Earth Sciences Commons^™

Late Holocene Paleoenvironmental Reconstruction In Barbados, Gilman Reno Ouellette

Masters Theses & Specialist Projects

Barbados is the easternmost island in the Caribbean region, and is uniquely situated between the Atlantic Ocean and Caribbean Sea. Being an isolated island with a karstified aquifer providing the majority of the nation’s water resources, Barbados has found itself in water scarce situations in recent years. In order to better understand natural shifts in groundwater recharge (which is determined by shifts in precipitation), longer records of precipitation are needed than are available from modern measurements. This study presents a paleoclimate reconstruction for the late Holocene on Barbados using stable and radiogenic isotope ratios in speleothem lamina as proxies. In …

Cyclic Distributional Model Of The Late Moscovian Fusulinids In The Donets Basin (Ukraine) In Response To Eustatic Sea Level Fluctuations And Its Application In Biostratigraphy And Correlation, Rimma Khodjanyazova

Boise State University Theses and Dissertations

The continuous Pennsylvanian shallow-marine, paralic, siliciclastic succession in the Donets Basin is pivotal for correlation of marine and continental strata in northern Pangaea with coeval shallow-marine mainly carbonate strata in the Moscow Basin, a historical type area of Moscovian Horizons. The details of the history of establishment, lithostratigraphy and current biostratigraphy of Podolskian and Myachkovian Horizons in the Moscow Basin that are not readily available in Western literature are reviewed.

A model of cyclic recurrence (~0.6 —1myr) of three main fusulinid assemblages in the Pennsylvanian siliciclastic-carbonate succession in the Donets Basin is proposed. A Hemifusulina-association (A) indicates the onset …

Assessment And Conceptualization Of Groundwater Flow In The Edwards Aquifer Through The Knippa Gap In Uvalde County, Texas, Jennifer Raye Adkins

Graduate Theses and Dissertations

The Edwards aquifer is one of the major regional karst aquifers in the United States, with an average withdrawal of 950 million liters per day (L/d). This investigation focuses on the connection between the Uvalde pool and the San Antonio pool of the Edwards aquifer, known as the Knippa Gap, west of the San Antonio metropolitan area in Uvalde County. This is a major zone of recharge to the Edwards aquifer and is approximately 6.4 km wide. The Knippa Gap is bounded by northeast trending faults of the Balcones Fault Zone (BFZ) on the north (specifically the Cooks and Trio …

Effects Of Stream Restoration And Storm Events On Stream-Groundwater Interactions, Margaret Zimmer

Earth & Environmental Sciences - Theses

The body of literature on stream-groundwater interactions is rapidly growing, but little is known about the effects of either storm events or in-stream restoration on the interactions between surface water and groundwater. The chapters of this thesis explore two of these questions at the same locality of interest: (1) subsurface geochemical dynamics across a riffle bedform in an unrestored stream during a storm event and subsurface geochemical, and (2) hyporheic exchange dynamics at baseflow conditions pre- and one year post- stream restoration.

The study site was a 30 m stretch of stream that underwent stream restoration through installation of a …

Alluvial Sediment Or Playas: What Is The Dominant Source Of Sand And Silt In Desert Soil Vesicular A Horizons, Southwest Usa, Mark R. Sweeney, Eric V. Mcdonald, Christohper E. Markley

All Faculty Scholarship for the College of the Sciences

Vesicular A (Av) soil horizons form beneath desert pavements from the accretion of aeolian sediment (dust) commonly thought to be derived primarily from desiccating pluvial lakes and playas, with contributions from ephemeral washes and alluvial fans. Particle size distributions of Av horizons are typically bimodal with primary modes of very fine silt and fine sand, suggesting that the horizon matrix is derived from multiple sources. Here we conduct detailed chemical and physical analysis of both Av horizon soil samples and potential sources of aeolian sediment to better constrain the relative contributions of dust associated with the development of Av horizons. …

Epistemology And Synthesis: Instrumental Neutron Activation Analysis And The Caddo Tradition, Robert Z. Selden Jr.

