Earth Sciences Commons^™

A Histological Survey Of A Large, Sub-Adult Tylosaurus Nepaeolicus With Implications On The Validity Of Tylosaurus Kansasensis, Carson Cope

Master's Theses or Doctor of Nursing Practice

Tylosaurus nepaeolicus is a basal, medium-sized tylosaurine mosasaur that lived during the late Coniacian and early Santonian in the Western Interior Seaway. Despite being a well-studied species, there is debate over whether Tylosaurus kansasensis represents the juvenile form of T. nepaeolicus, or if the two species are distinct. Osteohistology can determine organism age at time of death and can be used to help resolve this debate and provide a better understanding of the growth of T. nepaeolicus. Thin-sections were taken from a humerus, rib, and vertebra of a single individual (FHSM VP-2209). All thin-sections show primarily parallel-fibered cortical …

Applying Transfer Learning For Street-Scale Nuisance Flood Forecasting In Coastal-Urban Cities, Binata Roy, Jonathan L. Goodall, Diana Mcspadden, Chetan Kumar, Steven Goldenberg, Yidi Wang, Malachi Schram

VMASC Publications

An important challenge with Machine Learning (ML) is its transferability; i.e., whether a ML model trained on one set of data can be applied to a second set of data without requiring full re-training of the model. Transfer Learning (TL) addresses this challenge by transferring knowledge learned in the source domain (the data it was trained on) to the target domain (a second set of data that is statistically different but related, which the model was not trained on). This study investigates the use of TL for street-scale nuisance flood forecasting by exploring whether a ML model trained for one …

Moderate Heating Renders 7.8-Million-Year-Old Sedimentary Organic Matter Bioavailable, Shuchai Gan, Verena B. Heuer, Frauke Schmidt, Lars Wormer, Faming Wang, Rishi R. Adhikari, Patrick Hatcher, Ann Pearson, Kai-Uwe Hinrichs

Chemistry & Biochemistry Faculty Publications

Marine sediments are a large reservoir of recalcitrant organic matter and host microbes at subsurface depths exceeding 2.4 kilometers and temperatures up to 120°C, yet the mechanisms supplying bioavailable substrates remain unclear. Here, we investigated 7.8-million-year-old sediment from IODP Site C0012 off the Nankai Trough, Japan, through incubations at 20°, 35°, 55°, and 85°C to simulate burial temperatures. Using 3D fluorescence spectroscopy and ultrahigh-resolution mass spectrometry, we tracked changes in dissolved organic matter (DOM). At 35°C, humic-like DOM was released alongside metal ions, exhibiting low bioavailability. At 55°C, abiotic decomposition of humic compounds generated smaller, more bioavailable DOM, promoting fermentation. …

Molecular Characterization Of Humic And Fulvic Acids On Watterlogged And Well-Drained Amazonian Podzols, Amanda M. Tadini, Aleksandar I. Goranov, Stéphane Mounier, Débora M.B.P. Milori, Célia R. Montes, Patrick G. Hatcher

Chemistry & Biochemistry Faculty Publications

The Amazon rainforest is the largest tropical rainforest in the world. Amazonian Podzol soils, characteristic of this region, are known to store substantial amounts of organic carbon in both their surface and deep horizons. Despite decades of research, the molecular-level composition of these soils remains uncharacterized. This study addresses this knowledge gap by employing ultrahigh resolution mass spectrometry, namely, Fourier transform–ion cyclotron resonance–mass spectrometry (FT-ICR-MS), to determine the molecular composition of humic acid (HA) and fulvic acid (FA) fractions from two Amazonian Podzol profiles of varying levels of groundwater exposure (waterlogged vs well-drained). In the waterlogged soil compounds containing nitrogen, …

Deciphering The Chemistry Of Condensed Aromatic "Black" Carbon And Nitrogen In Amazonian Anthrosols, João Vitor Dos Santos, Aleksandar I. Goranov, Laís G. Fregolente, Marcia C. Bisinoti, Zhenhuan Sun, Klaus Schmidt-Rohr, Patrick G. Hatcher

