Earth Sciences Commons^™

Geochemical And Sensor-Based Monitoring Of Fault-Associated Carbonic Springs In Grand Canyon And Northern New Mexico: Identifying Hydrologic Pathways And Establishing Baselines, Chris Mcgibbon

Earth and Planetary Sciences ETDs

This dissertation examines the interaction of spring systems and faulting. When springs discharge within a fault zone the interaction is often complex, and multiple methods are required to understand the flow, mixing and evolution of groundwater. In karst aquifer systems fracture networks can range from sub-millimeter to meters and only adds to the complexities involved in examining spring hydrology. The Interest in springs and faulting is not only driven by science, but also has applied applications. Faulting and fluid flow are of interest to the oil and gas industry, and potential CO₂ sequestration. In the southwestern US, water quantity …

Identifying Biogeochemical Factors Responsible For The Cyclical Precipitation Of Sphalerite And Galena In Low Temperature Mississippi Valley Type Ore Deposits, Daniel John Makowsky

Theses and Dissertations

Mississippi Valley Type (MVT) lead and zinc deposits provide a significant source of sedimentary galena and sphalerite. However, geochemical characteristics and genesis including the source and production of hydrogen sulfide required for galena and sphalerite ore formation and the reasoning for quick, episodic mineralization is not fully understood. By simulating regional MVT brines, the input and effect of biological by-products during the development of these ores as well as the cause of cyclicity within MVT deposits have been observed. Experiments using compositions from MVT fluid inclusions were conducted over two-week periods. Variables during the experiments included temperature, CO2, hydrogen sulfide …

Geochemical Investigation Of Monogenetic Volcanoes From The Pribilof Islands, Bering Sea, Alaska, Clayton L. Reinier

Graduate Theses/Dissertations

Small-volume basaltic magmas found at continental intraplate environments have not been as extensively studied compared to their polygenetic counterparts. Specifically, regions such as the Bering Sea basalt province, described as a diffuse igneous province, have commonly been overlooked. Assumptions that these systems are invoked by simple, single batches of magma has subsequently left a gap in understanding the processes responsible for primary magma generation away from plate boundaries with little tectonic influence. The following studies that constitute this thesis focus on an in-depth geochemical investigation at the crystal and sub-crystal scale to evaluate lithospheric mantle heterogeneities, processes that govern primary …

Volumetric Extrusive Rates Of Silicic Supereruptions From The Afro-Arabian Large Igneous Province, Jennifer E. Thines, Ingrid A. Ukstins, Corey Wall, Mark Schmitz

Geosciences Faculty Publications and Presentations

The main phase of silicic volcanism from the Afro-Arabian large igneous province preserves some of the largest volcanic eruptions on Earth, with six units totaling >8,600 km³ dense rock equivalent (DRE). The large volumes of rapidly emplaced individual eruptions present a case study for examining the tempo of voluminous silicic magma generation and emplacement. Here were report high-precision ²⁰⁶Pb/²³⁸U zircon ages and show that the largest sequentially dated eruptions occurred within 48 ± 34 kyr (29.755 ± 0.023 Ma to 29.707 ± 0.025 Ma), yielding the highest known long-term volumetric extrusive rate of silicic volcanism on …

The Sedimentary Geochemistry And Paleoenvironments Project, Úna C. Farrell, Rifaat Samawi, Savitha Anjanappa, Roman Klykov, Oyeleye O. Adeboye, Heda Agic, Anne Sofie C. Ahm, Thomas H. Boag, Fred Bowyer, Jochen J. Brocks, Tessa N. Brunoir, Donald E. Canfield, Xiaoyan Chen, Meng Cheng, Matthew O. Clarkson, Devon B. Cole, David R. Cordie, Peter W. Crockford, Huan Cui, Tais W. Dahl, Lucas D. Mouro, Keith Dewing, Stephen Q. Dornbos, Nadja Drabon, Julie A. Dumoulin, Joseph F. Emmings, Cecilia R. Endriga, Tiffani A. Fraser, Robert R. Gaines, Richard M. Gaschnig, Timothy M. Gibson, Geoffrey J. Gilleaudeau

Geosciences: Faculty Publications

No abstract provided.

