Geochemistry Commons^™

Stratigraphic Analysis Of The Capps Limestone In The North Norton Oil Field In Runnels County, Texas, William Thompson

Electronic Theses and Dissertations

The Desmoinesian (Middle Pennsylvanian) Capps Limestone Member of the Mineral Wells Formation is a carbonate reservoir located in North Central Texas. It consists of interbedded limestone, sandstone, and shale units. Much of the Capps Limestone exists in the subsurface of Brown, Coleman, Runnels, Coke, Nolan, and Taylor counties, however, the Capps Limestone outcrops on the surface in Brown, Eastland, and Palo Pinto counties.

The cored interval from Runnels County was deposited in a marginal marine environment during the Middle Pennsylvanian Period. Although the Capps Limestone was first described in the 1890s, there is still much to be discovered about its …

Identifying Biogeochemical Factors Responsible For The Cyclical Precipitation Of Sphalerite And Galena In Low Temperature Mississippi Valley Type Ore Deposits, Daniel John Makowsky

Theses and Dissertations

Mississippi Valley Type (MVT) lead and zinc deposits provide a significant source of sedimentary galena and sphalerite. However, geochemical characteristics and genesis including the source and production of hydrogen sulfide required for galena and sphalerite ore formation and the reasoning for quick, episodic mineralization is not fully understood. By simulating regional MVT brines, the input and effect of biological by-products during the development of these ores as well as the cause of cyclicity within MVT deposits have been observed. Experiments using compositions from MVT fluid inclusions were conducted over two-week periods. Variables during the experiments included temperature, CO2, hydrogen sulfide …

Using Sedimentary Mercury Geochemistry To Evaluate The Niagara-Salina Transition, Silurian Michigan Basin, Usa, Sara Hayes

Masters Theses

The Niagara-Salina boundary in the Michigan Basin is marked by an abrupt transition from carbonates to evaporites. Though the cause is uncertain, previous work suggests the onset of Salina evaporites was driven by basin restriction, but the presence of several global carbon isotope excursions (CIE) suggest a global driver. This study builds on this discussion using two relatively new geochemical proxies - elemental mercury concentrations [Hg] and Hg isotopes.

Mercury concentrations [Hg] were measured in 88 samples from the State Kalkaska #2-15 core from 6604.03 ft to 6797.42 ft. [Hg] ranges from 0.11 to 0.62 mg/kg and [Hg]/TOC from 0.038 …

Analysis Of Titan's Fluvial Features Using Numerical Modeling, Jeshurun Horton

Mechanical Engineering Undergraduate Honors Theses

River channels have been observed near the Huygens probe landing site on the surface of Titan, along with evidence of rounded water ice boulders transported through fluid flow. Evidence near the landing site suggests active flow of liquid methane, which has motivated the study of the effects of sediment load and channel sizes on Titan’s fluvial features. A numerical model is used to determine the viscosity, flow velocity, and critical boulder transport diameter based on channel size, slope, and a range of sediment concentrations. This model achieves two ends: first, observed boulder diameters are used to determine the ideal channel …

Geochemical Investigation Of Monogenetic Volcanoes From The Pribilof Islands, Bering Sea, Alaska, Clayton L. Reinier

Graduate Theses/Dissertations

Small-volume basaltic magmas found at continental intraplate environments have not been as extensively studied compared to their polygenetic counterparts. Specifically, regions such as the Bering Sea basalt province, described as a diffuse igneous province, have commonly been overlooked. Assumptions that these systems are invoked by simple, single batches of magma has subsequently left a gap in understanding the processes responsible for primary magma generation away from plate boundaries with little tectonic influence. The following studies that constitute this thesis focus on an in-depth geochemical investigation at the crystal and sub-crystal scale to evaluate lithospheric mantle heterogeneities, processes that govern primary …

Low Impact Sampling Of Speleothems – Reconciling Scientific Study With Cave Conservation, Claire L.V. Macgregor, John C. Hellstrom, Jon D. Woodhead, Russell N. Drysdale, Rolan S. Eberhard

International Journal of Speleology

Speleothems are increasingly valued as important paleoclimate archives and yet the removal of samples from caves can come at a cost to natural heritage, impacting delicate environments with limited mechanisms for repair. Conservation of cave environments is a key responsibility for scientists and, with this in mind, we are working to develop and implement techniques that allow us to extract valuable scientific data, with minimal impact. In this study, we demonstrate the utility of low-impact reconnaissance dating surveys on caves in southern Tasmania and southwest Western Australia as a precursor to the removal of stalagmites for paleoclimate reconstruction. Small flakes …

