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Full-Text Articles in Geochemistry

The Fossil Pearls Of The Million-Pearls Flowstone, Fairgrounds Room, Fort Stanton Cave, New Mexico Usa, Victor J. Polyak, Paula P. Provencio, Yemane Asmerom Sep 2026

The Fossil Pearls Of The Million-Pearls Flowstone, Fairgrounds Room, Fort Stanton Cave, New Mexico Usa, Victor J. Polyak, Paula P. Provencio, Yemane Asmerom

International Journal of Speleology

‘Fossil’ cave pearls in the Fairgrounds Room of Fort Stanton Cave form two distinct layers in a flowstone sample, FS-14-2. The flowstone in the Fairgrounds Room covers a mud-silt bank and the extinct streambed that extends across the room. Uranium-series dates of two pieces of flowstone from this room, one piece from the higher end of the flowstone (FS-14-1, devoid of pearls), and another piece from the lower end of the flowstone (FS-14-2, rich in pearls), show that the flowstone was deposited during the Last Glacial period (60,000 to 11,000 yr BP).  The two cave-pearl layers in FS-14-2 yielded U-series …


Response Of Botovskaya Cave To Local And Regional Environmental Dynamics, Jade Margerum, Oksana Gutareva, Franziska Lechleitner, Maria Box, Stuart Umbo, Anton Vaks, Hanno Meyer, Aleksandr Kononov, Aleksander Osintsev, Dimitri Sokol'nikov, Norbert Marwan, Ola Kwiecien, Sebastian Breitenbach Mar 2026

Response Of Botovskaya Cave To Local And Regional Environmental Dynamics, Jade Margerum, Oksana Gutareva, Franziska Lechleitner, Maria Box, Stuart Umbo, Anton Vaks, Hanno Meyer, Aleksandr Kononov, Aleksander Osintsev, Dimitri Sokol'nikov, Norbert Marwan, Ola Kwiecien, Sebastian Breitenbach

International Journal of Speleology

Speleothems from caves in near-permafrost regions can provide unique insights into the climatic history of temperature-sensitive environments. These regions are often remote and only seasonally accessible, which makes cave monitoring – a requirement for speleothem-based proxy interpretation – challenging. We document ventilation, the infiltration regime, and the isotopic composition of dripwater in Botovskaya Cave in southern Siberia, a host to speleothems previously used to reconstruct Quaternary permafrost dynamics in continental Eurasia. We explore surface and cave temperature records, cave air CO2 concentration data and stable isotopes in precipitation and dripwater and evaluate infiltration conditions and the sensitivity of speleothems …


Exceptional Variety Of Baryte-Celestine-Series Speleothems In Lechuguilla Cave (New Mexico, Usa), Max Wisshak, Johannes Birkenstock, Andrea Schröder-Ritzrau, Norbert Frank, Hazel A. Barton, Harvey R. Duchene Feb 2026

Exceptional Variety Of Baryte-Celestine-Series Speleothems In Lechuguilla Cave (New Mexico, Usa), Max Wisshak, Johannes Birkenstock, Andrea Schröder-Ritzrau, Norbert Frank, Hazel A. Barton, Harvey R. Duchene

International Journal of Speleology

An inventory of speleothems primarily composed of the closely related sulfate minerals baryte (BaSO4) and celestine (SrSO4) in Lechuguilla Cave (New Mexico, USA) has revealed an extraordinary variety. This includes subaerial stalactites, stalagmites, flowstone, coralloids, wall crusts, floor crystals, snow, frostwork, and subaqueous pool crystals. Large baryte and celestine crystals have also been documented in hydrothermal veins in the host rock, predating the cave and truncated when intersected by it. The respective carbonate mineral phases witherite (BaCO3) and strontianite (SrCO3), in contrast, were found to be rare in the studied speleothem samples, …


Assessing The Impact Of Visitors On Airborne Particle Deposition In The Giant Gypsum Geode Of Pulpí (Se Spain), Ana Camila Mendoza, Ángel Fernández-Cortés, Fernando Gázquez, Jesús Morilla, Milagros Carretero, Jose Maria Calaforra, David Benavente Jan 2026