Major Controls On Diagenesis In The Martin Bridge Formation: Wallowa Mountains, Oregon, Jane Lyra Eisenberg

Dissertations and Theses

Diagenetic alteration in carbonates has long frustrated scientists who wish to use their chemistry and/or texture to understand conditions at the time of deposition. Though indicators of diagenesis are well documented, their interpretation is not always straightforward. Despite the large volume of research on the subject, the positive identification and interpretation of diagenesis is a source of ongoing debate in the scientific community.

The goal of this study is to better understand the timing of, and controls on, diagenetic alteration in the Martin Bridge Formation (MBF), a Triassic-aged limestone that was altered following deposition. Thirty-nine samples of MBF with differing …

Mid-Miocene Icelandites Of Eastern Oregon: Petrogenesis And Magmatic Lineage To Main-Phase Crbg With Constraints On Storage Sites, Melissa Aileen Carley

Dissertations and Theses

The La-Grande Owyhee eruptive axis is a mid-Miocene to Pliocene ~300 km long volcanic belt located at the eastern margin of the Columbia River Basalt Group (CRBG) in Oregon. Within this volcanic belt there are numerous vents that have produced a large volume of petrologically diverse rocks ranging from the tholeiitic flood basalts of the CRBG to rhyolitic tuffs of caldera complexes such as the Lake Owyhee Volcanic field. Icelandites, which are iron rich andesites, are known to occur in association with silica saturated to oversaturated tholeiitic basalts as a minor part of continental flood basalt volcanism. This study investigates …

Laboratory Capabilities, University Of North Dakota. Energy And Environmental Research Center

EERC Brochures and Fact Sheets

Fact sheet about the Energy & Environmental Research Center’s laboratory capabilities including reservoir characterization, organic geochemistry, fluid sampling, and material analysis. A list of publications and laboratory information is also included.

Geologic Characterization Of The Nonconformity Interface Using Outcrop And Drillcore Analogs: Implications For Injection-Induced Seismicity, Kayla Smith

All Graduate Theses and Dissertations, Spring 1920 to Summer 2023

Starting around 2009, a greater number of earthquakes than anticipated have occurred in the midcontinent region of the United States. These earthquakes have been linked to increased rates and volumes of wastewater injection at several km’s depth into the Earth’s crust near a contact between crystalline metamorphic or igneous rock and overlying sedimentary rock, known as a nonconformity. While much is known about why these new earthquakes occur, comparatively little is known about the physical and chemical rock properties because the nonconformity contact is primarily buried under km’s of sedimentary rock in the midcontinent region. These rock properties are important …

Petrology And Geochemistry Of Evolved Achondrites: Planetesimal Mantles And Crusts, Zoltan Vaci

Earth and Planetary Sciences ETDs

Melting and differentiation are fundamental to early solar system evolution on planetary bodies that accreted enough material to heat up radioactively or through impacts and breach their solidi. Partially and fully melted material is present in the meteorite record in the form of primitive achondrites and achondrites, which are fragments of planetesimals that underwent heating events in the first few million years of solar system history. Although the vast majority of this material is mafic or ultramafic, new evolved samples, recovered in the last few decades, are pushing the petrologic and geochemical boundaries of planetesimal melting, differentiation, and crust formation. …

Barriers To And Uncertainties In Understanding And Quantifying Global Critical Mineral And Element Supply, Brian A. Mcnulty, Simon M. Jowitt

Geoscience Faculty Research

The critical minerals and elements are natural substances that are essential to modern life but have insecure supply. This lack of a secure supply clashes with the increasing importance of these elements, especially given their use in technologies needed to reduce global CO2 emissions and mitigate against anthropogenic climate change. In this contribution we review the by-product nature of the critical minerals and elements and the inherant uncertainties in reported critical mineral and element annual production as well as the relationships between these commodities and main-product metals and associated concentrates. We explore the geological and geographical barriers to critical mineral …

