Geology Commons^™

Production And Composition Of Pyrogenic Dissolved Organic Matter From A Logical Series Of Laboratory-Generated Chars, Kyle W. Bostick, Andrew R. Zimmerman, Andrew S. Wozniak, Siddhartha Mitra, Patrick G. Hatcher

Chemistry & Biochemistry Faculty Publications

Though pyrogenic carbon (pyC) has been assumed to be predominantly stable, degradation and transfers of pyC between various pools have been found to influence its cycling and longevity in the environment. Dissolution via leaching may be the main control on loss processes such as microbial or abiotic oxidation, mineral sorption, or export to aquatic systems. Yet, little is known about the controls on pyrogenic dissolved organic matter (pyDOM) generation or composition. Here, the yield and composition of pyDOM generated through batch leaching of a thermal series of oak and grass biochars, as well as several non-pyrogenic reference materials, was compared …

Evidence For Ephemeral Middle Eocene To Early Oligocene Greenland Glacial Ice And Pan-Arctic Sea Ice, Aradhna Tripati, Dennis Darby

OES Faculty Publications

Earth's modern climate is defined by the presence of ice at both poles, but that ice is now disappearing. Therefore understanding the origin and causes of polar ice stability is more critical than ever. Here we provide novel geochemical data that constrain past dynamics of glacial ice on Greenland and Arctic sea ice. Based on accurate source determinations of individual ice-rafted Fe-oxide grains, we find evidence for episodic glaciation of distinct source regions on Greenland as far-ranging as ~68°N and ~80°N synchronous with ice-rafting from circum-Arctic sources, beginning in the middle Eocene. Glacial intervals broadly coincide with reduced CO_{2 …}

Volcanogenic Pseudo-Fossils From The ~3.48 Ga Dresser Formation, Pilbara, Western Australia, David Wacey, Nora Noffke, Martin Saunders, Paul Guagliardo, David M. Pyle

OES Faculty Publications

The ~ 3.48 billion-year-old Dresser Formation, Pilbara Craton, Western Australia, is a key geological unit for the study of Earth's earliest life and the habitats it occupied. Here, we describe a new suite of spheroidal to lenticular microstructures that morphologically resemble some previously reported Archean microfossils. Correlative microscopy shows that these objects have a size distribution, wall ultrastructure, and chemistry that are incompatible with a microfossil origin and instead are interpreted as pyritized and silicified fragments of vesicular volcanic glass. Organic kerogenous material is associated with much of the altered volcanic glass; variable quantities of organic carbon line or fill …

Climate-Change-Driven Accelerated Sea-Level Rise Detected In The Altimeter Era, R. S. Nerem, B. D. Beckley, J. T. Fasullo, B. D. Hamlington, D. Masters, G. T. Mitchum

CCPO Publications

Using a 25-y time series of precision satellite altimeter data from TOPEX/Poseidon, Jason-1, Jason-2, and Jason-3, we estimate the climate-change-driven acceleration of global mean sea level over the last 25 y to be 0.084 ± 0.025 mm/y². Coupled with the average climate-change-driven rate of sea level rise over these same 25 y of 2.9 mm/y, simple extrapolation of the quadratic implies global mean sea level could rise 65 ± 12 cm by 2100 compared with 2005, roughly in agreement with the Intergovernmental Panel on Climate Change (IPCC) 5th Assessment Report (AR5) model projections.

Global Sea-Level Budget 1993-Present, Wcrp Global Sea Level Budget Group, Benjamin Hamlington

CCPO Publications

Global mean sea level is an integral of changes occurring in the climate system in response to unforced climate variability as well as natural and anthropogenic forcing factors. Its temporal evolution allows changes (e.g.,acceleration) to be detected in one or more components. Study of the sea-level budget provides constraints on missing or poorly known contributions, such as the unsurveyed deep ocean or the still uncertain land water component. In the context of the World Climate Research Programme Grand Challenge entitled "Regional Sea Level and Coastal Impacts", an international effort involving the sea-level community worldwide has been recently initiated with the …

