Earth Sciences Commons^™

Relationships Between Geochemistry, Carbon Content, And Grain Size In Clastic Cave Sediments, Rebekah Rose Nicholas

Graduate Theses, Dissertations, and Problem Reports (ETD)

Understanding geochemical and physical properties of cave sediment gives insight to sediment characterization and carbon storage in the cave system. Previous work on clastic sediments largely encompasses physical properties, neglecting the importance of geochemical parameters on sediment deposition.

This study reports physical and chemical properties of sediment cores from three caves: two caves in Puerto Rico and one cave in Virginia. A total of 25 cores were used in this study; 6 of these cores were new and collected in 2022 from Butler Cave (BTC) in Virginia to focus on the effects of water level. Core samples were analyzed for …

Well Cave Field Report: Bracken Bat Cave And Preserve, Anthony J. Coronado, Byron T. Cox, Allison De La Houssaye, Fernando Jaime Sepulveda, Anthony Sadler, Aaron S. Yamazi

Geophysics

Well cave is a small cave entrance that sits northeast of Bracken Bat Cave on the Bracken Bat Cave Preserve Property. The cave entrance sits above the Balcones Fault Zone, a primarily karst environment, and is mostly comprised of Edwards Limestone (EAA, 2022). The goal of this project is to successfully detect the main cave passageway, and any other potential paths that branch from it, beneath Well Cave. In order to accurately detect any passages, GPR surveying and ER testing were chosen as the main methods to do so.

Carbon Cycling And Critical Zone Dynamics In An Urbanized Karst Groundwater System, Amy Hourigan

Masters Theses & Specialist Projects

Increasing atmospheric CO₂ concentrations are correlated to rising global temperatures. Investigating the cumulative global carbon cycling processes is important to understand and quantify the global carbon cycle. By investigating basic geochemical parameters, EpCO₂, DIC, and δ¹³C_DIC, at four sites along Lost River Cave (LRC), in Bowling Green, Kentucky, concentrations, fluxes and sources of C dissolved in groundwater were determined. Urban karst groundwater systems, compared to more natural karst landscapes, typically exhibit widespread impervious, heat-absorbing surfaces, urban heat island effects, and increased anthropogenic groundwater inputs and localized CO₂ emissions. Carbonate hydrogeochemical …

Hydrogeologic Investigation Of A Covered Karst Terrain, Joseph Peter Honings

LSU Doctoral Dissertations

Increasing demand for water for agricultural use within the Dougherty Plain of the Southeastern United States has depleted surface water bodies. In karstic landscapes, such as the Dougherty Plain in southwest Georgia where the linkages between surface and ground waters are close, there is a need to understand the physical characteristics of the subsurface that allow these close linkages. Having a better understanding of the subsurface characteristics will aid numerical modeling efforts that underpin policy decisions and economic analyses. Two common features on this karstic landscape are draws and geographically isolated wetlands. Using LiDAR, aerial imagery, and ground-penetrating radar, this …

Isotopic Study Of The Waters From The Sulphur Springs Catchment, Tampa, Florida, Esra Zengin

USF Tampa Graduate Theses and Dissertations

A stable isotope study was carried out using precipitation, spring water, groundwater well sample, and a seawater sample during the wet season in the Sulphur Springs watershed in Tampa, Florida. Studies that track long term isotopic variation over wet seasons are limited in the region. To fill this knowledge gap, this study aims to quantify the contributions of precipitation and diffuse sources to discharge in Sulphur Springs. A three-component mixing model was applied using δ18O and δ2H values to determine different source water contributions to spring water discharge. The three-component mixing model calculations suggest spring water consists mainly of diffuse …

Geospatial Applications Of Cave Resource Data To Better Understand Epikarst And Unsaturated Zone Groundwater Flow Path Development, Sierra M. Heimel, Benjamin W. Tobin

Faculty, Staff, and Affiliated Publications--KGS

The unsaturated zone is a critical component of karstic groundwater systems and is shown to provide substantial storage capacities. Understanding the spatial patterns and controls on flow path activation is often a challenge. Previous research focused on remotely sensed data or inferential analyses to quantify these patterns. Here, we use two cave systems—one in Arizona, USA and a second in Kentucky, USA—to show the value of the cave survey and inventory data in the direct observation of speleogenesis and unsaturated zone processes. Using geospatial statistical analyses, we show that passage size varies with distance from some faults, indicating that these …

Surficial Geologic Map Of The Flaherty 7.5-Minute Quadrangle, Kentucky, Ann Hislop, Matthew Massey, Maxwell L. Hammond Iii, Antonia E. Bottoms, Michele Mchugh, Emily Morris