Revisiting The Cretaceous-Paleogene Boundary In Western Kentucky, Usa, Jarred Asselta

Scholars Week

This study revisits a Cretaceous-Paleogene (K-Pg) sedimentary section in western Kentucky to determine the nature of this boundary and the depositional environments. Although previous pollen work identified the boundary over four decades ago, to our knowledge no work has been carried out at this important K-Pg boundary site. A combination of stratigraphy and sedimentology were used to characterize the section in detail. Bulk and oriented samples were collected for grain-size, geochemical, and petrographic analysis. We relocated the site and measured 1.5m of section that includes the K-Pg boundary. Four distinct units were identified and from base to top of section …

Hydrological Feedbacks On Peatland Ch4 Emission Under Warming And Elevated Co2: A Modeling Study, Fenghui Yuan, Yihui Wang, Daniel M. Ricciuto, Xiaoying Shi, Fengming Yuan, Thomas Brehme, Scott Bridgham, Jason Keller, Jeffrey M. Warren, Natalie A. Griffiths, Stephen D. Sebestyen, Paul J. Hanson, Peter E. Thornton, Xiaofeng Xu

Biology, Chemistry, and Environmental Sciences Faculty Articles and Research

Peatland carbon cycling is critical for the land–atmosphere exchange of greenhouse gases, particularly under changing environments. Warming and elevated atmospheric carbon dioxide (eCO₂) concentrations directly enhance peatland methane (CH₄) emission, and indirectly affect CH₄ processes by altering hydrological conditions. An ecosystem model ELM-SPRUCE, the land model of the E3SM model, was used to understand the hydrological feedback mechanisms on CH₄ emission in a temperate peatland under a warming gradient and eCO₂ treatments. We found that the water table level was a critical regulator of hydrological feedbacks that affect peatland CH₄ dynamics; the …

Timescales Of Magma Transport In The Columbia River Flood Basalts, Determined By Paleomagnetic Data, Joseph Biasi, Leif Karlstrom

Other Staff Materials

Flood basalts represent major events in Earth History, in part because they are linked to large climate perturbations and mass extinctions. However, the durations of individual flood basalt eruptions, which directly impact potential environmental crises, are poorly constrained. Here we use a combination of paleomagnetic data and thermal modeling to create a magnetic geothermometer (MGT) that can constrain the active transport lifetime of magmatic conduits and intrusions. We apply the MGT technique to eight feeder dike segments of the Columbia River basalts (CRB), demonstrating that some dike segments were actively heating host rocks for less than one month, while other …

Diffusional Fractionation Of Helium Isotopes In Silicate Melts, Haiyang Luo, Bijaya Karki, Dipta B. Ghosh, Huiming Bao

Faculty Publications

Estimating Helium (He) concentration and isotope composition of the mantle requires quantifying He loss during magma degassing. The knowledge of diffusional He isotope fractionation in silicate melts may be essential to constrain the He loss. Isotopic mass dependence of He diffusion can be empirically expressed as D3He/D4He = (4/3)^β, where D is the diffusivity of a He isotope. However, no studies have reported any β values for He in silicate melts due to technical challenges in both experiments and computations. Here, molecular dynamics simulations based on deep neural network potentials trained by ab initio data …

Continuous Color Model As A Tool To Improve Speleothem Age Model Development, Celia Campa-Bousoño, Ángel García-Pérez, Ana Moreno, Miguel Iglesias, Hai Cheng, R Lawrence Edwards, Heather Stoll

International Journal of Speleology

Because they can archive a variety of geochemical proxies and be precisely and accurately dated with the U-Th decay series chronometer, stalagmites are widely used for paleoclimate reconstructions. However, limitations in the use of this chronometer arise because U-Th dating is analytically time consuming, expensive, and requires a relatively large sample size. These limitations restrict the number of absolute dates usually obtained, which can result in significant uncertainties in the age model and inhibit the ability to archive high resolution records of environmental variability, particularly in those stalagmites where there are variations in growth rate not constrained by U-Th dates. …

Timescales And Dynamics Of Rhyolitic Melt Generation In Upper Crustal Magmatic Reservoirs: Insights From New Geochronologic And Petrologic Data On The Valle Mosso Pluton And Sesia Caldera, Sesia Magmatic System, Italy, Lorenzo Tavazzani

Earth Sciences Theses and Dissertations

This work may have a narrow geographic focus, namely a handful of steep and densely forested valleys of the Southern Italian Alps, but its scientific goals are certainly wide. Through a combined analyses of the spatial distribution, geochemical characteristics and temporal duration of the Permian silicic magmatism in the renown Ivrea crustal section (Sesia Magmatic System), this dissertation addresses fundamental questions regarding the physical mechanisms of rhyolitic magma storage, mobilization and eruption.