Leveraging Detrital Zircon Geochemistry To Study Deep Arc Processes: Ree-Rich Magmas Mobilized By Jurassic Rifting Of The Sierra Nevada Arc, D. Clemens-Knott, Kathleen Degraaff Surpless, A. P. Barth, J. L. Wooden

Earth and Environmental Geosciences Faculty Research

Anomalous trace element compositions of Middle to Late Jurassic detrital zircon separated from Sierra Nevada forearc and intra-arc strata reveal processes of differentiation occurring within the deep arc lithosphere. REE-Sc-Nb-Ti-Hf-U-Th covariations define three populations of atypically REE-rich grains that we interpret as crystallizing from (1) differentiates produced by olivine+clinopyroxene+plagioclase+garnet±ilmenite fractionation; (2) mixing between mafic arc magmas and partial melts of Proterozoic Mojave province crust; and (3) compositionally transient, low Gd/Yb magmas generated by hornblende resorption during decompression. We interpret a fourth population of Middle Jurassic to Early Cretaceous zircons having REE contents similar to “typical” arc zircon but with atypically …

Past Ice-Ocean Interactions On The Sabrina Coast Shelf, East Antarctica: Deglacial To Recent Paleoenvironmental Insights From Marine Sediments, Kara J. Vadman

USF Tampa Graduate Theses and Dissertations

The East Antarctic Ice Sheet (EAIS) contains ~53 meters of sea level equivalent (SLE) ice, and observations suggest it is sensitive to ongoing and past climate change. The EAIS has traditionally been considered insensitive to climate perturbations because it is largely grounded above sea level. However, aerogeophysical surveys, oceanographic observations, and models indicate that large areas of the EAIS are grounded below sea level and contain 19.2 m SLE. Marine-based parts of the EAIS are thought to be located on inland-sloping beds that drain through marine terminating outlet glaciers, indicating large areas of the EAIS may be more sensitive to …

Petrogenesis Of Hawaiian Lavas: Investigations Using Radiogenic And Non-Traditional Stable Isotopes, Christopher Defelice

UNLV Theses, Dissertations, Professional Papers, and Capstones

Earth’s mantle is the most voluminous part of the planet and is inaccessible to direct investigations. It is only possible to study it through indirect methods, such as the chemical makeup of erupted lavas. The Hawaiian Islands are thought to be the product of the mantle plume hypothesis, sometimes called a hot spot. Material from the Earth’s mantle is brought to the surface and erupted as magnesium rich lavas and form basalts. Hawaii is the longest lived active hot spot on Earth and makes it an ideal candidate for understanding the evolution of the Earth’s mantle and how lavas cool …

Geochemical Characteristics And Genesis Of Coalbed Methane In Baode Area, Li Yangbing, Zeng Lei, Hu Weiqiang, Chen Xin, Ma Litao, Liu Cheng, Huang Ying, Qiao Fang

Coal Geology & Exploration

In order to find out the geochemical characteristics and origins of coalbed methane(CBM)in Baode area, coal, CBM and water samples were collected, gas component analysis, quality detection of CBM well-produced water and stable isotope analysis were carried out. The results show that CH₄ is the main hydrocarbon gas in CBM composition and its volume fraction ranges from 88.60% to 97.59%; a small amount of ethane is contained, and the volume fraction is only 0.01%-0.14%. The drying coefficient is greater than 0.99, the CBM belongs to the extremely dry CBM. The non-hydrocarbon components mainly contain CO₂ and N_{2 …}

A Record Of Vapour Pressure Deficit Preserved In Wood And Soil Across Biomes, Adrian Broz, Gregory J. Retallack, Toby M. Maxwell, Lucas C.R. Silva