Chemistry & Biochemistry Faculty Publications

Amazonian anthrosols are renowned for their high fertility and dark color, properties primarily attributed to the abundance of condensed aromatic carbon (ConAC) in the soil organic matter. ConAC, commonly referred to as black carbon, play a key role in the stability and nutrient retention of these soils. However, the processes governing the formation of ConAC and its transformation into oxygenated derivatives remain poorly understood. In this study, we used multiple analytical platforms to investigate the chemistry of ConAC-rich humic acids (HA) extracted from Terra Mulata de Indio, a type of Amazonian anthrosol. The results reveal that ConAC are predominantly …

Oxidation Camouflages Terrestrial Organic Matter To Appear Marine-Like, Aleksandar I. Goranov, Susan J. Carter, Ann Pearson, Patrick G. Hatcher

Chemistry & Biochemistry Faculty Publications

The export of terrestrial organic matter (TOM) to the ocean has been traditionally viewed to be minimal or only of significance in near-coastal continental margins. The broadly accepted explanation for the widespread loss of terrestrial lignin biomarkers and apparent disappearance of the <-25‰ stable carbon isotopic signature (δ¹³C) of TOM is that TOM is almost fully degraded before reaching the open ocean. Oceanic carbon (δ¹³C value ≥ -22‰) is therefore thought to be derived primarily from algae. However, an alternative explanation for the different molecular and δ¹³C signatures in terrestrial and marine environments may be that oxidative processing transforms TOM to appear marine-like. To test this hypothesis, we subjected eight TOM samples to a strong oxidation gradient. At carbon losses typical of TOM degradation during transport and sedimentation (above 60%), the differentiators of provenance disappeared, leaving a residue that was marine-like both chemically (aliphatic- and nitrogen-rich) and isotopically (δ¹³C enrichment of 4 to 9‰). This challenges the validity of conventional two-endmember mixing models, suggesting that a much larger fraction than previously estimated of the organic matter found in the ocean may originate from terrestrial sources, impacting global models of carbon cycling and sequestration.

Restoring Rattlesnake Creek: Using Citizen Science To Assess The Ecological And Morphological Impacts Of Dam Removal In Western Montana, Bethany Blakey

Undergraduate Theses, Professional Papers, and Capstone Artifacts

As dam removals increase in frequency across the U.S., most research has focused on the impact of larger dam removals, despite the removal of small dams being much more common. Given the hundreds of small dams in Montana, this research uses citizen science data collected over eight years spanning before and after a 2020 small dam removal in Rattlesnake Creek, Montana, to investigate impact on stream ecology and morphology. We analyzed pebble count grain size distributions and aquatic macroinvertebrate biotic indices from 2017 to 2024 to assess changes in sediment transport and macroinvertebrate population as well as evaluate the efficacy …

Geochemical And Sedimentological Signals Of Bottom Water Oxygen Dynamics From Lake Tanganyika (Zambia), Njahi Mwangala

Theses and Dissertations--Earth and Environmental Sciences

Lake Tanganyika is a large, ancient freshwater body with exceptional biodiversity that is located in the East African Rift System. Lake Tanganyika’s size and longevity make its sedimentary record useful for understanding environmental changes that cross spatial and temporal boundaries. Lake Tanganyika is known to be susceptible to global warming given its tropical location. Over 12 million people living within Lake Tanganyika’s watershed rely on fishing for their income and nutrition. Changes to limnological function driven by climate could therefore have serious implications for human health and biodiversity conservation. This study focuses on using geochemical properties of modern lake bottom …

Late Holocene Paleolimnology Of Lake Tanganyika (East Africa), Leandro Domingos Luz

Theses and Dissertations--Earth and Environmental Sciences

Understanding the long-term responses of ecosystems to climate variability is crucial for predicting and mitigating future changes in the Afrotropics, a region where a significant portion of the population is highly vulnerable to extreme climatic events. Lake Tanganyika, the largest rift lake in East Africa, offers a unique sedimentary archive that can be used to investigate the limnological changes, hydroclimatic shifts, and vegetation dynamics across various timescales. A multi-proxy approach was employed to assess the landscape responses to hydroclimatic fluctuations in the Late Holocene, integrating paleoenvironmental records from radiocarbon-dated sediment cores. This approach involved sedimentology, mineralogy, geochemistry, phytolith analysis, and …

