Geochemistry Commons^™

Preservation Of Sedimentary Rubidium Isotopic Signatures In Subduction Zones: Insights From The Schistes Lustrés Hp-Uhp Metasediments, Western Alps, Mary Clarich

UNLV Theses, Dissertations, Professional Papers, and Capstones

When oceanic plates bend and sink into the mantle at subduction zones, they carry sediments from the surface down into the mantle. The recycled sediments contain elements, that are depleted in the mantle, thereby influencing the composition of the mantle wedge and the formation of arc magmas, which are the building blocks of juvenile continental crust. However, it remains poorly constrained how much these elements, particularly fluid-mobile elements such as rubidium (Rb), are lost into fluids during metamorphic dehydration, and how much is transported to sub-arc depths where arc magmas are generated. Rubidium in subducting sediments is mainly hosted in …

Reconstructing Central American Hydroclimate Changes Across Time From Isotopic Signatures In Modern And Paleo-Rainfall Records, Giuseppe Lucia

UNLV Theses, Dissertations, Professional Papers, and Capstones

Tropical monsoon rainfall is a key component of Earth’s climate system and supports the livelihood and economy of billions of people. Yet, projections of future monsoons remain highly uncertain, particularly in regions with distinct physiography and complex land-ocean-atmosphere interactions like Central America, where long and continuous high-resolution paleoclimate data to test climate model simulations are still limited. This series of studies aims to reconstruct monsoon dynamics and underlying forcing controls in Central America on multiple timescales by the analysis and integration of stable isotope data in modern and paleo-rainfall records from Guatemala.

In Chapter 2, I present a daily-resolution, two-year-long …

Mechanisms Of Gold Enrichment In Seafloor Massive Sulfide Deposits: A Study On The Higashi-Aogashima Hydrothermal Field, Claudia Martinez

UNLV Theses, Dissertations, Professional Papers, and Capstones

The study of Seafloor Massive Sulfides (SMS) deposit formation is vital for assessing both the economic potential and environmental risks posed by future marine mining projects. Metal-rich SMS deposits form in hydrothermal vent systems within tectonically active regions, such as back-arc basins, where faults enhance crustal permeability, enabling fluid migration driven by magmatic heat sources at depth in the crust. Currently our understanding of SMS formation processes is based on bulk-rock geochemical and isotopic data, lacking the necessary spatial and temporal resolution to understand ore forming processes. As a result, critical gaps remain in understanding the exact mechanisms responsible for …

Analyzing Fe/Mg-Silicate Chemical Gardens As Analogs To Silicate-Rich Hydrothermal Chimneys On Early Earth And Mars, Nancy Alejandra Carman

UNLV Theses, Dissertations, Professional Papers, and Capstones

Hydrothermal systems have been proposed as environments for prebiotic chemistry on early Earth. Ancient Mars was an ocean world and could also have had hydrothermal vents supporting biological or prebiotic processes. The Strytan Hydrothermal Field (SHF) in Iceland is a basalt-hosted alkaline vent that forms massive hydrothermal Mg-saponite chimneys and is a potential analog to basalt-hosted alkaline vents that may have existed at the Eridania basin on Mars, where saponite deposits are thought to have formed from ancient hydrothermal activity. Chemical garden experiments have previously been used to simulate aspects of hydrothermal chimney growth for other types of vent systems; …

Investigating Controls On Temporal And Spatial Variation Of Dissolved Uranium At Springs In Horn Creek Drainage, Grand Canyon National Park, Arizona, Usa, Collin Davidson

UNLV Theses, Dissertations, Professional Papers, and Capstones

Groundwater is a critical resource in the Grand Canyon, providing water to local communities, millions of annual visitors, and ecosystems. One major concern for this critical resource is the potential for uranium contamination in conjunction with uranium mining efforts. Upper Horn Bedrock Spring (UHB) in the Horn Creek drainage of the Grand Canyon sits below the oldest uranium mine in the region, Orphan Lode mine. UHB spring contains the highest concentration of dissolved uranium in the region, eclipsing the Maximum Contaminant Level (MCL) set by the USEPA by an order of magnitude on average. This research and recent collaboration with …

