Geology Commons^™

Using Geological Facies To Estimate Chromate Sorption To Soils, Victoria Smith, Daja Scurlock, Chauntilena Butler, Eddie Hollins, Kennedy Smith, Tim Spearman, Christina Fulghum, John Dickson, Daniel I. Kaplan, Miles Denham, Garriet Smith

Journal of the South Carolina Academy of Science

Quantifying the extent to which contaminant metals bind to subsurface soils is important for risk assessment, the tendency for a contaminant to migrate, and developing environmental remediation strategies. Unfortunately, subsurface soils vary widely in their composition, which in turn affect their tendency to bind metals. The hypothesis of this study was predicated on how a better understanding of geological facies would reduce uncertainty associated with predicting contaminant metal sorption. Facies are layers of sediment deposited in the subsurface due to similar depositional conditions, including energy of an overlying waterway. As such, facies are expected to have similar assemblages of minerals, …

Salt Tectonism In The Carolina Trough, Ceren Postaagasi

Theses and Dissertations

The Carolina Trough is a major linear sedimentary basin along the eastern continental margin of North America which formed as a result of tectonic and thermal subsidence during continental rifting in Mesozoic time (Hutchinson et al., 1982). The Carolina Trough is unique along the southeastern U.S. margin where the only known evaporite deposits are found, and this salt basin may reserve large amounts of oil and gas (Carpenter & Amato, 1992). Therefore, analysis of 2D multichannel seismic reflection surveys that were conducted in the Mid-South Atlantic Ocean in 1982 plays an important role in Petroleum industry. In addition, current interpretations …

The Impact Of Upland Development And Marsh Width On Groundwater Composition In Estuarine Tidal Creeks In The Southeastern Coastal United States, Meghan Shanahan

Theses and Dissertations

Coastal upland development has been shown to negatively impact surface water quality in tidal creeks along the southeastern coastal United States, but the impact of development on groundwater quality is not well understood. Increases in impervious cover associated with development has the potential to increase groundwater contamination as well as reduce fresh rainwater infiltration into the subsurface, which may decrease discharge of fresh groundwater to the estuary. We hypothesized that groundwater nutrient concentrations and salinity ranges would be higher in developed watersheds than in undeveloped watersheds.

Groundwater discharging from coastal uplands often travels through salt marshes before discharging to tidal …

The Sedimentary Record Of Eocene Deformation In The Interior Of The Southern Canadian Cordillera, Erica May Rubino

Theses and Dissertations

Eocene sedimentary strata exposed in the interior of the southern Canadian Cordillera (SCC) in British Columbia (BC) and northernmost Washington (WA) record a poorly understood history of extension-related deformation in the hinterland of the orogen. Today these strata are exposed in isolated, distinct outcrop belts, although the nature of the original basin(s) is unknown. We examined 650 m of Eocene strata, analyzed 2,995 detrital zircons for uranium-lead (U-Pb) ages, and measured 67 detrital zircons for Hf isotope systematics in an effort to better understand the physiography of the SCC during this time period. Eocene strata consist of clast- and matrix-supported …

Re-Evaluation Of The Extent And Tectonic History Of The Helena Banks Fault Zone, Offshore South Carolina, Ahmet Postaagasi

Theses and Dissertations

The Helena Banks Fault Zone (HBFZ), first identified in the early 1980’s offshore Charleston, S.C., was originally interpreted to be a major, high-angle, basin-bounding normal fault associated with Mesozoic rifting. Subsequent work suggests that (1) Mesozoic rift basins are not present on the continental shelf of South Carolina, (2) the HBFZ originated as a strike-slip fault within Paleozoic sedimentary rocks of the Suwannee Basin sequence, (3) a mafic intrusion inferred from aeromagnetic data is coincident with a broadly circular zone of highly-complex faulting along the north-eastward continuation of the HBFZ where (4) up to 300 m of local relief can …

Organic Acids And Amino Acids In Serpentinization Related Fluids From The Atlantis Massif, Nicholas Camper

Theses and Dissertations

Serpentinization is a low temperature, low pressure process that occurs when water reacts with ultramafic rocks. Fluids that have interacted with serpentinites have elevated concentrations of hydrogen and reduced carbon species that can fuel chemolithoautotrophy. International Ocean Discovery Program Expedition 357 drilled a series of boreholes into the Atlantis Massif with the goal of investigating how serpentinization impacts carbon cycling and sustains life in the subseafloor. Bottom water samples (CTD), fluids flushed from the boreholes during drilling (Rock Drill), and fluids that were trapped in the liners of the cores (Liner fluids) were collected. The changes and distributions of organic …