Applications Of Remote Sensing Data To Understanding Geohazards In Wyoming And Kentucky, Meredith Swallom

Theses and Dissertations--Earth and Environmental Sciences

Shallow geohazards such as earthquakes, landslides, and floods profoundly impact communities globally. Constraining susceptibility to these hazards is critical for effective hazard mitigation and building more resilient communities. This dissertation includes multiple studies that leverage remotely sensed datasets to address hazard susceptibility, including: (1) characterizing a potential northern extension of the Teton fault system, (2) deriving a vegetation-based metric to improve landslide susceptibility maps in eastern Kentucky, with potential global implications, and (3) combining numerical modeling, landscape models, and field constraints to understand how anthropogenic factors affect flood severity in southern Appalachian catchments.

In the first study, analysis of new …

Multi-Scale Analysis Of Karst Aquifer Vulnerability To Climate Change And Contamination Processes, Shishir Sarker

Theses and Dissertations--Earth and Environmental Sciences

Karst aquifers represent some of the world’s most productive yet vulnerable groundwater systems, supplying freshwater to approximately 10% of the global population across 15% of Earth’s ice-free land surface. Their distinctive hydrological characteristics— including rapid recharge, preferential flow paths, and limited natural filtration— create unique vulnerabilities to both climate variability and contamination that pose significant challenges for sustainable water resource management. This dissertation presents a comprehensive multi-scale analysis of karst aquifer vulnerability through three interconnected studies that examine climate change impacts, microbial contamination dynamics, and contaminant transport processes across diverse geographic and hydrogeologic settings.

Chapter two investigates climate change impacts …

Monazite Ages In And Fertility Of Crystalline Basement Rocks Of The Eastern Inner Piedmont Province: Potential Source Of Detrital Ree Critical Mineral Resources In The Coastal Plain And Modern Fluvial Systems, Abagale K. Ramsey

Theses and Dissertations--Earth and Environmental Sciences

The southeastern United States has been known for over a century as a potential resource for rare earth elements due to the abundance of monazite in sediments and crystalline basement rocks. However, sedimentary evolution of the monazite from bedrock to placer deposit and the provenance of the monazite remain untested. This study examined samples collected from the basement rocks of the Piedmont terrane in South Carolina and western North Carolina including peraluminous granites, metagranites, mica schists, and biotite gneisses, and heavy-mineral concentrates of first-order streams draining from these rocks, for age comparison and monazite abundance. Monazite grains were analyzed for …

Geochronologic Constraints On The Meso-Neoproterozoic Tectonic Evolution Of Eastern Laurentia: An Investigation Of Sediment Recycling During And After The Grenvillian Orogeny, John M. Clay Iii

Theses and Dissertations--Earth and Environmental Sciences

The Grenvillian orogeny and Midcontinent Rift shaped the Mesoproterozoic basement of eastern Laurentia. Their convergence beneath Kentucky and Ohio formed a foreland basin, preserved as the Middle Run Formation. Detrital zircon U-Pb geochronology constrains deposition to ~1.0 Ga, reflects Grenville unroofing phases, includes Midcontinent Rift input, and minor Ottawan components. This formation constitutes the most proximal preserved segment of the Grenvillian clastic wedge in Laurentia.

Neoproterozoic-Cambrian rifting followed by Cambrian transgression formed the Great Unconformity in eastern Laurentia. Detrital zircon and basement U-Pb ages from Kentucky and the Appalachians constrain sediment provenance and recycling. Kentucky basement shows Eastern Granite-Rhyolite crust …

Chemical Compositions Of Initial And Residual Silicate Source Glasses From Degassing Experiments: Implications For Mars, Natalie Zimmermann

Geosciences Research Data

These files contain supporting data for the JGR manuscript Trace Element Transport and Deposition during Magmatic Degassing: The Effect on Martian Rocks and Fines. They report the chemical compositions (major oxides and volatiles) of initial and residual silicate source glasses from degassing and vapor-transport experiments. Composition (wt%) of major oxides calculated from EMPA (renormalized on a volatile-free basis); Cl and SO2 from EMPA (wt% based on total of oxides+Cl+SO2); wt% H2O calculated from micro-FTIR. Files include the raw EMPA and FTIR data, processing, and calculations used to obtain the chemical compositions presented in Table 5 of the manuscript.