Precipitation And Sea Level Rise Impacts On Groundwater Levels In Virginia Beach, Virginia, Brett A. Buzzanga

OES Theses and Dissertations

Global sea level rise (SLR) is one of the most immediate impacts of climate change, and poses a significant threat to low-lying coastal communities worldwide. The metropolitan region of Hampton Roads in Southeastern Virginia is one such community, and one where knowledge surrounding SLR is rapidly accumulating. However, most of the research is focused exclusively on surface water processes despite the presence of a shallow groundwater table closely connected to them. SLR will continue to cause the groundwater table to increase in tidally influenced areas of Hampton Roads, and thereby decrease storage capacity of the unsaturated zone.

This study investigates …

Robustness Of Observation-Based Decadal Sea Level Variability In The Indo-Pacific Ocean, A. G. Nidheesh, M. Lengaigne, J. Vialard, T. Izumo, A. S. Unnikrishnan, B. Meyssignac, B. Hamlington, C. De Boyer Montegut

OES Faculty Publications

We examine the consistency of Indo-Pacific decadal sea level variability in 10 gridded, observation-based sea level products for the 1960-2010 period. Decadal sea level variations are robust in the Pacific, with more than 50% of variance explained by decadal modulation of two flavors of El Nino-Southern Oscillation (classical ENSO and Modoki). Amplitude of decadal sea level variability is weaker in the Indian Ocean than in the Pacific. All data sets indicate a transmission of decadal sea level signals from the western Pacific to the northwest Australian coast through the Indonesian throughflow. The southern tropical Indian Ocean sea level variability is …

Hydrologic Response Caused By Wetland Expansion At Huntley Meadows Park In Hybla Valley, Virginia, Stephen Fraser Stone

OES Theses and Dissertations

The goal of this study was to understand the effects of wetland expansion across a watershed. The 2013 restoration and expansion of the wetlands at Huntley Meadows Park (Fairfax County, VA) performed by Wetland Studies and Solutions, Inc. provided the opportunity to study this process. The 630 ha park contains more than 364 ha of freshwater emergent and freshwater forested wetlands. The restoration and expansion project used a subsurface vinyl-piling dam that impedes groundwater flow leaving the wetland, thus expanding the existing pond and the surrounding wetland.

This study used a network of more than twenty monitoring instruments making observations …

Groundwater And Tidal Controls On Wetland Hydrology, Julie J. Metz Wetland Mitigation Bank, Woodbridge, Virginia, Benjamin Stuart Hiza

OES Theses and Dissertations

Julie J. Metz Wetlands Mitigation Bank, a 92-hectare freshwater wetland located in Woodbridge, Virginia, borders the tidally-influenced Neabsco Creek. Seven pods separated by earthen berms were built by Wetland Studies and Solutions Inc. (WSSI) in 1995 and 1997 by removing the toe of small sandy alluvial fans and covering the underlying coarse gravel bed with a low permeability cap. The basal Quaternary gravels were deposited in a creek valley incised into a thick sand-and-clay Cretaceous delta. The alluvial-fan apron developed at the base of steep slopes along the sides of the valley. Pressure transducer data from five monitoring wells along …

Upper Water Structure And Mixed Layer Depth In Tropical Waters: The Seats Station In The Northern South China Sea, Jen-Hua Tai, George T. F. Wong, Xiaoju Pan

OES Faculty Publications

The variability of the upper water hydrographic structure, the efficacy of the different schemes for estimating the mixed layer depth (MLD), the inter-comparability estimation of the MLDs and diurnal and intra-annual MLD climatology in the tropical waters in the northern South China Sea were accessed in 702 depth-profiles of potential temperature (θ) and salinity collected in 64 cruises between 17.5 and 18.5°N and 115.3 and 116.3°E from 1997 to 2013. The hydrographic structure may be subdivided into three principal types: the classical type, with quasi-isopycnal surface mixed layer followed by an abrupt increase in the depth-gradient in θ and potential …

Holocene Cyclic Records Of Ice-Rafted Debris And Sea Ice Variations On The East Greenland And Northwest Iceland Margins, D. A. Darby, J. T. Andrews, S. T. Belt, A. E. Jennings, P. Cabedo-Sanz

