Earth Sciences Commons^™

Metabasite Blocks From The Koçyaka Hp-Lt Metamorphic Rocks, Konya, Central Anatolia: Geochemical Evidence For An Arc-Back-Arc Pair?, Peter A. Floyd, L. Özgül, M. Cemal Göncüoğlu

Turkish Journal of Earth Sciences

The Kütahya-Bolkardağ Belt, situated on the northern margin of the Tauride-Anatolide Platform, includes slices of HP/LT metamorphic rocks adjacent to allochthonous ophiolitic fragments. The Koçyaka Metamorphic Complex is one such thrust slice and is located to the northeast of Konya. The local tectonostratigraphic succession consists of Upper Cretaceous calcareous metasediments overlain respectively by the Altınekin and Akçasar mélanges of ophiolitic character. Both mélanges contain metabasites (pillow lavas and amphibolites) overprinted with HP-LT glaucophanitic assemblages and later low-grade facies associations. The geodynamic significance of the ophiolites prior to dismemberment (as oceanic crust) is in dispute, being either interpreted as a separate …

Low Salinity Waters In Deep Sedimentary Basins, David Scott Szalkowski

LSU Master's Theses

While the composition and origin of brines in deep sedimentary basins has been extensively discussed, the composition and origin of low salinity waters is not as well documented. Since the 1960s, the presence of deep, low-salinity waters has been observed in some sedimentary basins and is commonly present in overpressured sections. The episodic release of low salinity, overpressured fluids upward into sediments containing high salinity formation waters likely occurs at <100-year intervals. Because there is a growing body of evidence that suggests mixing formation waters of varying salinity could induce the dissolution and precipitation of minerals, it is important to have detailed information about chemical compositions of both end-member fluids to adequately predict such mixing results. This study concludes that low salinity waters (<35 g/l) are generally not unique in major solute composition when compared to high salinity waters (>35 g/l). On log-log plots, monovalent cations plot along 1:1 slopes with respect to salinity and total anionic charge, while divalent cations plot along 2:1 slopes. However, this study concludes …

Thermochronological Evolution Of Calcite Formation At The Potential Yucca Mountain Repository Site, Nevada: Part 2 Fluid Inclusion Analyses And Upb Dating, Jean S. Cline, Amy J. Smiecinski, Robert Bodnar

Publications (YM)

The presence of two-phase fluid inclusions in thin secondary mineral crusts at the potential Yucca Mountain nuclear waste repository has raised questions regarding the origin, timing, and temperature of past fluid flow through the repository horizon. The geologically recent passage of fluids with high temperatures would call into question the suitability of the site for the storage of high level nuclear waste. This study determined the thermal history of fluid flow through the site using fluid inclusion analyses and constrained the timing of thermal fluids by dating silica minerals spatially associated with the fluid inclusions using U-Pb techniques. Results provide …

Thermochronological Evolution Of Calcite Formation At The Proposed Yucca Mountain Repository Site, Nevada: Part 1, Secondary Mineral Paragenesis And Geochemistry, Jean S. Cline, Amy J. Smiecinski, Robert Bodnar

Publications (YM)

In the near future a decision will be made as to whether or not Yucca Mountain, 90 miles northwest of Las Vegas, Nevada is a suitable site for a permanent, underground, high level nuclear waste repository. A major factor in determining the suitability of Yucca Mountain as a repository is the potential for the site to be flooded by water during the regulatory lifetime. The current study was undertaken to examine the past fluid history at the site, to gain a better understanding of the possibility of flooding in the near geologic future. To estimate the past fluid flux into …

Geochemistry Of Atmospheric Aerosols Generated From Lava-Seawater Interactions, Francis J. Sansone, Claudia R. Benitez-Nelson, Joseph A. Resing, Eric H. Decarlo, Sue M. Vink, Jacqueline A. Heath, Barry J. Huebert