Sem Images And Eds Spectra Of Vapor Deposited Phases, Natalie Zimmermann

Geosciences Research Data

This file contains supplemental data for the JGR manuscript Trace Element Transport and Deposition during Magmatic Degassing: The Effect on Martian Rocks and Fines (Zimmermann et al., in review). It includes SEM images and associated EDS spectra of vapor deposited phases produced in experiments.

Analyzing Acid Rain And Industrial Activity, Jooyoung Jeon

Open Educational Resources

This assignment by Jooyoung Jeon asks students to explore the relationship between acid rain occurrences and industrial activity by analyzing open datasets. It was created as part of a workshop on OER-based Active Learning at John Jay College in 2025.

An Understanding Of The Feeding Ecology Of Teleoceras Fossiger And Teleoceras Aepysoma Using Dental Microwear And Mesowear Analysis, Gabriel S. Goncalves

Master's Theses or Doctor of Nursing Practice

Teleoceras is a genus of rhinocerotids that belongs to the Tribe Teleoceratines and was widespread across North America from the late Early Miocene into the Early Pliocene. This genus was very successful, spreading across the continental United States from Florida and Tennessee to California and Washington state down to central Mexico and Honduras. Teleoceras is characterized by having a large, rounded chest cavity and short limbs with relatively high crowned teeth and lower incisors modified into tusk-like teeth. Initial ecological comparisons were made to the modern hippopotamus based on proportions of the chest cavity and its hypsodont dentition. Stable carbon …

Geochemical Assessment Of Sediment Flux In A Sediment Core From A Tidal Flat In A Tropical Estuary, Olumide Ajulo

Master's Theses or Doctor of Nursing Practice

Sediment flux in estuaries is influenced by both natural processes and anthropogenic activities. Understanding the historical and current trends in sediment flux inputs and geochemical composition are essential for evaluating the estuary’s response to natural and human-induced changes and for developing effective environmental management strategies. The tropical Wouri Estuary in Cameroon receives water and sediment inputs from three main rivers draining urban, industrial, and agricultural areas, as well as different rock terrains. The complex inputs into the estuary can significantly affect sediment flux, consequently impacting the ecosystem. Thereby making an understanding of the temporal variations in sediment inputs in the …

Quantifying Landscape Variability Of Dynamic Soil Properties In The James River Valley, Eastern South Dakota, Sage Reuter-Schmitt

Electronic Theses and Dissertations

Dynamic soil properties (DSP) are a great tool for monitoring land-use change, and they are frequently used as soil health metrics. The NRCS and other soil researchers often use repeating, single-point or nested-point DSP studies to monitor and better understand the effects of land management decisions. While these studies capture the temporal variability of DSPs, they overlook the field-scale spatial variability of DSPs. Soil organic carbon (SOC) provides critical services to the ecosystem and other environments. These traits, as well as its susceptibility to management decisions, make SOC an important soil health indicator and DSP. Measuring SOC is often time …

The Spatial And Temporal Dimensions Of Plant–Soil Feedback In Native Perennial Monocultures, Bret Lang

Electronic Theses and Dissertations

Plant-soil feedbacks (PSFs) describe how plants change their soil environment in ways that can either negatively or positively affect subsequent plant growth. In doing so, they offer an opportunity to connect ecological processes with agricultural practice. My dissertation examines PSFs created by native perennial monocultures, commonly used for native seed production, across time and space, and through soil legacies. Specifically, I focus on how plant species identity shapes both soil nutrient and soil microbial community responses. To address these questions, I conducted field experiments with monocultures of five forb species native to South Dakota and established plots with these species …

