Geology Commons^™

Geophysical And Remote Sensing Applications For A Better Understanding Of The Structural Controls On Groundwater Flow In The Lucerne Valley, California, Dale R. Dailey

Masters Theses

An integrated study was conducted in the Mojave Basin to investigate the potential role of faults and basement uplifts for groundwater flow in the Mojave Desert. Observations made include: 1) Very Low Frequency (VLF) measurements across mapped (using LIDAR and Geoeye-1 imagery) fault traces showed significant radio field dip angles indicative of presence of shallow sub-vertical, sheet-like conductors; many of the VLF tilt peaks coincided with changes in the magnetic profiles; 2) Vertical Electric Soundings indicate shallow basement west of, and parallel to, the Helendale Fault and deep saturated zones east of the fault/basement outcrop (F/B); and 3) isotopic analyses …

A Localized Investigation Of High Resolution Groundwater Flow Properties Of The Saginaw Aquifer Mason, Michigan, Amanda Hayden

Masters Theses

High resolution groundwater models can aid in better management of groundwater resources through more accurate characterization and quantification of aquifer systems. Detailed assessments of flow properties in the context of sedimentary facies can provide high quality data input for more accurate groundwater models.

The Pennsylvanian Grand River and Saginaw bedrock formations comprise the Saginaw Aquifer located in the Lansing, Michigan Tri-County region. The Saginaw Aquifer consists of a predominately shale and sandstone successions. These sandstone facies range up to 40 meters thick, and supply a significant amount water resources to the Lansing Tri-County area. Data used in this study was …

Paleoclimatic Regimes Of The African Sahara Desert During Pleistocene And The Origin Of Groundwater In The Nubian Sandstone Aquifer System, Abdou A. Abouelmagd

Dissertations

This study involves an integrated three-fold approach to better understand the paleoclimatic regimes over the North African Sahara Desert with emphasis on the origin of groundwater in the Nubian Sandstone Aquifer System. Specifically, the nature and origin of the paleo-wind regimes that produced the precipitation that recharged the fossil aquifers in North Africa in the previous wet climatic periods are deciphered using inferences from stable isotope data, noble gases, remote sensing and GIS.

In the first phase, the progressive depletion trend of stable isotopic composition in the fossil groundwaters under influence of paleowesterlies across North African Sahara Desert is simulated …

Evaluating The Effects Of Lithofacies And Thin Shales On The Lateral Distribution Of Hydrothermal Dolomite Reservoirs In The Michigan Basin, Peter J. Feutz

Masters Theses

The southern Michigan Basin contains numerous hydrothermal dolomite hydrocarbon fields, including the giant Albion-Scipio Field. The fields typically encompass narrow zones of faulting and fracturing which have been altered from a tight host limestone into a more porous and permeable dolomite by upward-moving hydrothermal fluids. Alternating layers of dolomite that spread laterally away from the main vertical fault conduits imply that structure alone may not define the resulting reservoir architectures within the region. A detailed analysis of primary depositional facies and thin shale seams suggests that secondary stratigraphic controls play a significant role in the development of reservoir rock within …

High Resolution Depositional Analysis Of The Black River Group (Ordovician), Michigan Basin, Jennifer Elaine Schulz

Masters Theses

The Ordovician Trenton and Black River carbonates of the Michigan Basin are significant hydrocarbon reservoirs that are characterized by hydrothermal dolomitization. Production has exceeded 132 million barrels of oil with forty new discoveries made in the past three years. The giant Albion-Scipio Trend is often used as a model for other prolific hydrothermal dolomite reservoirs around the world with current models focused on the structural control of reservoir quality dolomite.

Previous studies of the Black River Group have not delimited a well-constrained depositional model. This study integrates high-resolution core interpretations, whole core analysis, and thin section evaluation to determine how …

Prediction Of Petrophysical Properties Of Trenton-Black River (Ordovician) Reservoirs By Comparing Pore Architecture And Permeability To Sonic Velocity, John E. Thornton

Masters Theses

Reservoir characterization of carbonate rocks is complicated by heterogeneous pore architecture related to primary depositional facies and subsequent diagenesis; this is especially true in diagenetically-altered and structurually-influenced Trenton-Black River reservoirs of the Michigan Basin. Accurate and reliable prediction of reservoir properties within hydrothermal dolomite reservoirs through the use of acoustic properties would aid exploration and characterization both within and outside of the Michigan Basin.