CRHR: Archaeology

The statistical groupings illustrated herein represent the current iteration of Caddo INAA compositional groups based upon the chemical composition of archaeologically-recovered ceramics. For some time, a number of Caddo archaeologists have thought these results to be lacking. This poster symbolizes the first step toward a new interpretation of chemical composition groups, and the initial instancce within which GIS has been employed as an analytical tool.

Influences Of Lithology On Water Quality: A Study Of The Ngam And Mou Watersheds In West Cameroon (Central Africa), E. Kemayou Tchamako, Rv Tsinkou Fotsing, Jp Tchouankoue, Jr Ndam Ngoupayou, B Ngounou Ngatcha, Nancy W. Hinman

Geosciences Faculty Publications

The Ngam and Mou Rivers belong to the river system of the central part of the Cameroon Volcanic Line. The Ngam River watershed comprises 51 Ma old basalts, while the Mou River watershed comprises younger, < 5 Ma pyroclastic basalts. The physico-chemical characteristics of water samples from both watersheds indicated pH between 4.2 and 8.2, and 4.2 to 7.5, and very low mineralization between 11 and 246 μS/cm and 45 to 165 μS/cm, respectively, for the Ngam River and the Mou River. Chemical data showed that waters from old, highly weathered plateau basalts (Ngam River watershed) were dominated by calcium and sodium (signatures of feldpars from syenites and orthogneisses), while waters in the Mou River watershed were dominated by magnesium (signature of olivines and pyroxenes from basalts). Mineralizations in the two watersheds are thus primarily controlled by lithology rather than anthropic activities. These results are promising for identifying potential potable water resources in these areas.

Geochemical Source Components In Seafloor Lavas In The Aleutian Back-Arc, Max Thomas Siegrist

Theses and Dissertations

Whole-rock compositions of seafloor lavas are used to constrain the processes and source characteristics contributing to the formation of geochemically distinctive, primitive magma types located in the Aleutian back-arc. Samples were dredged primarily from small volcanic cones on the seafloor, located between the emergent volcanoes and in the back-arc up to 60 km from the volcanic front. Compositions vary from basalt to dacite, with 48-70 % SiO₂ and 4-13 % MgO. Nearly 30% of the samples are primitive, with Mg/Mg+Fe >0.60. Most primitive samples are basalts, which fall into two groups, based on minor and trace element abundances. Low/med-K …

Genesis Of The Hydrothermal Karaçayır Kaolinite Deposit In Miocene Volcanics And Palaeozoic Metamorphic Rocks Of The Uşak-Güre Basin, Western Turkey, Selahatti̇n Kadi̇r, Hülya Erkoyun

Turkish Journal of Earth Sciences

The Karaçayır kaolinite deposit, situated in the Uşak-Güre basin of western Turkey, is hosted by rhyolite and andesite of the Miocene Dikendere volcanics, and by muscovite schist, glaucophane schist, talc schist and chlorite schist of the Palaeozoic Eşme Formation. The association of kaolinization with silicification and Fe-oxidation, and the presence of pyrite, chalcopyrite and gypsum, suggest that hydrothermal alteration processes in the volcanics and schists were controlled by faults. Thus, prevalent kaolinite is associated with quartz, smectite, illite and opal-CT in the centre of the deposit, with relative increases in smectite, illite, chlorite and Fe (oxyhydr)oxide phases outwards and upwards. …

Petrology, Geochemistry, And Evolution Of The Iron Skarns Along The Northern Contact Of The Eğrigöz Plutonic Complex, Western Anatolia, Turkey, Tolga Oyman, İsmet Özgenç, Murat Tokcaer, Mehmet Akbulut

Turkish Journal of Earth Sciences

The Çatak and Küreci skarn districts are located approximately 10 km NW of Emet (Kütahya) in Western Turkey. The skarn and associated ore formations mainly occur at the contact between intrusive rocks of the Eğrigöz Plutonic Complex (EPC) and calcareous pelitic schists with limestone lenses of the Sarıcasu Formation and meta-carbonate rocks of the Arıkaya Formation. The major, trace, and rare earth element analysis of the igneous rocks indicate that they are high level, subalkaline, calc-alkaline, peraluminous to metaluminous I-type intrusions, generated in a continental arc setting. Three distinct skarn-type mineralization, differing in their host rocks and distance from the …