Contract Reports--KGS

The Flaherty 7.5-minute quadrangle is located southwest of Louisville and northwest of Elizabethtown along the boundary between Hardin and Meade Counties. The quadrangle includes mostly the Pennyroyal region of the Mississippian Plateau and also smaller areas of the Mammoth Cave plateau and the highly dissected Dripping Springs escarpment in the western half of the map area (McDowell, 1986). Topography is mostly characterized by pervasive sinkhole development in a lower elevation and low-relief plain, and high-relief plateaus, ridges, and knobs of the Dripping Springs escarpment scattered along the west side of the quadrangle. Swadley (1963) mapped the bedrock geology of the …

Morphometric Quantification Of Cockpit Karst In A Jamaican Bauxite Mining Concession, M Sean Chenoweth

Research, Publications & Creative Work

A digital surface model (DSM) is used to characterize the landscape and topical karst landforms within a bauxite mining lease in north central Jamaica. Five case study sites are selected for detailed geomorphic analysis and cartographic visualization using a GIS. In Jamaica, tropical cockpit karst landscapes are composed of several landforms: cockpits, glades, corridors, saddles, and talus slopes. Evidence for the existence and quantification of these landforms is provided in this paper. Study sites have a mean basin area of 96,514 m2 , an average highest elevation of 541 m, mean lowest point of 444 m, with an average enclosed …

Dye Tracing And The Effects Of Infrastructure In Hidden River Cave, Horse Cave, Ky, Alexa G. Franks

Master's Theses or Doctor of Nursing Practice

Hidden River Cave is a stream cave system found in Horse Cave, KY with continuous water flow of its two branches, Wheet River and East River. The infrastructure of the city of Hose Cave, KY was originally designed to utilize natural sinkholes for drainage of all wastewaters. The city uses many of these, now modified, sinkholes for wastewater disposal and storm water drainage. Historically, Hidden River Cave has been severely impacted by unmonitored dumping of contamination. To better understand and identify specific flow paths from sinkholes and infrastructure into Hidden River Cave, this study documented various sinkholes and other infrastructure, …

Investigation Into Karst Of Southwest Missouri Using Electrical Resistivity, Donald Zachary Wormington

Graduate Theses/Dissertations

Nixa, Missouri is located on the southwestern edge of the Ozark Dome which has a karst geomorphological environment. Near surface geophysical methods can be used in determining the location and nature of karst features such as caves and sinkholes. Electrical resistivity methods have been shown to be among the most useful methods in deciphering sinkholes and caves. To investigate a known cave and related sinkholes and faults within Mississippian carbonates south of Nixa, Missouri, a series of two-dimensional electrical resistivity profiles were collected using the dipole-dipole and Schlumberger arrays. Terrain data was collected to include in modeling. The data were …

Chemical Characterization Of Clastic Cave Sediments And Insights Into Particle Transport And Storage In Karst Aquifers, Jill L. Riddell

Graduate Theses, Dissertations, and Problem Reports (ETD)

Abstract

Chemical characterization of clastic cave sediments and insights into particle transport and storage in karst aquifers

Jill L. Riddell

Cave sediments can be divided into two groups: precipitates and clastics. Precipitates are speleothems, or lithologic or mineral features that are chemically precipitated in the cave environment. Clastic cave sediments are frequently described by depositional facies, sorting, and particle size (Bosch and White, 2004). Robust analytical chemical analyses of these sediments to quantify their physical and chemical components is rarely performed although some chemical characterization of mineralogy and paleomagnetism has become prevalent in recent years (Chess et al., 2010; Sasowsky …

Void Hunting: Ambient Noise Tomography For Spatio-Temporal Subsurface Imaging And Monitoring In Karst Environments, John B. Paustian

Boise State University Theses and Dissertations

Karst environments are characterized by voids, i.e. sinkholes and conduits of varying size that arise from the active dissolution of carbonate rock by acidic groundwater. These voids, whether air-, water-, or soil-filled, can be difficult to image using near-surface geophysical methods due to the limited investigation depths of most active-source methods. In addition, due to the significant effort it takes to collect active-source data, investigators are often unable to monitor spatio-temporal variations in the subsurface. The ability to detect, image, and monitor subsurface voids improves the understanding of processes that create and transform voids, a vitally important insight across a …

The Application Of Opposing Coils Transient Electromagnetics In The Detection Of Karst Subsidence Area, Xie Jia, Liu Yang, Li Xingqiang, Lu Yulong, Li Ganlong