Proximal Seismic Tracking Of Pyroclastic Density Currents At Volcán De Fuego, Guatemala, Jacob A. Krier

Dissertations, Master's Theses and Master's Reports

Pyroclastic Density Currents (PDCs) are deadly flows of ash, tephra, gas, and solidified magma which predominantly occur when an ash plume collapses during a volcanic eruption. PDCs are also able to form when large deposits of ash at the summit of a volcano are displaced during an eruption and flow downslope. This is typically the mechanism behind PDCs that occur at Volcán de Fuego such as one that occurred in 2018 killing at least 430 people. The purpose of this paper is to track the propagation of PDCs that occurred at Fuego seismologically in order to better understand how they …

A Seismological Investigation Of Ground Deformation From Meteotsunami And Seiche Activity On Lake Michigan, Bryan Lowney

Dissertations, Master's Theses and Master's Reports

The mechanisms behind the formation and propagation of meteotsunamis and seiches—anomalous water waves generated by meteorological events that share similar spatial, temporal, and behavioral characteristics with seismically-generated tsunamis—are poorly understood. Small-scale ground tilt (microradians-nanoradians) triggered by these anomalous water waves in Lake Michigan is investigated with an array of 10 near-shore (< 100 km) seismometers installed from 2012-2014 by calculating tilt from seismic recordings and comparing it with data from relatively nearby (10s of km) NOAA water level stations in Holland and Ludington, Michigan. After determining an appropriate period band from 15 minutes to four days to isolate these events, we show that potential meteotsunami and seiche activity on eastern Lake Michigan can be deduced from long-term trends (multiple weeks) in tilt and water level time series. Exploratory in nature, the methods and observations presented in this paper serve as an initial step in quantifying the potential for nearshore seismometers to monitor shoreline inundation. Integrating these observations with meteorological data could provide insights into the origins of these hazards by linking them to the specific weather events that generated them. This approach offers a novel method for improving the understanding and potential future mitigation of meteotsunami and seiche impacts in the Great Lakes region.

Geochronology And Geomorphology Of The Brule Spillway Of Glacial Lake Duluth, Madeline Josephine Laaksonen

All Graduate Theses, Dissertations, and Other Capstone Projects

During the Late Pleistocene and Early Holocene, a series of dyssynchronous advances and retreats resulted in the evolution of the Upper St. Croix River Valley. Proglacial lakes forming at the margins of the retreating ice within the Lake Superior Basin and subsequent multiple drainage events through the Brule Spillway have also drastically shaped the landscape. As a result, the Brule Spillway and broader St. Croix River valley presents an important case study to spillover processes occurring in proglacial landscapes and the reorganization of regional drainage networks and creation of a new hydrogeomorphic regime. While prior literature on the Spillway exists, …

Advancing The Characterization Of Geophysical Signals Through Array Processing And Artificial Intelligence, Miro Ronac Giannone

Earth Sciences Theses and Dissertations

In geophysics, seismic and infrasound observations are routinely employed to constrain the nature and origin of events. Seismoacoustics, as a discipline, is built upon the simultaneous detection and integrated analysis of these data types. This joint approach is critical not only for advancing scientific understanding but also for supporting global monitoring efforts in hazard mitigation and nuclear explosion treaty verification. The data analyzed in this dissertation were recorded by array deployments, which consist of multiple sensors arranged in predetermined configurations to enhance signal detection, resolve directionality, and quantify waveform coherence. Leveraging these array recordings, I introduce novel approaches which combine …

The Signal Of Airplane Combustion In Soil At A Small Airport In Ohio, Rachel Engels

Williams Honors College, Honors Research Projects

Leaded gas has been banned for automobile use in the interest of public health since 1996. However, leaded gas is still used for small piston aircraft so the engine can run safely. To investigate potential environmental impacts of leaded gas, 90 soil samples were taken from around a small airport in Ohio. Soil elemental composition was measured by X-ray fluorescence (XRF), soil organic content determined by Loss-on-Ignition (LOI), and soil ferrimagnetic content measured by magnetic susceptibility. There is an unmistakable airplane fuel combustion signal in the soil at the ends of the runway, where aircraft wait to take off on …