Water-Rock Interaction And Life, Nancy W. Hinman

Geosciences Faculty Publications

Water-rock interactions play a critical role in the origin, existence, and prospects of life. Minerals are sources of energy and nutrients. Life uses aqueous chemical gradients to access and use minerals. Chemical disequilibrium, therefore, represents one type of biotic signature. Life also controls other types of disequilibrium, including isotopic disequilibrium and morphology. Water is a fundamental contributor to all of these biosignatures, acting as a medium for mass transfer and a reservoir for components. Distinguishing biosignatures from abiotic signatures challenges instrumental capabilities. Finally, the ubiquity and heterogenous distribution of life on Earth challenges the ability to interpret different types of …

Magmatic Processes At The Volcanic Front Of Central Mexican Volcanic Belt: Sierra De Chichinautzin Volcanic Field (Mexico), Fernando Velasco-Tapia, Surendra Pal Verma

Turkish Journal of Earth Sciences

The Sierra de Chichinautzin (SCN) volcanic field is considered one of the key areas to understand the complex petrogenetic processes at the volcanic front of the Mexican Volcanic Belt (MVB). New as well as published major- and trace-element and Sr and Nd isotopic data are used to constrain the magma generation and evolution processes in the SCN. From inverse and direct modelling, combined ^{87}Sr/^{86}Sr and ^{143}Nd/^{144}Nd data, and use of multi-dimensional log-ratio discriminant function based diagrams and other geological and geophysical considerations, we infer that mafic magmas from the SCN were generated by partial melting of continental lithospheric mantle in …

Intrusive History And Petrogenesis Of The Ash Mountain Complex, Sierra Nevada Batholith, California (Usa), Julie E. Holland, Benjamin E. Surpless, Diane R. Smith, S. L. Loewy, J. S. Lackey

Earth and Environmental Geosciences Faculty Research

The Ash Mountain Complex (AMC) in the western Sierra Nevada batholith (SNB; California, USA) is an exposure of six compositionally diverse intrusive lithologies with clear crosscutting relationships that permit a focused investigation of magma source characteristics and the relative roles of petrogenetic processes on the evolution of the system. We use new field observations, zircon U-Pb dates, major and trace element data, and Sr-Nd-Pb isotopic data to develop a model that can be applied to similar SNB intrusive suites. Stage 1 units, emplaced ca. 105 Ma, consist of two gabbros, a gabbrodiorite, and a granite. Stage 2 and stage 3 …

Metamorphic And Geochemical Signatures Of Calc-Silicate Gneisses From The Sawtooth Metamorphic Complex, Idaho, Usa : Implications For Crustal Evolution In Western North America, Isis Fukai

LSU Master's Theses

The Sawtooth Metamorphic Complex (SMC) of central Idaho contains exposures of metasupracrustal rocks that may provide constraints on Precambrian crustal evolution in northwestern United States. Petrographic textures, whole-rock geochemistry, and thermobarmetry of SMC calc-silicate gneisses, collected at high-resolution, record multiple stages of crustal development, including: contiguous deposition of a sandstone-to-shale sequence derived from post-Archean continental sediments, metamorphism during two medium-high-grade thermal events (M1, M2), and two distinct episodes of deformation (D1, D2). Whole-rock concentrations of Cr (23.97-76.43 ± 3.0 ppm), Ni (6.82-33.10 ± 3.5 ppm), Th (2.11-12.04 ± 1.6 ppm), Sc (3.81-11.53 ± 1.6 ppm), and Zr (322-658 ± 3.9 …

Salt Lakes Of The African Rift System: A Valuable Research Opportunity For Insight Into Nature’S Concenrtated Multi-Electrolyte Science, Jyn Philip, Dms Mosha