Assessment Of Upper Cretaceous Strata For Offshore Co2 Storage: Southeastern United States, Khaled F. Almutairi

Theses and Dissertations

This is the first assessment of Upper Cretaceous strata for offshore CO2 storage resources in the southeastern United States outer continental shelf. This research focuses on Upper Cretaceous geological units using legacy industry 2-D seismic reflection and well data. It provides an integrated description and reliable subsurface evaluation of Upper Cretaceous potential storage reservoirs. In addition, it provides a detailed evaluation on how rock porosities and permeabilities are distributed across the Upper Cretaceous strata restricted to the South Georgia Embayment (SGE). Structure and thickness (isochore) maps were generated for the main potential reservoirs and seals on a regional and local …

Utilizing Structure-From-Motion Photogrammetry And Unmanned Aerial Vehicles To Characterize Variability In Fluvial Deposits From The Salt Wash Member Of The Morrison Formation, East-Central Utah, John Chesley

Theses and Dissertations

Modern fluvial systems are highly variable, often containing the entire spectrum of fluvial styles (e.g., braided to meandering). This variability is difficult to capture in ancient fluvial deposits due to limited 1- and 2-dimesional exposures, which provide only a snapshot of the depositional history at one location. As a result, researchers are forced to interpolate between exposures and develop regional scale models that often underestimate the complexity and variability seen in modern environments. Outcrops of the Upper Jurassic Salt Wash Member of the Morrison Formation in east-central Utah, USA provide a relatively unique opportunity to examine ancient fluvial sandstone bodies …

Carbon Sources To Microbes And Cryoconite On Alaskan Alpine Glacier Surfaces, Drake Mccrimmon

Theses and Dissertations

Cryoconite are depressions in the ice surface filled with diverse microorganisms and dark debris, which are reducing albedo and increasing glacier melt. In order to understand cryoconite carbon composition and carbon sources to microorganisms living on glacier surfaces, bulk organic carbon and microbial lipids from supraglacial cryoconite sediment within the ablation zones of Spencer, Matanuska, and Mendenhall glaciers in southern Alaska have been coupled with radiocarbon (14C) analyses. The microbial lipids analyzed in these studies, phospholipid fatty acids (PLFA), are components of microbial membranes, quickly degrade after cell death, and give a snapshot of the viable microbial community. PLFA structure …

Drivers Of Sediment Accumulation And Nutrient Burial In Coastal South Carolina Residential Stormwater Detention Ponds, William Schroer

Theses and Dissertations

Stormwater detention ponds are widely utilized as control structures to manage runoff waters during storm events. These sediments also represent significant sites of organic carbon and nutrient burial. Here, carbon (C) and nutrient sources and burial rates were determined in 14 residential stormwater detention ponds throughout coastal counties of South Carolina. Bulk sediment accumulation was directly correlated with catchment impervious surface coverage (R2 = 0.90) with sediment accumulation rates ranging from 0.06 to 0.50 cm y-1. These rates of sediment accumulation and subsequent pond volume loss are lower than expected indicating that required maintenance dredging schedules be reassessed. Strong, positive …

Tectonic Studies Of Southeastern North America: The Suwannee Basin, Brunswick Suture Zone, Osceola Arc, And Pangean Transcurrent Fault System, Susannah Katherine Boote

Theses and Dissertations

A series of exotic terranes with complex tectonostratigraphic relationships construct the North American margin and record information critical to understanding the evolution of the Appalachian orogen. The Coastal Plain cover remains a challenge in this region; however, synthesis of seismic reflection, seismic refraction, well, and aeromagnetic data allows for a substantially revised interpretation of the basement rocks and structures that comprise the pre-Mesozoic crust of southeastern North America. These data reveal: (1) a Neoproterozoic subduction zone and paired continental-margin arc are preserved in Gondwanan crust in southeastern North America, (2) the Gondwanan Suwannee Basin of Early to Mid-Paleozoic age is …

High Resolution Gravity, Helicopter Magnetic, And Electromagnetic Study, Haile Gold Mine, South Carolina, Saad Saud Alarifi

Theses and Dissertations

The goal of this research was to calibrate and test geophysical methods for the detection of disseminated sulfides in the area of the Haile Gold Mine, South Carolina. The work focused on the calibration of high resolution gravity, and helicopter electromagnetic (EM) and magnetic data provided by OceanaGold. While high resolution potential field data (gravity and magnetics) has not been proven to be effective at small scales in exploration for disseminated sulfides, there is a strong regional correlation between high amplitude gravity and magnetic anomalies and the most productive gold mines in the Carolina terrane. Helicopter EM methods have been …