Coal Geology & Exploration

Ground collapse caused by karst is both disastrous and covert. In order to forecast and control it effectively, a research area with strong karst collapse development was selected in this study, and a method that combines Opposing Coils Transient Electromagnetics with engineering geological drilling was used to verify the formation occurrence through the factors including buried depth of overburden, resistivity and isoline variation. The results of geophysical inversion maps and borehole information verification show that the Opposing Coils Transient Electromagnetics method can effectively identify the development of underground corrosion. Especially in the area where the conventional geophysical exploration methods may …

Terrestrial Lidar Scanning And Gaming Engines: Using Unity3d To Visualize High-Resolution Point Clouds From Big Bat Cave, Kentucky, Jeffrey Aaron Baggett

Theses and Dissertations

Terrestrial LiDAR scanning has become a staple of modern speleological research and mapping due to its increasing availability, rapid deployment, and ability to collect large quantities of spatial data in a short period of time. In addition to spatial data, LiDAR scanners’ ability to record reflection intensity is of interest in the geoscience community as a proxy for surface reflectivity and as a means of aiding in visualizations when a lack of lighting prevents the use of photography at a useful scale. In this study, a methodology for rendering a stereoscopic, real-time rendering of a 10 scan, 425-million point portion …

Atmosphere/Landscape Co2 Interactions In Mammoth Cave National Park: Hydrochemistry Of Cascade River, Great Onyx Cave, Jessica Williams

Mahurin Honors College Capstone Experience/Thesis Projects

High-resolution analysis of water/CO₂/carbonate rock geochemistry was conducted at the Great Onyx Groundwater Basin in Mammoth Cave National Park. The purpose of this work has been to undertake hydrochemical characterization of the karst groundwater in Cascade River, the largest cave stream in the upper level of Great Onyx Cave, which is below a relatively pristine karst landscape.

Hydrochemical monitoring of Cascade River at Biz Falls using field, laboratory, and high-resolution electronic data-sonde measurements has provided a detailed picture of the stream’s behavior with respect to the transport and influence of carbon dioxide in the surface and groundwater system …

Topographic Gradients In Bulk Soil Properties In Central Kentucky Karst Sinkholes, Anne Kathryn Mcgraw

Theses and Dissertations--Plant and Soil Sciences

The Bluegrass physiographic region of Kentucky is underlain by the late Ordovician Lexington Limestone formation. This area has many identifiable karst features, including sinkholes. Karst sinkholes and associated soils coevolve, which may influence the distribution of bulk soil properties and storage of carbon across karst landscapes. Two sinkholes on the University of Kentucky’s C. Oran Little Animal Research Center in Woodford County, central Kentucky, were selected for analysis. We described and sampled nine pedons at the dominant landscape positions (e.g., summit, shoulder, backslope, footslope, and toeslope) within the two sinkholes; we characterized the physical, chemical, and mineralogical soil properties across …

Porosity And Permeability Extremes In An Eogenetic Carbonate Platform: Mechanisms For Formation And Implications For Fluid Flow, Charles I. Breithaupt

USF Tampa Graduate Theses and Dissertations

Carbonate rocks contain about a third of the worlds drinking water and host 60-70% of proven hydrocarbon reserves. Effective development and management of these resources relies heavily on geologic concepts used to predict the distribution, and magnitude of porosity and permeability in the aquifer or reservoir. Most geologic concepts used for flow prediction have been developed in telegenic limestones, where fracture networks, bedding plains, and conduits hosted in effectively impermeable bedrock control the movement of fluids, and evolution of porosity. However, a growing body of work has recognized fluid flow within eogenetic limestones is fundamentally different, and that new concepts …

Using Tidal Analysis To Examine Lake-Aquifer Connectivity On A Modern Carbonate Platform, Ronald A. Knoll

USF Tampa Graduate Theses and Dissertations

Lake-aquifer connectivity on carbonate platforms is governed by basin morphology which is influenced by diagenetic and depositional processes. Both these processes cause aquifer permeability to vary significantly with scale of measurement (i.e., pore-scale, well-scale, and regional-scale). Because coastal aquifers are well-known to have tidally controlled water level fluctuations, inland lakes may be used to expand the areal measurement of permeability and establish a link between well-scale and regional scale connectivity in the aquifer. To evaluate the impact of lake basin morphology on aquifer connectivity, water level fluctuations were collected at high temporal resolution in the ocean and twenty-four surface water …

Bubble Trail And Folia In Cenote Zapote, Mexico: Petrographic Evidence For Abiotic Precipitation Driven By Co2 Degassing Below The Water Table, Rafael López-Martínez, Fernando Gázquez, José M. Calaforra, Philippe Audra, Jean Y. Bigot, Teresa Pi Puig, Rocío J. Alcántara-Hernández, Ángel Navarro, Philippe Crochet, Liliana Corona Martínez, Raquel Daza Brunet

