Geochemistry Commons^™

Hydrogeophysical Assessment Of Groundwater And Saltwater–Freshwater Interface In A Quaternary– Neogene Coastal Aquifer, Kilwa Kisiwani Island, Southeast Tanzania, Simon R. Melchioly

Tanzania Journal of Science

This study aims to identify and explore new potential sites of groundwater resources using geophysical methods, and to demarcate the depth to the saltwater-freshwater interface. Kilwa Kisiwani Island is geologically covered mostly by Neogene and Quaternary alluvial sediments, sand and gravel. The geophysical techniques employed during the research include Vertical Electrical Sounding (VES), Electrical Resistivity Tomography (ERT), and Transient Electromagnetics (TEM). The Island has the potential for groundwater occurrences, but the layer with fresh water is shallow and thin. Out of the 18 VES sites, 2 (11%) points have shown non-potential, but the remaining 16 (89%) of the VES sites …

Hydrogeochemical Characterization Of Groundwater In Fractured Crystalline Basement Aquifers In Dodoma, Central Tanzania: Implications On Water Quality For Domestic And Irrigation Applications, George J. Ishabairu, Simon R. Melchioly, Charles H. Kasanzu, Gabriel D. Mulibo

Tanzania Journal of Science

Assessment of groundwater hydrogeochemistry characteristics of aquifers plays a vital role in establishing water quality status and its suitability for human and industrial use. The main objective of this research was to carry out hydrogeochemical characterization of groundwater and assess its impacts on water quality and spatial variability of groundwater geochemistry in Dodoma, Tanzania. The methods used include groundwater sampling, laboratory analysis to determine physico- chemical parameters and data processing to classify the groundwater hydrochemical facies. The results show that the average value for pH is 7.2, for electrical conductivity (EC) is 1108 µS/cm and for total dissolved solids (TDS) …

Response Of Botovskaya Cave To Local And Regional Environmental Dynamics, Jade Margerum, Oksana Gutareva, Franziska Lechleitner, Maria Box, Stuart Umbo, Anton Vaks, Hanno Meyer, Aleksandr Kononov, Aleksander Osintsev, Dimitri Sokol'nikov, Norbert Marwan, Ola Kwiecien, Sebastian Breitenbach

International Journal of Speleology

Speleothems from caves in near-permafrost regions can provide unique insights into the climatic history of temperature-sensitive environments. These regions are often remote and only seasonally accessible, which makes cave monitoring – a requirement for speleothem-based proxy interpretation – challenging. We document ventilation, the infiltration regime, and the isotopic composition of dripwater in Botovskaya Cave in southern Siberia, a host to speleothems previously used to reconstruct Quaternary permafrost dynamics in continental Eurasia. We explore surface and cave temperature records, cave air CO₂ concentration data and stable isotopes in precipitation and dripwater and evaluate infiltration conditions and the sensitivity of speleothems …

Hydrogeochemical And Redox Controls On Nitrate And Arsenic Co-Occurrence In The Western Kansas High Plains Aquifer (Usa): A Composite Health Risk Assessment And The Case For Risk-Informed Private Well Governance, Jonathan Kuffour Owusu

Master's Theses or Doctor of Nursing Practice

Fifty-one private domestic wells across western Kansas were sampled to quantify nitrate and arsenic occurrence, identify geochemical controls, and evaluate carcinogenic and non-carcinogenic health risks for adult and child receptors in a region where groundwater serves as the primary drinking water source with no routine regulatory oversight. Samples were analyzed for major ions, nutrients, and trace elements by ICP-MS, ion chromatography, and UV-Vis spectrophotometry. Shapiro-Wilk testing confirmed non-normal distributions for both contaminants; inter-county comparisons were therefore conducted using Kruskal-Wallis tests with Dunn's post-hoc correction. Health risk was quantified via chronic daily intake (CDI), hazard quotient (HQ), HQ-based Water Quality Index …

A Combined Multi-Isotope And Machine Learning Approach To Determine Groundwater Salinity And Solute Sources, Lower Valley Area, El Paso County, Texas, Gloria A. Ortiz Gamboa