Assessing The Impact Of Visitors On Airborne Particle Deposition In The Giant Gypsum Geode Of Pulpí (Se Spain), Ana Camila Mendoza, Ángel Fernández-Cortés, Fernando Gázquez, Jesús Morilla, Milagros Carretero, Jose Maria Calaforra, David Benavente

International Journal of Speleology

The Giant Geode of Pulpí is a unique mineralogical phenomenon worldwide, remarkable for its large selenite gypsum crystals. Its recent development as a tourist site and inclusion on UNESCO’s Tentative World Heritage List, highlight the need to assess the impact of visits on its conservation. This study investigates airborne particle dynamics inside the Geode, focusing on tourist activity and natural ventilation. We measured deposition rates and composition of airborne particles using passive traps and a continuous laser-optical particle counter. Microenvironmental variables linked to ventilation, such as temperature and radon gas concentration (²²²Rn), were simultaneously monitored. Results show a predominance of …


Non-Destructive Characterization Of Variously Colored Gypsum And Aragonite/Calcite Speleothems From The Cigalère Cave (Ariège, France), Martin Vlieghe, Johan Wouters, Gérald Fanuel, Jean-François Drion Du Chapois, Anne Gallez, Stéphane Pire-Stevenne, Gaëtan Rochez, Johan Yans Jan 2026

Non-Destructive Characterization Of Variously Colored Gypsum And Aragonite/Calcite Speleothems From The Cigalère Cave (Ariège, France), Martin Vlieghe, Johan Wouters, Gérald Fanuel, Jean-François Drion Du Chapois, Anne Gallez, Stéphane Pire-Stevenne, Gaëtan Rochez, Johan Yans

International Journal of Speleology

The Cigalère Cave is a 21 km-long karstic cave located in the Ariège Department, in the French Pyrenees, and underlies directly the Bentaillou Pb-Zn-Fe sulfide ores. The cave hosts abundant gypsum mineralizations, some of them exhibiting various colorations including blue, yellow, purple, orange and black. Due to strict preservation policies, these colored mineralizations have not been studied much. Here we propose a non-destructive characterization of five distinct gypsum or carbonate speleothem structures from the Cigalère, exhibiting different colorations. To comply with the preservation policies, no sample was taken from the cave, and all speleothems were analyzed in situ using portable …


Pre-Calibration Of Δ18O For Paleoclimatic Interpretations Using Stalagmites In Cueva Ensueño, Puerto Rico, Gabriel Enrique López Borobia, Ny Riavo G. Voarintsoa, Ricardo Sánchez-Murillo, Pablo Antonio Llerandi Román Oct 2025

Pre-Calibration Of Δ18O For Paleoclimatic Interpretations Using Stalagmites In Cueva Ensueño, Puerto Rico, Gabriel Enrique López Borobia, Ny Riavo G. Voarintsoa, Ricardo Sánchez-Murillo, Pablo Antonio Llerandi Román

International Journal of Speleology

Stalagmites are invaluable archivers of past climate conditions, as their oxygen isotopic composition (δ¹⁸Oc) closely mirrors the isotopic signature of the drip water (δ¹⁸Ow) from which they precipitate. This isotopic relationship is governed by the fractionation factor (1000ln¹⁸α), which is temperature dependent. In this research, we studied 1000ln¹⁸α within Cueva Ensueño, a cave situated in Puerto Rico’s northern karst region, as a step toward calibrating δ¹⁸Oc for paleoclimate interpretations using stalagmites. We collected drip waters, measured their temperature in situ, and sampled carbonates from ten selected stations within the cave. Sampling was conducted in December …


The Taxonomy And Origins Of Folia: A Brief Review, Donald G. Davis, Louise D. Hose, Harvey R. Duchene Oct 2025

The Taxonomy And Origins Of Folia: A Brief Review, Donald G. Davis, Louise D. Hose, Harvey R. Duchene

International Journal of Speleology

All folia demonstrate a few common elements: folia (singular, folium) are planar or sub-planar speleothems, slanting downward and away from cave walls and ceilings, and genetically associated with fluctuating environmental interfaces. They were first identified and named from examples in western USA hypogenic caves but have since been identified elsewhere in the world. Folia shelves are typically composed of calcite and interweave smoothly along sub-horizontal contours. Calcite accretion, both chemical and mechanical from suspended particles, follows water-surface fluctuations to form protrusions in arrays along walls and ceilings where new accretion tends to follow the water-surface downward during descending phases, gradually …