Glacial To Holocene Changes In Eastern Equatorial Pacific Deep-Water Chemistry And Circulation, Natalie E. Umling

Theses and Dissertations

It has been hypothesized that the oceans store CO2 during glacial periods and then release it to the atmosphere, causing the onset of warm interglacial periods (Sigman and Boyle, 2000). Documenting this past transfer of CO2 between the oceans and atmosphere is of utmost importance for better understanding the impact that anthropogenic CO2 has and will have on Earth’s climate. The last deglaciation is a good analogue to modern increases in CO2 and temperature and is recent enough to be studied using radiocarbon. This period provides important insights into the nature of climate changes during the transition from glacial to …

Subsurface Transport In A North Inlet, South Carolina Salt Marsh: A Porewater Salinity Model, Carolyn Ryan

Theses and Dissertations

Subsurface transport in coastal salt marshes influences the nutrient budget of coastal environments, but is not fully understood. To expand our understanding of this transport, a simple numerical model was developed. The model simulated vertical transport of salt through the surficial muds at a North Inlet marsh on the coastal plain of South Carolina. To improve the model, a tracer study was utilized to calculate the average velocity of groundwater flow through the system. The model was compared with porewater salinity measured using tension samplers and passive diffusion samplers. Each method produced different, uncorrelated results. However, accounting for macro-pores in …

Serpentinization And Synthesis: Searching For Abiotic And Biotic Non-Volatile Organic Molecules In The Subsurface Of The Atlantis Massif, Katherine A. Hickok

Theses and Dissertations

High concentrations of hydrogen created during serpentinization can promote the formation of abiotic organic carbon molecules such as methane, formate, and short chain hydrocarbons and, in laboratory experiments, larger molecules containing up to 32 carbon atoms. Subsurface archaeal and bacterial communities can use these reduced compounds for metabolic energy. International Ocean Discovery Project Expedition 357 drilled 17 boreholes into the Atlantis Massif with the goals of investigating carbon cycling and the presence of life in a zone of active serpentinization. The expedition recovered multiple lithologies including gabbros, basalts, carbonate sands, and serpentinites. A subset of contrasting lithologies were analyzed for …

The Summerville Formation: Evidence For A Sub-Horizontal Stratigraphic Sequence Below The Post-Rift Unconformity In The Middleton Place Summerville Seismic Zone, Joseph Edward Getz

Theses and Dissertations

The Middleton Place Summerville Seismic Zone (MPSSZ) near Summerville, South Carolina was the site of renewed extensive investigation, beginning in the 1970’s, for the source of the 1886 Charleston earthquake. Reactivation of faults associated with a putative fault-bounded Triassic rift basin through analysis of seismic reflection, seismic refraction, and well data has since become the favored interpretation for the source of MPSSZ seismicity. Critical to this interpretation is the association of continental redbed sedimentary rocks in Triassic basins throughout the North American Atlantic margin. Reanalysis of 18 seismic reflection profiles and 25 seismic refraction profiles within the MPSSZ suggests that …

Small Mud And Sand Filled Paleochannels Offshore Charleston, Sc, Erin Smoak

Theses and Dissertations

The spatial variations of Quaternary sediments on the continental shelf record the progression of depositional environments during the latest sea-level rise, and are fundamental controls on submarine groundwater discharge (SGD) flow. SGD on continental shelves is an important but poorly constrained process. Spatial variations of lithologies on continental shelves, such as sand-filled paleochannels, are assumed to play a fundamental role in controlling where SGD occurs but coincident seismic mapping and sedimentological data are rare. Here we combine seismic mapping of paleochannel locations with sediment cores to examine the sedimentary characteristics of paleochannel fill and interfluvial deposits. To establish paleochannel locations …

Platinum Decoupling From Pge In Peridotitic Sulfides From The St. Elena Ophiolite In Costa Rica, Jessica A. Holm

Theses and Dissertations

The platinum group elements (Os, Ir, Ru, Rh, Pt, Pd) are important petrogenetic tracers of mantle processes and the Re-Os isotope system an important tool for tracing ancient depletion and refertilization processes in the mantle. A key characteristic of these elements is that they are siderophile and chalcophile, and their abundance in the Earth’s mantle is thought to be controlled by sulfides. Existing thermodynamic data suggests that at reducing conditions similar to those found at the early stages of serpentinization, PGE may exist as alloys in the mantle. While numerous studies report on the bulk peridotite PGE and sulfide PGE …