Biology Faculty Publications and Presentations

The drying power of air, or vapour pressure deficit (VPD), is an important measurement of potential plant stress and productivity. Estimates of VPD values of the past are integral for understanding the link between rising modern atmospheric carbon dioxide (pCO₂) and global water balance. A geological record of VPD is needed for paleoclimate studies of past greenhouse spikes which attempt to constrain future climate, but at present there are few quantitative atmospheric moisture proxies that can be applied to fossil material. Here we show that VPD leaves a permanent record in the slope (S) of least-squares …

Multiple Fluid-Mineral Equilibria Approach To Constrain The Evolution Of Thermal Watersin The Hisaralan Geothermal Field, Simav Graben, Western Turkey, Ali̇ Gökgöz, Hali̇m Mutlu, Mehmet Özkul, Ali̇ Kami̇l Yüksel

Turkish Journal of Earth Sciences

In this study seasonal changes in the geochemical and stable isotope compositions of Hisaralan thermal waters in Simav Graben, western Turkey, were investigated with regards to a variety of mineral-water interactions and mixing processes. The Hisaralan and Emendere geothermal waters, with temperatures of up to 99 °C, were mostly of Na-HCO3 and Ca-HCO3 types. The δ18O and δ2H values of the Hisaralan waters ranged from -9.32‰ to -8.73‰ and -65.02‰ to -61.10‰, with maximum seasonal differences of 0.3‰ and 1.8‰. The Emendere waters were represented by a more positive range of δ2H values (-54.95‰ to -54.61‰), while their δ18O compositions …

Variations In Produced Water Chemistry And Relation To Regional Geology And Production In The Marcellus Shale, Northcentral West Virginia, Jonathan M. Brady

Graduate Theses, Dissertations, and Problem Reports (ETD)

An investigation of 74 Marcellus Shale wells across northcentral West Virginia indicates changes in produced water chemistry and quantity can be related to geologic conditions based on well logs and core data. These changes are determined by reviewing multiple produced water analyses for individual wells for periods up to ten years. Results show variations among the areas in this study. From west to east across central Harrison County to central Taylor County, then north into Monongalia County, gamma-ray logs show increasing intensity, especially in the middle and lower Marcellus. XRD mineralogy from core data shows increasing clay content from west …

Stratigraphy And Geochemistry Of Paleocene-Aged Bauxites From North Mississippi, Timothy Brendan Clark

Electronic Theses and Dissertations

Bauxite is a heavily-mined aluminum ore that forms through the relative depletion of silica to aluminum. In North Mississippi, bauxite occurring within the Upper Midway and Lower Wilcox groups has been the subject of study for over a century. Despite the abundance and duration of research, controversy surrounds the subjects of bauxite genesis and economic value. The last detailed study of North Mississippi bauxite was in the 1980’s, so the goal of this project is to apply newly available technologies and modern hypotheses on bauxite formation to refine and obtain new data. Fieldwork observations yielded pisoliths, horizonation, and possible rhizoliths, …

Internal Loading Of Nitrogen (N) And Phosphorus (P), Reduced N Forms, And Periodic Mixing Support Cyanobacterial Harmful Algal Blooms (Habs) In Shallow, Eutrophic Honeoye Lake (New York, Usa), Justin Adam Myers

Browse all Theses and Dissertations

Cyanobacteria are important primary producers, but large cyanobacterial harmful algal blooms (HABs) have many negative ecological and health impacts and are becoming increasingly common. Honeoye Lake (New York, USA) is a shallow, eutrophic lake characterized by increasingly frequent HABs. Nitrogen (N) and phosphorus (P) loads often drive HABs in lakes, and sediment processes can contribute to N removal (e.g., denitrification) or loading (e.g., N fixation, remineralization). Sediment cores and lake water were collected during May–October (2016–2018) at two sites and incubated with no amendments (controls) or 15N stable isotopes to measure sediment nutrient fluxes and N cycling dynamics in Honeoye …

Alteration Reactions In A Hornblende-Biotite-Anthophyllite-Fluid System: Implications For Cu-Au Ore Deposits, James Mitchell Lightner