Faculty Publications

[1] Trace elements were measured in the aerosol plume produced by lava‐seawater interactions along the shoreline of Kilauea volcano, Hawaii. Plume concentrations were normalized relative to Hawaiian basalt composition and showed a linear log‐log co‐variation with their emanation coefficient (an indicator of element volatility). Normalized aerosol concentrations also consistently covaried with corresponding normalized concentrations in dilute fumarolic gas from Kilauea volcano and fumarolic gas condensates from Kudryavy and Merapi volcanoes, despite different mechanisms of element volatilization. Conservatively estimated regional ocean deposition rates of Cu, Cd, Ni, Pb, Mn, Zn, Fe and P were >50 times background rates. Thus, upper ocean …

Field Relations, Structural Geology, And Geochemistry Of The Jonestown Volcanic Field, Lebanon County, Southeastern Pennsylvania, Tristan J. Ashcroft

Geology Theses and Dissertations

The Jonestown Volcanic Field is a five kilometer by fifteen kilometer area of volcanic and hypabyssal rocks, basalt and diabase, located in southeastern Pennsylvania. These igneous rocks presently occur within an allochthonous belt of Ordovician deep water sedimentary rocks and Taconic flysch rocks known collectively as the Hamburg Klippe. Detailed field mapping during this project has revealed that the contacts between the igneous rocks and the flysch are not conformable. The volcanic rocks are associated with the Ordovician limestone that is adjacent to these volcanics. This limestone also is not conformable to the Hamburg Klippe sediments, rather it shares outcrop …

The Use Of A Synthetic Binary Solid Solution To Model Igneous Textural Evolution, Elizabeth Scott

Geology Theses and Dissertations

Crystallization experiments using a synthetic igneous analog have shown that grain boundary migration can take place in melt-present environments (Means and Park, 1994). In order to evaluate the importance of metamorphic processes during the textural evolution of a crystal mush, microstructural evidence is needed to link them with final igneous textures. In natural magmatic systems, plagioclase may provide a microstructural link; plagioclase solid solution enables the process of chemical zoning and preserves a record of crystal morphology (and chemistry) during growth. If metamorphic processes are common, they should affect the zoning patterns of plagioclase crystals.
A petrographic stage heater apparatus …

Origin Of Late Quaternary Dune Fields On The Southern High Plains Of Texas And New Mexico, Daniel R. Muhs, Vance T. Holliday

United States Geological Survey: Staff Publications

Mostly stabilized late Holocene eolian sands on the Southern High Plains of the United States were studied to determine their origins and to assess whether present dune stability depends more strongly on sediment supply, sediment availability, or transport limitations. Geomorphic, sedimentological, and geochemical trends indicate that late Holocene dunes formed under westerly paleowinds, broadly similar to those of today. Mineralogical and geochemical data indicate that the most likely source for the sands is not the Pecos River valley, but the Pleistocene Blackwater Draw Formation, an older, extensive eolian deposit in the region. These observations suggest that new sand is supplied …

Stratigraphy, Geochemistry And Depositional Environment Of The Celestine-Bearing Gypsiferous Formations Of The Tertiary Ulaş-Sivas Basin, East-Central Anatolia (Turkey), Erdoğan Teki̇n

Turkish Journal of Earth Sciences

Celestine-bearing evaporite mineralization is widespread in the Tertiary evaporitic units of the Ulaş-Sivas Basin, east-central Anatolia. The oldest deposition of gypsum, which is of laminated character, occurred in a shallow inner-lagoonal environment or in depressions during Late Eocene regression. Thick gypsum and overlying beds composed of alternating bedded, nodular gypsum and sandstone developed in coastal sabkhas and abandoned channels within a meander-river complex during Oligocene time. The last occurrence of evaporitic units, namely massive and bedded gypsum alternating with sandstones and fossiliferous limestones, resulted from limited marine transgression of an Early Miocene sea along the southern margin of the Sivas …

Tectonic Implications Of Some Cretaceous Pillow Basalts From The North Anatolian Ophiolitic Mélange(Central Anatolia-Turkey) To The Evolution Of Neotethys, Bora Rojay, Kenan M. Yaliniz, Demi̇r Altiner