Behavior Of Rare Earth Elements And High-Field Strength Elements During Peridotite - Seawater Interaction, Carl Pasquale Frisby

Theses and Dissertations

Serpentinized abyssal peridotites are evidence for active communication between the Earth’s hydrosphere and the upper mantle, where exchange and retention of both major and trace elements occur. Rare earth elements (REE) and high-field strength elements (HFSE: Ti, Zr, Hf, Nb, Ta) are generally thought of as immobile during serpentinization. In partially serpentinized abyssal peridotites, clinopyroxenes typically retain radiogenic Nd and Hf isotopic signatures that have been used to infer the composition and high temperature processes in the upper mantle. However, bulk rock Nd isotopes in some serpentinized abyssal peridotites less radiogenic values that approach that of seawater, which has been …

An Integrated Structural Analysis On Seismic Of A Paleo Mound Development (Woolsey Mound, Northern Gulf Of Mexico), Ricardo Tomas Troco Kabila

Theses and Dissertations

Woolsey Mound is ~1 km diameter thermogenic gas hydrate and cold seep (GHCS) complex system. It is located at ~900 m water depth in the Mississippi Canyon Lease Block 118 (MC–118) on the upper continental slope of the northern Gulf of Mexico (GOM). Due to its complex geology, widespread hydrate seepage activity and presence of benthic habitat, the mound serves as a permanent research site for a multidisciplinary seafloor observatory, thus providing insights into the dynamics of shallow fluid expulsion, their spatial and time variations and possible geological forcing mechanisms.

This study utilizes a set of high resolution 2D autonomous …

Ecohydrology And Groundwater Dynamics In A Salt Marsh Island, Andrea L. H. Hughes

Theses and Dissertations

Tidal salt marshes are extraordinarily productive and valuable ecosystems that provide via groundwater a not insignificant portion of coastal solute and nutrient budgets. Among the many goods and services they provide are habitat for diverse wildlife, protection for coastal communities during storms, and protection for coastal surface waters by filtering anthropogenic pollutants. One threat to the health of tidal salt marshes along the East Coast have been episodes of Acute Marsh Dieback (AMD) from 1999 to 2001. Dieback was observed at North Inlet salt marsh from 2000 to 2001. Since salt marsh hydrology is dominated by the local tidal regime, …

From Near And Far: Utilization Of In-Situ And Remotely Sensed Satellite Data From Nasa And Noaa, Jessica Rochelle Price Sutton

Theses and Dissertations

Satellite remote sensing observations have been used for numerous studies to better understand physical and biological properties over varying spatial and temporal scales. Depending on the satellite and sensor, the satellite-derived observations can provide high spatial and temporal resolution for many important physical and biological variables. While there are many limitations in utilizing satellite remote sensing products, there are also many advantages. This dissertation investigates three different applications for satellite remote sensing products to address climatological and ecological concerns. This dissertation is motivated by two overall research questions: (1) How can satellite remote sensing products be used to address important …

Implications Of Hf-Nd Isotopes In West Philippine Basin Basalts For The Initiation And Early History Of The Izu-Bonin-Mariana Arc, Benjamin D. Hocking

Theses and Dissertations

Drilling at Site U1438, located immediately west of Kyushu-Palau Ridge (KPR), the site of IBM subduction initiation, penetrated 1,460 m of volcaniclastic sedimentary rock and 150 m of underlying basement. Biostratigraphic controls indicate a probable age for the oldest sedimentary rocks at around 55 Ma. This is close to the 48-52 Ma time period of IBM subduction initiation, based on studies in the forearc. There, the first products of volcanism are tholeiitic basalts termed FAB (forearc basalt), which are more depleted than average MORB and show subtle indicators of geochemical enrichment due to subduction. Site U1438 basement basalts share many …

Neuro-Fuzzy Classification Of Felsic Lava Geomorphology At Alarcon Rise, Mexico, Christina Hefron Maschmeyer

Theses and Dissertations

The Alarcon Rise is the only submarine oceanic spreading ridge setting where rhyolitic lavas have been found. This intermediate-rate spreading ridge provides a unique natural laboratory for studying the geomorphology of felsic submarine lava flows at oceanic spreading ridges. Seafloor observations of felsic lava indicate the flow morphology differs from typical submarine basaltic lava at the few other oceanic spreading ridges where differentiated compositions have been recorded. Morphologic variation between mafic and felsic lava flows, especially rhyolites, was also observed at Alarcon Rise.

