Geology Commons^™

Drivers Of Pb, Sb And As Release From Spent Gunshot In Wetlands: Enhancement By Organic Matter And Native Microorganisms, Anna Potysz, Łukasz J. Binkowski, Jakub Kierczak, Barnett A. Rattner

United States Geological Survey: Staff Publications

In many countries the use of lead-based ammunition is prevalent, and results in exposure and poisoning of waterfowl and other species of birds. In waterfowl hunting areas large quantities of spent shot may be deposited in wetland and terrestrial habitats. These pellets can undergo transformations, which are influenced by various abiotic and biotic factors. In addition to lead (Pb), other elements like antimony (Sb) and arsenic (As) can be leached from Pb shot into the environment. In vitro simulations that included organic matter and microorganisms were utilized to examine elemental leaching from gunshot. We found that leaching efficiency was the …

Limits To Coseismic Landslides Triggered By Cascadia Subduction Zone Earthquakes, Alex R.R. Grant, William T. Struble, Sean R. Lahusen

United States Geological Survey: Staff Publications

Landslides are a significant hazard and dominant feature throughout the landscape of the Pacific Northwest. However, the hazard and risk posed by coseismic landslides triggered by great Cascadia Subduction Zone (CSZ) earthquakes is highly uncertain due to a lack of local and global data. Despite a wealth of other geologic evidence for past earthquakes on the Cascadia Subduction Zone, no landslides have been definitively linked to such earthquakes, even in areas otherwise highly susceptible to failure. While shallow landslides may not leave a lasting topographical signature in the landscape, there are thousands of deep-seated landslides in Cascadia, and these deposits …

Very High Middle Miocene Surface Productivity On The U.S. Mid-Atlantic Shelf Amid Glacioeustatic Sea Level Variability, Marci M. Robinson, Harry J. Dowsett, Timothy D. Herbert

United States Geological Survey: Staff Publications

The Miocene Climatic Optimum (MCO) provides important insights into how the climate system operates under elevated temperatures and atmospheric CO₂ levels. Few western North Atlantic paleotemperature or paleoecological records exist from the MCO, despite their importance for understanding both regional and global climate dynamics. Here we present quantitative MCO paleoecological data from the western North Atlantic, specifically from the Baltimore Gas & Electric (BG&E) marine sediment core from southern Maryland, USA. We examine alkenones and planktic foraminifera and document the first sea surface temperature (SST) and productivity estimates for the MCO and the Middle Miocene Climate Transition (MMCT) from …

Discovering Hidden Geothermal Signatures Using Non-Negative Matrix Factorization With Customized K-Means Clustering, V. V. Vesselinov, B. Ahmmed, M. K. Mudunuru, J. D. Pepin, E. R. Burns, D. L. Siler, S. Karra, R. S. Middleton

United States Geological Survey: Staff Publications

Discovery of hidden geothermal resources is challenging. It requires the mining of large datasets with diverse data attributes representing subsurface hydrogeological and geothermal conditions. The commonly used play fairway analysis approach typically incorporates subject-matter expertise to analyze regional data to estimate geothermal characteristics and favorability. We demonstrate an alternative approach based on machine learning (ML) to process a geothermal dataset from southwest New Mexico (SWNM). The study region includes low- and medium-temperature hydrothermal systems. Several of these systems are not well characterized because of insufficient existing data and limited past explorative work. This study discovers hidden patterns and relations in …

Neural Net Detection Of Seismic Features Related To Gas Hydrates And Free Gas Accumulations On The Northern U.S. Atlantic Margin, Urmi Majumdar, Nathaniel C. Miller, Carolyn D. Ruppel

United States Geological Survey: Staff Publications

Bottom-simulating reflections (BSRs) that sometimes mark the base of the gas hydrate stability zone in marine sediments are often identified based on the reverse polarity reflections that cut across stratigraphic layering in seismic amplitude data. On the northern U.S. Atlantic margin (USAM) between Cape Hatteras and Hudson Canyon, legacy seismic data have revealed pronounced BSRs south of the deepwater extension of Hudson Canyon and more subtle ones from offshore Delaware south to Cape Hatteras, where the reflections sometimes follow stratigraphic layering. Using high-resolution seismic data acquired during the 2018 Mid-Atlantic Resource Imaging Experiment and a supervised neural net, we identify …