Turkish Journal of Earth Sciences

The most widespread blocks within the North Anatolian ophiolitic mélange of central Anatolia (Turkey) are ophiolitic fragments, Jurassic-Cretaceous carbonate blocks and pillow basalts. The blocks of pillow basalts have an immobile trace-element geochemistry that is characteristic of ocean-island alkali basalts. An N-MORB-normalized spider diagram shows a distinctive enrichment of most incompatible trace elements and exhibits a far greater range of absolute abundances than N-MORB. Selected incompatible-element contents and ratios of basalts show high Ba/Nb (~8),low Zr/Nb(~5)and low La/Nb(~0.5)relative to N-MORB. The presence of thin-shelled \"Protoglobigerina\" and Cadosina associated with miliolids and epistominid foraminifers indicates that the age of the pink …

Post-Collisional Magmatism On The Northern Margin Of The Taurides And Its Geological Implications: Geology And Petrology Of The Yahyalı-Karamadazı Granitoid, Gonca Gençali̇oğlu Kuşcu, M. Cemal Göncüoğlu, İlkay Kuşcu

Turkish Journal of Earth Sciences

The Karamadazı Granitoid (Yahyalı-Kayseri) is a typical example of bimodal magmatism on the northern margin of the Eastern Tauride belt. The Karamadazı Granitoid intrudes the Palaeozoic-Mesozoic Yahyalı metamorphic rocks and is unconformably overlain by Upper Maastrichtian clastics. It consists of granodiorite-quartz diorite as the main intrusive phase, and includes leucogranites and aplitic dykes in its marginal parts. Samples from the Karamadazı Granitoid are calc-alkaline and calcic in character. The granodiorites are mainly metaluminous, whereas leucogranites and aplites are weakly peraluminous in nature. Plots of major-element oxides against SiO2 indicate a poor fractionation trend for the granodiorites. The leucogranites represent highly …

Geochemistry And Significance Of Mafic Dyke Swarms In The Pozantı-Karsantı Ophiolite (Southern Turkey), Osman Parlak

Turkish Journal of Earth Sciences

The Pozantı-Karsantı ophiolite, which is one of a number of the Late Cretaceous oceanic lithospheric remnants in southern Turkey, is situated in the eastern Tauride belt and consists of three distinct thrust sheets: an ophiolitic melange, a metamorphic sole, and an ophiolitic stratigraphic sequence. These units (except the ophiolitic melange) are intruded by isolated microgabbro-diabase dykes at all structural levels. The dykes from the lower crustal rocks (cumulates) are subalkaline in character and chemically similar to island arc tholeiitic basalts and basaltic andesites. They are enriched in some LIL elements (Rb, Ba, K and Sr) and depleted in HFS elements …

The Geochronology And Geochemistry Of The Bearhead Rhyolite, Jemez Volcanic Field, New Mexico, Leigh Justet

UNLV Theses, Dissertations, Professional Papers, and Capstones

Around 82% of mapped Bearhead Rhyolite (Main Cluster) and Peralta Tuff appears to have been derived from a relatively long-lived (~680 ka), large, shallow (Earth's surface) magma chamber that did not produce a caldera-forming eruption. Although volatile contents were great enough (~ wt.% H₂O), no large-scale explosive eruptions occurred because magma may have been tectonically vented. The lack of systematic chemical variation within the Main Cluster with time during this ~680 ka interval may imply that erupted magmas were physically separated from each other by fault-formed cupolas in the roof of the magma chamber. These results are significant …

Compositional Variations In The Fire Clay Coal Bed Of Eastern Kentucky: Geochemistry, Petrography, Palynology, And Paleoecology, Cortland F. Eble, James C. Hower, William Morton Andrews Jr.

Report of Investigations--KGS

Bench samples of the Fire Clay coal bed, collected from 28 localities in a study area of eight 7.5-minute quadrangles in the Eastern Kentucky Coal Field, were analyzed geochemically, petrographically, and palynologically to determine any spatial or temporal trends among the studied parameters.