Results indicate that measures of pore architecture when integrated with measures of physical properties into multiple variable linear regression can accurately predict permeability of core plugs. However, due to the highly-heterogeneous distribution of pore architecture and …

Investigation Of Carbon Sequestration Potential Of The Middle Devonian Sylvania Sandstone, Michigan Basin, U.S.A, Farsheed Rock

Masters Theses

The Sylvania Sandstone is an important brine reservoir in Michigan. This study investigates the geological carbon sequestration potential of this reservoir through integrated reservoir characterization using cores, thin sections, core analysis data and modern wireline log data.

Core-to-wireline-log correlation can be used to subdivide the Sylvania Sandstone into conventional reservoir sandstone, and mixed dolostone, low permeability reservoir tripolitic chert and low permeability limestone lithologies. Isolith maps and cross sections indicate that the reservoir sandstone lithology dominates in southeast Michigan and is transitional to a mixture of sandstone, dolostone, tripolitic chert and limestone lithologies toward the northwest that in turn are …

Geological Controls On Reservoir Quality And Geologic Carbon Sequestration Potential In The Upper Cambrian Mount Simon Sandstone, Kyle Patterson

Masters Theses

The Upper (?) Cambrian Mount Simon Sandstone is an important deep saline geological carbon sequestration (GCS) target throughout the Midwest, USA. The distribution of sedimentary facies, primary mineralogy, and diagenetic alterations and the relationship to wireline log response and reservoir quality throughout the Michigan basin are not well known. This study uses rock core, thin section point counts, x-ray diffraction, inferred spectroscopy, conventional core plug porosity and permeability and pressure fall-off test data to constrain wireline log interpretations of regional geology and reservoir quality.

Prior to the permitting of a CO₂ sequestration project, documentation of a robust transient injection …

Investigating The Influence Of Organic Acids On Uraninite Solubility And Uranyl Sorption Onto Kaolinite, Michelle L. Barger

Dissertations

Within anoxic near surface aqueous settings where U0_2(S) may be released an opportunity to encounter and complex with organic acids may occur. Reactions between U0_2(S) and ligands may promote the solubility and mobility of uranium. Organic ligands investigated in the dissolution work include citric acid, NTA and EDTA. Exposure to the ligands had little effect on U0_2(S) solubility. The log activity of U0_2(S) hydrolysis under reduced conditions was -6.56. Under all measured conditions of ligand concentration, the data consistently show an increase in uranium concentration to a median log U activity of -4.89. The observed solubility …

Integrated Approach For The Assessment And Development Of Groundwater Resources In Arid Lands: Applications In The Quetta Valley, Pakistan, Zhanay Sagintayev

Dissertations

The lack of adequate field measurements (e.g., precipitation and stream flow) and difficulty in obtaining them often hampers the construction and calibration of rainfall-runoff models over many of the world's watersheds, leaving key· elements of the hydrologic cycle unconstrained. I adopted methodologies that rely heavily on readily available remote sensing datasets as viable alternatives and useful tools for assessing, managing, and modeling the water resources of such remote and inadequately gauged regions.

The Soil and Water Assessment Tool was selected for continuous (1998-2005) rainfall-runoff modeling of the northeast part of the Pishin Lora basin (NEPL), a politically unstable area that …

Glaciotectonic Deformation Along The Valparaiso Upland In Southwest Michigan, Usa, Brian C. Bird

Dissertations

Glaciotectonic deformation has been observed and analyzed across parts of the Valparaiso, Kendall, and Inner Kalamazoo Moraines in southwest Michigan, USA. Deformation structures such as folds and faults have been analyzed using techniques typically used by structural geologist along with the fabric of elongated clasts in the surficial diamicton. The structures are consistent with simple shear, horizontal compressional stresses, and pure shear. A series of drumlin fields exist along the western boundary of the study area. Direct investigation of the deformed sediments was conducted at a gravel pit in one of these drumlins. Lacustrine derived sediments interbedded with coarse sand …

Origin Of Tunnel Valley And Esker Assemblages In The Saginaw Lobe, Barry County, Michigan, Caleb J. Woolever

Masters Theses

Surficial mapping, borehole analysis, and ground penetrating radar surveys are used to reconstruct conditions leading to the formation of tunnel valley and esker networks within the Dowling 7 .5 minute quadrangle. The relationship between tunnel valleys and eskers has important implications on the subglacial hydrology beneath the Saginaw Lobe of the Laurentide Ice Sheet.