Tanzania Journal of Science

The Tanzanian rift system salt lakes present significant cultural, ecological, recreational and economical values. Beyond the wealth of minerals, resources of these rift salt lakes include unique wildlife, for instance Lesser Flamingo (Phoenicopterus minor) and Cichlids (Alcolapia spp), which adapted chemically aggressive environments like that of Lake Natron. The general hydrochemical equilibria of these salt lakes is governed by Na+ > K+ >> Ca2+ ~ Mg2+ : (CO32- + HCO3-) > Cl- > SO42-~ F- ionic concentration pattern. Salt accumulation mechanism in these endorheic lakes is considered to base on thermo-mechanical disintegrative stress of the geochemistry sourcing. The rains chemically interact with rift terrains, …

Assessing Eolian Dust Inputs To Soils In Dry Creek Experimental Watershed, Sw Idaho, Brian Jameson Stark

Boise State University Theses and Dissertations

A geochemical investigation of upland soils in the Dry Creek Experimental Watershed (DCEW) near Boise, Idaho was conducted to assess the potential contributions of eolian dust. Major and trace element compositions of soils within the watershed, loess deposits in the adjacent Western Snake River Plain (WSRP), and underlying granodiorite bedrock were evaluated. Multiple lines of evidence suggest a significant contribution of dust in the soils. Plots of Co/Ti, V/Ti and Cr/Ti indicate that the loess and bedrock occupy distinctly different compositional spaces and that the soils are of intermediate composition, suggesting that the soils are a mixture of the loess …

Geochemical Constraints On Groundwater Recharge In The Royal Slope Area, Grant County, Washington, Zoe Danielle Weis

All Master's Theses

Groundwater, the primary source for potable water in the Columbia Plateau, has experienced significant declines over the past 25 years. Groundwater geochemistry and multivariable statistics were employed to identify and characterize the hydrofacies present, constrain recharge sources, and assess mixing of groundwater in the Royal Slope area of the Columbia Plateau. Geochemical analyses for major ions, stable isotopes, and radiogenic isotopes (14C and tritium) for age dating were performed on groundwater samples collected in 2010 from 24 wells in the study area. The results confirmed that the groundwater evolution in the study area follows the typical Columbia River Basalt Group …

Petrogenesis Of The East Fork Member Rhyolites, Valles Caldera, New Mexico, Usa, Carla Eichler

UNLV Theses, Dissertations, Professional Papers, and Capstones

The most recent volcanism in the Valles caldera is represented by the El Cajete Pyroclastic Beds (ECPB), Battleship Rock Ignimbrite (BRI), and Banco Bonito Flow (BBF) as well as the VC-1 rhyolite, which are collectively known as the East Fork Member (EFM) of the Valles Rhyolite. The EFM was erupted at approximately 55 ka and 40 ka after an approximate 460 ka lull in volcanism. Previous studies suggested a mafic intrusion at depth triggered the eruptions. This thesis represents the first detailed study of the EFM.

Crystal assemblages consist of plagioclase, biotite, clinopyroxene, orthopyroxene, amphibole, sanidine, quartz, and oxides. Electron …

Volcanic Evolution Of The Southern Quinn Canyon Range: Implications For Regional Correlation Of Volcanic Units, Christina Emery

UNLV Theses, Dissertations, Professional Papers, and Capstones

The southern Quinn Canyon Range lies in an area of the Great Basin subjected to large-volume Oligocene-Miocene silicic volcanism and smaller volume basaltic volcanism during the Pliocene. Three major ash-flow tuff units were correlated in the southern Quinn Canyon Range (the Pahranagat Tuff, Clifford Spring Tuff, and the Cow Canyon Tuff) with regional units by utilizing U/Pb and 40 Ar/ 39Ar geochronology, geochemical correlation, and field mapping. Isotopic analysis suggests that basalt in the southern Quinn Canyon Range is part of the Death Valley-Pancake Range Basalt Zone and is similar to Reveille Range Episode 1 and 2 basalts. Further comparison …

Northern Thailand Geothermal Resources And Development: A Review And 2012 Update, Fongsaward Suvagondha Singharajwarapan, Spencer H. Wood, Natthaporn Prommakorn, Lara Owens