Evaluation Of Practical Methods To Determine If A Karst Creek Is Gaining Or Losing: Case Study Of Leith Creek, Elizabeth Jones Jan 2025

Evaluation Of Practical Methods To Determine If A Karst Creek Is Gaining Or Losing: Case Study Of Leith Creek, Elizabeth Jones

Graduate Theses/Dissertations

Karst landscapes are abundant in Missouri, with features such as caves, springs, and sinkholes that form through the dissolution of limestone. Leith Creek is a small stream in Polk County, Missouri fed by two springs and the shallow unconfined Springfield Plateau aquifer, a highly karstified aquifer which is made up of limestone and minor interbedded shale-mudstone units. To determine if Leith Creek is gaining or losing, stream flow, water chemistry and temperature sensors were monitored. Stream flow results required multiple visits to take measurements while temperature sensors required two visits, one to install the dataloggers and another to remove the …


Manifestations Of Sulfuric Acid Speleogenesis In The Mulapampa Travertine, Central Andes Of Peru: Evidence From The Gruta Con Lago, Andrzej Tyc, Krzysztof Gaidzik, Justyna Ciesielczuk, Katarzyna Wątor Oct 2024

Manifestations Of Sulfuric Acid Speleogenesis In The Mulapampa Travertine, Central Andes Of Peru: Evidence From The Gruta Con Lago, Andrzej Tyc, Krzysztof Gaidzik, Justyna Ciesielczuk, Katarzyna Wątor

International Journal of Speleology

Sulfuric acid speleogenesis (SAS) is a form of hypogene speleogenesis characterized by the formation of caves in carbonate rocks due to the presence of sulfuric acid. This study focuses on the Gruta con Lago, one of three caves identified in the Mulapampa travertine, located in the central Andes of Peru. These caves are accessed through collapse sinkholes, and much of their morphology results from roof breakdown. The bottom of the studied cave is situated at the current water table. Despite the absence of typical solutional features associated with SAS caves, mineralogical and geochemical evidence of speleogenesis involving H2SO …


Hypogenic Caves Of Syracuse Area, Sicily (Italy): Geomorphological Evidence Of Co2 Degassing, Fresh-Salt Water Mixing, And Late Condensation Corrosion, Philippe Audra, Jean-Yves Bigot, Didier Cailhol, Pierre Camps, Ilenia M. D'Angeli, Hai Cheng, R. Lawrence Edwards, Fernando Gàzquez-Sanchez, Gabriella Koltai, Giuliana Madonia, Jean-Claude Nobécourt, Marjan Temovski, Marco Vattano, Jo De Waele Aug 2024

Hypogenic Caves Of Syracuse Area, Sicily (Italy): Geomorphological Evidence Of Co2 Degassing, Fresh-Salt Water Mixing, And Late Condensation Corrosion, Philippe Audra, Jean-Yves Bigot, Didier Cailhol, Pierre Camps, Ilenia M. D'Angeli, Hai Cheng, R. Lawrence Edwards, Fernando Gàzquez-Sanchez, Gabriella Koltai, Giuliana Madonia, Jean-Claude Nobécourt, Marjan Temovski, Marco Vattano, Jo De Waele

International Journal of Speleology

Many caves in Sicily have been shown to have a sulfuric acid or other hypogenic origin. We studied three caves (Palombara, Scrivilleri, Monello) near Syracuse (eastern Sicily), in an area that was strongly uplifted and faulted, creating multiple Pleistocene marine terraces. Mineralogy, stable isotopes and dating methods (paleomagnetism, U/Th) were used to characterize cave sediments, some of which were related to the initial hypogenic phase (Fe and Mn oxides, calcite spar), others were introduced by surface runoff later. Many other sediments are the result of in situ weathering, such as lime sands produced by condensation-corrosion processes on the calcarenite walls. …


Hypogene Speleogenesis In Carbonates By Cooling Hydrothermal Flow: The Case Of Mt. Berenike Caves, Israel, Roi Roded, Boaz Langford, Einat Aharonov, Piotr Szymczak, Micka Ullman, Shemesh Yaaran, Boaz Lazar, Amos Frumkin Aug 2024