Establishment Of Invasive Black Carp (Mylopharyngodon Piceus) In The Mississippi River Basin: Identifying Sources And Year Classes Contributing To Recruitment, Gregory W. Whitledge, Patrick T. Kroboth, Duane C. Chapman, Quinton E. Phelps, Wes Sleeper, Jennifer Bailey, Jill A. Jenkins

United States Geological Survey: Staff Publications

Black Carp (Mylopharyngodon piceus) was imported to the USA to control aquaculture pond snails. This species has escaped captivity and occurs in parts of the Mississippi River, several tributaries, and floodplain lakes, which is concerning due to potential competition with native fishes and predation on native mussels, many of which are imperiled. However, Black Carp captures have primarily been incidental by commercial fishers, and evidence of reproduction in the wild is limited. The objectives of this study were to assess relative abundance of aquaculture- origin and wild Black Carp using ploidy and otolith stable isotope analysis, identify spatial …

Multi-Omics Responses In Tree Swallow (Tachycineta Bicolor) Nestlings From The Maumee Area Of Concern, Maumee River, Ohio, Chi Yen Tseng, Christine M. Custer, Thomas W. Custer, Paul M. Dummer, Natalie Karouna-Renier, Cole W. Matson

United States Geological Survey: Staff Publications

A multi-omics approach was utilized to identify altered biological responses and functions, and to prioritize contaminants to assess the risks of chemical mixtures in the Maumee Area of Concern (AOC), Maumee River, OH, USA. The Maumee AOC is designated by the United States Environmental Protection Agency as having significant beneficial use impairments, including degradation of fish and wildlife populations, bird or animal deformities or reproduction problems, and loss of fish and wildlife habitat. Tree swallow (Tachycineta bicolor) nestlings were collected at five sites along the Maumee River, which included wastewater treatment plants (WWTPs) and industrial land-use sites. Polychlorinated …

A Systematic Review And Meta-Analysis Of The Direct Effects Of Nutrients On Corals, Eileen M. Nalley, Lillian J. Tuttle, Emily E. Conklin, Alexandria L. Barkman, Devynn M. Wulstein, Madeline C. Schmidbauer, Megan J. Donahue

United States Geological Survey: Staff Publications

Chronic exposure of coral reefs to elevated nutrient conditions can modify the performance of the coral holobiont and shift the competitive interactions of reef organisms. Many studies have nowquantified the links between nutrients and coral performance, but fewhave translated these studies to directly address coastal water quality standards. To address this management need, we conducted a systematic review of peer-reviewed studies, public reports, and gray literature that examined the impacts of dissolved inorganic nitrogen (DIN: nitrate, nitrite, and ammonium) and dissolved inorganic phosphorus (DIP: phosphate) on scleractinian corals. The systematic review resulted in 47 studies with comparable data on coral …

Coastalimagelib: An Open- Source Python Package For Creating Common Coastal Image Products, Maile P. Mccann, Dylan L. Anderson, Christopher R. Sherwood, Brittany Bruder, A. Spicer Bak, Katherine L. Brodie

United States Geological Survey: Staff Publications

CoastalImageLib is a Python library that produces common coastal image products intended for quantitative analysis of coastal environments. This library contains functions to georectify and merge multiple oblique camera views, produce statistical image products for a given set of images, and create subsampled pixel instruments for use in bathymetric inversion, surface current estimation, run-up calculations, and other quantitative analyses. This package intends to be an open-source broadly generalizable front end to future coastal imaging applications, ultimately expanding user accessibility to optical remote sensing of coastal environments. This package was developed and tested on data collected from the Argus Tower, a …

Transcriptome Signatures Of Wastewater Effluent Exposure In Larval Zebrafish Vary With Seasonal Mixture Composition In An Effluent-Dominated Stream, Emma B. Meade, Luke R. Iwanowicz, Nicklaus Neureuther, Gregory H. Lefevre, Dana W. Kolpin, Hui Zhi, Shannon M. Meppelink, Rachael F. Lane, Angela Schmoldt, Aurash Mohaimani, Olaf Mueller, Rebecca D. Klaper