A brief introduction serves to define the broader context of the scientific questions addressed in the three main chapters of this dissertation. Through Chapters 2 to 4 we …

Geochemistry Of Phosphatic Nodules As A Tool For Understanding Depositional And Taphonomical Settings In A Palaeolithic Cave Site (San Teodoro, Sicily), Gerlando Vita, Vittorio Garilli, Mirko Andrea Vizzini, Renato Giarrusso, Angelo Mulone, Massimiliana Pinto Vraca, Valeria La Parola, Pierluigi Rosina, Laura Bonfiglio, Luca Sineo

International Journal of Speleology

Interpreting depositional settings of cave sites is generally problematic, especially in absence of paleontological/archaeological evidence. This is the case of some deposits at San Teodoro Cave (Sicily), a key site for the Mediterranean Palaeolithic. In a stratigraphic level interrupted by a carbonatic concretion, phosphatic nodules are present only in the part enclosed between the concretion and the cave wall. The discovery of these nodules combined with the punctual lack of fossils had initially suggested an erosion phenomenon and subsequent formation of nodules at a vadose level. Here we show the usefulness of an integrated, geochemical-paleoecological approach in defining stratigraphy and …

Spatiotemporal Variability Of Soil Water Δ18o And Δ2h Reveals Hydrological Processes In Two Floodplain Soils, Amanda Ceming-Barbato

LSU Master's Theses

The movement of water through soil is preferential and heterogeneous. Subsurface interactions between mobile flows and the soil matrix are not uniform and are therefore difficult to predict through time and space. The use of stable isotopes of hydrogen (²H) and oxygen (¹⁸O) as conservative tracers of water movement is improving understanding of soil hydrological processes, yet field-scale observations of isotopic variability remain scarce despite implications for identifying dominant hydrologic processes. We sampled two adjacent soils at a ridge-swale topography floodplain forest to determine soil water isotopic variability at a 20 cm depth resolution in soils …

Sorption Of Metals At The Barite (001)-Water Interface, Inva Braha

Student Theses

Abstract

Ion desorption processes control the retention of ions, such as Pb²⁺, at barite surfaces, whereas ion adsorption processes are a likely initial step in the incorporation of divalent cations, such as Sr²⁺ and Pb²⁺, into barite. Based on previous studies on samples dominated by flat terraces with relatively few defects, Sr²⁺ and Pb²⁺ adsorb and incorporate at the barite (001)-water interface (Bracco et al., 2019; Bracco et al., 2020). Here, I measured how susceptible lead (Pb) is to desorption and the role surface variability plays in its sorption behavior. First, I measured …

Laboratory Capabilities, University Of North Dakota. Energy And Environmental Research Center

EERC Brochures and Fact Sheets

Fact sheet about the Energy & Environmental Research Center’s laboratory capabilities including reservoir characterization, organic geochemistry, fluid sampling, and material analysis. A list of publications and laboratory information is also included.

Palynology And Paleoclimatology Of The Chicxulub Impact Crater In The Early Paleogene, Vann Smith

LSU Doctoral Dissertations

At the end of the Cretaceous Period, a large bolide impacted the Earth and formed the Chicxulub impact crater in the Yucatán Peninsula, Mexico. In 2016, International Ocean Discovery Program (IODP) Expedition 364 Site M0077 drilled into the buried peak ring of the crater, recovering a marine Paleocene to early Eocene post-impact section deposited on top of the impact breccia. Palynological analysis of 195 samples from the post-impact section has yielded the first pre-Holocene vegetational record from inside the Chicxulub impact crater and the first palynological record of the recovery of life following the end-Cretaceous mass extinction from inside the …

Impacts Of Oil And Gas Wastes On Landfill Leachate, Sewage Treatment Plants, And The Environment, Lauren Badertscher

Electronic Theses and Dissertations

Between January 2011 and March 2021 oil and gas wells in Pennsylvania produced

305,637,795 barrels of liquid waste and 6,992,957 tons of solid waste with the majority from

Marcellus Shale unconventional wells. This waste is not considered hazardous and over 89% of

the solid waste generated by unconventional and conventional oil and gas extraction has been

disposed of in landfills over the past decade. This study examined trends in the quantity of waste

produced and methods of disposal. Landfills accepting this waste were identified and their

general method of leachate treatment, using onsite facilities or offsite at wastewater treatment

plants, …

Geology Of The Clairmont Springs 7.5-Minute Quadrangle And Geochronology Of The Alabama Blue Ridge, Adelie Ionescu