Surficial mapping reveals northeast-southwest trending tunnel valleys, some containing eskers of the same orientation, in hummocky topography mapped as the Saginaw Kalamazoo Moraine. A borehole hole drilled through one such tunnel valley and esker pair reveals sand and gravel fining upwards to fine sand. Stratigraphy suggests …

Influence Of Bioirrigation On Metal Distribution Within Burrows, Terri Shattuck

Masters Theses

Bioirrigation is the increase of solute transport resulting from introduction of oxygenated water from the surface into the more reduced environment deep within the burrow. Fe and Mn hydr-(oxides) accumulate on burrow margins in response to the oxygen flux into suboxic porewaters. This has been shown to trap trace metals (Harding and Risk, 1986; Tessier and Campbell, 1988; Tessier et al., 1979, 1982). The diagenesis, mobility, and transport of metals contribute to the bioavailability of metals in the environment possibly to the extent of harming ecosystems; especially in coastal areas with buried waste. This study assesses Fe and trace metal …

Remote Sensing Studies For The Assessment Of Geohazards: Toxic Algal Blooms In The Lower Great Lakes, And The Land Subsidence In The Nile Delta, Richard H. Becker

Dissertations

Remote sensing techniques provide valuable tools for assessing a wide variety of environmental phenomena. They have been used for monitoring and assessment of various types of geologic and environmental hazards occurring on land, in the air, or in oceans. I present results from two studies, the first of which examines the spatial and temporal distribution of algal blooms in the Great Lakes; the second measures subsidence in the Nile Delta.

In the first study, methodologies to investigate the extent and distribution (temporally and spatially) of algal blooms in Lake Erie and Lake Ontario are studied. Millions of people in the …

Analysis Of Pore Architecture And Correlation To Sonic Velocity Values In Silurian (Niagaran) Reefs Of The Michigan Basin, Amy Kathryn Noack

Masters Theses

Recent work has shown that there is a complex relationship among porosity, permeability, and rock fabric in carbonate rocks. Porosity/permeability transforms are of limited value when evaluating carbonate reservoirs because permeability is controlled by pore type. Vuggy, moldic, or fenestral pore types have high porosity but poor permeability; in contrast, intergranular and intercrystalline pore networks have high porosity and high permeability. Visible pore types of key facies in five Middle Silurian (Niagaran) Reef reservoirs of the Michigan Basin were evaluated to better understand related permeability. Image analysis was performed on key facies to understand pore geometries and pore connectivity. Facies …

Remote Sensing Solutions For Estimating Runoff And Recharge In Arid Environments, Adam M. Milewski

Dissertations

Efforts to understand and to quantify the interplay between precipitation, runoff, and recharge are often hampered by the paucity of appropriate monitoring systems. We developed methodologies for rainfall-runoff and groundwater recharge computations that heavily rely on observations extracted from a wide-range of global remote sensing data sets (TRMM, SSM/I, AVHRR, and AMSR-E,) using the arid Sinai Peninsula (SP; area: 61,000 km²) and the Eastern Desert (ED; area: 220,000 km²) of Egypt as our test sites. A two-fold exercise was conducted. Temporal remote sensing data (TRMM, AVHRR and AMSR-E) were extracted from global data sets over the …

Morphological Analysis Of The Charlevoix-Antrim And Northport Drumlin Fields, Michigan Using Digital Elevation Models, Alan M. Lefever

Masters Theses

The Charlevoix-Antrim and Northport drumlin fields, located in northwest Lower Michigan, lie on opposite sides of Grand Traverse Bay. Morphological measurements were derived from topographic maps and Digital Elevation Models (DEMs), combined with grain size analyses performed on collected drumlin sediments. Comparison of the morphological results demonstrates that statistical analysis of equal or better accuracy can be performed on drumlins using high resolution DEMs. The grain size analysis determined that the drumlins contain more gravel near the coast and become sandier to the south and east.

Spindle drumlins are the dominant drumlin form in both the Charlevoix-Antrim and Northport fields. …

Backstripping The Chesapeake Bay Impact Structure: Differentiating Regional Tectonics From Impact Effects, Travis Gary Hayden

Masters Theses

The Chesapeake Bay impact structure is a ca. 35.4 Ma old crater located on the coastal plain of Virginia along the eastern seaboard of North America. The impact generated a crater between 85 and 90 km in diameter, and over 2000 meters deep. Deposition returned to normal shortly after impact, resulting in a unique record of both the impact related and subsequent passive margin sedimentation. We use backstripping to show that the impact strongly affected sedimentation for 7 m.y. through a combination of impact derived crustal scale tectonics, dominated by the introduction and subsequent removal of a negative thermal anomaly, …