United States Geological Survey: Staff Publications

Wastewater treatment plant (WWTP) effluent-dominated streams provide critical habitat for aquatic and terrestrial organisms but also continually expose them to complex mixtures of pharmaceuticals that can potentially impair growth, behavior, and reproduction. Currently, few biomarkers are available that relate to pharmaceutical-specific mechanisms of action. In the experiment reported in this paper, zebrafish (Danio rerio) embryos at two developmental stages were exposed to water samples from three sampling sites (0.1 km upstream of the outfall, at the effluent outfall, and 0.1 km below the outfall) during base-flow conditions from two months (January and May) of a temperate-region effluent-dominated stream …

Sinistral Shear During Middle Jurassic Emplacement Of The Matancilla Plutonic Complex In Northern Chile (25.4◦ S) As Evidence Of Oblique Plate Convergence During The Early Andean Orogeny, S. P. Mavor, J. S. Singleton, G. Heuser, R. Gomila, N. M. Seymour, S. Williams, G. Arancibia

United States Geological Survey: Staff Publications

Arc magmatism in a continental subduction zone facilitates rheological weakening of the rigid upper plate, and can accommodate the partitioned trench-parallel component of oblique subduction into an intra-arc shear zone. We document a shear zone at latitude 25.4^◦ S near Taltal, Chile that was associated with intrusion of the Matancilla Plutonic Complex at ~169 Ma to evaluate intra-arc deformation and possible tectonic plate configurations during this time period. Polyphase folding of Paleozoic metasedimentary rocks is overprinted by mylonitic fabrics that are most extensive in a zone up to 1.4 km wide in the thermal aureole of the granodioritic Matancilla …

Sinistral Shear During Middle Jurassic Emplacement Of The Matancilla Plutonic Complex In Northern Chile (25.4◦ S) As Evidence Of Oblique Plate Convergence During The Early Andean Orogeny, S.P. Mavor, J.S. Singleton, G. Heuser, R Gomila, N.M. Seymour, S. Williams, G. Arancibia

United States Geological Survey: Staff Publications

component of oblique subduction into an intra-arc shear zone. We document a shear zone at latitude 25.4^◦ S near Taltal, Chile that was associated with intrusion of the Matancilla Plutonic Complex at ~169 Ma to evaluate intra-arc deformation and possible tectonic plate configurations during this time period. Polyphase folding of Paleozoic metasedimentary rocks is overprinted by mylonitic fabrics that are most extensive in a zone up to 1.4 km wide in the thermal aureole of the granodioritic Matancilla pluton, where contact metamorphic andalusite porphyroblasts are synkinematic with fabric development. Mylonite in metasedimentary rocks is overprinted by a ~130 Ma …

Discovering Hidden Geothermal Signatures Using Non-Negative Matrix Factorization With Customized K-Means Clustering, V.V. Vesselinov, B. Ahmmed, M.K. Mudunuru, J.D. Pepin, E.R. Burns, D.L. Siler, S. Karra, R.S. Middleton

United States Geological Survey: Staff Publications

Discovery of hidden geothermal resources is challenging. It requires the mining of large datasets with diverse data attributes representing subsurface hydrogeological and geothermal conditions. The commonly used play fairway analysis approach typically incorporates subject-matter expertise to analyze regional data to estimate geothermal characteristics and favorability. We demonstrate an alternative approach based on machine learning (ML) to process a geothermal dataset from southwest New Mexico (SWNM). The study region includes low- and medium-temperature hydrothermal systems. Several of these systems are not well characterized because of insufficient existing data and limited past explorative work. This study discovers hidden patterns and relations in …

The Effects Of Estradiol-17Β On The Sex Reversal, Survival, And Growth Of Green Sunfish Lepomis Cyanellus, Chad N. Teal, Daniel J. Schill, Susan B. Fogelson, Colby M. Roberts, Kevin Fitzsimmons, Javan M. Bauder, William T. Stewart, Scott A. Bonar

United States Geological Survey: Staff Publications

The feminization of green sunfish Lepomis cyanellus could expand their utility as a game fish or aquacultured species by preventing overcrowding and precocious reproduction in stocked systems. Feminization of green sunfish could also help elucidate information on their sex determination system. We report the feminization of green sunfish cohorts via oral administration of estradiol-17β (E2) during early development. A low-dose (100 E2 mg per kg of diet) and a high-dose (150 E2 mg per kg of diet) experimental E2 treatment were fed to juvenile green sunfish from 30 to 90 days post-hatch. Fish were subsequently evaluated for any treatment effect …

Climate Change Alters Aging Patterns Of Reservoir Aquatic Habitats, Leandro E. Miranda, Nicky M. Faucheux