Hypogene Speleogenesis In Carbonates By Cooling Hydrothermal Flow: The Case Of Mt. Berenike Caves, Israel, Roi Roded, Boaz Langford, Einat Aharonov, Piotr Szymczak, Micka Ullman, Shemesh Yaaran, Boaz Lazar, Amos Frumkin

International Journal of Speleology

The Berenike hypogenic cave system near Lake Kinneret, Israel, provides a valuable case study for investigating the recently proposed Confined-Cooling-Flow (CCF) speleogenesis model. Field and speleological surveys, along with existing research, are used to provide a thorough analysis. The CCF model relies on a simple thermo-hydro-chemical scenario, involving the rise of CO2-rich hydrothermal fluids discharging into a confined layer. The cooling of these CO2-rich fluids turns them into aggressive solutions due to the inverse relation between temperature and solubility of carbonates (retrograde solubility). Previous geochemical and numerical analyses of the CCF model predict localized and persistent dissolution and speleogenesis on …


Constraining The Evolutionary Stages Of A Hypogene Karst System By Combining Morphological, Geochemical And Geochronological Data - The Example Of Carbonate Breccia-Hosted Melnička Peštera, Marjan Temovski, Zsófia Ruszkiczay-Rüdiger, Kata Molnár, László Rinyu, Alexander Wieser, Oscar Marchhart, László Palcsu Jul 2024

Constraining The Evolutionary Stages Of A Hypogene Karst System By Combining Morphological, Geochemical And Geochronological Data - The Example Of Carbonate Breccia-Hosted Melnička Peštera, Marjan Temovski, Zsófia Ruszkiczay-Rüdiger, Kata Molnár, László Rinyu, Alexander Wieser, Oscar Marchhart, László Palcsu

International Journal of Speleology

A combination of morphological observations, geochemical data from calcite minerals and geochronology by burial age dating and U-series is used to constrain the geological and geomorphological setting and the evolutionary stages of a hypogene karst system. This methodological suit is applied to Melnička Peštera, a horizontal cave developed in carbonate breccia overlying dolomite marble in Melnica locality (N. Macedonia), where hydrothermal karst development occurred in both dolomite and calcite marble. The passage morphology of the cave, having a reverse triangle, Laughöhle cross-sections, suggests development near the water table by slowly moving waters. Calcite crusts are found throughout the cave, and …


Revealing The Ongoing Speleogenetic Processes In An Underwater Cave Through The Application Of Natural Radionuclides And Stable Isotopes: Case Study From The Hypogene Buda Thermal Karst, Anita Erőss, Katalin Hegedűs-Csondo, Petra Kovács-Bodor, Dénes Szieberth, Ákos Horváth, György Czuppon, Andrea Mindszenty Dr, Szabolcs Leél-Őssy, Judit Mádl-Szőnyi Jul 2024

Revealing The Ongoing Speleogenetic Processes In An Underwater Cave Through The Application Of Natural Radionuclides And Stable Isotopes: Case Study From The Hypogene Buda Thermal Karst, Anita Erőss, Katalin Hegedűs-Csondo, Petra Kovács-Bodor, Dénes Szieberth, Ákos Horváth, György Czuppon, Andrea Mindszenty Dr, Szabolcs Leél-Őssy, Judit Mádl-Szőnyi

International Journal of Speleology

The underwater Molnár János Cave in the hypogene Buda Thermal Karst system (Budapest, Hungary) provides a unique site to study the effects of flowing groundwater and the interplay of fluids of different origin. The aim of the present study is to characterize the groundwater in different parts of the cave with temporal resolution, hence describe the recent speleogenetic processes within the cave. This study uses natural radioisotopes (uranium, radium, and radon) besides stable isotope ratios of oxygen and hydrogen to identify the different fluid components. The results show that the majority of the cave is situated in the flow path …


Correlation Of Geochemical Zones In Great Onyx Cave, Mammoth Cave National Park, To Surficial Geological Units, William Strehl Jan 2024

Correlation Of Geochemical Zones In Great Onyx Cave, Mammoth Cave National Park, To Surficial Geological Units, William Strehl