At most sample sites the Fire Clay is split by a flint-clay parting of probable volcanic origin. The upper bench of the Fire Clay coal generally is thick, laterally continuous, low in ash yield and sulfur content, has a moderate to high calorific value, and is high in total vitrinite content. In contrast, the lower bench generally …

Petrology And Geochemistry Of Late-Stage Intrusions Of The A-Type, Mid-Proterozoic Pikes Peak Batholith (Central Colorado, Usa): Implications For Petrogenetic Models, Diane R. Smith, J. Noblett, R. A. Wobus, D. Unruh, J Douglass, R. Beane, C. Davis, S. Goldman, G. Kay, B. Gustavson, B. Saltoun, J. Stewart

Earth and Environmental Geosciences Faculty Research

The ~1.08 Ga anorogenic, A-type Pikes Peak batholith (Front Range, central Colorado) is dominated by coarse-grained, biotite ± amphibole syenogranites and minor monzogranites, collectively referred to as Pikes Peak granite (PPG). The batholith is also host to numerous small, late-stage plutons that have been subdivided into two groups (e.g. Wobus, 1976. Studies in Colorado Field Geology, Colorado School of Mines Professional Contributions, Colorado): (1) a sodic series (SiO₂ = ~44–78 wt%; K/Na = 0.32–1.36) composed of gabbro, diabase, syenite/quartz syenite and fayalite and sodic amphibole granite; and (2) a potassic series (SiO₂ = ~70–77 wt%; K/Na = 0.95–2.05), …

A Review Of The Pikes Peak Batholith, Front Range, Central Colorado: A "Type Example" Of A-Type Granitic Magmatism, Diane R. Smith, J. Noblett, R. A. Wobus, D. Unruh, K. R. Chamberlain

Earth and Environmental Geosciences Faculty Research

The N 1.08-Ga Pikes Peak composite batholith of central Colorado is a type example of an Atype granitic system. From the 1970s through the 1990s, details of the field relations, mineralogy, major and trace element compositions, and isotopic geochemistry of Pikes Peak rocks were documented, and they reveal the existence of two chemical groups, a potassic and a sodic series. The potassic series (~64-78 wt % SiO₂) includes the Pikes Peak Granite, which is mostly coarse-grained biotite f hornblende syenogranite and minor monzogranite that dominates the batholith. The potassic series also includes fine- to medium-grained biotite granite found …

Identification Of Past Climate Variability Of The Eastern Pacific Ocean Using Both D13c And D18o Records In Corals From Clipperton Atoll (1994-1906), Lei Ren

Geology Theses and Dissertations

The ENSO (El Nino and the Southern Oscillation) is a fundamental ocean-atmosphere phenomenon that dominates interannual global climate variability. Reconstructing past ENSO events is therefore important for documenting and understanding the past behavior of the global climate system and enabling us to predict future climate change. However, the present understanding of ENSO events has been mainly based on the instrumental record of Pacific climate which provides detailed data only for the past few decades. Recent studies have shown that the stable isotope record in coral skeletons can be used as a valuable indicator of paleoclimatic changes in tropical regions, and …

Geochemical, Petrologic, And Structural Characterization At Multiple Scales Of Deformation Associated With The Punchbowl Fault, Southern California, Steven E. Schulz

All Graduate Theses and Dissertations, Spring 1920 to Summer 2023

Three traverses across the exhumed trace of the Punchbowl fault zone in the Pelona Schist, southern California, were examined at the millimeter to kilometer scales to determine the morphology, deformation mechanisms, and geochemistry of the fault zone in schistose rocks. The Pelona Schist is predominantly a quartz-albite-muscovite-actinolite schist with associated minor metabasalts. The Punchbowl fault zone, which is exhumed 2-4 km, has 44 km of right lateral slip, and is composed of a fault core enveloped by a damaged zone.

The fault core is a region of extreme slip localization that records most fault displacement. Deformation in the fault core …

Petrogenesis Of Mid-Proterozoic Granitic Magmas: Examples From Central And West Texas, Diane R. Smith, C. Barnes, W. Shannon, R. Roback, E. James

Earth and Environmental Geosciences Faculty Research

Circa 1.1 Ga granitic magmatism in Texas was manifested as two compositional groups: (1) the 1.12 Ga Red Bluff granitic suite in west Texas; and (2) 1.12-1.07 Ga granites of the Llano uplift of central Texas. Both suites share some characteristics typical of 'anorogenic' granites (e.g. potassium- and iron-rich bulk compositions, Fe-rich hydrous silicates, emplacement conditions involving low oxygen fugacities and water contents) and exhibit similar isotopic characteristics. However, rock associations, mineral chemistries, and trace element compositions of the two suites are distinct and no single petrogenetic model for the two suites is possible.