OES Faculty Publications

The dynamics of the Greenland Ice Sheet and drift of sea ice from the Arctic Ocean reaching Denmark Strait are poorly constrained. We present data on the provenance of Fe oxide detrital grains from two cores in the Denmark Strait area and compare the Fe grain source data with other environmental proxies in order to document the variations and potential periodicities in ice-rafted debris delivery during the Holocene. Based on their Fe grain geochemistry, the sediments can be traced to East Greenland sources and to more distal sites around the Arctic Basin. On the Holocene time scales of the two …

Exploring The Reasons For The Seasons Using Google Earth, 3d Models, And Plots, Declan G. De Paor, Mladen M. Dordevic, Paul Karabinos, Stephen Burgin, Filis Coba, Steven J. Whitmeyer

Physics Faculty Publications

Public understanding of climate and climate change is of broad societal importance. However, misconceptions regarding reasons for the seasons abound amongst students, teachers, and the public, many of whom believe that seasonality is caused by large variations in Earth's distance from the Sun. Misconceptions may be reinforced by textbook illustrations that exaggerate eccentricity or show an inclined view of Earth's near-circular orbit. Textbook explanations that omit multiple factors influencing seasons, that do not mesh with students' experiences, or that are erroneous, hinder scientifically valid reasoning. Studies show that many teachers share their students' misconceptions, and even when they understand basic …

Subsidence Monitoring In Hampton Roads Using Satellites, Ben Hamlington

July 29, 2016: The Latest in Sea Level Rise Science

No abstract provided.

Reevaluating The Geologic Formations Of The Upper Coastal Plain In Chesterfield County, South Carolina, Bradley Aaron Fitzwater

OES Theses and Dissertations

Data from a new geological map of the Patrick, S.C. 7.5 minute quadrangle (1:24,000) and detailed descriptions of two cores collected nearby (Middendorf and Cheraw, S.C.) permit improved interpretation of the geology of this portion of the Carolina Sandhills. Geologic mapping incorporated analyses of outcrops with LiDAR data, soil survey maps, ground-penetrating radar transects, and hand auger borings. Micro- and macrofossil identification and optically-stimulated luminescence (OSL) dating provided age control.

Four distinct mappable units occur throughout the Patrick quadrangle. Resting unconformably on schist of the Paleozoic Persimmons Fork Formation, the Cretaceous Middendorf Formation is more than 85.3 m thick and …

Developing Priority Variables (“Ecosystem Essential Ocean Variables” — Eeovs) For Observing Dynamics And Change In Southern Ocean Ecosystems, Andrew J. Constable, Daniel P. Costa, Oscar Schofield, Louise Newman, Edward R. Urban Jr., Elizabeth A. Fulton, Jessica Melbourne-Thomas, Tosca Ballerini, Philip W. Boyd, Angelika Brandt, Eileen E. Hofmann

CCPO Publications

Reliable statements about variability and change in marine ecosystems and their underlying causes are needed to report on their status and to guide management. Here we use the Framework on Ocean Observing (FOO) to begin developing ecosystem Essential Ocean Variables (eEOVs) for the Southern Ocean Observing System (SOOS). An eEOV is a defined biological or ecological quantity, which is derived from field observations, and which contributes significantly to assessments of Southern Ocean ecosystems. Here, assessments are concerned with estimating status and trends in ecosystem properties, attribution of trends to causes, and predicting future trajectories. eEOVs should be feasible to collect …

Tropical North Atlantic Subsurface Warming Events As A Fingerprint For Amoc Variability During Marine Isotope Stage 3, Andrew O. Parker, Matthew W. Schmidt, Ping Chang

OES Faculty Publications

The role of Atlantic Meridional Overturning Circulation (AMOC) as the driver of Dansgaard-Oeschger (DO) variability that characterized Marine Isotope Stage 3 (MIS 3) has long been hypothesized. Although there is ample proxy evidence suggesting that DO events were robust features of glacial climate, there is little data supporting a link with AMOC. Recently, modeling studies and subsurface temperature reconstructions have suggested that subsurface warming across the tropical North Atlantic can be used to fingerprint a weakened AMOC during the deglacial because a reduction in the strength of the western boundary current allows warm salinity maximum water of the subtropical gyre …