Graduate Theses/Dissertations

The Alabama Blue Ridge (USA) of the southern Appalachians contains metamorphic rocks and structures associated with island arc accretion and continent-continent collision that record the Acadian and Alleghenian orogenies. The western Blue Ridge is underlain by Cambrian to Mississippian, clastic and carbonate, low-grade, greenschist facies metamorphic Talladega belt that formed outboard from the Alabama promontory or along the Laurentian margin. The eastern Blue Ridge contains the Neoproterozoic to Paleozoic, lithologically diverse, high grade, middle to upper amphibolite facies Ashland Supergroup. Geologic mapping of the Clairmont Springs 7.5- minute quadrangle unveils tectonic relationships between the eastern and western Blue Ridge and …

Re-Evaluation Of The First Metamorphic P-T Path Using Quig Barometry And Equilibrium Thermodynamics, Sam Couch

Boise State University Theses and Dissertations

Quartz in garnet (“QuiG”) barometry is a relatively new technique that uses physical properties of minerals to estimate the pressure of garnet nucleation and growth history independent of chemical equilibrium. QuiG barometry was used to determine pressures of garnet growth and compared to thermodynamically calculated P-T conditions for two samples (FH-1M and Z3H) from the Lower Shieferhülle (Formation), Tauern Window, Austria. FH-1M was the first sample for which a P-T path was calculated through inversion of chemical zoning in garnet (Selverstone et al., 1984). Mineral Assemblage Diagrams (MADs) and geothermobarometric techniques were used to determine P-T conditions for garnet nucleation …

Understanding The Chemical Weathering Rate And Element Mobility Of Soils: Using U-Series, Nd-Sr Isotopes Ree And Quantum Chemistry Computational Simulation, Jiye Guo

Open Access Theses & Dissertations

Soil played as the central role in the interaction of biosphere, hydrosphere, lithosphere and atmosphere and is the heart of earth's critical zone study. The weathering and element mobility of soils have drawn considerable attention in soil studies since the complexity of these processes and the critical influence towards the earth and humanity, e.g., the global carbon cycles and fertilization. However, the interaction between soils and various factors including precipitation, bedrock ages, altitude is not well understood. Basse-Terre Island at French Guadeloupe, a small volcanic tropical island that has steep environmental gradients of bedrock ages, topography and precipitation, can be …

Develop A Multi-Functional Green Pervious Concrete (Mgpc) Pavement With Polycyclic Aromatic Hydrocarbons (Pahs) Removal Function., Hong Shang

Electronic Theses and Dissertations

Stormwater runoff induced Polycyclic Aromatic Hydrocarbons (PAHs) contaminant increasingly imperils the groundwater quality and the sustainable development of human society due to the potential carcinogenic risks. Pavement can be considered as the first line of defense for contaminant removal of the stormwater runoff. New construction materials with stormwater runoff quantity and quality control are in urgent demand for updating the existing pavement system. An innovative material called Multi-functional Green Pervious Concrete (MGPC) was developed in the department of Civil and Environmental Engineering at University of Louisville. This material uses organoclay as the amendment to enhance the PAHs removal capacity of …

Reconstructing 1856-7 California Mining Patterns From Placer Gold Recovered From The Wreck Of The Ss Central America, Kathryn Ruth Vonsydow

Electronic Theses, Projects, and Dissertations

The discovery of the SS Central America 1857 shipwreck site provides a time capsule that can be used to address questions about the spatial and temporal patterns of placer mining in California during the peak of the gold rush. Samples of placer gold in the collections of museums and private individuals can have uncertain pedigree due to labeling issues and alterations by cleaning and curatorial processes. However, placer gold from the 1857 shipwreck could only have come from the Mother Lode Country of California, as no other gold districts had yet been found in western North America. I compared the …

New Perspectives On Prolific And Voluminous Rhyolite Volcanism Of The Mahogany Mountain--Three Fingers Rhyolite Field, Eastern Oregon, Robert Andrew Jackson

Dissertations and Theses

Voluminous silicic volcanism of the Mahogany Mountain--Three Fingers rhyolite field (MM--TFrf) is spatially and temporally associated with mid-Miocene flood basalts of the Columbia River Basalt province. Early studies of the area advocated for a two-caldera model consisting of the Mahogany Mountain and the slightly younger Three Fingers caldera with pre- and post-caldera effusive rhyolite eruptions. Although close in time, the calderas were thought to be spatially offset producing the tuff of Leslie Gulch and the tuff of Spring Creek. Finding that the tuff of Spring Creek, that is exposed in Leslie Gulch, is an altered product of the tuff of …