The Red Bluff granitic suite includes …

Geochemical Evolution Of A Mid-Miocene Synextensional Volcanic Complex: The Dolan Springs Volcanic Field, Northwestern Arizona, Scott Michael Mcdaniel

UNLV Theses, Dissertations, Professional Papers, and Capstones

The Dolan Springs volcanic field (DSV), of northwestern Arizona, is dominated by andesite and basaltic-andesite flows and breccias, with minor amounts of basalt, rhyolite, and ash-flow tuff. Geochemistry is used here as a tool to evaluate the roles and contributions of the lithospheric and asthenospheric mantles to magmatism related to Miocene extension in the Colorado River extension corridor (CREC). The majority of synextensional volcanic rocks in the DSV are geochemically similar to regional trends, but rare tholeiitic basalts erupted near the end of extension. The tholeiites have trace element signatures similar to ocean island basalt (OIB), but have isotopic values …

The Geology Of The Tuff Of Bridge Spring: Southern Nevada And Northwestern Arizona, Shirley Ann Morikawa

UNLV Theses, Dissertations, Professional Papers, and Capstones

The Tuff of Bridge Spring (TBS) is a regionally-widespread, andesite to rhyolite (59.50 to 74.91 wt. %) ash-flow tuff of mid-Miocene age (ca. 15.2 Ma) that is exposed in the northern Colorado River extensional corridor of southern Nevada and northwestern Arizona. Determination of the areal distribution, geochronology, lithology, geochemistry, and internal stratigraphy of the TBS is important for its establishment as a reliable stratigraphic reference horizon for tectonic reconstructions of the extensional corridor during the middle Miocene. Based on reoccurring patterns of major and trace element variation, the TBS is divided into constant Cr/variable SiO₂ and variable Cr/variable SiO …

An Overview Of Some Of The Large Scale Mechanisms Of Salt Dissolution In Western Canada, Neil Lennart Anderson, Ralph W. Knapp

Geosciences and Geological and Petroleum Engineering Faculty Research & Creative Works

Well log and seismic data indicate that the bedded rock salts of the Devonian Prairie Formation were widely distributed and uniformly deposited in the Lloydminster area, Western Canada; however, as a result of extensive leaching, the distribution of these salts is not now what it once was. The Lloydminster area is now bisected by the north-south trending main dissolutional edge of the Prairie salt. Thick salt (up to 150 m) is preserved to the west of this edge; to the east the salt is mostly absent. The paper presents an overview of the envisioned principal mechanisms of salt dissolution. The …

Trace-Element Modelling Of Melting In Spinel Peridotites, Susanne Petra Vogel

Geology Theses and Dissertations

This study addresses three independent topics related to trace element modeling of spinel peridotites that are suggested by the pioneering work of Johnson et al. (1990) on abyssal harzburgites.
First, the fractional non-modal melting equation derived by Johnson and coworkers (1990) is algebraically modified to present a "one-element/two-phase" model. This model suggests a simple test for estimating mantle heterogeneity in the source rock of spinel lherzolites. This model is applied to data from the literature for samples from Dreiser Weiher, Germany; San Luis Potosi, Mexico; and Western Victoria, Australia.
Second, trace elements in clinopyroxenes of abyssal peridotites and continental spinel …

The Sloan Sag: A Mid-Miocene Volcanotectonic Depression, North-Central Mccullough Mountains, Southern Nevada, Hayden L. Bridwell

UNLV Theses, Dissertations, Professional Papers, and Capstones

In the Hidden Valley area of the north-central McCullough Mountains, southern Nevada, mid-Miocene andesite and dacite domes, flows and pyroclastic units (the Sloan volcanics) partially fill a sag in the underlying Hidden Valley volcanics. The 13.5 km diameter sag formed during and/or after the eruption of the Sloan volcanics. Sagging was accommodated by a combination of movement on the McCullough Wash fault system, and subsidence into evacuated chambers.