Open Access Theses & Dissertations

Groundwater salinization is increasingly troublesome in aquifers in and around El Paso, Texas, where concern for available water resources has grown due to frequent droughts and increasing population. Both groundwater and surface water have experienced an increase in total dissolved solids (TDS), a trend that can pose future health and economic problems for residents who primarily rely on groundwater. To address this issue, this research focuses on the Hueco Bolson Aquifer and the Rio Grande Alluvial Aquifer within the Lower Valley area of El Paso, Texas, utilizing a multi-analysis approach to evaluate and determine solute sources and their possible end-members …

Pre-Calibration Of Δ18O For Paleoclimatic Interpretations Using Stalagmites In Cueva Ensueño, Puerto Rico, Gabriel Enrique López Borobia, Ny Riavo G. Voarintsoa, Ricardo Sánchez-Murillo, Pablo Antonio Llerandi Román

International Journal of Speleology

Stalagmites are invaluable archivers of past climate conditions, as their oxygen isotopic composition (δ¹⁸O_c) closely mirrors the isotopic signature of the drip water (δ¹⁸O_w) from which they precipitate. This isotopic relationship is governed by the fractionation factor (1000ln¹⁸α), which is temperature dependent. In this research, we studied 1000ln¹⁸α within Cueva Ensueño, a cave situated in Puerto Rico’s northern karst region, as a step toward calibrating δ¹⁸O_c for paleoclimate interpretations using stalagmites. We collected drip waters, measured their temperature in situ, and sampled carbonates from ten selected stations within the cave. Sampling was conducted in December …

New Precipitation Is Scarce In Deep Soils: Findings From 47 Forest Plots Spanning Switzerland, Emily I. Burt, Scott T. Allen, Sabine Braun, Simon Tresch, James W. Kirchner, Gregory R. Goldsmith

Biology, Chemistry, and Environmental Sciences Faculty Articles and Research

As precipitation infiltrates into soils, it can recharge them, displace previously stored waters, or bypass already-filled pores. Using 3,697 δ2H and δ18O measurements of water collected nearly monthly over >3 years in 47 forest plots across Switzerland, we present a systematic investigation of the controls on mobile soil water transport. We quantified the lags and damping of water as it percolates downward using young water fraction analysis (Fyw), and the fractions of soil water composed by precipitation that fell within the previous month (new water fractions, Fnew). The Fnew of water sampled in surface soils ranged …

Dream Pilot Project: Analysis Of Groundwater Development At Six Villages In Ethiopia, Lindsay K. Gordon

All Graduate Reports and Creative Projects, Fall 2023 to Present

This study presents a hydrogeologic assessment of the Distributed Renewable Energy Agriculture Modalities (DREAM) pilot project, an ongoing groundwater development initiative in rural Ethiopia. This project integrates solar-powered groundwater infrastructure across six villages to improve water access, agricultural productivity, and economic stability.

Fourteen production wells were installed at Murche, four at Dalle, and additional test wells at Murche, Dalle, Chefe Kora, and Huluku. Transmissivity values and the number of wells at Murche suggest that local water needs are currently being met. In contrast, fewer wells were drilled at Dalle. This reflects the high cost of well construction relative to yield, …

Spatial Analysis Of Heavy Metal Enrichment In A Historic Appalachian Mining Stream, Eric M. Torres

Research and Creativity Symposium

This study examined the spatial distribution of heavy metals along the Levisa Fork and primary tributaries in Buchanan County, VA and Pike County, KY. Buchanan and Pike Counties have a long history of coal mining, a process known to release heavy metals into surrounding waterways. Exposure to certain heavy metals, such as arsenic and lead, has been known to cause health problems, such as cancer and organ damage. The study looked at concentrations in riverine sediments, surface water and groundwater for As, Al, Cr, Cu, Fe, Li, Mg, Mn, Ni, Pb and Zn. Sediment samples were collected, dried and digested …

Hydrogeochemical Characterization Of The Ahtanum Alluvial Fan For Managed Aquifer Recharge, Yakima Basin, Washington, Brook M. Bauer

All Master's Theses

Overallocation of water resources in the Yakima River Basin, central Washington, has prompted investigation into facilitated aquifer recharge to enhance water supply during drought as part of the Yakima Basin Integrated Plan (YBIP). This study evaluates and characterizes the recharge potential of the Ahtanum Creek alluvial fan within the lower Ahtanum Sub-Basin by integrating geologic, hydraulic, and geochemical data.