Petrology And Geochemistry Of Evolved Achondrites: Planetesimal Mantles And Crusts, Zoltan Vaci

Earth and Planetary Sciences ETDs

Melting and differentiation are fundamental to early solar system evolution on planetary bodies that accreted enough material to heat up radioactively or through impacts and breach their solidi. Partially and fully melted material is present in the meteorite record in the form of primitive achondrites and achondrites, which are fragments of planetesimals that underwent heating events in the first few million years of solar system history. Although the vast majority of this material is mafic or ultramafic, new evolved samples, recovered in the last few decades, are pushing the petrologic and geochemical boundaries of planetesimal melting, differentiation, and crust formation. …

Computer Simulations Of Diffusional Isotope Effects And Dynamical Properties Of Silicate Melts, Haiyang Luo

LSU Doctoral Dissertations

Silicate melts have served as transport agents in the chemical and thermal evolution of Earth. Diffusional isotope effect in silicate melts is the key to interpret isotope variations in lots of geological samples. Isotopic mass dependence of diffusion is commonly expressed as (Di/Dj)=(mj/mi)^β, where Di and Dj are diffusion coefficients of two isotopes whose masses are mi and mj. However, how the dimensionless empirical parameter β depends on temperature, pressure, and composition remains poorly constrained. Viscosity and electrical conductivity are two fundamental dynamical properties of silicate melts needed to constrain melt distribution in Earth's interior but remain unclear for most …

Barriers To And Uncertainties In Understanding And Quantifying Global Critical Mineral And Element Supply, Brian A. Mcnulty, Simon M. Jowitt

Geoscience Faculty Research

The critical minerals and elements are natural substances that are essential to modern life but have insecure supply. This lack of a secure supply clashes with the increasing importance of these elements, especially given their use in technologies needed to reduce global CO2 emissions and mitigate against anthropogenic climate change. In this contribution we review the by-product nature of the critical minerals and elements and the inherant uncertainties in reported critical mineral and element annual production as well as the relationships between these commodities and main-product metals and associated concentrates. We explore the geological and geographical barriers to critical mineral …

Geological And Geochemical Analysis Of Phosphorus Bearing Minerals And Natural Glasses On Earth And In Meteorites: Implications Of The Origin Of Life, Tian Feng

USF Tampa Graduate Theses and Dissertations

Phosphorus is a key element in biogenic molecules and the mineral schreibersite is a major reactive phosphorus source for organic compounds on the prebiotic Earth. In this dissertation, a suite of reactions of phosphorus species, which originate from schreibersite minerals on chondrite meteorites and on the early Earth, have been studied to determine the intermediate geochemical pathways between phosphides and common minerals on meteorites and on the early earth.

I first investigated a unique blue fulgurite that was studied to clarify if this blue color was caused by rich phosphorus content, as has been reported for impact glasses that also …

Ware And Tear In Ancient Tampa Bay: Ceramic Elemental Analyses From Pinellas County Sites, Mckenna Loren Douglass

USF Tampa Graduate Theses and Dissertations

This research tested a null hypothesis on whether ceramics from a variety of archaeological sites around the Pinellas County peninsula were sourced locally for their materials. The sites in this study include Weeden Island (8PI1-5-6-A/B/C/D), Bayshore Homes (8PI41), Yat Kitischee (8PI1753), and Maximo Point (8PI19). Since there were multiple sites that I assessed in the Tampa Bay, Florida area, I focused on one cultural period, Safety Harbor (AD 900-1500), and the ceramics created during it at the various locations. My research questions included: Were materials locally sourced for ceramic production at each of these sites? If not, what is the …

Archaeology And Seasonality Of Stock Island (8mo2), A Glades-Tradition Village On Key West, Ryan M. Harke

USF Tampa Graduate Theses and Dissertations

Later Glades-period cultures (ca. 500–1760 CE) of south Florida and the Florida Keys are understudied and thus poorly understood, especially those that pre-date the arrival of Spaniards to the New World. Recent archaeological models of their sociopolitical organization suggest that by the Glades I-II transition (750/800 CE), south Florida peoples were organized into what appear to be regional population centers (e.g., Pineland and Mound Key, Granada, Turner River) and smaller hinterland towns in the Everglades (e.g., Cane Patch, Bear Lake) and the Florida Keys (e.g., Stock Island, Clupper Site). Smaller towns are hypothesized to be sedentary, heterarchically-organized, simple chiefdoms from …