Graduate Research Theses & Dissertations

High-grade porphyry Cu-Au ore deposits are typically contained in the potassic alteration zone, which forms through the alteration of preexisting country rock by a magmatic volatile phase (MVP) exsolved from an igneous intrusion. The MVP is a H2O dominant phase that contains high concentrations of NaCl, KCl, FeCl2, HCl, sulfur (as H2S or SO2) and minor concentrations of metals. The minerals in the potassic alteration zone are predominantly K-feldspar and biotite with a shreddy texture. Shreddy biotite forms from the replacement of prismatic-tabular shaped hornblende crystals, resulting in a characteristic shreddy texture. The alteration of hornblende to biotite can neutralize …

Application Of High-Precision 3d Seismic Exploration Technology In Huainan Mining Area, Liu Jun, Zhao Wei, Han Biwu

Coal Geology & Exploration

In order to deeply analyze the indication of oil shale development characteristics on paleoenvironments and provide theoretical guidance for oil shale resource evaluation, the organic geochemistry and elemental geochemistry characteristics of the Neogene Zhangcun Formation oil shale in the central part of the Qinshui basin were analyzed by Rock-Eval and TOC and the paleoclimate and paleogeographic environments of the depositional period were discussed as well. The results show that the oil shale of Zhangcun Formation has the low oil content which Tar=4.15%, higher hydrocarbon potential, kerogen is of sapropel type(I₁), which has relatively shallow burial depth. The element …

Mexican Obsidian On Maui: Hawaiian Connection, Harmonic Convergence, Or Hokum?, Matthew Boulanger

Anthropology Research

In 2014, the television show America Unearthed (A & E Networks) featured an episode discussing evidence for pre-Columbian contact between Polynesia and continental North and South America. Included in this “evidence” was a large spearpoint, allegedly found on the island of Maui. The show’s host argues that the spearpoint is made on obsidian from central Mexico, and therefore represents evidence for direct contact between Polynesian and Maya peoples prior to the sixteenth century CE. A detailed analysis of the spearpoint, including geochemical sourcing, reveals that it is indeed made of so-called Pachuca obsidian from central Mexico; however, the size, shape, …

Stable Isotope Composition Of Surface Water Across Central Mexico, Jordan Foote

Earth & Environmental Sciences Theses - Archive

Understanding the controlling factors of modern surface water stable isotope compositions is important for reconstructions of paleoclimate and paleoelevation. Few studies have attempted to understand patterns of surface water isotope compositions and their controlling factors in Mexico. Here I study the δ18O, δD and d-excess values of 124 modern river, lake and spring water samples across the Sierra Madre Occidental, Central Mexican Plateau and Sierra Madre Oriental to constrain the spatial pattern and lapse rate. These samples were collected at various elevations after the wet season in 2019. The isotope data were integrated with moisture back trajectory analysis and climatic …

Boron Adsorption In Clay Minerals: Implications For Martian Groundwater Chemistry And Prebiotic Processes, Matthew A. Nellessen, Laura Crossey, Patrick J. Gasda, Horton Newsom, Abdulmehdi Ali, Eric J. Peterson, Nina Lanza, Adriana Reyes-Newell, Dorothea Delapp, Chris Yeager, Andrea Labouriau, Roger C. Wiens, Samuel Clegg, Shelbie Legett, Debarati Das

Earth and Planetary Sciences ETDs

Boron has been detected on Mars [Gasda et al., 2017, Das et al., 2019, 2020] within calciumsulfate veins found within clay-rich rocks on Mars by the Mars Science Laboratory (MSL) rover using Laser Induced Breakdown Spectroscopy (LIBS) analysis. Boron plays a vital role in stabilizing ribose on Earth and has been suggested as a key requirement for life [Scorei et al., 2006, 2012; Furukawa et al., 2013, 2017; Becker et al., 2019]. Additionally, boron readily adsorbs to phyllosilicate clay minerals and is often associated with biologic processes in clay soils. The discovery of boron on Mars in proximity to phyllosilicate …

Plio-Pleistocene Antarctic Ice-Ocean Interactions In The Ross Sea, Catherine Prunella