Adsorption Of Lead On Single And Mixed Solid Systems, Soumya Das

Dissertations

Metal oxy-hydroxides and phyllosilicate minerals play a significant role in the fate and transport of heavy metals in the environment (Bertsch and Seaman, 1999). Chemical speciation of metals affects their bioavailability and chemical reactivity (Stumm and Morgan, 1996). Surface complexation models (SCMs) based on equilibrium thermodynamic principles have been successfully used to quantify adsorption of heavy metals on pure solid minerals, including phyllosilicates and oxy-hydroxides. For natural sediments with mixed mineralogy, Davis et al. (1998) suggested two different SCM approaches, namely, the component additivity and generalized composite models. In this study, adsorption of lead on pure HFO, silica and kaolinite …

Modified Fenton Oxidation Of Hydrocarbon Contaminated Soils With Cao2: Microbial Survival And Surfactant Production, Abraham Matthew Northup

Dissertations

The efficacy of CaO₂ for use in modified Fenton's (MF) reactions was investigated in this study, with the goal of developing a CaO₂-based MF oxidation technology for use in in situ chemical oxidation. Traditionally, liquid H₂O₂ (HP) is used, and is injected into the subsurface in excess to ensure a sufficient radius of influence. CaO₂ was investigated as an alternative source of H₂O₂ for MF reactions.

First, the rate of dissolution of powdered CaO₂ and the yield of HP was investigated. Our results showed that the rate of dissolution …

Towards A Better Understanding Of The Hydrology Of The Tigris- Euphrates System And Its Marshlands, Christopher K. Jones

Masters Theses

Rising demands for fresh water supplies are leading to water management practices that are altering natural flow systems world-wide. One of the most devastated of these natural systems is the Tigris-Euphrates watershed that over the past three decades has witnessed the construction of over 60 engineering projects that eliminated seasonal flooding, reduced natural flow and dramatically reduced the areal extent (1966: 11000 km² ; 2002: 750 km²) of the Mesopotamian Marshes downstream. We constructed a continuous (1964 to 1998) catchment-based rainfall runoff model for the entire Tigris-Euphrates watershed (area: one million km²) using the SWAT …

Some Applications Of Gaussian Quadrature And Neural Network Modeling In Earth Flows And Other Slow-Moving Landslides In Cohesive Slope Materials, Rennie Bwalya Kaunda

Dissertations

Geometrical changes and progressive displacements in earth flows and other slow moving landslides triggered by climatic changes may be addressed by digital modeling. Gaussian quadrature, a numerical integration technique though fixed points, is employed to compute geometrical areas defined by stratigraphic (soil or rock layering) units, vertical pole projections and a slip surface, based on kinematic admissibility. An example from the Lake Michigan coast shows that the total internal geometrical area is found to be preserved during the course of the progressive deformation. Displacement monitoring of the slope shows that it became less stable over a period of eleven years …

Laboratory Based Chemical And Isotopic Investigations On Biotic (Microbial) And Abiotic Reduction Of Iron And Oxidation Of Organic Compounds, Tsigabu Asmelash Gebrehiwet

Dissertations

Studies using chemical and isotopic techniques have been conducted to investigate experimental microbial (biotic) iron reduction and abiotic redox processes. In the microbially mediated study Fe(III) reduction and lactate oxidation at circum-neutral pH and anaerobic conditions were used to characterize the metabolic pathways followed by dissimilatory Fe⁺³ -reducing bacterium Shewanella putrefaciens strain 200R. Iron (II), Iron (III), dissolved inorganic carbon (DIC) and carbon isotope ratios were measured under bicarbonate and phosphate buffered conditions. Carbon isotope disproportionation among organic carbon substrate (lactate), biomass and respired carbon dioxide at the lag to stationary phase of the microbial growth curve showed …

Geophysical Monitoring Probes And Their Applications To Some Hydrogeological Problems, Laura Smart

Dissertations

Geophysical monitoring probes were constructed to monitor the vertical changes of water content and ion concentration in the subsurface. These devices contain electrodes for resistivity measurements and thermistors for temperature measurements. They are designed to monitor the resistivity and temperature of the saturated zone, the transition zone, and the vadose zone near a groundwater/surface water interface. Additional installations at the site include four monitoring wells and four Time Domain Reflectometry (TDR) access tubes, each paired with the geophysical probe installations. Pole-Pole resistivity measurements with an a-spacing of 5 cm are made using a CR1000 Campbell Scientific, Inc. datalogger. Automated data …