Mahurin Honors College Capstone Experience/Thesis Projects

Cave passages in Great Onyx Cave, developed within the Girkin and Ste. Genevieve Limestones of Mammoth Cave National Park, contain a variety of secondary features on cave walls, including speleothems such as stalactites, stalagmites, and flowstone, evaporite minerals, and dissolution features such as pits and domes. What secondary features are present on the walls of a cave passage depends on the flow and geochemistry of capillary water that has interacted with the cave passage. In the Mammoth Cave aquifer, five distinct geochemical zones have been broadly defined and each typically contains a particular set of secondary features. Geochemical zonation in …


Reverse Pseudo-Gours: A New Sub-Type Of Folia Observed In The Nerja Cave (Se Spain), Cristina Liñán Baena, Concepción Jiménez De Cisneros, Yolanda Del Rosal, Paolo Forti Dec 2023

Reverse Pseudo-Gours: A New Sub-Type Of Folia Observed In The Nerja Cave (Se Spain), Cristina Liñán Baena, Concepción Jiménez De Cisneros, Yolanda Del Rosal, Paolo Forti

International Journal of Speleology

A new sub-type of folia named “reverse pseudo-gour” has been observed and described in the Nerja Cave, southern Spain. It consists of fairly vertical, thin barriers (about 5 mm high and 2 mm thick) that develop on the underside of a sub-horizontal surface (shelfstone) and grow in the opposite direction to normal gours (rimstone dams), generating sinuous shapes. Their mineral composition is essentially calcium carbonate, although globular aggregates composed of clay and phosphate minerals have also been identified. The genesis and evolution of these reverse pseudo-gours occur just at the air-water interface and are controlled by (1) the sub-horizontality of …


Cryogenic Ridges: A New Speleothem Type, Bogdan P. Onac, Daniel M. Cleary, Oana A. Dumitru, Victor J. Polyak, Ioan Povara, Jonathan G. Wynn, Yemane Asmerom Jan 2023

Cryogenic Ridges: A New Speleothem Type, Bogdan P. Onac, Daniel M. Cleary, Oana A. Dumitru, Victor J. Polyak, Ioan Povara, Jonathan G. Wynn, Yemane Asmerom

International Journal of Speleology

Cryogenic cave carbonates have been described from several formerly or presently glaciated karst caves. In most of these occurrences, they precipitated as loose grains or aggregates with various morphologies and sizes. Here, we report on a new speleothem type (cryogenic ridges) identified in Sohodoalele Mici Cave (SW Romania) within a large chamber near the entrance shaft. This study was motivated by the presence of a network of calcite ridges over the stalactites’ surface and by the observation that during winter, these speleothems are covered by a thin ice layer. The higher δ18O (−3.5 to –1‰) and …


Chemical Characterization Of Clastic Cave Sediments And Insights Into Particle Transport And Storage In Karst Aquifers, Jill L. Riddell Jan 2022

Chemical Characterization Of Clastic Cave Sediments And Insights Into Particle Transport And Storage In Karst Aquifers, Jill L. Riddell

Graduate Theses, Dissertations, and Problem Reports (ETD)

Abstract

Chemical characterization of clastic cave sediments and insights into particle transport and storage in karst aquifers

Jill L. Riddell

Cave sediments can be divided into two groups: precipitates and clastics. Precipitates are speleothems, or lithologic or mineral features that are chemically precipitated in the cave environment. Clastic cave sediments are frequently described by depositional facies, sorting, and particle size (Bosch and White, 2004). Robust analytical chemical analyses of these sediments to quantify their physical and chemical components is rarely performed although some chemical characterization of mineralogy and paleomagnetism has become prevalent in recent years (Chess et al., 2010; Sasowsky …


Low Impact Sampling Of Speleothems – Reconciling Scientific Study With Cave Conservation, Claire L.V. Macgregor, John C. Hellstrom, Jon D. Woodhead, Russell N. Drysdale, Rolan S. Eberhard Nov 2021

Low Impact Sampling Of Speleothems – Reconciling Scientific Study With Cave Conservation, Claire L.V. Macgregor, John C. Hellstrom, Jon D. Woodhead, Russell N. Drysdale, Rolan S. Eberhard

International Journal of Speleology

Speleothems are increasingly valued as important paleoclimate archives and yet the removal of samples from caves can come at a cost to natural heritage, impacting delicate environments with limited mechanisms for repair. Conservation of cave environments is a key responsibility for scientists and, with this in mind, we are working to develop and implement techniques that allow us to extract valuable scientific data, with minimal impact. In this study, we demonstrate the utility of low-impact reconnaissance dating surveys on caves in southern Tasmania and southwest Western Australia as a precursor to the removal of stalagmites for paleoclimate reconstruction. Small flakes …