USF Tampa Graduate Theses and Dissertations

Warm, intermediate-depth Southern Ocean waters are implicated in recent Antarctic ice mass loss. Direct observations of Antarctic Ice Sheet (AIS) retreat are temporally limited, necessitating paleoceanographic records of ocean-ice interactions during past warm climate intervals. Deepsea and ice-proximal sediments record orbitally-paced glacial-interglacial fluctuations in AIS volume during the Plio-Pleistocene (last 5 million years; Ma), but the total contribution of the AIS and the role of ocean heat in these fluctuations remain unresolved. To address the response of Antarctica’s ice sheets to changing ocean temperatures during the Plio-Pleistocene, International Ocean Discovery Program (IODP) Expedition 374 recovered sediments from the Ross Sea …

Evaluation And Analysis Of Paleoenvironments Of The Neogene Oil Shale Of Zhangcun Formation, Qinshui Basin, Liu Yanhai, Li Kunjie, Liu Dongna, Xue Shubin, Liu Yangfe, Chu Yonghui

Coal Geology & Exploration

In order to deeply analyze the indication of oil shale development characteristics on paleoenvironments and provide theoretical guidance for oil shale resource evaluation, the organic geochemistry and elemental geochemistry characteristics of the Neogene Zhangcun Formation oil shale in the central part of the Qinshui basin were analyzed by Rock-Eval and TOC and the paleoclimate and paleogeographic environments of the depositional period were discussed as well. The results show that the oil shale of Zhangcun Formation has the low oil content which Tar=4.15%, higher hydrocarbon potential, kerogen is of sapropel type(I₁), which has relatively shallow burial depth. The element …

Interpretations Of Lava Flow Properties From Radar Remote Sensing Data, Gavin Douglas Tolometti, Catherine Neish, Gordon R. Osinski, Scott S. Hughes, Shannon E. Kobs-Nawotniak

Earth Sciences Publications

The surface morphology and roughness of a lava flow provides insight on its lava properties and emplacement processes. This is essential information for understanding the eruption history of lava fields, and magmatic processes beneath the surface of Earth and other planetary bodies such as the Moon. The surface morphology is influenced by lava properties such as viscosity, temperature, composition, and rate of shear. In this work, we seek to understand how we can interpret the emplacement processes and lava properties of lava flows using remote sensing data. Craters of the Moon (COTM) National Monument and Preserve in Idaho hosts a …

Geochemical Characterization Of Base Metals In Stream Water And Sediments In The Caddo Lake Watershed, Cass, Harrison, And Marion Counties, Texas, Melinda S. Faulkner, Melanie L. Ertons, Joseph D. Watkins

Faculty Publications

The Caddo Lake watershed is located in northeastern Texas and encompasses much of Cass, Harrison, and Marion counties. The watershed is drained by major streams and tributaries flowing in an easterly direction over Eocene-aged rocks and sediments of the Wilcox and Claiborne groups, and empty into the western arm of Caddo Lake. Since 1995, Caddo Lake and some of its tributaries have been included on the State of Texas Clean Water Act 303(d) list by the Texas Commission on Environmental Quality (TCEQ) for impairment due to mercury content in edible tissue, depressed dissolved oxygen, base metal concentrations, and low pH …

Top–Down Control On Eruptive Style At Masaya Volcano Inferred From Melt Composition, Lisa Hlinka

Student Theses

Highly explosive, Plinian-type eruptions of basaltic magma are enigmatic because basaltic melts have lower viscosities than more silicic melts which have traditionally been considered essential for such explosive eruption style. Masaya volcano, Nicaragua, is one of the few basaltic volcanoes to have generated a wide range of eruptive styles, from effusive lava lake activity to voluminous Plinian fall deposits. This volcano thus offers a unique case study to better constrain ideas on basaltic eruption style controls.

We analyze olivine-, plagioclase- and clinopyroxene-hosted melt inclusions as well as matrix glasses from lava lake (LL) ejecta and two Plinian tephra deposits—the 2.1 …