Four main hydrogeologic units (unconsolidated, semi-consolidated, consolidated basin-fill deposits, and Columbia River Basalt aquifers) were identified from stratigraphic analysis of well logs across seven transects spanning the active fan and abandoned alluvial terrace portions of the alluvial fan study area. Stable …

Origins And Mechanisms Of Mobility Of Geogenic Arsenic Contamination In Toutle And Silver Lake, Wa, Usa, William A. Hays

All Master's Theses

Arsenic (As), a common contaminant in groundwater, is toxic to human health and has a maximum contaminant level of 10 ppb set by both the World Health Organization and the U.S. Environmental Protection Agency (ATSDR, 2007). In Toutle, WA, USA (30 km west of Mount Saint Helens), a private well, labelled TOU1, was previously identified with ~670 ppb of As and was the impetus of this study. This study targeted private wells in the vicinity of TOU1 to identify the extent of the arsenic contamination, identify the aquifer(s) of concern, and identify the mechanism(s) of mobility.

The wells were screened …

Evaluation Of Practical Methods To Determine If A Karst Creek Is Gaining Or Losing: Case Study Of Leith Creek, Elizabeth Jones

Graduate Theses/Dissertations

Karst landscapes are abundant in Missouri, with features such as caves, springs, and sinkholes that form through the dissolution of limestone. Leith Creek is a small stream in Polk County, Missouri fed by two springs and the shallow unconfined Springfield Plateau aquifer, a highly karstified aquifer which is made up of limestone and minor interbedded shale-mudstone units. To determine if Leith Creek is gaining or losing, stream flow, water chemistry and temperature sensors were monitored. Stream flow results required multiple visits to take measurements while temperature sensors required two visits, one to install the dataloggers and another to remove the …

Hypogenic Caves Of Syracuse Area, Sicily (Italy): Geomorphological Evidence Of Co2 Degassing, Fresh-Salt Water Mixing, And Late Condensation Corrosion, Philippe Audra, Jean-Yves Bigot, Didier Cailhol, Pierre Camps, Ilenia M. D'Angeli, Hai Cheng, R. Lawrence Edwards, Fernando Gàzquez-Sanchez, Gabriella Koltai, Giuliana Madonia, Jean-Claude Nobécourt, Marjan Temovski, Marco Vattano, Jo De Waele

International Journal of Speleology

Many caves in Sicily have been shown to have a sulfuric acid or other hypogenic origin. We studied three caves (Palombara, Scrivilleri, Monello) near Syracuse (eastern Sicily), in an area that was strongly uplifted and faulted, creating multiple Pleistocene marine terraces. Mineralogy, stable isotopes and dating methods (paleomagnetism, U/Th) were used to characterize cave sediments, some of which were related to the initial hypogenic phase (Fe and Mn oxides, calcite spar), others were introduced by surface runoff later. Many other sediments are the result of in situ weathering, such as lime sands produced by condensation-corrosion processes on the calcarenite walls. …

Hypogene Speleogenesis In Carbonates By Cooling Hydrothermal Flow: The Case Of Mt. Berenike Caves, Israel, Roi Roded, Boaz Langford, Einat Aharonov, Piotr Szymczak, Micka Ullman, Shemesh Yaaran, Boaz Lazar, Amos Frumkin

International Journal of Speleology

The Berenike hypogenic cave system near Lake Kinneret, Israel, provides a valuable case study for investigating the recently proposed Confined-Cooling-Flow (CCF) speleogenesis model. Field and speleological surveys, along with existing research, are used to provide a thorough analysis. The CCF model relies on a simple thermo-hydro-chemical scenario, involving the rise of CO2-rich hydrothermal fluids discharging into a confined layer. The cooling of these CO2-rich fluids turns them into aggressive solutions due to the inverse relation between temperature and solubility of carbonates (retrograde solubility). Previous geochemical and numerical analyses of the CCF model predict localized and persistent dissolution and speleogenesis on …