United States Geological Survey: Staff Publications

Two slow-moving developments are threatening reservoir aquatic habitats globally: aging and climate change. These events are projected to transform reservoir aquatic habitats in various and often unpredictable ways. Aging affects in-lake habitats directly, whereas climate change affects both in-lake and off-lake conditions. Climate change is expected to accelerate and, in some instances, possibly decelerate aging. Aging can be indexed as functional age, an index that signals the position of a reservoir along its lifespan relying on inlake descriptors of aquatic habitat. Using existing habitat datasets and climate projections, we developed semi-quantitative predictions about the effect of climate change on reservoir …

Sediment Source Fingerprinting As An Aid To Large-Scale Landscape Conservation And Restoration: A Review For The Mississippi River Basin, Zhen Xu, Patrick Belmont, Janice Brahney, Allen C. Gellis

United States Geological Survey: Staff Publications

Reliable quantitative information on sediment sources to rivers is critical to mitigate contamination and target conservation and restoration actions. However, for large-scale river basins, determination of the relative importance of sediment sources is complicated by spatiotemporal variability in erosional processes and sediment sources, heterogeneity in sediment transport and deposition, and a paucity of sediment monitoring data. Sediment source fingerprinting is an increasingly adopted field-based technique that identifies the nature and relative source contribution of sediment transported in waterways. Notably, sediment source fingerprinting provides information that is independent of other field, modeling, or remotely sensed techniques. However, the diversity in sampling, …

A Demonstration Of A Simple Methodology Of Flood Prediction For A Coastal City Under Threat Of Sea Level Rise: The Case Of Norfolk, Va, Usa, Tal Ezer

CCPO Publications

Many coastal cities around the world are at risk of increased flooding due to sea level rise (SLR), so here a simple flood prediction method is demonstrated for one city at risk, Norfolk, VA, on the U.S. East Coast. The probability of future flooding is estimated by extending observed hourly water level for 1927–2021 into hourly estimates until 2100. Unlike most other flood prediction methods, the approach here does not use any predetermined probability distribution function of extreme events, and instead a random sampling of past data represents tides and storm surges. The probability of flooding for 3 different flood …

Seasonality Of Precipitation In The Southwestern United States During The Late Pleistocene Inferred From Stable Isotopes In Herbivore Tooth Enamel, Matthew J. Kohn, Kathleen B. Springer, Jeffrey S. Pigati, Linda M. Reynard, Amanda E. Drewicz, Justin Crevier, Eric Scott

United States Geological Survey: Staff Publications

The late Pleistocene was a climatically dynamic period, with abrupt shifts between cool-wet and warmdry conditions. Increased effective precipitation supported large pluvial lakes and long-lived spring ecosystems in valleys and basins throughout the western and southwestern U.S., but the source and seasonality of the increased precipitation are debated. Increases in the proportions of C₄/(C₄+ C₃) grasses in the diets of large grazers have been ascribed both to increases in summer precipitation and lower atmospheric CO₂ levels. Here we present stable carbon and oxygen isotope data from tooth enamel of late Pleistocene herbivores recovered …

Collateral Damage: Anticoagulant Rodenticides Pose Threats To California Condors, Garth Herring, Collin A. Eagles-Smith, Rachel Wolstenholme, Alacia Welch, Chris West, Barnett A. Rattner

United States Geological Survey: Staff Publications

Anticoagulant rodenticides (ARs) are widespread environmental contaminants that pose risks to scavenging birds because they routinely occur within their prey and can cause secondary poisoning. However, little is known about AR exposure in one of the rarest avian scavengers in the world, the California condor (Gymnogyps californianus). We assessed AR exposure in California condors and surrogate turkey vultures (Cathartes aura) to gauge potential hazard to a proposed future condor flock by determining how application rate and environmental factors influence exposure. Additionally, we examined whether ARs might be correlated with prolonged blood clotting time and potential mortality …

Limited Rigor In Studies Of Raptor Mortality And Mitigation At Wind Power Facilities, Tara J. Conkling, Christopher J.W. Mcclure, Sandra Cuadros, Scott R. Loss, Todd E. Katzner