International Journal of Speleology

Folia are speleothems that resemble bells, inverted cups, or bracket fungi, and whose origins are still controversial. Cenote Zapote (an underwater cave) in the Yucatán Peninsula (México), is home to some of the largest folia reported to date. These speleothems are currently growing in an active underwater system, meaning this site offers an excellent opportunity to constrain the different formation models proposed for folia, which have traditionally relied on inactive examples. In Cenote Zapote, folia are closely related to bubble trails and cupolas, suggesting an underwater CO₂-degassing process. In thin section, they display a succession of columnar-open and …

Application Of Excitation-Emission Matrices To Fluorescent Dye Tracing Of Groundwater Flow, Cayla M. Baughn

Masters Theses & Specialist Projects

Fluorescent dye tracing of groundwater is a technique employed particularly in carbonate rock karst regions to examine karst hydrology by mapping underground flow paths. It is important to understand the hydrology of karst environments because solutionally-enlarged conduits may allow the rapid influx of contaminants into the groundwater system. Fluorescent dye tracing involves the injection of a fluorescent dye into an appropriate injection site (sinking streams, sinkholes, or even through soil flushed with water) and is followed by sampling at sites where the dye may be recovered (typically springs). Various methods exist by which sampling may occur, but all methods ultimately …

Impacts Of Forest Management And Timber Harvest Practices On Karst Critical Zone Processes In Tongass National Forest, Alaska, Anna Gwendolyn Harris

Masters Theses & Specialist Projects

This study characterizes the throughfall, hydrogeochemistry, dissolution rates, and carbon sources of two proximate temperate rainforest cave systems within the Tongass National Forest in Southeast Alaska (Tongass). Study sites include: an old-growth forest, characterized by having never been logged (containing Walkabout Cave system); and a previously logged – within thirty years, second-growth forest (containing Zina Cave system). Precipitation data were recorded over a five-month period at 10-minute intervals, to understand the effects of throughfall between the altering old and second-growth canopies. At each major spring for the two cave systems, high-resolution data were collected from June 29 through November 21, …

A Geochemical And Statistical Investigation Of The Big Four Springs Region In Southern Missouri, Jordan Jasso Vega

Graduate Theses/Dissertations

The Big Four Springs region hosts four major first-order magnitude springs in southern Missouri and northern Arkansas. These springs are Big Spring (Carter County, MO), Greer Spring (Oregon County, MO), Mammoth Spring (Fulton County, AR), and Hodgson Mill Spring (Ozark County, MO). Based on historic dye traces and hydrogeological investigations, these springs drain an area of approximately 1500 square miles and collectively discharge an average of 780 million gallons of water per day. The rocks from youngest to oldest that are found in Big Four Springs region are the Cotter and Jefferson City Dolomite (Ordovician), Roubidoux Formation (Ordovician), Gasconade Dolomite …

Hydrogeochemical Characterization And Speleogenesis Of Sistema Huautla In Oaxaca, Mexico, Fernando Hernandez

Masters Theses & Specialist Projects

Sierra Mazateca, Mexico is home to Sistema Huautla, the deepest cave in the Western hemisphere with 1,560 meters of depth and 90 kilometers of passage, including 26 entrances distributed in a high-relief, karstified terrain, within the Sistema Huautla Karst Groundwater Basin. Exploration of the cave has generated research questions about its evolution and geomorphology given the different vadose and phreatic zones impacted by tectonic and incision processes. Dye traces during this study of Cueva de La Peña Colorada confirmed it is a fossil resurgence of the cave system. An additional cave, Cueva Elysium, was connected hydrologically in 2019, expanding the …

Delineating Subsurface Karst Potential Using Electrical Resistivity In The Shell Mountain Province, Fort Hood Military Installation, Texas, Annie Robison

Electronic Theses and Dissertations

Fort Hood Military Installation is located within the Lampasas Cut Plain in Bell and Coryell counties, Texas, and is characterized by exposures of Lower Cretaceous Trinity and Fredericksburg Group carbonates. The Shell Mountain Province is an elevated plateau located in western Fort Hood utilized by the military for heavy mechanical (troop and wheeled) maneuver training and hosts significant surficial and subsurface karst. Ongoing karst inventories in western Fort Hood conducted by range managers have documented over 100 individual karst features. Recent studies utilizing LiDAR and remote sensing techniques delineated karst potential in this area and identified over 13,909 discrete depressions. …