Continuous Color Model As A Tool To Improve Speleothem Age Model Development, Celia Campa-Bousoño, Ángel García-Pérez, Ana Moreno, Miguel Iglesias, Hai Cheng, R Lawrence Edwards, Heather Stoll Oct 2021

Continuous Color Model As A Tool To Improve Speleothem Age Model Development, Celia Campa-Bousoño, Ángel García-Pérez, Ana Moreno, Miguel Iglesias, Hai Cheng, R Lawrence Edwards, Heather Stoll

International Journal of Speleology

Because they can archive a variety of geochemical proxies and be precisely and accurately dated with the U-Th decay series chronometer, stalagmites are widely used for paleoclimate reconstructions. However, limitations in the use of this chronometer arise because U-Th dating is analytically time consuming, expensive, and requires a relatively large sample size. These limitations restrict the number of absolute dates usually obtained, which can result in significant uncertainties in the age model and inhibit the ability to archive high resolution records of environmental variability, particularly in those stalagmites where there are variations in growth rate not constrained by U-Th dates. …


The Impact Of Burning On The Structure And Mineral Composition Of Bat Guano, Joyce Lundberg, Donald A. Mcfarlane May 2021

The Impact Of Burning On The Structure And Mineral Composition Of Bat Guano, Joyce Lundberg, Donald A. Mcfarlane

International Journal of Speleology

Here we addressed the question of whether burning of guano produces a characteristic suite of morphological changes and/or unique mineralogical products. The changes observed in our experimental burning of guano (both fresh and decayed) included colour change (blackening), grain size and morphological change (grain size generally reduced, morphology rendered generally less distinct), alteration of minerals by dehydration (e.g., gypsum to anhydrite, brushite to whitlockite), and production of new minerals or compounds (e.g., augelite, bayerite, giniite, graphite, oldhamite, strontium apatite, tridymite). The key morphological feature we found that may be diagnostic of burning was severe damage to crystals from rapid dehydration …


On The Genesis Of Aluminum-Rich Speleothems In A Granite Cave Of Nw Spain, Jorge Sanjurjo-Sanchez, Carlos Arce Chamorro, Juan Ramón Vidal Romaní, Marcos Vaqueiro-Rodríguez, Victor Barrientos, Joeri Kaal Feb 2021

On The Genesis Of Aluminum-Rich Speleothems In A Granite Cave Of Nw Spain, Jorge Sanjurjo-Sanchez, Carlos Arce Chamorro, Juan Ramón Vidal Romaní, Marcos Vaqueiro-Rodríguez, Victor Barrientos, Joeri Kaal

International Journal of Speleology

Granite massifs often contain caves, with dimensions ranging from a few meters up to 1,000 m, also referred to as pseudokarst. The speleothems in such caves are mostly composed of either Si-rich (commonly opal-A) or Al-rich authigenic mineraloids. Whereas the formation and geochemical composition of opal-A biospeleothems have been studied and are fairly well understood, knowledge on the Al-rich analogues is scarce. This work reports for the first time a study on the composition, accretion process, age and growth rate of an Al-rich speleothem type flowstone from the A Trapa Cave System (Galicia, NW Spain), developed in a granite cave. …


Creating Synthetic Analogs Of Fluorescent Speleothems In Wind Cave As An Astrobiological Model Cave, Teresa Feldman Jan 2021

Creating Synthetic Analogs Of Fluorescent Speleothems In Wind Cave As An Astrobiological Model Cave, Teresa Feldman

Honors Program Theses

The wind cave system represents a unique environment on Earth where the direct interplay of organic chemistry on the surface can possibly be traced to extremophiles living hundreds of meters below the surface. In many cases, minerals and organics from the surface become trapped in calcite formations creating fluorescent minerals. To understand the environment giving rise to the fluorescent minerals in Wind Cave, laboratory analogs of the calcite crystals found within the Wind Cave National Park cavern were synthesized and analyzed using SEM and fluorescence spectroscopy. This data was compared to the fluorescence and XRF data collected from speleothems in …