New Observations On The Age And Origin Of The Geologist Seamounts, South Hawaiian Seamount Province, Brandon Chester Scott

UNLV Theses, Dissertations, Professional Papers, and Capstones

Investigation into seamounts that stem from intraplate volcanism—that is volcanism occurring far from plate boundaries—presents an opportunity to deconvolve processes associated with mantle compositional heterogeneities and melting dynamics. Upwelling and decompression of thermochemically anomalous mantle plumes is the primary mechanism for significant intraplate volcanism; however, many seamounts dotted across the Pacific Plate do not correlate spatially, temporally, or geochemically with mantle plume volcanism. One region of enigmatic volcanism in the ocean basins that is not clearly attributable to plume-derived magmatism are the Geologist Seamounts and the wider South Hawaiian Seamount Province (∼19°N, 157°W). Here we present merged multibeam (<100 m) and satellite altimetry bathymetric maps of the Geologist Seamounts region, new ^{40 …}

Climatic Influences On Incipient Alteration In Mars-Relevant Ultramafic Soils, Anthony Feldman

UNLV Theses, Dissertations, Professional Papers, and Capstones

An ongoing debate exists around the nature of the climatic conditions present during the Noachian and early Hesperian periods (~4.1 to 3 Gyr ago) of Mars’ ancient history. The various theories put forward can reasonably be grouped into “warm and wet” vs “cold and icy” camps. Warm and wet approximates an Earth-like system with a relatively clement climate with significant liquid water present including potentially long-lived oceans. Cold and icy theories generally postulate thick ice sheets at high elevations with periodic warming events driving precipitation and the formation of river channels and leading to the formation of chemical alteration products. …

Magmatic Processes Leading To Compositional Diversity In The Mars Crust, Amanda Marie Ostwald

UNLV Theses, Dissertations, Professional Papers, and Capstones

The ancient Mars crust can yield insights into planet formation and evolution that Earth cannot. Direct investigation of the martian surface is limited to studies on meteorites and rover-obtained analyses. The nakhlites and chassignites, two classes of martian meteorites, are together the largest suite of martian meteorites derived from a single location on the surface. As such, they present a rare opportunity to study the Mars crust in detail using samples bearing a contextual relationship. Rover studies have found a surprising amount of compositional diversity in surface materials, the formation mechanisms of which are not well-constrained. This dissertation leverages meteorites …

Study Of Trace Elements In Southern Nevada Spring Waters And Lakes, Hyejeong Lee

UNLV Theses, Dissertations, Professional Papers, and Capstones

Comprehending the natural water resource is imperative for the entire state of Nevada and of particular significance for Southern Nevada, where rapid population growth and climate change are placing significant strain on supplies. This research underscores the significance of water chemistry in identifying potential water source areas through trace elements. For the first time, the study proposed measuring the compositions of the entire suite of metal elements, ranging from Li to U, in over 40 springs in the Moapa Valley and its upper gradient valleys, utilizing the iCAP Qc ICP-MS (Inductively Coupled Plasma Mass Spectrometer) at UNLV. The research evaluated …

Trace Element Behaviors During Igneous Evolution And Hydrothermal Alteration Of An Evolved Rhyolite, The Blawn Formation, Wah Wah Mountains, Utah: Implications For Critical Metal Abundances In Highly Evolved Rhyolites, Drew William Barkoff

UNLV Theses, Dissertations, Professional Papers, and Capstones

A-type rhyolites and granites often contain elevated concentrations of the rare earth elements (REE) and many other critical trace elements relative to I- and S-type rhyolites and granites. Their trace element-enriched nature makes them potentially prospective bulk tonnage, low-grade resources of the REE and many other critical trace elements, including Li, Be, Mo, Sn, and W, but little work has been performed to delineate their economic potential. The 22.1 Ma Red Beryl Rhyolite (RBR) and the 18.3 Ma Tetons Rhyolite (TR) units of the Blawn Formation represent two A-type rhyolite domes located in the southern Wah Wah Mountains of Utah. …