Storm Sampling To Assess Inclement Weather Impacts On Water Quality In A Karst Watershed: Sinking Creek, Watauga Watershed, East Tennessee, Porcha Mccurdy

Electronic Theses and Dissertations

Escherichia coli changes in Sinking Creek, an impaired water body in the Watauga watershed of northeast Tennessee, were assessed during storm events using water samples collected with ISCO automated samplers during eight storms at two locations. Turbidity and electrical conductivity (EC) data loggers were deployed in the creek, and dissolved oxygen (DO) was measured in situ to test the stream’s water quality and reaction to inclement weather. Cotton fabric was deployed at both locations and sent to an external lab to test for the presence of Optical Brighteners (OB), which are indicators of residential wastewater. E. coli and turbidity at …

Spatiotemporal Changes Of Microbial Community Assemblages And Functions In The Subsurface, Madison C. Davis

USF Tampa Graduate Theses and Dissertations

The subsurface hosts diverse microbial community assemblages and functions. These communities play an important role in biogeochemical cycling and groundwater purification. Many physicochemical factors affect microbial communities and can cause short-term or long-term perturbations. Subsurface microbes are susceptible to anthropogenic changes in the environment, which can be caused by nutrient inputs or municipal groundwater extraction. Despite the importance of the subsurface microbiome, these microbial communities are poorly characterized. This dissertation describes the characterization of spatiotemporal drivers of subsurface microbial communities through a variety of techniques that include eDNA analyses, bioinformatics, hydrochemical analyses, stable isotope geochemistry, and multivariate statistics. Three coastal …

Analysis Of Clastic Cave Sediment In A Fluviokarst System, Russell Cave, Northeast Alabama, Jonathan Camelo

Master's Theses or Doctor of Nursing Practice

Russell Cave is part of a fluviokarst system located along the edge of the Cumberland Plateau in northeast Alabama. The cave system acts as a surface-subsurface drainage system transporting, depositing, and accumulating large influxes of terrestrial-derived materials (sediments, organic material, and magnetic minerals) into the subsurface system forming sediment traps. Five core sites along various discontinuous sediment banks were collected and sampled in 2 cm intervals. Data collection involved Red-Green-Blue (RGB) color, loss on ignition (LOI), magnetic susceptibility (MS) grain-size analysis, end member mixing analysis (EMMA), and ¹⁴C radiocarbon dating. The goals for this research were to identify the …

A Karst Feature Predictability Model Within Barber County, Kansas, Gary M. Kelner

Master's Theses or Doctor of Nursing Practice

This research consisted of two topics: 1) geographic predictive models of karst features and 2), a petrographic study examining the lithology of the study area. The study area is a privately owned ranch in the Gypsum Hills of Barber County, Kansas and is known to have karst features. Two predictive models for karst features were utilized. Previously identified features, Light Detection and Ranging (LiDAR), and Advanced Spaceborne Thermal Emission and Reflection Radiometer (ASTER) imagery aided in the creation of these predictive models. These predictability models also used the ESRI ArcMap software platform. The data for these models consists of slope, …

Geophysical Assessment Of The Lake Chesterfield Site, Missouri, Diya Ali Ahmad Alfuqara

Doctoral Dissertations

"Since construction of the Lake Chesterfield, Missouri in 1986, significant leaks have occurred causing the lake to lose substantive volumes of water. Mitigation efforts, have not solved the problem. Indeed, in June of 2017, the water level in Lake Chesterfield dropped at an alarmingly rapid rate. Prior to authorizing additional mitigation work, the Lake Chesterfield. Home Owners Association (LCHOA) decided to acquire geophysical data across the drained and dry lake bed. These information would help a geotechnical engineering firm determine the most appropriate mitigation plan.

In the summer of 2018, electrical resistivity tomography, multichannel analysis of surface wave, and spontaneous-potential …

Physical And Chemical Properties Of Clastic Sediments From Two Caves In The Northern Karst Region Of Puerto Rico, Autum R. Downey

Graduate Theses, Dissertations, and Problem Reports (ETD)

Geochemical properties and organic characteristics are essential to understanding the general depositional dynamics of a cave. Most work on clastic cave sediments focuses on physical properties of sediments. Little work has been done on bulk organic matter and geochemical properties.

This project reports physical and geochemical characterization of cave sediments from two caves in the northern karst region of Puerto Rico: El Tallonal Cave and Cueva Clara. Core and grab samples were collected and analyzed for particle size, total organic carbon, total nitrogen, organic matter characteristics using fluorescence spectroscopy, and major and minor elements using X-ray fluorescence (XRF). The sediments …