United States Geological Survey: Staff Publications

Wind power is an expanding source of renewable energy. However, there are ecological challenges related to wind energy generation, including collisions of wildlife with turbines. Lack of rigor, and variation in study design, together limit efforts to understand the broad-scale effects of wind power infrastructure on wildlife populations. It is not clear, however, whether these types of limitations apply to groups of birds such as raptors that are particularly vulnerable to negative effects of wind energy. We reviewed 672 peer-reviewed publications, unpublished reports, and citations from 321 wind facilities in 12 countries to evaluate methods used to monitor and mitigate …

Investigations Of The Potential For Irrigated Agriculture On The Bonaparte Plains: Hydrogeology, Aquifer Properties And Groundwater Chemistry, Don Bennett, Paul Raper, Robert Paul, Tim Pope, Richard J. George Dr

Resource management technical reports

‘Cockatoo Sands’ is a common name for the Cockatoo Sands family of soils (comprising red to yellowish-red sands, sandy earths, and loamy earths) that have formed from quartz sandstone colluviums in relatively isolated patches throughout the East Kimberley region of Western Australia and the Northern Territory. Cockatoo Sands are recognised as potentially suitable for irrigated agriculture because they are generally well drained and not subject to waterlogging or inundation. These characteristics allow them to be cultivated and prepared for planting various crops during the wet and dry seasons of northern Australia.

Expanding agricultural production onto the Cockatoo Sands around Kununurra …

Application Of A 14c-Assay To Assess Methanotrophic Biodegradation Of Tce In Low Ph Groundwater, Evan Groome

All Theses

Current biological strategies for remediating trichloroethylene (TCE) in low pH aquifers (i.e., pH14C-TCE assay was developed to determine pseudo first-order rate constants for the degradation of TCE in microcosms containing soil and groundwater from the Boeing Michigan Aeronautical Research Center (BOMARC) superfund site, where the pH ranges from 4.1 to 4.9. The ¹⁴C-TCE assay was also adapted to calculate soil-normalized rate constants for data from this site, as well as data that Szwast²¹ collected from the Beltsville Agricultural Research Center (BARC). In addition to natural attenuation, biostimulation through amendments of methane and nutrients were also assessed. This treatment …

Water Sourcing Strategies Of Desert Vegetation In Varying Soil Textures With Vegetation Competition: A Stable Isotope Analysis, Martha Elizabeth Gardea

Open Access Theses & Dissertations

Recent studies have suggested an ecohydrological separation of water exists in the northern Chihuahuan Desert, where vegetation types, rainfall regimes, and location in the terrain seem to determine the type of water (e.g. isotopically depleted or enriched in 18O and 2H) plants are able to source and use throughout their growing cycle. That work found evidence of creosote (Larrea tridentata) and mesquite (Prosopis glandulosa) using tightly bound soil water at both a site on an ephemeral channel and a site in higher elevated flat area because the isotopic signature of plant water at the beginning of the study did not …

Spatial Stream Modeling Of Louisiana Waterthrush (Parkesia Motacilla) Foraging Substrate And Aquatic Prey In A Watershed Undergoing Shale Gas Development, Mack W. Frantz, Petra B. Wood, Steven C. Latta

United States Geological Survey: Staff Publications

We demonstrate the use of spatial stream network models (SSNMs) to explore relationships between a semiaquatic bioindicator songbird, Louisiana Waterthrush (Parkesia motacilla), and stream monitoring and benthic macroinvertebrate data in an area undergoing shale gas development. SSNMs allowed us to account for spatial autocorrelation inherent to these environmental data types and stream properties that traditional modeling approaches cannot capture to elucidate factors that affect waterthrush foraging locations. We monitored waterthrush along 58.1 km of 1st- and 2nd-order headwater stream tributaries (n = 14) in northwestern West Virginia over a two year period (2013–2014), sampled benthic macroinvertebrates in waterthrush …

Science Of The Total Environment, Benjamin Linhoff

United States Geological Survey: Staff Publications

Recently, the subsoils of ephemeral stream(arroyos) floodplains in the northern Chihuahuan Desert were discovered to contain large naturally occurring NO₃⁻ reservoirs (floodplain:~38,000 kg NO₃-N/ha; background:~60 kg NO₃-N/ha). These reservoirs may be mobilized through land use change or natural stream channel migration which makes differentiating between anthropogenic and natural groundwaterNO₃⁻sources challenging. In this study, the fate and sources of NO₃⁻ were investigated in an area with multiple NO₃⁻ sources such as accidental sewer line releases and sewage lagoons aswell as natural reservoirs of subsoil NO₃⁻. …