Geosciences Faculty Publications and Presentations

Northern Thailand has 16 hot spring systems with surface temperatures near or greater than 80°C with potential for binary plant power generation. Presently only Fang system generates power from wells flowing a total of 8.3 1/s of 116°C water to a 300 kW single module Ormat binary plant. Current production is 150-250 KW, which potentially can be increased by constructing new wells and increasing flow by pumping. Of the other 15 systems, 4 are in national parks and not considered for development. Several of the hot springs systems have silica geothermometry >130°C suggesting significant undeveloped resources exist in northern Thailand. …

Geochemical And 40ar/39ar Constraints On The Evolution Of Volcanism In The Woodlark Rift, Papua New Guinea, Joseph Paul Catalano

Earth & Environmental Sciences - Theses

The tectonic mechanisms producing Pliocene to active volcanism in eastern Papua New Guinea (PNG) have been debated for decades . In order to assess mechanisms that produce volcanism in the Woodlark Rift, we evaluate the evolution of volcanism in eastern PNG using 40Ar/39Ar thermochronology and whole rock geochemistry.

Active volcanism in southeastern Papua New Guinea occurs on the Papuan Peninsula (Mt. Lamington, Mt. Victory and Waiwa), in the Woodlark Rift (Dobu Island, SE Goodenough Island, and Western Fergusson Island), and in the Woodlark Basin . In the Woodlark Basin, seafloor spreading is active and decompression melting of the upper mantle …

Investigating The Utility Of Detrital Mineral Microchemistry And Radiogenic Isotope Compositions As Provenance Discriminators, Jack Hietpas

Earth & Environmental Sciences - Dissertations

The provenance of clastic sediments remains one of the key tools for understanding the complex dynamic history of the Earth. Detritus shed from ancient orogens may be the only evidence available for determining the timing, evolution, paleogeography, and existence of tectonic events active over the 4.56 Ga of Earth history. The focus of this dissertation research is to assess the strengths and limitations of existing, as well as novel, tools for determining the provenance of siliciclastic sediments.

The utility of detrital monazite crystallization ages was investigated as a provenance indicator in both modern and ancient sedimentary systems. The results from …

Deciphering The Evolution Of Ore Fluids At The Batu Hijau Copper-~Gold Porphyry Deposit, Sumbawa, Indonesia, Jordan Thomas Armstrong

UNLV Theses, Dissertations, Professional Papers, and Capstones

Fluid inclusions contained within quartz veins from the Batu Hijau Cu-Au porphyry deposit in Indonesia were analyzed to track the evolution of fluid temperature, pressure, and composition during the formation of the deposit to better understand the formation of this and other Cu-Au porphyry deposits in order aid future exploration. A combination of petrography, microthermometry, synchrotron x-ray fluorescence, and laser ablation-inductively coupled plasma-mass spectrometry were used to determine the temperature, pressure, and compositional aspects of the deposit.

Four types of fluid inclusions were recognized at Batu Hijau based on the volume percent of the vapor bubble; inclusions were classified as …

The Behavior Of Zircon During Partial Melting In Anatectic Migmatites: Insights To Metamorphism, Deformation And Tectonism In The Central Santa Fe Range, Northern New Mexico, Michelle Renee Stropky

UNLV Theses, Dissertations, Professional Papers, and Capstones

Three lithologic assemblages exposed in the central Santa Fe Range, northern New Mexico include (1) a septum of Proterozoic low temperature (~700oC, 5.5 kbars), semi-pelitic anatectic migmatites surrounded by (2) deformed megacrystic biotite granite that is intruded by (3) discrete plutons of largely undeformed hornblende biotite tonalite. Metamorphic fabrics in the migmatite record three deformation events (D1 - D3); a composite S1/S2 fabric (D1 and D2) that formed contemporaneous with anatexis and is folded about a southwest plunging map-scale (D3) antiform. The megacrystic granite exhibits a pervasive S1 subsolidus foliation that parallels the S1/S2 fabric in the migmatite and is …

Isotope Geochemistry And Geochronology Of Lavas From The Line Islands Chain, Central Pacific Basin: Insight Into The Origin Of The Line Islands, Lauren Storm