Diatom-Inferred Hydroclimate Variability In Marl Lake, Wi Over The Past ~2050 Years, Christian E. Sizemore

All-Inclusive List of Electronic Theses and Dissertations

Hydroclimate variability in the Midwest has increased over the past few decades, as as evidenced by increases in average precipitation and frequency of extreme hydroclimate events. Understanding natural climate variability in this region will help communities in the Midwest to better prepare and mitigate the risks associated with extreme hydroclimate variability in the future. Natural lakes in the Midwest are often effective archives of hydroclimate; many have been shown to respond directly to changes in climate both locally and regionally. We extracted a 4.5-meter sediment core, representing approximately 2050 years of sediment accumulation, from the deepest part of Marl Lake …

Revealing The Ongoing Speleogenetic Processes In An Underwater Cave Through The Application Of Natural Radionuclides And Stable Isotopes: Case Study From The Hypogene Buda Thermal Karst, Anita Erőss, Katalin Hegedűs-Csondo, Petra Kovács-Bodor, Dénes Szieberth, Ákos Horváth, György Czuppon, Andrea Mindszenty Dr, Szabolcs Leél-Őssy, Judit Mádl-Szőnyi

International Journal of Speleology

The underwater Molnár János Cave in the hypogene Buda Thermal Karst system (Budapest, Hungary) provides a unique site to study the effects of flowing groundwater and the interplay of fluids of different origin. The aim of the present study is to characterize the groundwater in different parts of the cave with temporal resolution, hence describe the recent speleogenetic processes within the cave. This study uses natural radioisotopes (uranium, radium, and radon) besides stable isotope ratios of oxygen and hydrogen to identify the different fluid components. The results show that the majority of the cave is situated in the flow path …

Role Of Hypogenesis In The Evolution Of Karst In The Taurus Mountains Range, Turkey, Serdar C. Bayari, Naciye Nur Özyurt, Lütfi Nazik, Koray A. Törk, Noyan İ. Güner, Emrah Pekkan, Pınar Avcı

International Journal of Speleology

Field observations and laboratory data collected from the Taurus Mountains Range, Turkey during the last two decades provided evidence for the link between the evolution of hypogene karst and the geodynamic history. Major evidence includes; carbonate-hosted secondary ore deposits that are converted from primarily hypogene minerals by epigene, oxygen-rich groundwater circulating at local to intermediate depths. Another piece of evidence of hypogene karst in the Tauride is the Kırkgöz springs’ huge submerged cave/conduit system, which formed the Antalya Travertine Plateau, which is the world’s largest deposit precipitated by cool karst groundwater. The obruks in central Tauride are giant collapse dolines …

Investigating Controls On Temporal And Spatial Variation Of Dissolved Uranium At Springs In Horn Creek Drainage, Grand Canyon National Park, Arizona, Usa, Collin Davidson

UNLV Theses, Dissertations, Professional Papers, and Capstones

Groundwater is a critical resource in the Grand Canyon, providing water to local communities, millions of annual visitors, and ecosystems. One major concern for this critical resource is the potential for uranium contamination in conjunction with uranium mining efforts. Upper Horn Bedrock Spring (UHB) in the Horn Creek drainage of the Grand Canyon sits below the oldest uranium mine in the region, Orphan Lode mine. UHB spring contains the highest concentration of dissolved uranium in the region, eclipsing the Maximum Contaminant Level (MCL) set by the USEPA by an order of magnitude on average. This research and recent collaboration with …

Unearthing The Past: A Comprehensive Study Of Natural And Anthropogenic Changes At An Archaeological Site Through Hydrogeologic Connectivity Utilizing Gis, Mehlich Ii Phosphorus Extractant, And Ph, Dana L. F. Herren

Theses

This thesis aims to thoroughly analyze the Mehlich II Phosphorus Extractant and pH levels at the Bains Gap Village Site in Anniston, AL., while examining the impact of various environmental factors and human activities on them. Phosphorus is often used in archaeology as an indicator of human activity. Soil core samples were collected to analyze anomalies in phosphorus levels.