Paleoenvironmental Changes Across The Devonian-Carboniferous Transition, Audrey M. Warren

UNLV Theses, Dissertations, Professional Papers, and Capstones

The Devonian-Carboniferous (D-C) transition was a critical interval in earth history, witnessing profound environmental changes associated with plant and animal evolution and extinction. Two first-order mass extinctions occurred leading up to the D-C boundary: the Kellwasser Event at the Frasnian-Famennian (F-F) boundary (~371 Ma) and the D-C boundary Hangenberg Event (~359 Ma). Both events were associated with significant sea level changes and major carbon cycle perturbations, evidenced by widespread deposition of black shale and positive carbon isotope (δ13C) excursions, all of which have been used to correlate these events across the globe. Because preservation of black shale requires anoxic conditions, …

Antler Foreland Basin Evolution Recorded In Detrital Zircon U-Pb Geochronology, James Duncan

UNLV Theses, Dissertations, Professional Papers, and Capstones

The Antler orogeny was a Devonian-Mississippian (375-320 Ma) mountain building event that occurred along the western Laurentian margin. The initiation of the Antler orogeny is marked by the emplacement of the Roberts Mountain Allochthon (RMA) that thrust Cambrian-Devonian deep water marine siliciclastic rocks 100 km eastward onto the western Laurentian margin. Shortening related to the Antler orogeny deformed RMA strata and caused a flexural response in the continental crust that resulted in the formation of the adjacent Antler Foreland basin. The paleogeographic history of the RMA strata and tectonic drivers for the Antler orogeny are still debated. Proposed models suggest …

Petrogenesis Of Hawaiian Lavas: Investigations Using Radiogenic And Non-Traditional Stable Isotopes, Christopher Defelice

UNLV Theses, Dissertations, Professional Papers, and Capstones

Earth’s mantle is the most voluminous part of the planet and is inaccessible to direct investigations. It is only possible to study it through indirect methods, such as the chemical makeup of erupted lavas. The Hawaiian Islands are thought to be the product of the mantle plume hypothesis, sometimes called a hot spot. Material from the Earth’s mantle is brought to the surface and erupted as magnesium rich lavas and form basalts. Hawaii is the longest lived active hot spot on Earth and makes it an ideal candidate for understanding the evolution of the Earth’s mantle and how lavas cool …

Chronicling Magma Transit Beneath Hawaiian Volcanoes: Every Isotope A Word, Every Crystal A Story, Jonathan Pinko

UNLV Theses, Dissertations, Professional Papers, and Capstones

At many oceanic volcanoes, such as Hawaii, mantle-derived magmas migrate to crustal level magma chambers, where they accumulate before eruption. Understanding the magma chamber residence times, or the time gaps between the arrivals of new magmas and eruptions, is important in volcanic hazard mitigation. Here I apply iron and magnesium isotope effects in olivines to constrain these times at Hawaiian volcanoes. Combined with published data, I present bulk ?56Fe (-1.706 to 0.489) and ?26Mg (-0.400 to 0.356) in 108 Hawaiian olivines erupted from the pre-shield, shield, and post-shield stages. The Hawaiian olivine ?56Fe and ?26Mg represent the largest Fe-Mg isotope …

Microbe-Mineral Interactions During Exceptional Fossil Preservation, Stromatolite Formation, And Desert Varnish Growth, Michael Strange

UNLV Theses, Dissertations, Professional Papers, and Capstones

The Ediacaran to Cambrian Deep Spring Formation consists of mixed carbonate-siliciclastic strata which contain an increasingly complex and biogeographically important biota. Past investigations of the Deep Spring Formation at Mt. Dunfee, Nevada, explored the highly diverse microbialite reefs consisting of a wide range of stromatolite morphologies which exerted significant control on local sedimentation and topography. Early investigations also documented the biomineralizing metazoan Cloudina (an Ediacaran index fossil). However, recent exploration of the area has resulted in the discovery of several new metazoan fossil communities consisting of a diverse assemblage of Ediacaran soft-tissue tubicolous vermiforms (tube fossils) similar to Cloudina. The …