Molecular Level Characterization Of Diatom-Associated Biopolymers That Bind 234th, ²³³Pa, ²¹°Pb, And 7be In Seawater: A Case Study With Phaeodactylum Tricornutum, Chia-Ying Chuang, Peter H. Santschi, Chen Xu, Yuelu Jiang, Yi-Fang Ho, Patrick G. Hatcher

Chemistry & Biochemistry Faculty Publications

In order to investigate the importance of biogenic silica associated biopolymers on the scavenging of radionuclides, the diatom Phaeodactylum tricornutum was incubated together with the radionuclides Th-234, Pa-233, Pb-210, and Be-7 during their growth phase. Normalized affinity coefficients were determined for the radionuclides bound with different organic compound classes (i.e., proteins, total carbohydrates, uronic acids) in extracellular (nonattached and attached exopolymeric substances), intracellular (ethylene diamine tetraacetic acid and sodium dodecyl sulfate extractable), and frustule embedded biopolymeric fractions (BF). Results indicated that radionuclides were mostly concentrated in frustule BF. Among three measured organic components, Uronic acids showed the strongest affinities to …

Theoretical Foundation Of Cyclostationary Eof Analysis For Geophysical And Climatic Variables: Concepts And Examples, Kwang-Yul Kim, Benjamin Hamlington, Hanna Na

CCPO Publications

Natural variability is an essential component of observations of all geophysical and climate variables. In principal component analysis (PCA), also called empirical orthogonal function (EOF) analysis, a set of orthogonal eigenfunctions is found from a spatial covariance function. These empirical basis functions often lend useful insights into physical processes in the data and serve as a useful tool for developing statistical methods. The underlying assumption in PCA is the stationarity of the data analyzed; that is, the covariance function does not depend on the origin of time. The stationarity assumption is often not justifiable for geophysical and climate variables even …

Use Of Esi-Fticr-Ms To Characterize Dissolved Organic Matter In Headwater Streams Draining Forest-Dominated And Pasture-Dominated Watersheds, Yuehan Lu, Xiaping Li, Rajaa Mesfioui, James E. Bauer, R. M. Chambers, Elizabeth A. Canuel, Patrick G. Hatcher

Chemistry & Biochemistry Faculty Publications

Electrospray ionization Fourier transform ion cyclotron resonance mass spectrometry (ESI-FTICR-MS) has proven to be a powerful technique revealing complexity and diversity of natural DOM molecules, but its application to DOM analysis in grazing-impacted agricultural systems remains scarce. In the present study, we presented a case study of using ESI-FTICR-MS in analyzing DOM from four headwater streams draining forest-or pasture-dominated watersheds in Virginia, USA. In all samples, most formulas were CHO compounds (71.8-87.9%), with other molecular series (CHOS, CHON, CHONS, and CHOP (N, S)) accounting for only minor fractions. All samples were dominated by molecules falling in the lignin-like region (H/C …

Crustal Accretion And Mantle Geodynamics At Microplates: Constraints From Gravity Analysis And Numerical Modeling, Katherine Ames

OES Theses and Dissertations

This study investigates crustal accretion and mantle geodynamics at microplates using mantle Bouguer anomaly (MBA) gravity calculations and exploratory numerical models. The Easter and Juan Fernandez microplates are located in the eastern Pacific Ocean along the Pacific, Nazca, and Antarctic plate boundaries. Both microplates formed 3-5 Ma and they are currently rotating clockwise at 15° myr^-1 and 9° myr^-1,respectively [ e.g., Searle et al., 1993]. The study area also encompasses the Easter /Salas y Gomez mantle plume located near the Easter microplate. Both microplates show a difference in average MBA between their west and east ridges, with …