To establish any relationships, phosphorus and pH levels from soil cores were correlated with findings from past excavation units and features. The potential effects of hydrogeologic connectivity on soil phosphorus and pH levels were investigated. Geospatial technologies were used to manage …

Migrating Whooping Crane Activity Near U.S. Air Force Bases And Airfields In Oklahoma, David A. Brandt, Aaron T. Pearse, Mark T. Bidwell, John Conkin, Matthew Butler

United States Geological Survey: Publications

The Aransas-Wood Buffalo population of Grus americana (Linnaeus, 1758; whooping cranes) migrates through the United States Great Plains, encountering places substantially altered by human activity. Using telemetry data from 2017 to 2022, we investigated whooping crane migration behavior around U.S. Air Force bases in Oklahoma. Our study focused on potential collision risks between whooping cranes and aircraft, a substantial concern for aviation safety. We determined that activity was greatest at Kegelman Air Force Auxiliary Airfield, near whooping crane critical habitat. On average, 61 percent of marked whooping cranes used locations west of Kegelman Air Force Auxiliary Airfield and Vance Air …

Water Quality Contaminants Long-Term Spatial Analysis Along The Upper Clark Fork River Superfund Site Between Warm Springs And Garrison, Montana, Raegan Michele Osentowski

Undergraduate Theses, Professional Papers, and Capstone Artifacts

Long-term data of heavy metal contaminants, cadmium, copper, lead, arsenic, and zinc were compiled from the Montana Department of Environmental Quality, DEQ, and the United States Geological Survey, USGS, to investigate the effects of remediation on water quality along the upper Clark Fork River superfund site. Long-term data sets were analyzed at CFR-03A, CFR-27H, CFR-34, and SS-25 along the upper Clark Fork River and Silver Bow Creek. CFR-03A and CFR-27H had full remediation in the immediate vicinity, SS-25 had on-going remediation in the immediate vicinity, and CFR-34 had no remediation in the immediate vicinity. Analysis of heavy metal contaminants is …

Geoelectrical And Hydrochemical Characterization Of Submarine Groundwater Discharge In Florida Bay, Ifeanyi Emmanuel Eze

College of Graduate Studies: Theses & Dissertations

Florida Bay, situated at the southern tip of Everglades National Park and underlain by the Miami Limestone formation, is an ecosystem of global significance. Over the past century, the bay has faced threats such as droughts, seagrass mortality, and hypersalinity. Despite various studies and management efforts, the dynamics of submarine groundwater discharge (SGD) in the region remain underexplored. Given that SGD plays a significant role in the chemical dynamics of coastal ecosystems, it warrants thorough investigation. This study aims to characterize the spatial and temporal patterns of SGD in Florida Bay by surveying three basins – Rankin, Whipray, and Rabbit …

Environmental Fate Of Sulfur In Sulphur Creek, Valles Caldera, Nm: Implications For Metal Transport And Water Quality, Daniel Lavery

Earth and Planetary Sciences ETDs

The 1.2 Ma Valles Caldera in north-central New Mexico hosts a young igneous volcanic hydrothermal system after the model proposed in Goff and Janik (2000). The Sulphur Springs area within Valles Caldera is an acid-sulfate area typical of this model, discharging acidic waters (pH 1.5-3) formed by oxidation of magmatic H₂S at the surface. We report on samples obtained from springs and streams collected between October 2021 and May 2023 in the Sulphur Creek and Alamo watersheds. Sulphur Creek receives input from Sulphur Springs and exhibits low pH (2-4) and high concentrations of Al (≤110 mg/L), Fe (≤60 …

Landscape/Atmosphere Interactions And Carbon-Dioxide Dynamics In The Great Onyx Groundwater Basin, Mammoth Cave National Park, Kentucky, Meghan Raines

Masters Theses & Specialist Projects

An increase in atmospheric CO2 since the Industrial Revolution has altered rates of global climate change and has motivated a need to better quantify the flux of carbon between Earth’s reservoirs. Attempts to quantify the exchange of atmospheric carbon between sources and sinks have led to an increasing interest in the terrestrial landscape, including the continental carbon sink associated with carbonate-mineral dissolution. This research sought to better inform an understanding of karst landscapes and their relationship with global climate change through carbon cycling. The study utilized high-resolution data collection of pH, temperature, and specific conductance of waters in the Cascade …