Insights On The Cranial Anatomy And Osteohistology Of Cyonosaurus, Alexander Acker

Dissertations

This study investigates the cranial anatomy and life history of the small-bodied gorgonopsian Cyonosaurus. Previous research on gorgonopsians has disproportionately focused on larger members of the clade, leaving smaller forms relatively understudied. This gap has led to several unresolved questions, the most pressing of which concerns gorgonopsian ontogeny. Specifically, it remains unclear whether small-bodied gorgonopsians represent genuinely diminutive adult individuals or juveniles of larger species. The specimen NHCC LB1087 presents an ideal opportunity to address this issue and gain new insights into the biology of small-bodied gorgonopsians. The first chapter focuses on cranial anatomy. Due to the specimen’s preservation, many …

Spatial Analysis Of Heavy Metal Enrichment In A Historic Appalachian Mining Stream, Eric M. Torres

Research and Creativity Symposium

This study examined the spatial distribution of heavy metals along the Levisa Fork and primary tributaries in Buchanan County, VA and Pike County, KY. Buchanan and Pike Counties have a long history of coal mining, a process known to release heavy metals into surrounding waterways. Exposure to certain heavy metals, such as arsenic and lead, has been known to cause health problems, such as cancer and organ damage. The study looked at concentrations in riverine sediments, surface water and groundwater for As, Al, Cr, Cu, Fe, Li, Mg, Mn, Ni, Pb and Zn. Sediment samples were collected, dried and digested …

Assessing Potential For Managed Aquifer Recharge On The Manastash Alluvial Fan: A Geochemical Analysis, Elif A. Myers

All Master's Theses

In south-central Washington, the Yakima River Basin spans 6,100 square miles, encompassing approximately 10% of the state. With a growing population and over 400,000 acres of irrigated cropland, reliable water availability is vital for supporting agricultural irrigation, municipal needs, and aquatic habitats. To ensure water for future use, Managed Aquifer Recharge (MAR), the practice of applying surface water to aquifers for storage or hydrologic system benefit, has been proposed within the Yakima Basin Integrated Plan (YBIP). This research explores the Manastash alluvial fan–located west of Ellensburg, Washington as a potential region for two MAR methods: Shallow Aquifer Recharge (SAR) and …

Hydrogeochemical Characterization Of The Ahtanum Alluvial Fan For Managed Aquifer Recharge, Yakima Basin, Washington, Brook M. Bauer

All Master's Theses

Overallocation of water resources in the Yakima River Basin, central Washington, has prompted investigation into facilitated aquifer recharge to enhance water supply during drought as part of the Yakima Basin Integrated Plan (YBIP). This study evaluates and characterizes the recharge potential of the Ahtanum Creek alluvial fan within the lower Ahtanum Sub-Basin by integrating geologic, hydraulic, and geochemical data.

Four main hydrogeologic units (unconsolidated, semi-consolidated, consolidated basin-fill deposits, and Columbia River Basalt aquifers) were identified from stratigraphic analysis of well logs across seven transects spanning the active fan and abandoned alluvial terrace portions of the alluvial fan study area. Stable …

Zircon Age And Oxidation State Estimates For Plutons Spatially Associated With Mineral Deposits Along The Kettle Detachment Fault In The Orient Quadrangle, Northeastern Washington, Karla Ortega

All Master's Theses

Critical minerals are essential to national security, economic stability, and the transition to clean energy, making them a priority in geologic research and exploration. To better understand the magmatic conditions associated with critical mineral concentration, zircon, a recorder of magmatic history, was analyzed using U-Pb geochronology and trace element geochemistry. The analyses were conducted via LASS-ICP-MS on ten plutonic samples from the Orient quadrangle in northeastern Washington and one sample from the Adams Mountain and Hunter (AMH) quadrangles to constrain the geological processes leading to ore deposit formation, including tungsten (W). This region, cut by the Kettle Detachment fault, is …