Open Access Theses & Dissertations

Geochemical compositions of melts produced in the Earth's mantle provide key data for understanding Earth's internal structure. Particularly, the compositions of unusually large outpourings of basaltic lavas in large igneous provinces involve substantial source volumes, thereby contributing to our understanding of mantle structure and dynamics. Although the origin of such lavas remains enigmatic, geochemically they may originate from Earth's oldest and deepest mantle reservoir, transported by a mantle plume or by entrainment in passive upwelling beneath a fast spreading center. The Pacific Ocean basin hosts several large igneous provinces that formed near a triple junction of three oceanic plates, and …

Aspects Of Final Disposal Of Radioactive Waste In Germany, Guido Bracke

Turkish Journal of Earth Sciences

Safe disposal of radioactive waste is required in all countries using nuclear power, radioactive materials in medicine and in industry or research. This contribution presents an overview of the strategy of final disposal of radioactive waste and summarizes the procedure and present status in Germany. It is concluded that the safe disposal of radioactive waste is feasible but that the public demand for safety has to be met by applying a stepwise, transparent, and traceable development procedure for a repository in a safety case to obtain regulatory and public approval.

Geochemical And Field Relationships Of Pillow And Dike Units In A Subglacial Pillow Unit Undirhliđar Quarry, Southwest Iceland, Lindsey J. Bowman

Senior Independent Study Theses

Undirhlíðar quarry is located on the Sveifluhals ridge, a Pleistocene subglacial pillow ridge within the NE-SW trending Krísuvík fissure swarm on the Reykjanes peninsula in Southwest Iceland. The walls of Undirhlíðar quarry provide excellent exposures of the internal architecture of the pillow ridge, yielding insights into the sequence of eruptive and intrusive events that construct subglacial ridges. In particular, the south and east walls expose at least 5 different pillow units and 3 dikes. Also seen in the east wall is a black, glassy breccia unit that appears on both the north and south sections of the east wall. Preliminary …

Evaluation Of Pgaa Data For Provenance Of Lithic Artifacts, Otis N. Crandell

Studia UBB Geologia

The objectives of the study were to determine whether Prompt Gamma Activation Analyses (PGAA) could be successfully used to trace the source(s) of various Neolithic artifacts made of microcrystaline quartz. Two macroscopically identical sources of jasper from central and western Romania were analyzed by PGAA along with five Neolithic artifacts from the Limba site (Alba County). Due to the limited number of trace elements, which can be measured by PGAA, this method when used alone might produce inconclusive results for discriminating between jaspers from different sources. The interpretation of the data may be used for general assessments of provenance involving …

Effects Of Sediment Mineralogy To High-Iron Content In The Groundwater Of Rrogozhina Aquifer (Western Albania), Arjan Beqiraj, Enkeleida Beqiraj

Studia UBB Geologia

The groundwater of Rrogozhina aquifer (western Albania) is generally characterized by high iron contents. Its water-bearing medium consists of soft to hard sandstone and conglomerate with intercalations of impermeable clay layers. The groundwater of Rrogozhina aquifer, that extends over a surface of 2100 km² in the pre-Adriatic depression of Albania, occurs under typically artesian conditions. The iron content in ground water ranges from 0.2% up to 2.5%, but most of them fall within the interval 0.5-1.0 %. In groundwater iron occurs as reduced divalent ferrous iron (Fe⁺²) which is conditioned by the lack of water exposure to …

The Formation History Of Layered Chondrules In Acfer-139 (Cr2), Matt Downen

Mahurin Honors College Capstone Experience/Thesis Projects

Chondrules are spherical grains made of silicates and metal that represent some of the oldest materials our solar system. Acfer-139 (CR) is a carbonaceous chondrite with large multilayered chondrules. The multilayered chondrules are composed of a silicate core surrounded by alternating layers of silicates and metals. Serial sectioning was used to analyze the sample in three dimensions. EMPA and LA-ICP-MS were used to create elemental maps of Acfer-139 (CR2) and determine the geochemistry of different layers in each thick section cut. XRCMT was used to construct a 3-D model of a large multilayered chondrule named Ch-1 with concentric layers of …