Did A Submarine Landslide Contribute To The 2011 Tohoku Tsunami?, David R. Tappin, Stephan T. Grilli, Jeffrey C. Harris, Robert J. Geller, Timothy Masterlark, James T. Kirby, Fengyan Shi, Gangfeng Ma, K.K.S. Thingbaijam, P. Martin Mai

Civil & Environmental Engineering Faculty Publications

Many studies have modeled the Tohoku tsunami of March 11, 2011 as being due entirely to slip on an earthquake fault, but the following discrepancies suggest that further research is warranted. (1) Published models of tsunami propagation and coastal impact underpredict the observed runup heights of up to 40. m measured along the coast of the Sanriku district in the northeast part of Honshu Island. (2) Published models cannot reproduce the timing and high-frequency content of tsunami waves recorded at three nearshore buoys off Sanriku, nor the timing and dispersion properties of the waveforms at offshore DART buoy #21418. (3) …

Hydrogeologic Variations Across A Barrier Island That Influence Inter-Dune Wetlands False Cape State Park, Virginia, Matthew Collier Richardson

OES Theses and Dissertations

False Cape State Park in southeastern Virginia Beach, Virginia contains a transgressive barrier island complex. Inter-dune swales located on the eastern coast of the barrier island contain soils that experience hydric conditions. However, these swales lack the prolonged presence of hydric soil indicators that are necessary for a site to be officially recognized as a jurisdictional wetland. The appearance and subsequent disappearance of redoximorphic wetland soil features in the young, sandy soils of the inter-dune swales here may stem from changes in the patterns of groundwater recharge and discharge across the island. These soils are being monitored by the Mid …

Distributions Of Particulate Heme B In The Atlantic And Southern Oceans- Implications For Electron Transport In Phytoplankton, Martha Gledhill, Eric P. Achterberg, David J. Honey, Maria C. Nielsdottir, Micha J.A. Rijkenberg

OES Faculty Publications

Concentrations of heme b, the iron-containing component of b-type hemoproteins, ranged from b concentrations were enhanced in the photic zone and decreased with depth. Heme b concentrations correlated positively with chlorophyll a (chl a) in the TNA (r=0.41, pb did not correlate with chl a in the IB or SS. In the IB and SS, stations with high-chlorophyll and low-nutrient (Fe and/or Si) concentrations exhibited low heme bconcentrations relative to particulate organic carbon (< 0.1 μmolmol^-1, and high chl a:heme b ratios (> 500). High chl a:heme b ratios resulted from relative decreases in …

Microbially Induced Sedimentary Structures Recording An Ancient Ecosystem In The Ca. 3.48 Billion-Year-Old Dresser Formation, Pilbara, Western Australia, Nora Noffke, Daniel Christian, David Wacey, Robert M. Hazen

OES Faculty Publications

Microbially induced sedimentary structures (MISS) result from the response of microbial mats to physical sediment dynamics. MISS are cosmopolitan and found in many modern environments, including shelves, tidal flats, lagoons, riverine shores, lakes, interdune areas, and sabkhas. The structures record highly diverse communities of microbial mats and have been reported from numerous intervals in the geological record up to 3.2 billion years (Ga) old. This contribution describes a suite of MISS from some of the oldest well-preserved sedimentary rocks in the geological record, the early Archean (ca. 3.48 Ga) Dresser Formation, Western Australia. Outcrop mapping at the meter to …

Stromatolites And Miss—Differences Between Relatives, N. Noffke, S. M. Awramik

OES Faculty Publications

Benthic microorganisms form highly organized communities called “biofilms.” A biofilm consists of the individual cells plus their extracellular polymeric substances (EPS). In marine and non-marine environments, benthic microbial communities interact with the physical sediment dynamics and other factors in the environment in order to survive. This interaction can produce distinctive sedimentary structures called microbialites. Binding, biostabilization, baffling, and trapping of sediment particles by microorganisms result in the formation of microbially induced sedimentary structures (MISS); however, if carbonate precipitation occurs in EPS, and these processes happen in a repetitive manner, a multilayered build-up can form—stromatolites. Stromatolites and MISS are first found …

