarst In Karst And Cave Hydrogeology: A Review, Paul W. Williams

International Journal of Speleology

The epikarst (also known as the subcutaneous zone) comprises highly weathered carbonate bedrock immediately beneath the surface or beneath the soil (when present) or exposed at the surface. Porosity and permeability are higher near the surface than at depth, consequently after recharge percolating rainwater is detained near the base of the epikarst, the detention ponding producing an epikarstic aquifer. Such an aquifer is found only where the uppermost part of the vadose zone is very weathered compared to the bedrock at depth. Sometimes this contrast in porosity and permeability does not occur either because the epikarst has been scraped off …

The Origin Of The Bemaraha Tsingy (Madagascar), Márton Veress, Dénes Lóczy, Zoltán Zentai, Gábor Tóth, Roland Schläffer

International Journal of Speleology

On Madagascar the most representative occurrences of tsingy are at Ankarana and Bemaraha. The tsingy are built up of giant grikes developed along cracks as well as karren features of much smaller size which cover the surfaces between grikes. We investigated the Bemaraha tsingy of Madagascar (surveyed profiles, measured grike directions, etc.) in order to reconstruct their development. The observations indicate that the majority of grikes of the tsingy are created from caves formed under the karst water table and subsequently opened up to the surface. The predominant processes may have been downward progressing dissolution or the collapse of cave …

Carbon Dioxide Concentration In Air Within The Nerja Cave (Malaga, Andalusia, Spain), Cristina Liñán, Iñaki Vadillo, Francisco Carrasco

International Journal of Speleology

From 2001 to 2005 the CO₂ concentration of the air in the interior and exterior of the Nerja Cave was studied and its relation with the air temperature and visitor number. The average annual CO₂ concentration outside of the cave is 320 ppmv, whilst inside, the mean concentration increases to 525 ppmv during autumn and winter, and in the order of 750 ppmv during spring and summer. The temporal variation of CO₂ content in the air of the cave is strongly influenced by its degree of natural ventilation which is, in turn, determined by the difference between …

A Taxonomic Survey Of Lamp Flora (Algae And Cyanobacteria) In Electrically Lit Passages Within Mammoth Cave National Park, Kentucky, Thomas Smith, Rick Olson

International Journal of Speleology

A taxonomic survey of the lamp flora from electrically lit passages in Mammoth Cave, Mammoth Cave National Park, identified 28 species. Overall, cyanobacteria were dominant represented by 14 species (50% of the total), green algae had eight species (29%), and six diatoms species (21%) were present. There was not a correlation between species diversity and temperature, but there is a general trend of increasing diversity with warmer temperatures. There were two algal or cyanobacterial species identified in this study that overlapped with previous studies. There is a lack of continuity between previous studies only having one species identified in more …

The Polygenetic Caves Of Cuatro Ciénegas (Coahuila, Mexico): Morphology And Speleogenesis, Leonardo Piccini, Paolo Forti, Italo Giulivo, Marco Mecchia

International Journal of Speleology

The Cuatro Ciénegas area is renown worldwide for its thermal springs, which feed a unique ecosystem consisting of many pools, lakes and marshes. The pools also represent a very important water resource in a region characterized by scarce rainfalls. Field investigation has emphasized the role of karst in the hydrogeology of the area. Only few and restricted forms of surface karst are represented; caves are mainly relics of old speleogenetic phases of thermal and bathyphreatic water flow.

Speleothems As Indicators Of Wet And Dry Periods, Ian John Fairchild, Emily Anne Mcmillan

International Journal of Speleology

Calcareous speleothems provide a record of dripwater composition which in turn is a function of climatic conditions. The historical focus of speleothem palaeoclimate studies has been on the derivation of palaeotemperatures through oxygen isotope studies. However, it is now realized that water availability is a more generally important control on their characteristics. Growth rate and growth morphology in principle should give rise to recognizable changes at low flow. However, accidental plumbing effects during aquifer evolution, can also lead to variations in water supply and it is not easy to distinguish these effects. In areas where there is a strong amount …

Climatic Differences And Similarities Between Indian And East Asian Monsoon Regions Of China Over The Last Millennium: A Perspective Based Mainly On Stalagmite Records, Ming Tan

International Journal of Speleology

Cave sediments, especially stalagmites, have been providing absolute dated climate records that can extend from the present to over 500,000 years ago. Based on the reconstructed temperature time series, a comprehensive overview of the climatic differences and similarities between the Indian and the East Asian Monsoon regions of China over the last millennium is presented. Evidence from accurately dated and high-resolution records including stalagmites, ice cores and tree rings show that there was a “Medieval Warm Period” (around 1000 to 1400 AD) in north and east China where climate is dominated by the East Asian monsoon; whilst no such interval …

The Impact Of Host Rock Geochemistry On Bacterial Community Structure In Oligotrophic Cave Environments, Hazel A. Barton, Nicholas M. Taylor, Michael P. Kreate, Austin C. Springer, Stuart A. Oehrle, Janet L. Bertog

International Journal of Speleology

Despite extremely starved conditions, caves contain surprisingly diverse microbial communities. Our research is geared toward understanding what ecosystems drivers are responsible for this high diversity. To asses the effect of rock fabric and mineralogy, we carried out a comparative geomicrobiology study within Carlsbad Cavern, New Mexico, USA. Samples were collected from two different geologic locations within the cave: WF1 in the Massive Member of the Capitan Formation and sF88 in the calcareous siltstones of the Yates Formation. We examined the organic content at each location using liquid chromatography mass spectroscopy and analyzed microbial community structure using molecular phylogenetic analyses. In …

Petrographic And Geochemical Study On Cave Pearls From Kanaan Cave (Lebanon), Fadi H. Nader

International Journal of Speleology

The Kanaan cave is situated at the coastal zone, north of Beirut City (capital of Lebanon). The cave is located within the upper part of the Jurassic Kesrouane Formation (Liassic to Oxfordian) which consists mainly of micritic limestone. Twenty seven cave pearls were subjected to petrographic (conventional and scanning electron microscopy) and geochemical analyses (major/trace elements and stable isotopes). The cave pearls were found in an agitated splash-pool with low mud content. They are believed to have formed through chemical precipitation of calcite in water over-saturated with calcium. The nucleus and micritic laminae show δ¹⁸O_V-PDB values of …

Seasonal Variations Of Co2 And 222Rn In A Mediterranean Sinkhole - Spring (Causse D’Aumelas, Se France), Christelle Batiot-Guilhe, Jean-Luc Seidel, Hervé Jourde, Olivier Hébrard, Vincent Bailly-Comte

International Journal of Speleology

Carbon dioxide and ²²²Rn monitoring of the atmosphere of a Mediterranean sink hole - spring (SE France) during two hydrological cycles (from September 2004 to September 2006) showed seasonal variations with very high concentrations during summer (greater than 6% and 20 000 Bq/m³, respectively). Gas dynamics in caves often show seasonal variations. Meteorological parameters (barometric pressure and temperature mainly), cave geometry and fracture networks control exchanges between the cavity and outside atmosphere. Carbon dioxide and ²²²Rn may have different sources (atmosphere, soil, bedrock, deep gas diffusion, in situ oxidation of organic matter and, in some caves, …