The Monterey Bay Aquarium Research Institute conducted mapping surveys with autonomous underwater vehicle D Allan B. in …

Submarine Groundwater Discharge And The Configuration Of The Freshwater-Saltwater Interface At The Nearshore And Embayment Scales, Tyler Brandon Evans

Theses and Dissertations

Submarine groundwater discharge (SGD) rivals riverine discharge to the world’s oceans but remains poorly understood. Until the early 1990’s, geochemical budgets for the ocean were developed using material fluxes from rivers only. SGD has been shown to carry high concentrations of dissolved nutrients, metals and carbon. However, SGD is a difficult to measure, complex phenomenon driven by multiple physical processes. Groundwater flow and the resultant chemical exchange at the land-sea interface are heavily impacted by the hydrodynamic effects of mixing between variable-density fluids. In order to better understand SGD, investigations have focused on the configuration of the freshwater-saltwater interface in …

Alongshore Momentum Balance Over Shoreface-Connected Ridges, Fire Island, Ny, Conor Ofsthun

Theses and Dissertations

Bathymetric variations, such as shoreface-connected ridges (SFCRs), modify inner shelf circulation, altering the significance of and relationships between alongshore momentum balance terms. The inner shelf of Fire Island, NY provides a study site representative of SFCRs around the world. During the winter of 2014, hydrodynamic observations (~12 m depth) from 6 ADCPs, 3 SeaGauge pressure sensors, 2 tide gauges, and 2 meteorological buoys were collected over a region of the inner shelf spanning a full wavelength of one such SFCR. Analysis of the data, under westward wind forcing, revealed a predominantly alongshore circulation with localized offshore (onshore) current veering over …

Three Dimensional Thermobaric Modeling Of A Gas Hydrate System, Amanda Quigley Williams

Theses and Dissertations

Seismic imaging is recognized as the most cost effective method for identifying the presence of gas hydrate resources. The base of the gas hydrate stability zone is recognized by the presence of regionally extensive bottom simulating reflectors (BSR). However, in some areas such as the Gulf of Mexico, regionally extensive BSRs are not found. In such cases, an understanding of the thermobaric conditions may be used to determine the location of gas hydrates and the base of the gas hydrate stability zone. The aim of this research is to combine seismic velocity analysis and thermal modeling to predict the base …

Delineation Of The Lower Permian Gas Sand Via Calibrated Avo And Pre-Stack Seismic Inversions In Majhol Field, Saudi Arabia, Abdullah Alhashel

Theses and Dissertations

The lower Permian formation in the central region of Saudi Arabia is a key hydrocarbon siliciclastic reservoir. However, in Majhol field, the reservoir properties vary laterally due to diagenesis and facies changes. Conventional seismic interpretation has failed to map the heterogeneities of the reservoir properties that control the gas production of this field. Therefore, there was an opportunity to employ more advanced quantitative seismic techniques to delineate the productive gas sand facies in the field.

The Majhol field was initially planned to be developed as an unconventional tight reservoir. Well-1 was drilled based on conventional seismic interpretation on the crest …

3d Seismic Depth Imaging And Velocity Model Building In Anisotropic Media: Serri Oil And Gas Field, Saudi Arabia, Ali Jomaah Alsalem

Theses and Dissertations

Seismic imaging is a significant element in hydrocarbon exploration to locate drilling prospects and it relies mainly on an accurate velocity model. Prestack depth migration (PreSDM) versus traditional post-stack time migration has become a common method for seismic velocity model building and imaging. This methodology accounts for seismic velocity anisotropy of the propagating waves in the subsurface with a higher level of accuracy in positioning the seismic events in their true positions in the subsurface.

In this thesis, we examine a 303 km2 of 3D seismic data acquired by Saudi Aramco in the Serri field of North-West Saudi Arabia. The …

Utilization Of Satellite-Derived Salinity For Enso Studies And Climate Indices, Caroline Mary Corbett

Theses and Dissertations

Conventionally, El Niño-Southern Oscillation (ENSO) is studied using sea surface temperature (SST) observations in the central and eastern equatorial Pacific Ocean. Recently, sea surface salinity (SSS) in the equatorial Pacific has been studied in relation to the phases of ENSO. Previously, SSS was observed in the equatorial Pacific using the Tropical Ocean Global Atmosphere (TOGA) / Tropical Atmosphere Ocean (TOA), the Argo float network, and Oceanic General Circulation Models (OGCM). The launch of NASA’s Aquarius Salinity Mission and ESA’s Soil Moisture Ocean Salinity (SMOS) opened a new era in which high resolution global near real-time SSS observations are readily available. …