Gravity Anomalies Along The East Scotia Ridge: Constraining The Relative Importance Of Magmatic And Tectonic Controls On Crustal Accretion, Briton Lee Nicholson

OES Theses and Dissertations

Similar to regions such as the Lau Basin and the Caribbean Sea, the eastern Scotia Sea is a geologically complex area that involves multiple plate boundary types. This study uses bathymetry and gravity data to infer upper mantle geodynamics in the eastern Scotia Sea region. Beneath this region is an intermediate-rate back-arc spreading center known as the East Scotia Ridge (ESR) that forms the boundary between the Scotia and Sandwich plates. To the east of the ESR are the South Sandwich island arc and the South Sandwich Trench. The ESR is a relatively young feature, with spreading estimated to have …

A New Phase Speciation Leaching Procedure For The Determination Of Metals In Oxic And Anoxic Sediments, Brandon R. Gipson

OES Theses and Dissertations

Toxic trace elements such as cadmium, lead, chromium, and arsenic released by human activities can accumulate in marine and estuarine sediments, where these metals are often sequestered until local environmental changes (e.g., redox, salinity, and/or pH) allow these elements to be reintroduced into the food web. In order to assess the extent of toxic trace element contamination in sediment, numerous leaching schemes have been developed that separate sediment-bound trace metals into operationally defined geochemical phases. These "phase speciation" leaching schemes are typically designed with the purpose of being used on either oxic or anoxic sediments. However, natural sediments often contain …

Impact Of Abrupt Deglacial Climate Change On Tropical Atlantic Subsurface Temperatures, Matthew W. Schmidt, Ping Chang, Jennifer E. Hertzberg, Theodore R. Them Ii, Link Li, Bette L. Otto-Bliesner

OES Faculty Publications

Both instrumental data analyses and coupled ocean-atmosphere models indicate that Atlantic meridional overturning circulation (AMOC) variability is tightly linked to abrupt tropical North Atlantic (TNA) climate change through both atmospheric and oceanic processes. Although a slowdown of AMOC results in an atmospheric-induced surface cooling in the entire TNA, the subsurface experiences an even larger warming because of rapid reorganizations of ocean circulation patterns at intermediate water depths. Here, we reconstruct high-resolution temperature records using oxygen isotope values and Mg/Ca ratios in both surface- and sub-thermocline-dwelling planktonic foraminifera from a sediment core located in the TNA over the last 22 ky. …

Deglacial Variability Of Antarctic Intermediate Water Penetration Into The North Atlantic From Authigenic Neodymium Isotope Ratios, Ruifang C. Xie, Franco Marcantonio, Matthew W. Schmidt

OES Faculty Publications

Understanding intermediate water circulation across the last deglacial is critical in assessing the role of oceanic heat transport associated with Atlantic Meridional Overturning Circulation variability across abrupt climate events. However, the links between intermediate water circulation and abrupt climate events such as the Younger Dryas (YD) and Heinrich Event 1 (H1) are still poorly constrained. Here, we reconstruct changes in Antarctic Intermediate Water (AAIW) circulation in the subtropical North Atlantic over the past 25 kyr by measuring authigenic neodymium isotope ratios in sediments from two sites in the Florida Straits. Our authigenic Nd isotope records suggest that there was little …

Solar Forcing Of Florida Straits Surface Salinity During The Early Holocene, Matthew W. Schmidt, William A. Weinlein, Franco Marcantonio, Jean Lynch-Stieglitz

OES Faculty Publications

Previous studies showed that sea surface salinity (SSS) in the Florida Straits as well as Florida Current transport covaried with changes in North Atlantic climate over the past two millennia. However, little is known about earlier Holocene hydrographic variability in the Florida Straits. Here, we combine Mg/Ca-paleothermometry and stable oxygen isotope measurements on the planktonic foraminifera Globigerinoides ruber (white variety) from Florida Straits sediment core KNR166-2 JPC 51 (24° 24.70' N, 83° 13.14' W, 198 m deep) to reconstruct a high-resolution (~25 yr/sample) early to mid Holocene record of sea surface temperature and δ¹⁸O_SW)(a …