Assessing Impact Of Unconventional Oil And Gas Development On Groundwater Quality In The Northern Appalachian Region With Mixed Land Uses, Favour C. Epuna

Theses - ALL

Over the past decade, the rapid growth of unconventional oil and gas development (UOGD) has raised public concerns about its potential impact on groundwater quality. High methane and salt levels in groundwater have been the most widely cited UOGD-related impairments. The attribution of these contaminants to UOGD is usually complex, especially in regions with mixed land uses. Here, we compiled a large hydrogeochemistry dataset containing 13 geochemical analytes for 17,794 groundwater samples from the rural northern Appalachia, i.e., 19 counties located on the boundary between Pennsylvania (PA; UOGD is permitted) and New York (NY; UOGD is banned). With this dataset, …

Population Genetics Reveals Bidirectional Fish Movement Across The Continental Divide Via An Interbasin Water Transfer, Audrey C. Harris, Sara J. Oyler-Mccance, Jennifer A. Fike, Matthew P. Fairchild, Christopher M. Kennedy, Harry J. Crockett, Dana L. Winkelman, Yoichiro Kanno

United States Geological Survey: Staff Publications

Interbasin water transfers are becoming an increasingly common tool to satisfy municipal and agricultural water demand, but their impacts on movement and gene flow of aquatic organisms are poorly understood. The Grand Ditch is an interbasin water transfer that diverts water from tributaries of the upper Colorado River on the west side of the Continental Divide to the upper Cache la Poudre River on the east side of the Continental Divide. We used single nucleotide polymorphisms to characterize population genetic structure in cutthroat trout (Oncorhynchus clarkii) and determine if fish utilize the Grand Ditch as a movement corridor. …

Foraging Habitat Selection Of Shrubland Bird Community In Tropical Dry Forest, Anant Deshwal, Steven L. Stephenson, Pooja Panwar, Brett A. Degregorio, Ragupathy Kannan, John D. Willson

United States Geological Survey: Staff Publications

Habitat loss due to increasing anthropogenic disturbance is the major driver for bird population declines across the globe. Within the Eastern Ghats of India, shrubland bird communities are threatened by shrinking of suitable habitats due to increased anthropogenic disturbance and climate change. The development of an effective habitat management strategy is hampered by the absence of data for this bird community. To address this knowledge gap, we examined foraging sites for 14 shrubland bird species, including three declining species, in three study areas representing the shrubland type of forest community in the Eastern Ghats. We recorded microhabitat features within an …

Speciation With Gene Flow In A Narrow Endemic West Virginia Cave Salamander (Gyrinophilus Subterraneus), Evan H. Campbell Grant, Kevin P. Mulder, Adrianne B. Brand, Douglas B. Chambers, Addison H. Wynn, Grace Capshaw, Matthew L. Niemiller, John G. Phillips, Jeremy F. Jacobs, Shawn R. Kuchta, Rayna C. Bell

United States Geological Survey: Staff Publications

Due to their limited geographic distributions and specialized ecologies, cave species are often highly endemic and can be especially vulnerable to habitat degradation within and surrounding the cave systems they inhabit. We investigated the evolutionary history of the West Virginia Spring Salamander (Gyrinophilus subterraneus), estimated the population trend from historic and current survey data, and assessed the current potential for water quality threats to the cave habitat. Our genomic data (mtDNA sequence and ddRADseq-derived SNPs) reveal two, distinct evolutionary lineages within General Davis Cave corresponding to G. subterraneus and its widely distributed sister species, Gyrinophilus porphyriticus, that …

Reactive Iron Mineral Coatings In Redox Transition Zones Of A Site With Historical Contamination: Abiotic Attenuation, Xin Yin

Dissertations

Reactive iron mineral coatings are found throughout reduction-oxidation (redox) transition zones and play a significant role in contaminant transformation processes. In this study, an 18.3-meter core is collected, subsampled, and preserved under anoxic conditions to maintain its original redox state. Screening analyses are conducted at sampling increments of 5.08 cm in depth for the following: elemental concentrations with X-ray fluorescence (XRF), sediment pH, sediment oxidation-reduction potential (ORP), total volatile organic carbon (TVOC) in the sample headspace, and abundant bacteria (16S rRNA sequencing). Using the Fe and S gradients correlated with microbial data, five RTZs are delineated. To characterize iron mineral …