Petrogenesis Of Unusual Occurrence Of Amphibole Asbestos In Mohave County, Arizona And Clark County, Nevada, Tomoyo Austin

UNLV Theses, Dissertations, Professional Papers, and Capstones

The term “asbestos” applies to six types of fibrous amphiboles or chrysotile with specific morphologies that are commercially mined and processed. Inhaling asbestos fibers is known to cause many negative health effects, including mesothelioma, several different cancers, various respiratory diseases and non-respiratory diseases, and fatalities. The recent years, several cases of non-occupational exposure to asbestos fibers raised an awareness of environmental exposure to naturally occurring asbestos (NOA) which refers to asbestiform minerals that fall out of the regulatory definition of asbestos.

There are two sources of NOA in the area, Wilson Ridge pluton, AZ, and Boulder City pluton, NV which …

Dissolution Rates Of Allophane, Fe-Allophane, And Hisingerite And Implications For Aqueous Alteration On Mars And In Potential Returned Martian Samples, S. J. Ralston

UNLV Theses, Dissertations, Professional Papers, and Capstones

Recent measurements from Mars document X-ray amorphous/nano-crystalline materials in multiple locations across the planet. However, despite their prevalence, little is known about these materials or what their presence implies for the history of Mars. The amorphous component of the martian soil in Gale Crater has an X-ray diffraction pattern that can be partially fit with allophane (approximately Al2O3•(SiO2)1.3-2•(H2O)2.5-3), as well as low-temperature water release consistent with allophane. The chemical data from Gale Crater suggest that other silicate phases similar to allophane, such as Fe-substituted allophane (here, approximately (Fe2O3)0.01(Al2O3)0.99(SiO2)2•3H2O) and hisingerite (approximately Fe3+2Si2O5(OH)4•(H2O)), may also be present. In order to investigate …

Petrology And Geochemistry Of The Enriched Poikilitic Shergottite Northwest Africa 10169: Insight Into The Martian Interior, Logan Matthew Combs

UNLV Theses, Dissertations, Professional Papers, and Capstones

The martian meteorite Northwest Africa (NWA) 10169 is classified as a new member of the geochemically enriched poikilitic shergottites, based on mineral composition, Lu-Hf isotope systematics, and rare earth element (REE) composition. Akin to other poikilitic shergottites, it shows a similar bimodal texture to other enriched and intermediate poikilitic shergottites. In addition, olivine and pyroxene in the poikilitic zone have higher Mg#’s (Mg/Mg+Fe) than those in the interstitial areas, suggesting that the poikilitic texture represents early-stage crystallization, opposed to late-stage non-poikilitic crystallization. Calculated fO2 values are reduced (FMQ -2.3 ± 0.23) within the poikilitic texture, and more oxidized (FMQ -1.07 …

Phosphate Release: The Effect Of Prebiotic Organic Compounds On Dissolution Of Merrillite, Whitlockite, Chlorapatite, And Fluorapatite, Courtney Lea Bartlett

UNLV Theses, Dissertations, Professional Papers, and Capstones

Phosphate is an essential nutrient on Earth, used by life for ATP, DNA, RNA, and phospholipid membranes. Therefore, if life is or ever was present on Mars, phosphorus may have played an important role in determining the habitability of an environment. Phosphorus does not have a significant volatile phase; its release from minerals is consequently critical to phosphorus availability and prebiotic chemistry. Phosphate release from Mars-relevant minerals such as merrillite and chlorapatite has been previously found to differ significantly from phosphate release from fluorapatite, the dominant phosphate phase on Earth. However, the environments in which phosphate release would have been …

An Elemental Highway: Investigation Of A High Nickel Anomaly In Olivine From The Island Of Niihau, Hawaii, Alexander James Valentine