Thermodynamics Of Metals Adsorption Onto Uranium Dioxide, Koi Ling Lim

Masters Theses

Wastes and pollution containing uranium are released to the environment through mining, ore processing, industrial manufacture of nuclear fuel and weapons materials, and the disposal of spent nuclear fuel. There are a wide variety of processes that can affect UO₂ stability. This research focuses on the surface reactivity of UO₂ in reducing aqueous solutions, with an emphasis on assessment of the pH-dependent surface charge, reactive surface area, and the adsorption of dissolved lead (Pb), cadmium (Cd), lanthanum (La) onto UO₂ particles. A surface complexation model was used to explain the adsorption and titration phenomena of UO_{2 …}

Investigation Of Oxy-Anion Legand Adsorption Onto Surfaces Of Iron Oxide And Bacteria In Groundwater Aquifers, Haile Mengistu

Dissertations

We have measured adsorption of dissolved phosphate onto synthetic hydrous ferric oxide (HFO), dissolved arsenate and chromate onto the cell membrane of a bacterium species, S. putrefaciens as a function of pH, ionic strength, and relative concentrations of the respective oxy-ligands. Our experimental data were used to constrain optimal values for surface complexation reactions involving dissolved oxi-ligands (phosphate, and chromate) and the HFO surface and the cell membrane of S. putrefaciens respectively according to the diffuse layer model.

Our results provide a more accurate fit to experimental measurements over a broader range of pH (3 - 12), ionic strength and …

Characterization Of Fracture Systems In Sublette County, Wyoming Using P-Wave And C-Wave 3d Seismic, Keith R. Johnson

Masters Theses

Birefringence of seismic shear waves has proven to be a useful tool for identifying fracture intensity and orientation in the subsurface. Naturally occurring fractures have been shown to contribute to the deliverability of natural gas production in some reservoir formations in Rocky Mountain sedimentary basins. A multicomponent 3D 3C seismic survey acquired on the southeastern end of Pinedale Anticline in Sublette County, Wyoming was mapped to characterize fault systems within the sedimentary section. The tectonic and depositional history in the study area was determined by literature search and by one-dimensional backstripping. Compressional and wrench fault systems were observed and mapped. …

Field Studies Of Hydrophobic Filter Pack Performance In Free Product Monitoring And Recovery, Nathan J. Brandner

Masters Theses

Multiple field experiments were conducted to determine the performance of hydrophobic filter packs, compared to the hydrophilic industry standard filter pack in free product hydrocarbon recovery. Laboratory and field studies have been previously performed in support of enhancing free product hydrocarbon recovery with the use of hydrophobic filter pack designs. This study was an attempt to test the efficacy of using hydrophobic filter pack materials to enhance free product recovery.

Six recovery wells were installed at three field sites, each site utilizing a pair of recovery wells, one hydrophobic and one hydrophilic, to compare their performances. Fine-grained hydrophobic filter pack …

Sedimentology And Stratigraphy Of The Pennsylvanian Saginaw Aquifer, Central Lower Michigan, U.S.A., Niah B. H. Venable

Masters Theses

The Saginaw Aquifer is an important bedrock aquifer serving the needs of over 400,000 people in the Tri-County area of the Central Lower Peninsula of Michigan. The aquifer is comprised of the Pennsylvanian Grand River and Saginaw Formations. This study focuses on expanding existing knowledge of the general sedimentologic and stratigraphic characteristics of these units using conventional geological methods including core analysis, local log to core correlation, local and regional log to log correlation, and biostratigraphy. Analysis of new core from the study area examines facies and depositional environments given cursory coverage in outcrop studies by past researchers.

Incised valley …

Competitive Effects Of Uranyl-Organic Complexes On U(Vi) Reduction By Shewanella Putrefaciens, Abraham M. Northup

Masters Theses

Haas and DiChristina (2002) have demonstrated that Fe(III) reduction by the facultative Fe(III)-reducing bacterium S. putrefaciens is mediated by competitive speciation among dissolved organic ligands and functional groups on the cell surface. They also showed that rates of Fe(III) reduction by S. putrefaciens correlate with the thermodynamic stability constants of the Fe(III)-organic ligand complexes. S. putrefaciens can also use U(VI) as a terminal electron acceptor, coupling U(VI) reduction to growth. In this study, S. putrefaciens was incubated in experimental media containing U(VI) in the form of aqueous complexes with a variety of organic ligands that differ significantly in structure and …