Impacts Of Forest Management And Timber Harvest Practices On Karst Critical Zone Processes In Tongass National Forest, Alaska, Anna Gwendolyn Harris Oct 2020

Impacts Of Forest Management And Timber Harvest Practices On Karst Critical Zone Processes In Tongass National Forest, Alaska, Anna Gwendolyn Harris

Masters Theses & Specialist Projects

This study characterizes the throughfall, hydrogeochemistry, dissolution rates, and carbon sources of two proximate temperate rainforest cave systems within the Tongass National Forest in Southeast Alaska (Tongass). Study sites include: an old-growth forest, characterized by having never been logged (containing Walkabout Cave system); and a previously logged – within thirty years, second-growth forest (containing Zina Cave system). Precipitation data were recorded over a five-month period at 10-minute intervals, to understand the effects of throughfall between the altering old and second-growth canopies. At each major spring for the two cave systems, high-resolution data were collected from June 29 through November 21, …


Active Growth Of Non-Hydrothermal Subaqueous And Subaerial Barite (Baso4) Speleothems In Lechuguilla Cave (New Mexico, Usa), Max Wisshak, Hazel A. Barton, Katey E. Bender, Harvey R. Duchene Jan 2020

Active Growth Of Non-Hydrothermal Subaqueous And Subaerial Barite (Baso4) Speleothems In Lechuguilla Cave (New Mexico, Usa), Max Wisshak, Hazel A. Barton, Katey E. Bender, Harvey R. Duchene

International Journal of Speleology

Barite (BaSO4) speleothems have been reported from caves around the globe and interpreted to have chiefly formed in phreatic, hypogene, hydrothermal settings. Here we report two contrasting types of barite speleothems (bluish tabular crystals in a shallow pool and actively dripping greenish stalactites), which today form at lower temperatures in the non-hydrothermal and vadose environment of Lechuguilla Cave, New Mexico, USA. Scanning electron microscopy analysis, along with energy- and wavelength-dispersive X-ray spectroscopy (EDS, WDS), as well as X-ray diffraction (XRD), characterize the habit and chemical composition as barite. Fractionation of the minor element calcium is related to growth …


Influence Of Spring Flow Reversals On Cave Dissolution In A Telogenetic Karst Aquifer, Mammoth Cave, Ky, Chelsey Kipper Oct 2019

Influence Of Spring Flow Reversals On Cave Dissolution In A Telogenetic Karst Aquifer, Mammoth Cave, Ky, Chelsey Kipper

Masters Theses & Specialist Projects

An often overlooked connection between karst groundwater systems and surface water is spring flow reversal, the flow of river water into karst springs caused by changes in hydraulic gradient. Karst aquifers are subject to the intrusion of river water when the hydraulic head of a base level river is higher than the hydraulic head of a base level spring. When this occurs, the flow out of the spring reverses, allowing river water to enter base level conduits. River water thus becomes a source of recharge into karst basins, transporting both valuable nutrients and harmful contaminants into karst aquifers. The rapid …


Genesis Of Iron And Manganese Sediments In Zoloushka Cave (Ukraine/Moldova) As Revealed By Δ13C Organic Carbon, Piotr Kotula, Viacheslav Andreychouk, Jacek Pawlyta, Leszek Marynowski, Izabela Jendrzejewska Sep 2019

Genesis Of Iron And Manganese Sediments In Zoloushka Cave (Ukraine/Moldova) As Revealed By Δ13C Organic Carbon, Piotr Kotula, Viacheslav Andreychouk, Jacek Pawlyta, Leszek Marynowski, Izabela Jendrzejewska

International Journal of Speleology

Zoloushka Cave is one of the largest maze gypsum caves in the world. Mining of the gypsum bedrock and lowering of the water level due to the pumping of groundwater led to exposure of the cave passages to vadose conditions and changed the hydrochemistry of the karst water. As a result, large quantities of Fe and Mn hydroxides were deposited in the passages. It was found that at least two groups of various organisms were involved in depositing ferrous and manganese sediments. In order to establish the mechanism of deposition, we conducted chemical analyses of the sediments and isotopic analyses …


Morphological And Mineralogical Evidence For Ancient Bat Presence In Cova Des Pas De Vallgornera (Llucmajor, Mallorca, Western Mediterranean), Antoni Merino, Joan J. Fornós, Antoni Mulet, Joaquín Ginés May 2019