Major, trace and rare-earth element geochemistry suggests that the rocks of the Sloan volcanics belong to four groups, each of which were produced by partial melting of chemically distinct sources. With the …

Mineral Paragenesis Of The Granulite Facies In The Lake George Area, New York, Boknam Ree

Geology Theses and Dissertations

The Lake George Area belongs to the southeastern part of the Adirondack Highlands. The rocks of this area show variations in mineral assemblages which are caused by differences in bulk chemical composition. This makes it unsuccessful to use a subdivision of the granulite facies which is suggested by de Waard (1965).
The CFM diagram (Abbott, 1982) is used to show the relationship between composition and paragenesis of the Lake George Area. In this study, a different result has been found in the order of partitioning of Fe between coexisting minerals, namely, garnet>hornblende>biotite>orthopyroxene>clinopyroxene. The hornblende granitic gneiss …

Geochemistry Of Selected Maine Peat Deposits, Stephen A. Norton

Maine Collection

Geochemistry of Selected Maine Peat Deposits

by Steven Allen Norton

Maine Geological Survey, Department of Conservation, Augusta, Maine, 1990.

Contents: Introduction / Purpose of Study / Location of Study Sites / Methods / Acknowledgements / Results / Water Chemistry / Dating of Short Cores / Chemistry of Short Cores / Core Interpretations / Summary / References Cited

Identification Of Endmembers For Magma Mixing In Little Sitkin Volcano, Alaska, Douglas A. Wolf

Geology Theses and Dissertations

Little Sitkin island is an Aleutian calc-alkalic volcanic center that has erupted a suite of lavas ranging from andesite through rhyodacite. Whole-rock chemistry of these lavas indicates contrasting evolutionary processes; major-oxide silica variation diagrams exhibit linear trends that are suggestive of magma-mixing while trace-element trends are largely controlled by accessory-phase fractionation.
Plagioclase, the dominant phenocryst phase in all lavas, commonly occurs in two distinct populations with markedly different compositions and textures. Both normal and reverse zonation is noted in the plagioclase and clinopyroxene of several samples. In addition, clinopyroxene is found as rims on orthopyroxene grains and as cores with …

Genesis Of Marine Terrace Soils, Barbados, West Indies: Evidence From Mineralogy And Geochemistry, Daniel R. Muhs, Russell C. Crittenden, John N. Rosholt, Charles A. Bush, Kathleen C. Stewart

United States Geological Survey: Staff Publications

Well-developed, clay-rich soils dominated by interstratified kaolinite-smectite are found on the uplifted coral reef terraces on the island of Barbados. The reef limestone is unlikely to have been the soil parent material however, because it is 98 per cent CaCO, and geomorphic evidence argues against the 20 m of reef solution required to produce the soils by this process. The mineralogy of the sand, silt, and clay fractions of the soils, and trace element geochemistry, suggest that aeolian materials carried on the trade winds from Africa, volcanic ash from the island of St. Vincent, and quartz from Tertiary bedrock on …

The Continental Crust: Its Composition And Evolution, Stuart Ross Taylor, Scott M. Mclennan

Department of Geosciences Faculty Publications

Graduates in geology, geochemistry and geophysics will find this book a valuable reference text. The book begins by describing the known composition of the present upper crust, then deals with possible compositions for the total crust and the inferred composition of the lower crust. The question of the uniformity of crustal composition throughout geological time is discussed, the rate of growth of the crust and the effects of extraction of the crust on mantle compositions are considered. Finally, the question of early pre-geological crusts on Earth is debated and comparisons are given with crusts on the Moon, Mercury, Mars, Venus …

Some Chemical And Mineralogical Aspects Of Plutonic Rocks From The North Arm Mountain Massif, Bay Of Islands Ophiolite, Newfoundland, Jerry W. Sullivan

Geology Theses and Dissertations

Whole-rock major and trace element compositions of one basalt, one diabase, and 21 rocks from the magmatic-plutonic units of the North Arm Mountain massif, Bay of Islands ophiolite, Newfoundland, were determined. Mineral compositions of a subset of the plutonic rocks were also determined.
The major and trace element compositions of the basalt and diabase are similar to abyssal tholeiites, and this is consistent with the REE data of Malpas (1978) and Suen, et. al. (1979) that suggest the lavas and dikes formed from a depleted or slightly enriched abyssal tholeiitic magma. The alkaline nature of the magma proposed by several …