UNLV Theses, Dissertations, Professional Papers, and Capstones

The study of volcanic geochemistry is one of the main gateways for investigating the Earth’s mantle. One important topic in the field is that of nickel (Ni) in the mineral olivine. While Ni is a compatible element in olivine, its high concentration at a given MgO content is not well understood. A variety of hypotheses have been proposed, including attributing presence of Ni to pyroxenite source melting, contribution from the core, or variation in peridotite source melting. In addition to the other hypotheses, chemical diffusion may also be a mechanism for enriching olivine Ni concentration. Magnesium-iron (Mg-Fe) isotopic measurements have …

Characterizing Crystal Populations For The Petrogenesis Of The Post-Collapse Rhyolites In The Long Valley Caldera, California, William Joseph

UNLV Theses, Dissertations, Professional Papers, and Capstones

Post-collapse rhyolites of the Long Valley in eastern California are the product of remelting of crystal mush bodies via mafic rejuvenation following the eruption of the Bishop Tuff. This is supported by mineral textures and major element geochemistry from the Resurgent Dome rhyolite, the Moat rhyolite, the Hot Creek Flow, and the Deer Mountain rhyolite. New 40Ar/39Ar eruptive ages are reported for the Moat rhyolites (525 ka, 333 ka, 118 – 94 ka), Hot Creek Flow (312 – 295 ka), and the Deer Mountain rhyolite (65 ka). The initial post-collapse eruptions, resulting in the Resurgent Dome rhyolite, appear to be …

Characterizing The Earliest Stages Of Partial Melting: A Study Of The Pyrometamorphic Aureole Of Miocene Mt. Perkins Pluton, Northwest Arizona, Mathew Beshears

UNLV Theses, Dissertations, Professional Papers, and Capstones

Partial melting is an important process in the evolution of continental crust. Due to its progressive nature, evidence of the early stages of partial melting is often overprinted by later, advanced stages of partial melting. Experimental work has provided a model for the early stages of partial melting, but is limited to timescales of hours to weeks. Pyrometamorphic environments within the contact aureole of mafic intrusions provide natural laboratories for the study of the earliest stages of partial melt production on geologic time scales of 102 collected along two traverses of the tilted pyrometamorphic aureole of the Mt. Perkins pluton …

Characterization Of Gold And Related Mineralization At The North Bullion Carlin System, Railroad Project, A Nevada Carlin-~Type Gold Prospect, Melanie Nicole Newton

UNLV Theses, Dissertations, Professional Papers, and Capstones

A study of the North Bullion Carlin system, a Nevada Carlin-type gold prospect located on trend with the large Carlin-type gold deposits (CTGD) of the Carlin Trend, identified characteristics of ore and alteration mineralization, mineral paragenesis, and pyrite and whole rock geochemistry that are similar to characteristics that typify Carlin-type gold deposits. The North Bullion Carlin system is hosted in Devonian shelf carbonates and the Mississippian overlap assemblage, host rocks that are different from typical CTGD shelf-slope carbonate assemblage host rocks. The mineralogy and ore-stage gold-bearing pyrite rims at North Bullion are not as well developed as they are in …

Ediacaran Ocean Redox Evolution, Swapan Kumar Sahoo

UNLV Theses, Dissertations, Professional Papers, and Capstones

The relative role that environmental versus intrinsic biological factors played in

shaping the history of life on Earth is a fundamental but unanswered question in the

natural sciences. Most famously, it has been heavily debated if the emergence and

diversification of early animals during the Ediacaran Period (ca. 635–541 Ma) was tied to

a rise in atmospheric-oceanic oxygen levels. Temporally discontinuous geochemical data and patchy fossil record in literature are inadequate to chart the Ediacaran redox history and its causal relationship with the biotic evolution. My PhD study aims for a multiproxy geochemical record within a well-established stratigraphic framework of …

Dissolution Of Nontronite In Low Water Activity Brines And Implications For The Aqueous History Of Mars, Michael Henry Steiner

UNLV Theses, Dissertations, Professional Papers, and Capstones

Water is essential to life on Earth and is likely to play a role in determining the habitability of other planets. Pure liquid water is not stable on the surface of Mars but brines can temporarily remain liquid, and increasing evidence suggests the presence of recent liquid water, including brines, on Mars. Brines can host life at temperatures as low as -30 ºC and some organisms can live at activities of water as low as 0.61. Therefore, if brines have been present on Mars, they may act as habitable environments.