Morphological And Mineralogical Evidence For Ancient Bat Presence In Cova Des Pas De Vallgornera (Llucmajor, Mallorca, Western Mediterranean), Antoni Merino, Joan J. Fornós, Antoni Mulet, Joaquín Ginés

International Journal of Speleology

Cova des Pas de Vallgornera is a unique karst cave located at the Llucmajor coastal platform that stands out not only because of its length, more than 78 km, but also for its particular morphological suite, richness and variety of speleothems and mineral infillings. Although the mineralogy of speleothems and minerals related to hypogene morphologies has been studied and described, the existence of minerals derived from guano deposits was still poorly investigated. The cave hosted bat colonies until the collapse of its natural entrances, circa 2.4 My ago, since then until its discovery in 1968, the cave remained sealed. These …


Protocol Implementation Plan For Cave Water Quality Monitoring In The Northern Great Plains Network, Narrative Version 1.0, Isabel W. Ashton, Justin S. Mills, Marc Ohms, Daniel Austin, Michael Wiles, Kara Paintner-Green Apr 2019

Protocol Implementation Plan For Cave Water Quality Monitoring In The Northern Great Plains Network, Narrative Version 1.0, Isabel W. Ashton, Justin S. Mills, Marc Ohms, Daniel Austin, Michael Wiles, Kara Paintner-Green

United States National Park Service: Publications

Executive Summary

The Northern Great Plains Inventory and Monitoring Network includes thirteen park units located in five northern Great Plains states across six ecoregions. Two park units, Jewel Cave National Monument (JECA) and Wind Cave National Park (WICA), protect significant cave resources. These two caves are among the longest caves in the world and have an assortment of underground water resources ranging from drip sites to cave lakes. Subsurface water quantity and quality in the caves is a concern due to groundwater depletion and groundwater contamination from pesticides (aboveground applications), hydrocarbons (vehicle use and related activities), and wastewater effluent (sewage …


Cave Dripwater Isotopic Signals Related To The Altitudinal Gradient Of Mount-Lebanon: Implication For Speleothem Studies, Carole Nehme, Sophie Verheyden, Fadi H. Nader, Jocelyne Adjizian-Gerard, Dominique Genty, Kevin De Bont, Benedicte Minster, Ghada Salem, David Verstraten, Philippe Clayes Mar 2019

Cave Dripwater Isotopic Signals Related To The Altitudinal Gradient Of Mount-Lebanon: Implication For Speleothem Studies, Carole Nehme, Sophie Verheyden, Fadi H. Nader, Jocelyne Adjizian-Gerard, Dominique Genty, Kevin De Bont, Benedicte Minster, Ghada Salem, David Verstraten, Philippe Clayes

International Journal of Speleology

An important step in paleoclimate reconstructions based on vadose cave carbonate deposits or speleothems is to evaluate the sensitivity of the cave environment and speleothems to regional climate. Accordingly, we studied four caves, located at different altitudes along the western flank of Mount-Lebanon (Eastern Mediterranean). The objectives of this study are to identify the present-day variability in temperature, pCO2, and water isotopic composition and to assess the possible influence of the altitudinal gradient on cave drip waters and cave streams. We present here an overview of the spatial variability of rainwater based on local and regional data, and …


Multivariate Analysis Of Hydrochemical Data For Jewel Cave, Wind Cave, And Surrounding Areas, Andrew J. Long, James B. Paces, William G. Eldridge Mar 2019

Multivariate Analysis Of Hydrochemical Data For Jewel Cave, Wind Cave, And Surrounding Areas, Andrew J. Long, James B. Paces, William G. Eldridge

United States National Park Service: Publications

Abstract

Jewel Cave National Monument and Wind Cave National Park in South Dakota contain two of the six longest caves worldwide. These caves contain subterranean lakes that are important points of intersection between the water table of the Madison aquifer and the caves. During 2015 to 2017, several subterranean lakes were discovered in Jewel Cave, which previously was thought to be above the regional water table. The objectives of this study were to better understand the hydrology of the recently discovered subterranean lakes in Jewel Cave and to evaluate their relation or possible connection to similar lakes in Wind Cave. …