A Hybrid Lateral Flow Sand Filter Wastewater Treatment System: An Evaluation On The Treatment And Disposal Capabilities Of A Modified Sand Filter, Harry Mccaskill Iv

Graduate Theses and Dissertations (2019 - present)

Decentralized wastewater treatment exists primarily in suburban and rural areas where centralized treatment is not an option. Traditional on-site treatment systems usually include the use of a septic tank and a drain field. This orthodox method works well when implemented into environments that are accommodating for the infiltration of effluents, and thus allowing for soil treatment. Unfortunately, there are some circumstances that prevent traditional systems from working such as impermeable soil conditions. The Wastewater Treatment System analyzed in this thesis was created to overcome such inhospitable environments. More specifically, this system is catered towards the rural residences of The Alabama …

Understanding The Connection Between Gypsum Blooms And Human Health At The Salton Sea, Isabel Ichiyama

Undergraduate Honors Theses

The Salton Sea is a closed hypersaline lake in Southern California that has been receiving little input over the past few decades, leading to desiccation that is rapidly increasing every year. This large-scale evaporation of the sea has led to increased dissolved solutes, high salinity, and gypsum blooms. Gypsum blooms, the precipitation of gypsum (CaSO42H2O) in the sea, have been a prominent facet of the sea and their distribution is well known. However, much of their chemistry and potential health hazards are still undetermined. Potential health effects from gypsum salt, an atmospheric dust particle present at the sea, have known …

Geochemical Analysis And Numerical Modeling Of Central And East Tennessee Mississippi Valley-Type Ore Districts: Constraints On Ore Genesis, Jackson Price Copeland

Geosciences Undergraduate Honors Theses

A simple two-way stochastic mixing model is presented for analysis of the lead (Pb) isotope compositions of the North American Mississippi Valley-Type (MVT) districts of East Tennessee, Central Tennessee, and Central Kentucky. Four distinct mixing scenarios were run to critically evaluate the stochastic model and examine different hypotheses regarding the genesis of Central Tennessee and Central Kentucky MVT deposits. Additionally, Pb isotope analysis was conducted on sphalerite samples from the Central and East Tennessee MVT districts. Model and sampling results suggest that Central Tennessee and Central Kentucky ores likely formed by mixing of three fluids. In contrast to conclusions from …

Differentiating Biotic Vs. Abiotic Co2 In The Formation Of Pedogenic Carbonate In Agriculture And Natural Dryland Soils, Valeria Isabel Molina

Open Access Theses & Dissertations

Drylands, characterized by low and sporadic precipitation, require irrigation for crop growth. However, irrigation practices can lead to salt accumulation in soil due to high evaporation rates and reduced leaching. In addition to loading salts to soil, irrigation promotes the accumulation of secondary calcite. In natural systems, the formation of pedogenic carbonate (secondary calcite, CaCO3) is critical, impacting the soil properties hydrologically and biogeochemically, and modifying the global carbon cycle over geological time, albeit at a lower rate. In agricultural sites, irrigation water supplies HCO3- and Ca2+, accelerating the rates of CaCO3 formation and releasing abiotic CO2. This study investigated …

Synthetic Aperture Radar Observations At Salar De Pajonales, Chile, Michael A. A. Mcinenly

Graduate Student Theses, Dissertations, & Professional Papers

Remotely sensed microwave radars provide the spatial and temporal coverage needed to improve our understanding of the relationship between moisture content and salt pan mineralogy and, ultimately, climate variability. Moisture content in the surface and near-surface crusts found in salt pan environments, such as salt pan, has a significant impact on the backscatter values recorded by synthetic aperture radar (SAR) systems. This is because moisture affects the dielectric constant and surface roughness of the saline surface, which in turn influences the amount of electromagnetic energy reflected back to the SAR sensor. Changes in backscatter values are attributed to seasonal and …

Acid Mine Drainage In The Shamokin Creek Watershed: A Spatial Analysis Of Economic And Environmental Consequences Of Coal Mining, Ben Shimer

Student Project Reports

No abstract provided.