The Fe-rich smectite nontronite, (CaO0.5,Na)0.3 Fe3+2(Si,Al)4O10(OH)2·nH2O, has been detected on …

Predictive Modeling Of Terrestrial Radiation Exposure From Geologic Materials, Daniel A. Haber

UNLV Theses, Dissertations, Professional Papers, and Capstones

Aerial gamma ray surveys are an important tool for national security, scientific, and industrial interests in determining locations of both anthropogenic and natural sources of radioactivity. There is a relationship between radioactivity and geology and in the past this relationship has been used to predict geology from an aerial survey. The purpose of this project

is to develop a method to predict the radiologic exposure rate of the geologic materials in an area by creating a model using geologic data, images from the Advanced Spaceborne Thermal Emission and Reflection Radiometer (ASTER), geochemical data, and pre-existing low spatial resolution aerial surveys …

An Investigation Into Transitions In Clay Mineral Chemistry On Mars, Seth Gainey

UNLV Theses, Dissertations, Professional Papers, and Capstones

This dissertation is comprised of three studies investigating clay mineralogy on, or near the martian surface, with an introductory chapter, introducing and linking the three studies. Chapter two is on the subject of clay mineral synthesis, including Fe/Mg clay minerals which have been detected at multiple locations across the southern highlands. These Fe/Mg clay minerals have been previously interpreted as forming in anoxic/reducing environments, conducive to the preservation of organic matter. The results of this study suggest that the previous interpretation of Fe/Mg-rich clay as requiring anoxic/reducing conditions may not be accurate, as the minor presence of Mg (below what …

Modeling Background Radiation Using Geochemical Data, Kara Marsac

UNLV Theses, Dissertations, Professional Papers, and Capstones

Aerial gamma ray surveys have many applications in geology and science in general, such as locating mining prospects, defining radioactive plumes, and detecting nuclear weapons. Unfortunately there is currently no simple way to separate the natural gamma radiation of soil and rocks from that of contaminants such as radioactive plumes. This project used geochemical data (uranium, potassium and thorium concentrations) collected from national databases, private companies, and the NURE (National Uranium Resource Evaluation) Survey, to create forward models of exposure rates measured by aerial gamma ray surveys. We developed these techniques using an area in north central Arizona known as …

Carbon Isotope Variations Associated With A Middle Ordovician Karstic Unconformity, Patricia Suzanne Williams

UNLV Theses, Dissertations, Professional Papers, and Capstones

Large negative carbon isotope (δ¹³C) excursions have been documented from late Neoproterozoic-Paleozoic successions. These δ¹³C excursions have been widely used for regional and global stratigraphic correlation, particularly in strata with limited paleontological and radiometric age controls. Recent studies, however, argued that some negative δ¹³C excursions from stratigraphic record may have been resulted from meteoric/burial diagenesis, which commonly shifts both carbon and oxygen isotopes toward lower values. Testing the diagenetic origin of δ¹³C excursions in stratigraphic successions without independent stratigraphic framework has been difficult because it evolves into circular arguments about stratigraphic completeness …

Subalklaine Volcanism In The Eastern Basin And Range Province: Examples From The Miocene Mccullough Range Volcanic Field And The Pliocene To Holocene Black Rock Desert Volcanic Field, Racheal Leighann Johnsen

UNLV Theses, Dissertations, Professional Papers, and Capstones

This dissertation is composed of three papers that apply geologic mapping, whole rock geochemical and isotopic analysis, and mineral chemistry to describe two large, long-lived (~6 million years), and compositionally heterogeneous volcanic fields and posit sources of the rock types present in each. These fields are the McCullough Range in southern Nevada, which was a locus of volcanic activity from ~19 - 12 Ma and the Black Rock Desert volcanic field in west-central Utah, which began forming at ~6 Ma and is still active today, with the most recent eruption occurring ~720 years ago.

Chapter Two is composed of a …